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Quantum dynamics and isotope effects of hydrogen
Quantum dynamics and isotope effects of hydrogen

review by Alicea
review by Alicea

... fermions’: particles that, unlike electrons and positrons, constitute their own antiparticles.1 The monumental significance of this development required many intervening decades to fully appreciate, and despite being an ‘old’ idea Majorana fermions remain central to diverse problems across modern ph ...
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Solving Problems: A Chemistry Handbook

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Scanning tunneling microscopy and spectroscopy

... (or dry N2 jet for cleaner processing) unto a substrate, typically a highly doped Si substrate capped with 300nm of SiO2, which enables detection under an optical microscope [1] as described in detail in the next section on optical characterization [24-26]. Often one follows up this step with an AFM ...
Perspective: Fifty years of density-functional theory in chemical physics
Perspective: Fifty years of density-functional theory in chemical physics

theories of intramolecular vibrational energy transfer
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Quantum dots on bilayer graphene made on a substrate of boron
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Stoichiometry Chapter 3 CHEMA1301 [Compatibility Mode]

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Stoichiometry - Social Circle City Schools

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Resolution-of-identity approach to Hartree–Fock, hybrid

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Chapter 6: Thermochemistry

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... ____ 11. The 2p orbitals in oxygen have three unpaired electrons. ____________________ ____ 12. The shape of SO2 is trigonal planar. ____________________ ____ 13. The valence p orbitals in phosphorus, P, are half-filled. ____________________ ____ 14. All of the valence electrons in Fe2+ must have th ...
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... graphene [12]. The reason this rather simple phenomenon was not understood earlier, was the lack of interest by the scientific community. In 1937 Landau had theoretically demonstrated that strictly two-dimensional crystals were thermodynamically unstable [13], and thus scientific interest in a clear ...
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X-ray photoelectron spectroscopy



X-ray photoelectron spectroscopy (XPS) is a surface-sensitive quantitative spectroscopic technique that measures the elemental composition at the parts per thousand range, empirical formula, chemical state and electronic state of the elements that exist within a material. XPS spectra are obtained by irradiating a material with a beam of X-rays while simultaneously measuring the kinetic energy and number of electrons that escape from the top 0 to 10 nm of the material being analyzed. XPS requires high vacuum (P ~ 10−8 millibar) or ultra-high vacuum (UHV; P < 10−9 millibar) conditions, although a current area of development is ambient-pressure XPS, in which samples are analyzed at pressures of a few tens of millibar.XPS is a surface chemical analysis technique that can be used to analyze the surface chemistry of a material in its as-received state, or after some treatment, for example: fracturing, cutting or scraping in air or UHV to expose the bulk chemistry, ion beam etching to clean off some or all of the surface contamination (with mild ion etching) or to intentionally expose deeper layers of the sample (with more extensive ion etching) in depth-profiling XPS, exposure to heat to study the changes due to heating, exposure to reactive gases or solutions, exposure to ion beam implant, exposure to ultraviolet light.XPS is also known as ESCA (Electron Spectroscopy for Chemical Analysis), an abbreviation introduced by Kai Siegbahn's research group to emphasize the chemical (rather than merely elemental) information that the technique provides.In principle XPS detects all elements. In practice, using typical laboratory-scale X-ray sources, XPS detects all elements with an atomic number (Z) of 3 (lithium) and above. It cannot easily detect hydrogen (Z = 1) or helium (Z = 2).Detection limits for most of the elements (on a modern instrument) are in the parts per thousand range. Detection limits of parts per million (ppm) are possible, but require special conditions: concentration at top surface or very long collection time (overnight).XPS is routinely used to analyze inorganic compounds, metal alloys, semiconductors, polymers, elements, catalysts, glasses, ceramics, paints, papers, inks, woods, plant parts, make-up, teeth, bones, medical implants, bio-materials, viscous oils, glues, ion-modified materials and many others.XPS is less routinely used to analyze the hydrated forms of some of the above materials by freezing the samples in their hydrated state in an ultra pure environment, and allowing or causing multilayers of ice to sublime away prior to analysis. Such hydrated XPS analysis allows hydrated sample structures, which may be different from vacuum-dehydrated sample structures, to be studied in their more relevant as-used hydrated structure. Many bio-materials such as hydrogels are examples of such samples.
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