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Unit 3: Chemical Kinetics
Unit 3: Chemical Kinetics

... through these two steps: Step 1: 2 NO → N2O2 Step 2: N2O2 + O2 → 2 NO2 Notice that if you add these two reactions together, you end up with the overall reaction: Step 1: 2 NO → N2O2 Step 2: N2O2 + O2 → 2 NO2 Overall: 2 NO(g) + O2 → 2 NO2  The series of steps a reaction undergoes is called the ...
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... drop to zero. In fact, while the quantum yield decreases, it remains in the region 0.1-0.2 (Fig 3.3, Chapter 3). This is because a second, spin forbidden process that forms an O( 1D) atom and a O2(3) molecule occurs. The fate of the electronically excited oxygen atom produced in reactin 2.1 is eith ...
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... • Determining the concentration of an unknown solution. • Use a 2nd solution of known concentration (standard solution) that undergoes a reaction with the unknown solution. • Use the ratios in the balanced equation along with the M = mol/L equation to determine molarity of unknown. ...
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... steps which occur to get to the final product(s).  These various intermediate steps can occur at different rates.  The slowest step is the rate-determining step. ...
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... Where Lt: conductivity of the dissolved HBr gas at any time (t). L∞: conductivity of the dissolved HBr gas at infinite time (t∞). t: time in sec. k: rate constant of reaction in sec-1. (L∞-Lt): concentration of product at any time. The value of k for each temperature was evaluated from the slope of ...
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... 1.1, 0.8, and 0.6 Å for Li, N, and H, respectively, and a plane-wave cutoff energy of 400 eV were employed. For defect calculations, supercells containing 300 atoms were constructed by the 5 ⫻ 5 ⫻ 3 expansion of the Li3N unit cell. k-point sampling was conducted only at the ⌫ point since the test ca ...
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CHAPTER 4 | Solution Chemistry and the Hydrosphere

... Referring to Table 4.5 we see that all hydroxides, except those of Na + (and other alkali metals and NH4+) and those of Ba2+, Ca2+, Sr2+, are insoluble so Cr3+ and Cd2+ form precipitates in a hydroxide solution. Using the rules to write formulas for the salts learned in Chapter 2, cadmium hydroxide ...
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... decreased by 1/2 of its original concentration: Example: 1.0 M “A” ...
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Chemical equilibrium



In a chemical reaction, chemical equilibrium is the state in which both reactants and products are present in concentrations which have no further tendency to change with time. Usually, this state results when the forward reaction proceeds at the same rate as the reverse reaction. The reaction rates of the forward and backward reactions are generally not zero, but equal. Thus, there are no net changes in the concentrations of the reactant(s) and product(s). Such a state is known as dynamic equilibrium.
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