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6 Electronic Structure of Atoms
6 Electronic Structure of Atoms

Lecture 3
Lecture 3

Wilson-Sommerfeld quantization rule revisited
Wilson-Sommerfeld quantization rule revisited

... E in a potential field V that is a function of the coordinates. The momentum p is then well defined as long as E ≥ V {p = ±[2m(E − V)]1/2 }; but here it becomes a function. If we restrict ourselves again to motion in one dimension and wish to extend the applicability of (3) to include such cases of ...
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... • The danger of errors grows exponentially with the size of the quantum system. • Without error-correction techniques, quantum computation would be a pipe dream. • To reach the thresholds for fault-tolerant computation, it is likely that error-protection techniques will first need to be tailored to ...
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... • But this is ALSO a state of a particle … in both arms ...
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... So what is Ĥ? We must figure out how these electrons interact with each other. What effect could one electron have on the other electron, and vice versa? Well, we know that an electron has a magnetic dipole moment that is related to its spin. Magnetic dipole moments come up classically when you hav ...
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Particle in a box



In quantum mechanics, the particle in a box model (also known as the infinite potential well or the infinite square well) describes a particle free to move in a small space surrounded by impenetrable barriers. The model is mainly used as a hypothetical example to illustrate the differences between classical and quantum systems. In classical systems, for example a ball trapped inside a large box, the particle can move at any speed within the box and it is no more likely to be found at one position than another. However, when the well becomes very narrow (on the scale of a few nanometers), quantum effects become important. The particle may only occupy certain positive energy levels. Likewise, it can never have zero energy, meaning that the particle can never ""sit still"". Additionally, it is more likely to be found at certain positions than at others, depending on its energy level. The particle may never be detected at certain positions, known as spatial nodes.The particle in a box model provides one of the very few problems in quantum mechanics which can be solved analytically, without approximations. This means that the observable properties of the particle (such as its energy and position) are related to the mass of the particle and the width of the well by simple mathematical expressions. Due to its simplicity, the model allows insight into quantum effects without the need for complicated mathematics. It is one of the first quantum mechanics problems taught in undergraduate physics courses, and it is commonly used as an approximation for more complicated quantum systems.
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