Download 241outline

Chem 241
Schedule F04
updated June 27, 2017
227 Fulton, 10:30 MWF
21.
#
Date
1.
2.
3.
4.
5.
8/23
8/25
8/27
8/30
9/1
6.
9/3
7.
8.
9.
10.
11.
12.
9/6
9/8
9/10
9/13
9/15
9/17
9/20
13.
9/22
14.
15.
16.
9/24
9/27
9/29
10/1
10/4
10/6
10/8
17.
18.
19.
Topic (A&P Chapter)-#of Lect
Properties of Gases (1)-5
I. Equations of State
(Phia, Chusuei)
II. Intermolecular Forces
III. Mixtures
First Law of Thermodynamics
(2,3)-7
I. Heat and Work
II. First Law
Labor Day, no class
“
(PS #1 due)
III. Enthalpy (quiz #1, Durr)
IV. Enthalpy Changes
V. State Functions
VI. Enthalpy Revisted
“
Second Law of Thermo-dynamics
(4, 5)-8
I. Statements and Implications
II. Entropy (PS #2 due)
“
Exam #1 (100 pts)
“ …..
Student Council Free Day
“ (examples)
III. Third Law, IV. Free Energy
IV. Some Useful Equations
22.
23.
24.
25.
26.
27.
28.
29.
30.
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
41.
42.
43.
44.
45.
10/13 VIII. Rubber Elasticity
Equilibrium in Pure Substances
(6)-4
10/15 I. Phase Diagrams II. Dependence
on Conditions
10/18 III. Boundries, (PS #3 due)
10/20 " Quiz#2 (30 pts),
10/22 IV. Surface Behavior
10/25
Mixtures (7)-8
10/27 I. Important Quantities
10/29 II. Thermodymanic of Mixing
11/30 Exam #2 (100 pts)
11/3 III. Solutions
11/5
(inc. colligative properties)
11/8 IV. Activities
11/10 (Raoult & Henry)
11/12 V. Consequences of G-D Eq.
11/15 VI. Real Solutions
Phase Diagrams (8)
11/17 I. Gibbs Phase Rule (PS #4 due)
11/19 II. 2-Component Systems T-Fixed
11/22 Quiz 3, then no class
11/24 Thanksgiving Vacation
11/26 Thanksgiving Vacation
11/29 III. 2-Component Systems P-Fixed
12/1
" (start next)
Chemical Equilibria(9-9.3)
12/3 I. Free Energy and Eq. Consts.
12/6 II. Effect of Temperature
12/8 III. Eq. Consts at High Pressure
12/9 IV. Extent of Reaction
12/14 Final Exam10:30 (#3), (100 pts)
20
10/11 VII. Real Gases
Office Hours: 3:00 -4:00 M, W, F.
PS #1:
PS#2:
PS#3:
PS #4
PS #5
PS #6
Hand in (due 9/9): E.119b, P1.1, 1.8, 1.15, 1.38, Don't hand in: E1.28, P1.2, 1.3, 1.13, 1.23
Hand in: (due 9/25) E2.4b, E2.26b, E2.44b, E3.10b, P3.5, E3.29. Don't hand in: E2.13, E2.29,
E3.13, P3.2, P3.9, P3.11 plus any others you may want.
Hand in: P4.1, P4.6, P4.11, P4.18, P4.30, P5.26, P5.27. Don't hand in E4.4, E4.14, E4.19,
P5.21, P5.22 plus any others you may want.
Hand in: E6.2b, P6.2, P6.18, F6.1, F6.2. Don't hand in: E612b, E6.13b, P6.10, P6.16, P6.21
plus any others you may want.
Hand in: E7.6b, E7.13b, E7.16b, P7.6, P7.15. Don't hand in: E7.10b, E7.13a, P7.9, P7.10, P7.12
plus any others you may want.
Hand inP8.9, P8.15, E9.6b, E9.11b, P9.15 Don't hand in: none, plus any others you may want.
Grading: Exams (3 x 100 pts) + Quizzes (3 x 30 pts) + Homework (6 x 5 pts)
Schedule: Chapt 0-3(1+4+7+1), Chapt 4-6(8+4+1), Chapt 7-9.3 (8+4+4+1); total (41).
Ye Olde Physical Chemistry
Chemistry 241
Fall 2004, MWF 10:00-10:50, 125 Schrenk Hall
Frank D. Blum (138 Schrenk)
[email protected]
Tentative Outline
Topic (Atkins and de Paula Chapters)
We will basically cover Part 1 of this text.
4. Phase Equilibria and Transitions (6,8,9)
1. Properties of Gases (1)
5. Mixtures and Solutions(7)
2. First Law of Thermodynamics (2,3)
6. Electrochemistry (10)
3. Second Law of Thermodynamics (4,5)
Text: Primary: Physical Chemistry, 7th ed., P. Atkins and de Paula, Freeman, 2002 (earlier versions of this
text will work, but make sure you do the right problems.) Don't forget to look at the appendices.
Grading/Exams: Grades will be based on 3 (probably) equally weighted exams, plus home work
assignments. We will decide, in class, on how much weight will be given to home work
assignments. Exams will be announced prior to when they will be given. You will be allowed
to bring a calculator and one note card (w/ equations, etc.) to class for the exam. The material
covered by the exam will include the text and lecture.
Advice:
Try to work the problems assigned by yourself. If you don't get the right answer, discuss the
approaches with your classmates.
Office Hours: Generally, I will try to be available from 3-4 M, T, Th. I will also be available by
appointment (afternoons preferred). I have set up a discussion list on e-mail. It is called
[email protected]. If you send questions here, the whole class will benefit from the answers
(I hope).
Web Page: http://web.umr.edu/~fblum/fdbinfo/c243fs03.html