Lecture #
... This is a list of topics we will be covering to help you in preparation for exams. Topics from Clayden are indicated clearly by chapter and page numbers where necessary. Topics NOT from Clayden are listed in italics. PLTL topics are in CAPS. This document will be updated throughout the term. The goa ...
... This is a list of topics we will be covering to help you in preparation for exams. Topics from Clayden are indicated clearly by chapter and page numbers where necessary. Topics NOT from Clayden are listed in italics. PLTL topics are in CAPS. This document will be updated throughout the term. The goa ...
Unit 5 Notes
... -18It has such a strong tendency to reduce (note its position on the table - _____________________) that it is able to oxidize a large number of substances (the K+ in KMnO4 is left out as it is a spectator ion). Ex. To find the [Fe2+] in an unknown solution, react it with acidic MnO4- as follows: ...
... -18It has such a strong tendency to reduce (note its position on the table - _____________________) that it is able to oxidize a large number of substances (the K+ in KMnO4 is left out as it is a spectator ion). Ex. To find the [Fe2+] in an unknown solution, react it with acidic MnO4- as follows: ...
Topic 20 Organic Chemistry
... (c) 2-chloropropanoic acid and 2-hydroxypropanoic acid can both show optical activity. Identify the feature which both molecules possess that accounts for this property. When 2-hydroxypropanoic acid is formed from 2-chloropropanoic acid, the product shows no optical activity. Deduce the type of nucl ...
... (c) 2-chloropropanoic acid and 2-hydroxypropanoic acid can both show optical activity. Identify the feature which both molecules possess that accounts for this property. When 2-hydroxypropanoic acid is formed from 2-chloropropanoic acid, the product shows no optical activity. Deduce the type of nucl ...
Chapter 14
... mol/L, it takes __________ s for the concentration to decrease to 0.11 mol/L. A) 0.017 B) 0.68 C) 9.1 D) 40. E) 5.2 Chapter 15 Chemical Equilibrium 1) At equilibrium, __________. A) all chemical reactions have ceased B) the rates of the forward and reverse reactions are equal C) the rate constants o ...
... mol/L, it takes __________ s for the concentration to decrease to 0.11 mol/L. A) 0.017 B) 0.68 C) 9.1 D) 40. E) 5.2 Chapter 15 Chemical Equilibrium 1) At equilibrium, __________. A) all chemical reactions have ceased B) the rates of the forward and reverse reactions are equal C) the rate constants o ...
Chapter16McMurryPPP
... The addition of bromine occurs in two steps In the first step the electrons act as a nucleophile toward Br2 (in a complex with FeBr3) This forms a cationic addition intermediate from benzene and a bromine cation The intermediate is not aromatic and therefore high in energy (see Figure 16.2) ...
... The addition of bromine occurs in two steps In the first step the electrons act as a nucleophile toward Br2 (in a complex with FeBr3) This forms a cationic addition intermediate from benzene and a bromine cation The intermediate is not aromatic and therefore high in energy (see Figure 16.2) ...
Article Summaries
... One of the major downsides to the original Shilov reaction is the fact that it uses platinum consumptively. The goal of this set of experiments was to determine if a non-consumptive pathway was possible. The scorpionate ligands Tp’ (hydrotris(3,5-dimethylpyrazolyl)borate) and Tp (hydridotris(pyrazol ...
... One of the major downsides to the original Shilov reaction is the fact that it uses platinum consumptively. The goal of this set of experiments was to determine if a non-consumptive pathway was possible. The scorpionate ligands Tp’ (hydrotris(3,5-dimethylpyrazolyl)borate) and Tp (hydridotris(pyrazol ...
• Pergamon
... A variety of substituted 2-methylpyrroles underwent allylic oxidation with the perchlorinated metalloporphyrin 2 and iodosylbenzene in 'IFAlCH2CI2 (9:1). Subsequent addition of an a-free pyrrole to the same reaction mixture afforded an efficient one-pot route to dipyrromethanes. ...
... A variety of substituted 2-methylpyrroles underwent allylic oxidation with the perchlorinated metalloporphyrin 2 and iodosylbenzene in 'IFAlCH2CI2 (9:1). Subsequent addition of an a-free pyrrole to the same reaction mixture afforded an efficient one-pot route to dipyrromethanes. ...
Thermochemistry
... book), is the sum of all potential and kinetic energies of the molecules in that system. – Kinetic energies include the motion of atoms and subatomic particles in a system; the temperature of a substance is directly proportional to its total kinetic energy. • The exact value of U is very difficult t ...
... book), is the sum of all potential and kinetic energies of the molecules in that system. – Kinetic energies include the motion of atoms and subatomic particles in a system; the temperature of a substance is directly proportional to its total kinetic energy. • The exact value of U is very difficult t ...
PTT102 Aldehydes and Ketones
... carbonyl compound is the nucleophile and second molecule is electrophile. The new C-C bond connect the α-carbon of one molecule and the carbon that was formerly the carbonyl carbon of the other molecule ...
... carbonyl compound is the nucleophile and second molecule is electrophile. The new C-C bond connect the α-carbon of one molecule and the carbon that was formerly the carbonyl carbon of the other molecule ...
PTT102 Aldehydes and Ketones
... carbonyl compound is the nucleophile and second molecule is electrophile. The new C-C bond connect the α-carbon of one molecule and the carbon that was formerly the carbonyl carbon of the other molecule ...
... carbonyl compound is the nucleophile and second molecule is electrophile. The new C-C bond connect the α-carbon of one molecule and the carbon that was formerly the carbonyl carbon of the other molecule ...
Get Reprint - McMaster Chemistry
... spectroscopic,17,18 kinetic,16,17 and product studies15,16b,17 of the reaction. The suggestion that for addition of methanol and tert-butyl alcohol, the proton transfer step is slower than that for complex formation is consistent with the small but clearly primary deuterium kinetic isotope effects t ...
... spectroscopic,17,18 kinetic,16,17 and product studies15,16b,17 of the reaction. The suggestion that for addition of methanol and tert-butyl alcohol, the proton transfer step is slower than that for complex formation is consistent with the small but clearly primary deuterium kinetic isotope effects t ...
BONUS: Which line in the above graph represents G for the reaction
... 8. The acid HGr has an ionization constant of 1 10–4. A solution is 0.1 M in HGr and 1.0 M in the salt K+Gr–. What is a close approximation of the hydrogen ion concentration? (A) ...
... 8. The acid HGr has an ionization constant of 1 10–4. A solution is 0.1 M in HGr and 1.0 M in the salt K+Gr–. What is a close approximation of the hydrogen ion concentration? (A) ...
Study guide/lecture topics
... This is a list of topics we will be covering to help you in preparation for exams. Topics from Clayden are indicated clearly by chapter and page numbers where necessary. Topics NOT from Clayden are listed in italics. PLTL topics are in CAPS. This document will be updated throughout the term. The goa ...
... This is a list of topics we will be covering to help you in preparation for exams. Topics from Clayden are indicated clearly by chapter and page numbers where necessary. Topics NOT from Clayden are listed in italics. PLTL topics are in CAPS. This document will be updated throughout the term. The goa ...