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LDA preparation and other lab techniques
LDA preparation and other lab techniques

... 25 g Cr(VI)O3 is dissolved in 25 mL H2SO4 (conc.). Solution is added very slowly to 75 mL H2O that had been cooled to 0oC and is stirring. Workup Formulas for Specific Reagents ...
View/Open
View/Open

Common aldehydes and ketones
Common aldehydes and ketones

MS PowerPoint - Catalysis Eprints database
MS PowerPoint - Catalysis Eprints database

Organolithium reagent
Organolithium reagent

Hydroxyl-Directed Stereoselective Diboration of Alkenes
Hydroxyl-Directed Stereoselective Diboration of Alkenes

... conversion in a reasonable time frame, the reaction was run at a increased substrate concentration (0.5 M). After 12 h at 70 °C, followed by oxidative workup, triol 2 was obtained in 84% yield and as a 17:1 mixture of syn:anti diastereomers. Also in connection to synthesis utility, the ability to ad ...
thermodynamics
thermodynamics

... do not. Explain whether the following properties are extensive or intensive. Mass, internal energy, pressure, heat capacity, molar heat capacity, density, mole fraction, specific heat, temperature and molarity. 60. The lattice enthalpy of an ionic compound is the enthalpy when one mole of an ionic c ...
Chemistry
Chemistry

18.10 CONJUGATE ADDITIONS
18.10 CONJUGATE ADDITIONS

Homo-coupling of terminal alkynes on a noble metal surface
Homo-coupling of terminal alkynes on a noble metal surface

... are rendered with the same colour code. The characteristic outline, the smooth connection via the thinner waist, as well as the slightly brighter benzene rings compared to the waist, all agree well with the simulation. We furthermore analysed the small regular dimer patch depicted in Fig. 3c. With ...
Alkenes
Alkenes

... The repeating unit is enclosed within the brackets. n is a large number, which typically lies in the range 100 to 10,000. The end groups constitute such a small fraction of the polymer molecule that they are usually omitted. Under the right conditions, ethene molecules will add to each other to form ...
The Acid Hydrolysis Mechanism of Acetals Catalyzed
The Acid Hydrolysis Mechanism of Acetals Catalyzed

Acyl Anions Derived from Enol Ethers
Acyl Anions Derived from Enol Ethers

Chapter 11, Kinetics
Chapter 11, Kinetics

... 21. The decomposition of ethane, C2H6, is a first order reaction. It is found that it takes 212 s to decompose 0.00839 M C2H6 to 0.00768 M. a. What is the rate constant for the reaction? Ans. 4.17 x 10-4 s-1 b. What is the rate of decomposition (in M/hr) when [C2H6] = 0.00422 M? Ans. 6.34 x 10-3 M/ ...
12.1 Alcohols: Structure and Physical Properties
12.1 Alcohols: Structure and Physical Properties

ppt
ppt

Development of Novel Catalytic Asymmetric Reactions using
Development of Novel Catalytic Asymmetric Reactions using

ch17
ch17

The characteristic reaction of aromatic rings
The characteristic reaction of aromatic rings

Ch 17 Equilibrium
Ch 17 Equilibrium

... forward reaction is equal to the rate of the reverse reaction. At that point, the concentrations of all species are constant. • Using the collision model: – as the amount of NO2 builds up, there is a chance that two NO2 molecules will collide to form N2O4. – At the beginning of the reaction, there i ...
Salame - The City College of New York
Salame - The City College of New York

... "Makeup exam for INC grades in Chemistry courses will be completed no later than two weeks after the end of classes (tentatively scheduled on January 11). INC may be assigned to students who have a passing grade in the course but who are unable to take the final examination. A passing grade is compu ...
Suggested Problems for Chapter 1
Suggested Problems for Chapter 1

... Please write your name above and on the back of the last page. ...
3.8 Aldehydes and ketones
3.8 Aldehydes and ketones

Nuggets of Knowledge for Chapter 13 – Alcohols (II)
Nuggets of Knowledge for Chapter 13 – Alcohols (II)

Unit #8 - consumerchem
Unit #8 - consumerchem

... Many equations can be balanced by trial and error… However, the following five rules will make balancing quicker. 3) 1. Write the correct formulas: a) For all reactants to the left of the arrow. b) For all products to the right of the arrow. c) If more than one reactant or product, separate them wit ...
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George S. Hammond

George Simms Hammond (May 22, 1921 – October 5, 2005) was a chemist at Iowa State University and the California Institute of Technology. Born and raised in Auburn, Maine, he attended nearby Bates College in Lewiston, Maine where he graduated Magna Cum Laude with a B.S. in Chemistry in 1943. He completed his doctorate at Harvard in 1947, under the mentorship ofPaul D. Bartlett, and a postdoc at UCLA with Saul Winstein in 1948.Among his awards were the Norris Award in 1968, the Priestley Medal in 1976, the National Medal of Science in 1994, and the Othmer Gold Medal in 2003.Hammond was a leader in the field of photochemistry and was widely credited with creating the discipline of organic photochemistry. Hammond's postulate, also known as the Hammond-Leffler postulate, was based on his 1955 publication.
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