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1. SCHOOL SECTION School of Elements 1 MT SCIENCE & TECHNOLOGY Q.I 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. *25. *26. *27. *28. *29. *30. (A) Fill in the blanks : The horizontal rows in the periodic table are ....................... . From left to right, the atomic size of an atom ....................... . There are ....................... periods in the periodic table.. An element is placed in group II A, so the number of valence electrons is ....................... . An element is placed in 2nd period, so it has ....................... shells. Noble gases have valency as ....................... . Metals have a tendency to ....................... electrons.. Valency across a period ....................... . Valency down the group ....................... . Elements of group I A and II A are ....................... . An atom is said to be a non-metal if it ....................... electrons. ....................... is the only element in duplet state. The electronic configuration of Neon is ....................... . Sodium is a ....................... . Silicon and antimony are ....................... . Group 1A is called ....................... . Group II A is called as ....................... . Group VII A is called as ....................... . The chemical properties down the group ....................... . First period contains ....................... elements. Moseley arranged elements according to ....................... . The non-metals are present in ....................... . The number of shells down the group ....................... . The transition character of elements is from ....................... to ....................... . The formula of chloride of metal is MCl 2 , the metal M belongs to ....................... group. ....................... group contains all gases at room temperature. The arrangement of elements in a group of three is called ....................... . The law used by Newlands to arrange elements is called ....................... . Elements showing properties of both metals and non-metals are called as ....................... . The element eka-Aluminium is called as ....................... . Answers : 1. periods 3. 7 5. 2 7. donate 9. ramains the same 11. gains or shares 13. 2, 8 15. metalloids 17. alkaline earth metals 19. remain the same 21. Atomic number 23. increases 25. II A 27. triad 29. metalloids 2 EDUCARE LTD. 2. 4. 6. 8. 10. 12. 14. 16. 18. 20. 22. 24. 26. 28. 30. decreases 2 0 varies gradually metals Helium metal alkali metals halogens 2 upper right hand corner metallic to Non-metallic 18 or zero Newlands Law of octaves gallium. SCHOOL SECTION MT SCIENCE & TECHNOLOGY EDUCARE LTD. Q.I 1. (i) (ii) (iii) Ans. (B) Match the following : Column I Mendeleev Dobereiner Newlands (i - b), (ii - c), (iii - a). 2. (i) (ii) (iii) (iv) Ans. Column I Alkali metals Alkaline earth metals Halogens Noble gases (i - b), (ii - a), (iii - d), (iv - c). 3. (i) (ii) (iii) (iv) Ans. (a) (b) (c) Column II Octaves Periodic law Triads (a) (b) (c) (d) Column II II A group I A group zero group VII A group Column I Helium Chlorine Hydrogen Magnesium (i - d), (ii - a), (iii - c), (iv - b). (a) (b) (c) (d) Column II Halogen Alkaline earth metal H Noble gas 4. *(i) (ii) (iii) (iv) Ans. Column I Sodium Sulphur Manganese Cerium (i - c), (ii - a), (iii - d), (iv - b). (a) (b) (c) (d) Column II Non-metal Lanthanide Metal Transition metal 5. (i) (ii) (iii) Ans. Column I Mendeleev Dobereiner Newlands (i - a), (ii - b), (iii - c). (a) (b) (c) Column II Russian scientist German scientist Englishman Q.I 1. Ans. 2. Ans. 3. Ans. 4. Ans. 5. Ans. 6. Ans. (C) State whether the following statements are true or false. If false write the corrected statement : Atomic number is the number of protons or electrons in the nucleus. True. Fourth and fifth periods are longest periods. False. Fourth and fifth periods are long periods, 6th period is the longest period Newlands arranged elements based on their atomic number. False. Newlands arranged elements based on their atomic mass. Mendeleev was the first scientist to create a periodic table for the elements. True. Mendeleev arranged 63 elements in the periodic table. True. Eka boron is known as Germanium. False. Eka boron is known as Scandium SCHOOL SECTION 3 SCIENCE & TECHNOLOGY 7. Ans. 8. Ans. MT EDUCARE LTD. Ans. 17. Ans. 18. Ans. Tellurium, Polonium are metalloids. True. Isotopes have same atomic masses. False. Isotopes are atoms of the same element having same atomic number but different atomic masses. Isotopes have similar chemical properties. True. La stands for Lutetium. False. La stands for Lanthanum. s-block includes I A, II A and hydrogen. True. d-block elements are called normal elements. False. d-block elements are called transition elements. f-block elements are metalloids. False. f-block elements are metals. Metalloids are also called as semi-metals. True. Bordering the zig-zag line are elements called as metalloids. True. In an atom of an element, extra-nuclear electrons take part in the chemical. reaction. True. The number of shells increases down the group. True. Helium is the only element in octet state. False. Helium is the only element in duplet state. Q.I 1. Ans. 2. Ans. 3. Ans. (D) Find the odd man out : Carbon, Nitrogen, Oxygen, Sulphur. Sulphur. It is in third period while the rest are in second period. Hydrogen, Helium, Neon, Argon. Hydrogen. The rest are noble gases. Lithium, Sodium, Iodine, Potassium. Iodine as a halogen and rest belong to group 1A. 9. Ans. 10. Ans. 11. Ans. 12. Ans. 13. Ans. 14. Ans. 15. Ans. 16. 4. Ans. *5. Ans. 6. Ans. 7. Ans. 4 MEMORISE : Fluorine and Chlorine are gases, bromine is a liquid, iodine and astatine – Extra Information. are solids. Boron, Silicon, Arsenic, Sodium. Sodium belongs to group IA and rest are metalloids. Li, Sr, K, Na. Sr is an element of a different triad whereas Li, Na, K are elements of same triad. B and Al, O and S, Be and Mg, N and S. N and S. It does not show similarities in properties according to Newlands law of octaves whereas the others show similarities. Electrons, protons, neutrons, lanthanides. Lanthanides. It is a series and rest all make up an atom. MEMORISE : Electrons, Protons and neutrons are called as sub-atomic or elementary – Extra Information. particles. SCHOOL SECTION MT Q.I 1. Ans. 2. Ans. 3. Ans. 4. Ans. 5. Ans. 6. Ans. 7. Ans. Q.I SCIENCE & TECHNOLOGY EDUCARE LTD. (E) Write the correlated terms : Newlands : Octaves :: ....................... : Triads. Dobereiner. Ca, Sr, Ba : Triad II :: ....................... Triad I. Li, Na, K. Fluorine : ....................... :: Chlorine : Third period. Second period. Neon : Inert element :: Bromine : ....................... . Halogen/normal element. Fifth period : 18 elements :: Sixth period : ....................... . 32 elements. Alkali metals : Monovalent :: Alkaline earth metal : ....................... . Divalent. Tellurium : ....................... :: Radium : Metal. Metalloid. (F) Complete the following table : Element Symbol Group Sodium Lithium Fluorine Barium Calcium ........... ........... ........... ........... ........... IA IA VII A II A II A Ans. Element Symbol Group Na Li F Ba Ca IA IA VII A II A II A Sodium Lithium Fluorine Barium Calcium Q.I 1. 2. 3. 4. 5. 6. 7. 8. Molecular formula of Valency compound with chlorine NaCl ........... ........... 1 ClF ........... BaCl 2 2 CaCl 2 2 Molecular formula of Valency compound with chlorine NaCl 1 LiCl 1 ClF 1 BaCl 2 2 CaCl 2 2 MEMORISE : To get the molecular formula of a compound: Eg: Sodium chloride Symbol Na Cl Valency 1 1 Cl 1 Criss cross Na 1 i.e. NaCl (G) Give two names of the following Member of 1st period : nd : Member of 2 period Alkali metals : Alkaline earth metals : : Member of 3rd period Elements of zero group : Elements of halogen family : Metalloid : SCHOOL SECTION – Extra Information. : Hydrogen, Helium Carbon, Nitrogen. Lithium, Sodium Magnesium, Calcium Phosphorus, Sulphur Neon, Argon Fluorine, Chlorine Silicon, Antimony 5 SCIENCE & TECHNOLOGY Q.II 1. Ans. 2. Ans. 3. Ans. 4. Ans. Q.II 1. Ans. 2. Ans. 3. Ans. 4. Ans. 5. Ans. 6. Ans. 7. Ans. 8. Ans. 9. Ans. MT EDUCARE LTD. (A) State the following : Dobereiner’s triads law. He arranged chemically similar elements in the increasing order of their atomic weights in a group of three which is known as “Dobereiner’s triads”. In a Triad, atomic mass of the middle element is approximately equal to the mean of atomic masses of other two elements in that triad. Newlands law of octaves. When the elements are arranged in increasing order of their atomic masses, the properties of every eighth element are similar to the first, as in the octave of music. Mendeleev’s periodic law. The physical and chemical properties of elements are periodic function of their atomic masses. Modern periodic law. The physical and chemical properties of elements are periodic function of their atomic numbers. (B) Define the following : Groups. Vertical column of elements in a periodic table are called as a groups. Periods. Horizontal row of elements in a periodic table are called as a periods. Inert gas elements. The elements in which all the shells including the outermost shell is completely filled are called as inert gas elements. Normal elements. The elements in which only the last shell is incompletely filled are called as normal elements. Transition elements. The elements in which last two shells are incompletely filled are called transition elements. Inner transition elements. The elements in which last three shells are incompletely filled are called inner transition elements. Metalloids. Elements showing properties of both metals and non-metals are called as metalloids Lanthanides. 14 elements (post lanthanum) with atomic numbers 58 to 71 (Ce to Lu) are called lanthanides. Actinides. 14 elements (post actinium) with atomic numbers 90 to 103 (Th to Lr) are called actinides. Q.III (A) Give scientific reasons : 1. Group VII A elements are strong non-metals and group I A elements are strong metals. Ans. 1. Non-metals are electron acceptors and metals are electron donors. The elements of group VII A have seven electrons in their outermost shell. So, they have a strong tendency to accept one electron and form a negatively charged ion (anion) with octet state. 2. The elements of group I A have one electron in their outermost shell. So, they have a strong tendency to donate one electron and form positively charged ion (cation) with octet state or duplet state. 6 SCHOOL SECTION MT 2. Ans. 3. Ans. 4. Ans. 5. Ans. 6. Ans. 7. Ans. EDUCARE LTD. SCIENCE & TECHNOLOGY MEMORISE : Electropositivity is the property of an atom to donate electrons when combined in a compound. Electronegativity is the property of an atom to accept electrons when combined in a compound. – Extra Information. Metallic character decreases across a period. 1. Metals have a tendency to lose electrons and are said to be electro positive. 2. As we move across a period, the atomic number and the nuclear charge increases. So, the atomic size decreases. 3. As a result, electrons are more tightly bound to the nucleus and more amount of energy is needed to remove an electron from the outermost shell. So, metallic character decreases across the period. MEMORISE : Nuclear charge is the positive charge on the nucleus of an atom. – Extra Information. Non-metallic character increases across a period. 1. Non-metals have a tendency to gain electrons. 2. As we move across a period, the atomic number and the nuclear charge increases. So, the atomic size decreases. 3. As a result, the electron that is gained is pulled more strongly. So, non-metallic character increases across the period. Atomic size decreases across a period. 1. Atomic size is defined as the distance between the centre of the nucleus of an atom to its outermost shell. 2. Across a period, the nuclear charge increases. Nuclear charge is the positive charge on the nucleus of an atom. Also, across the period electrons are added to the same shell. So, electrons experience greater pull from the nucleus. 3. Therefore, atomic size decreases across a period. Atomic size increases down the group. 1. Atomic size is defined as the distance between the centre of the nucleus of an atom to its outermost shell. 2. As we go down the group, the number of shells increases and so the nuclear distance from valence electrons increases. 3. The nuclear charge also increases but increase in number of shells dominates over increase in nuclear charge. So, atomic size increases down the group. Valency varies gradually across a period. 1. In the modern periodic table, the elements are arranged in increasing order of atomic number (Z). 2. Atomic number is related to the electronic configuration. 3. As the atomic number increases, the number of valence electrons increases. The first element has one electron in its outermost shell while the last element in a period has either completed duplet or octet. 4. So, valency varies gradually across a period. Elements in a particular group have similar chemical properties. OR Elements in the same group show same valency 1. Position of an element in the periodic table is related to its electronic configuration. The elements of a particular group have the same number of electrons in the outermost shell (i.e. valence electrons). 2. Chemical properties of an element depends on the number of electrons in the valence shell. Eg, Chemical properties of sodium and potassium in group I A are similar. 3. Hence, elements in a particular group have similar chemical properties. SCHOOL SECTION 7 SCIENCE & TECHNOLOGY 8. Ans. 9. Ans. MT EDUCARE LTD. The family of noble gases is called as zero group. 1. Zero group or group 18 is a family of inert gases also called as noble gases or rare gases. 2. In their atoms, all the electronic shells including the outermost shell are completely filled. They have stable electronic configuration with complete duplet (Helium) or complete octet (Neon, Argon etc). 3. So, atoms do not gain, lose or share electrons and hence have zero valency. 4. Hence, the family of noble gases is called as zero group. MEMORISE : Noble gases have a stable electronic configuration, they are in duplet or octet state. So, they don't lose, gain, share electrons. So, inert gases exist in their free atomic state. – Extra Information. Chlorine is placed in VII A group in the modern periodic table. 1. Number of valence electrons is equal to the group number. 2. Chlorine has atomic number 17 and hence its electronic configuration is 2, 8, 7. 3. There are 7 electrons in the valence shell. 4. Hence, Chlorine is placed in VII A group in the modern periodic table. Q.III (B) Answer the following questions in short : 1. From the list of elements given below, make three triads and name the family of each triad. List : Cl, Li, Ca, Br, Na, Sr, I, K, Ba. Ans. Alkali metal triad : Li Na K. Alkaline earth metal : Ca, Sr, Ba. Halogens triad : Cl, Br, I. 2. The elements A and B obey the law of octaves. How many elements are there between A and B? Ans. There are 6 elements between A and B. 3. What was the basis of classification of elements in Mendeleev's periodic table? Ans. Basis of Mendeleev's periodic table : 1. Similarities in the chemical properties of the elements. 2. Increasing order of atomic mass of the elements. 4. What are transition elements ? Which amongst the following are transition elements ? K, Mn, Ca, Cr, Cu, Cs, Fe Ans. 1. The elements in which last two shells are incompletely filled are called transition elements. 2. The elements Mn, Cr, Cu, Fe are transition elements. 5. Name alkali metals, to which group do they belong? Ans. 1. The alkali metals are Lithium, Sodium, Potassium, Rubidium, Cesium, Francium. 2. These elements belong to group I A. 6. Name alkaline earth metals, to which group do they belong? Ans. 1. The alkaline earth metals are Beryllium, Magnesium, Calcium, Strontium, Barium, Radium. 2. These elements belong to group II A. 8 SCHOOL SECTION MT 7. Ans. 8. Ans. 9. Ans. 10. Ans 11. Ans. Ans. Ans. Ans. Ans. 12. Ans. 13. Ans. 14. Ans. 15. Ans. EDUCARE LTD. SCIENCE & TECHNOLOGY Name halogens, to which group do they belong? 1. The halogens are Fluorine, Chlorine, Bromine, Iodine, Astatine. 2. These elements belong to group VII A. Oxygen (Z = 8) and sulphur (Z = 16) belong to the same group of the periodic table. On the basis of electronic configuration, name the group and period to which they belong. 1. Group number indicates number of valence electrons. 2. Period number indicates no of shells. 3. The electronic configuration of oxygen is 2, 6. So, it belongs to Group VI A and 2nd period. 4. The electronic configuration of sulphur is 2, 8, 6. So, it belongs to Group VI A and 3rd period. Name the noble gases, to which group do they belong? 1. The noble gases are Helium, Neon, Argon, Krypton, Xenon, Radon 2. These elements belong to group 18. What are the names of the periods and how many elements do they have ? 1. First period is the shortest period with 2 elements. 2. Second, Third period are short periods with 8 elements. 3. Fourth, Fifth period are long periods with 18 elements. 4. Sixth period is the longest period with 32 elements. 5. Seventh period is the incomplete period with 30 elements. An element is in the second period and group VI A of the periodic table. 1. Is it metal or non-metal. Non-metal. 2. Number of valence electrons. 6. 3. Electronic configuration. 2, 6. 4. Name of the element. Oxygen. 5. Formula of compound with sodium. Na 2O. Label each of the following as either metal, metalloid or a non-metal : K, Ni, As, Br, S, Al. Metals : K, Ni, Al Non-metals : Br, S Metalloid : As. Which are the three elements having single electron in the outermost shell? Lithium, Sodium, Potassium. Which are the three elements with filled outermost shell? Helium, Neon, Argon. Which are the three elements having seven electrons in the valence shell? Chlorine, Bromine, Iodine. SCHOOL SECTION 9 MT SCIENCE & TECHNOLOGY EDUCARE LTD. Q.IV 1. Ans. Distinguish between : Periods and Groups. Periods Groups 1. Modern periodic table has 7 1. Modern periodic table has 18 horizontal rows called as periods. vertical columns of elements called groups. 2. The number of shells present in 2. The number of electrons present the atom of an element in the outermost shell of an atom determines the period number. of the element determines the group number. 3. Elements show gradual variation 3. Elements belonging to a in chemical properties along a particular group show strong period. Neighbouring elements resemblance in their chemical show some similarities but nonproperties like valency, formulae neighbouring elements show of compounds and chemical appreciable dissimilarity in their reactions. properties. 2. Ans. Alkali metals and Alkaline earth metals. Q.V 1. Ans. Answer the following in detail : Explain Dobereiner’s law of triads giving examples. 1. He arranged chemically similar elements in the increasing order of their atomic masses in a group of three which is known as “Dobereiner’s Triads”. In a triad atomic mass of middle element is approximately equal to the mean of atomic masses of other two elements in that Triad. Eg.: Lithium (Li), Sodium (Na), Potassium (K) form a triad as they show similar chemical properties. The atomic weights are 6.9, 23, 39 respectively. 2. According to Dobereiner’s law of triads, 6.9 39 45.9 = = 22.95 ~ 23 = Atomic weight of sodium. 2 2 Thus, the atomic weight of sodium (23) is the average of the atomic weights of lithium (7) and potassium (39). The other examples are: Alkali metals Alkaline earth metals 1. In the modern periodic table, IA 1. In the modern periodic table, IIA group elements including group elements including lithium, sodium, potassium, beryllium, magnesium, calcium, rubidium, caesium and strontium, barium, radioactive radioactive francium are alkali radium are alkaline earth metals. metals. 2. Atoms of these elements have 2. Atoms of these elements have one electron in the valence shell. two electrons in their valence shell. 3. They are monovalent. 3. They are divalent. 4. Their oxides and hydroxides 4. Their oxides and hydroxides dissolve readily in water. dissolve slightly in water. Elements Calcium Strontium Barium 10 Atomic (Ca) (Sr) (Ba) Mass 40.1 87.6 137.3 SCHOOL SECTION MT 2. Ans. SCIENCE & TECHNOLOGY EDUCARE LTD. Elements Chlorine Bromine Iodine Atomic (Cl) (Br) (I) Mass 35.5 79.9 126.9 Elements Sulphur Selenium Tellurium Atomic (S) (Se) (Te) Mass 32 79 128 Explain the limitations of Dobereiner's law of triads. 1. All the elements known at that time could not be classified as triads (i.e. law was applicable to a few elements only. 2. It does not take into account the isotopes of elements. 3. It cannot be applied to other chemically similar elements. Eg. : Triads Elements Atomic weights Mean of atomic weights 3. Ans. 4. Ans. III IV Cu Ag Au Zn Cd Hg 63.5 108 197 65 112.5 200 130.25 132.5 The above set of triads do not obey Dobereiner's law. Explain Newlands law of octaves giving examples. Newlands Law : When the elements are arranged in increasing order of their atomic masses, the properties of the eighth element are similar to that of the first. Examples : 1. The eight element from lithium is sodium. Similarly, eight element from sodium is potassium. Lithium, sodium, potassium have similar chemical properties. 2. The eighth element from fluorine is chlorine. Fluorine and chlorine have similar chemical properties. Explain the limitations of Newlands law of octaves. 1. Newlands law was applicable to elements with low atomic masses only. He could arrange elements only upto calcium out of total 56 elements known. 2. The law fails to explain similarities in properties of elements with higher atomic weights. After calcium, every eighth element did not possess properties similar to the first. 3. Newlands thought only 56 elements existed, but later several elements were discovered. 4. In order to fit the existing elements, Newlands adjusted two elements in the same position which differed in their properties. 5. This periodic table did not include inert gases as they were not discovered. Eg. : Sa (Do) H F Cl SCHOOL SECTION Re (Re) Li Na K Ga (Mi) Be Mg Ca Ma (Fa) B Al Ti Pa (So) C Si Cr Da (La) N P Mn Ni(Ti) O S Fe 11 MT SCIENCE & TECHNOLOGY 5. Ans. EDUCARE LTD. In the above table, Ti is the eighth element with respect to Al, but does not show similar properties. Similarly, Cr is different from Si. The elements Ti, Cr, Mn, Fe and Co, Ni do not show similarities as per Newlands law. Explain the merits of Mendeleevs periodic table. 1. Mendeleev was the first who successfully classified all known elements. 2. Mendeleev kept some blank places in his periodic table. These vacant spaces were for elements that were yet to be discovered. He also predicted properties of these elements even before they were discovered. Later they were found to be correct. 3. In the periodic table, some gaps were left by Mendeleev for unknown elements that could be found in the future. Three such unknown elements were named as Eka-Boron, Eka-Aluminium and Eka-Silicon. Even the properties of these unknown elements were predicted and these were found to accurate. Predicted element Eka-boron Eka-Aluminium Eka-Silicon Actual element discovered after Scandium Gallium Germanium Comparison of properties of eka-aluminium and gallium. Eka-Aluminium Atomic weight About 68 Density of solid 6.0g/cm3 Melting point Low Valency 3 Method of discovery Probably from its spectrum Oxide Ea2O 3 Density = 5.5 g/cm3 Soluble in acids and bases 4. Gallium 69.72 5.9g/cm3 29.78 3 Spectroscopically Ga 2 O 3 Density = 5.8 g/cm3 Soluble in acids and bases When noble gases were discovered later, they were placed in Mendeleev’s periodic table without disturbing the positions of other elements. MEMORISE : Spectrum : A vacuumised cylindrical discharge tube is taken and filled with hydrogen gas (whose spectrum is to be obtained). Electric current is passed through it. Hydrogen (Z=1), so Total number of protons = total number of electrons = 1 The electron present in the first shell absorbs electrical energy and goes in an excited state, i.e jumps to the next shell. As a result, the atom becomes unstable. To gain stability, the electron emits the same amount of energy that was absorbed and comes back to its ground state. This energy emitted is in the form of light. This light when passed through a prism, gets dispersed to give coloured bands. This is spectrum. This similar to dispersion of white light when passed through the prism. The spectrum of each element is unique as fingerprints vary from person to person. This method of obtaining the spectrum is spectroscopy. – Extra Information. 12 SCHOOL SECTION MT *6. Ans. 7. Ans. *8. Ans. 9. Ans. EDUCARE LTD. SCIENCE & TECHNOLOGY Explain the demerits of Mendeleevs periodic table. 1. Hydrogen resembles alkali metals as well as halogens. Therefore, no fixed position could be given to hydrogen in the periodic table. 2. Isotopes of same elements have different atomic masses; therefore each one of them should be given different position. On the other hand as isotopes are chemically similar, they had to be given same position. 3. At certain places, an element of higher atomic mass has been placed before an element of lower atomic mass. For eg, cobalt (Co = 58.93) is placed before nickel (Ni = 58.71) 4. Some elements placed in the same sub-group had different properties. Eg. Manganese (Mn) is placed with halogens which totally differs in the properties. Explain the modern periodic table. 1. In 1913, Henry Moseley, an English physicist found that it was atomic number (Z) and not atomic mass which was the fundamental property of an element. Thus atomic number is useful for arrangement of elements in the periodic table. 2. The modern periodic table is also called as long form of periodic table. 3. In the modern periodic table, elements are arranged in the increasing order of atomic number (Z). 4. The modern periodic table contains 7 horizontal rows called as periods and 18 vertical columns called as groups. 5. Apart from the seven rows, there are two additional rows called lanthanide series and actinide series placed at the bottom of the periodic table. 6. Based on electronic configuration, the modern periodic table is divided into four blocks namely, s-block, p-block, d-block and f-block. 7. The blocks gives rise to 4 types of elements namely normal elements, zero group elements, transition elements and inner-transition elements. 8. Elements belonging to a particular group show strong resemblance in their chemical properties like valency, formulae of compound and chemical reactions. 9. Elements show gradual variation in chemical properties along a period. 10. Neighbouring elements within a period show some similarities but nonneighbours show appreciable dissimilarity in their chemical properties. Explain the merits of modern periodic table. OR How could the modern periodic table remove various anomalies of Mendeleev's table? 1. The modern periodic table was classified based on atomic number. All isotopes of the same elements have different masses but same atomic number. Therefore, they occupy the same position in the modern periodic table. 2. When elements are arranged according to their atomic numbers, the anomaly regarding certain pairs of elements in Mendeleev's periodic table disappears eg.atomic number of cobalt and nickel are 27 and 28 respectively. Therefore, cobalt will come first and then nickel although its atomic mass is greater. 3. Elements are classified according to their electronic configuration into different blocks. Explain the four blocks of periodic table Based on electronic configuration, the modern periodic table is divided into four blocks namely, s-block, p-block, d-block, f-block. SCHOOL SECTION 13 MT SCIENCE & TECHNOLOGY s-block 10. Ans. 11. Ans. 14 p-block d-block EDUCARE LTD. f-block No. of shells incomplete/ valence electrons Outermost shell incomplete (1 or 2 valence electrons). Position I A, II A and III A to VII A and hydrogen. zero group. Group IIIB to II B along with group VIII. Lanthanides and actinides placed separately at the bottom of the periodic table. Includes All metals except hydrogen. Metals, non-metals, metalloids, zero group elements. Metals. Metals. Types of elements Normal elements. Normal and inert elements. Transition elements. Innertransition elements. Outermost shell Last two Last three incomplete except shells shells zero group elements incomplete. incomplete. that have completely filled shells (3 to 8 valence electrons). MEMORISE : Position of hydrogen : Hydrogen is at the head of table 1A and it has one valence electron much like the other members of group. However hydrogen is not considered as part of group 1A because chemically it is a non-metal whereas all other members of group are strong alkali metals. In fact position of hydrogen in periodic table is unresolved. – Extra Information. Explain the zig-zag line in the periodic table. 1. On the basis of electronic configuration of elements, the periodic table is divided into four blocks namely, s-block, p-block, d-block and f-block. 2. The elements of s-block (except hydrogen), d-block and f-block are all metals. 3. In the p-block, all the three types of elements, i.e metals, non-metals and metalloids are present. 4. A zig-zag line separates the metals on the left side form the non-metals on the right side of the periodic table. 5. The bordering elements along the zig-zag line are the metalloids. These are Antimony (Sb), Germanium (Ge), Boron (B), Silicon (Si), Arsenic (As), Tellurium (Te), Polonium (Po). They show intermediate properties and are called as metalloids or semi-metals. MEMORISE : The zigzag line on the periodic table, sometimes referred to as the Hays-McDaniel line, distinguishes between the metals and non metals. It is also called as stair case. – Extra Information. Explain the term periodic properties and explain the following trends of the periodic table with respect to : 1. Valency 2. Metallic character *3. Atomic size. 1. Valency : (a) In the modern periodic table, the elements are arranged in increasing order of atomic number (Z). Atomic number is related to the electronic configuration. SCHOOL SECTION MT SCIENCE & TECHNOLOGY EDUCARE LTD. (b) As the atomic number increases, the number of valence electrons increases. The first element has one electron in the outermost shell while the last element in a period has either completed duplet or completed octet. So, valency varies gradually across a period. (c) The group number indicates number of valence electrons. So, elements in a group have the same number of valence electrons. Therefore, down the group, valency remains the same. MEMORISE : Valency is the combining power of an atom or it is the number of electrons donated or accepted or shared to attain the nearest inert gas configuration. – Extra Information. 2. Metallic character : The tendency of an element to lose electrons and form positively charged ions (cations) is called as metallic character. Non-metallic character : The tendency of an element to gain electrons and form negatively charged ions (anions) is called as non-metallic character. As we go down a group, the atomic size increases. So, the nuclear attraction on the outermost electron decreases and electrons can be lost more easily. So, down the group, metallic character increases and non-metallic character decreases. Across a period, the nuclear charge increases. Consequently, the attraction on the valence electrons increases and so more energy is required to lose the electron. So, across a period, metallic character decreases and non-metallic character increases. MEMORISE : Factors affecting metallic and non-metallic character: 1. Atomic size : The greater the atomic size, the electron can be lost more easily. 2. The energy required to remove the electron is also less. So, lower the energy, more is the metallic nature of element. The energy required to remove a loosely bound electron from the outermost shell of an isolated gaseous atom is called as ionization potential. – Extra Information. 3. Atomic size is defined as the distance from the centre of the nucleus to the outermost shell of an atom. Across a period, the number of shells remain the same. So, as nuclear charge increases due to increase in atomic number, the attraction to the outermost electron increases and pulls the electrons inwards. So, atomic size decreases across a period. Li Be B C N O F Down the group, the number of shells increases. So, although the nuclear charge increases, the attraction to the outermost electron decreases. So, down the group, the atomic size increases. F Cl Br I SCHOOL SECTION 15 SCIENCE & TECHNOLOGY 12. Ans. 13. Ans. 14. Ans. 15. Ans. *16. Ans. 16 MT EDUCARE LTD. What are the causes of the periodicity of elements? Periodicity in properties of elements are seen because 1. In the modern periodic table, the elements are arranged according to their increasing atomic numbers. 2. The physical and chemical properties of elements largely depends upon the outermost electronic configuration, that is the valence electrons. 3. Hence the outermost electronic configuration for each group remain the same. 4. Since periodicity in properties of elements are seen due to same outermost electronic configuration. State Dobereiners law of triads. P, Q, R are elements of a Dobereiner's triad. If atomic mass of P is 35.5 and R is 127, what would be the atomic mass of Q? Dobereiner's law of triads : He arranged chemically similar elements in the increasing order of their atomic masses in a group of three which is known as "Dobereiner's Triads". In a Triad, atomic mass of middle element is approximately equal to the mean of atomic masses of other two elements in that Triad. Atomic weight of P Atomic weight of R Atomic weight of Q = 2 35.5 127 162.5 = = = 81.25. 2 2 Why is atomic number said to be a fundamental property? 1. Atomic number (Z) is defined as the number of protons or electrons in an atom. 2. It is more important than atomic mass because atomic number tells us about the chemical properties of an element. 3. It tell us about the number of valance electrons and valance electrons decide the chemical properties. It tell us about the nature of an element and its electronic configuration. Explain the features of Mendeleev's periodic table. Main features of Mendeleev’s periodic table are as follows : 1. The horizontal rows in the periodic table are called periods. There are seven periods. These are numbered from 1 to 7. 2. Properties of elements in a particular period show regular gradation from left to right. 3. Vertical columns in the periodic table are called groups. There are eight groups numbered from I to VIII. Groups I to VII are further divided into A and B subgroups. Among the first twenty elements, which are metals, non-metals and metalloids? Metals : Lithium, Beryllium, Sodium, Magnesium, Aluminium, Potassium, Calcium. Non-metals : Hydrogen, Helium (zero group), Carbon, Nitrogen, Oxygen, Fluorine, Neon(zero group), Phosphorus, Sulphur, Chlorine, Argon (Zero group). Metalloids : Boron, Silicon. SCHOOL SECTION MT SCIENCE & TECHNOLOGY EDUCARE LTD. ACTIVITY BASED QUESTIONS ACTIVITY : 1.3 Q. Ans. Q. Ans. Q. Ans. Consider isotopes of oxygen 16O and 18O. Would you able to place them in Mendeleev’s periodic table ? No, we cannot place 16O and 18O in Mendeleev’s periodic table. Find resemblance between hydrogen and alkali metals by writing compounds of both with chlorine, sulphur and oxygen. Alkali metals are : Li, Na, K, Rb, Cs, Fr. H2O Na 2 O H2S Na 2 S HCl NaCl Hydrogen and alkali metals form similar formulae with, oxygen, sulphur and chlorine. Find out a pair of elements from the periodic table where higher mass element is placed before lower mass element. Co Ni ; Te I (58.9) (58.7) (12.8) (12.7) ACTIVITY : 1.4 Q. Ans. Q. Ans. Q. Ans. How are isotopes of different elements placed in the Modern Periodic Table ? Isotopes have same atomic number, but different atomic mass. In modern periodic table the elements are arranged in increasing order of atomic numbers. So, all isotopes of an element can be given the same position. What should be the position of Hydrogen in the Modern Periodic Table ? Why? In modern periodic table, elements are arranged in the increasing order of their atomic number, so a Hydrogen must be the first element in modern periodic table, because it has the least atomic number. Write the name, symbol and electronic configuration of first ten elements. Elements Symbol Atomic number E.C. Hydrogen Helium Lithium Beryllium Boron Carbon Nitrogen Oxygen Flurorine Neon H He Li Be B C N O F Ne 1 2 3 4 5 6 7 8 9 10 (1) (2) (2,1) (2,2) (2,3) (2,4) (2,5) (2,6) (2,7) (2, 8) SCHOOL SECTION 17 MT SCIENCE & TECHNOLOGY EDUCARE LTD. ACTIVITY : 1.5 Q. Ans. Write the electronic configuration of elements from atomic number 11 to 18. Elements Sodium Magnesium Aluminium Silicon Phosphorous Sulphur Chlorine Argon Symbol Atomic No. Na Mg Al Si P S Cl Ar 11 12 13 14 15 16 17 18 E.C. (2, (2, (2, (2, (2, (2, (2, (2, 8, 8, 8, 8, 8, 8, 8, 8, 1) 2) 3) 4) 5) 6) 7) 8) Q. Ans. Q. What similarities do you find in their electronic configuration ? They all have three shells in their atoms. How many valence electrons are present in sodium, aluminium and chlorine ? Ans. Elements No. of valence electrons Sodium Aluminium Chlorine Q. Ans. Write the electronic configuration of 1. Mg and Ca. 2. F and Cl. Elements Magnesium Calcium Flurine Chlorine Q. Ans. Q. Ans. 18 1 3 7 Atomic number Electronic configuration 12 20 9 17 (2, 8, 2) (2, 8, 8, 2) (2, 7) (2, 8, 7) Do these elements contain same number of valence electrons ? Yes, they contain same number of valence electrons. Write the electronic configuration of B, O, Na, Al, S and K. Symbol Atomic number Electronic configuration B O Na Al S K 3 8 11 13 16 19 (2, 1) (2, 6) (2, 8, 1) (2, 8, 3) (2, 8, 6) (2, 8, 8, 1) SCHOOL SECTION MT SCIENCE & TECHNOLOGY EDUCARE LTD. ACTIVITY : 1.6 Q. Ans. Classify elements from atomic number 11 to 18 as metals or non metals depending on the electrons present in the outermost shell. Symbol Na Mg Al Si P S Cl Ar Atomic number 11 12 13 14 15 16 17 18 Electronic configuration (2, 8, 1) (2, 8, 2) Metals (2, 8, 3) (2, 8, 4) (2, 8, 5) (2, 8, 6) Non metals (2, 8, 7) (2, 8, 8) ACTIVITY : 1.8 Q. Ans. Q. Ans. How do you calculate valency of an element from its electronic configuration ? Electronic configuration tells about the valence electrons. If the number of valence electrons are 1, 2 or 3, then such elements will donate 1, 2 or 3 electrons their valency is also 1, 2 or 3 respectively. If an element has 4 valence electrons, it shares all 4 electrons, so the valency is 4. If the number of valence electrons are 5, 6 or 7 electrons, then such elements accept 3, 2 or 1 electrons respectively. Thus their valency is 3, 2 or 1. When the valence electrons are 2 (for only one shell) or 8 then it is a stable electronic configuration. Thus, the valency is zero. What is the valency of elements with atomic number 8, 14, 17 and 20 ? Atomic number Electronic configuration Valency 8 14 17 20 (2, 6) (2, 8, 4) (2, 8, 7) (2, 8, 8, 2) 2 4 1 2 ACTIVITY : 1.9 Q. Ans. Atomic radii of elements of third period are given below. Period 3 elements S Atomic radius (pm) 127 Na Cl P Mg Si Al 190 99 128 160 132 143 1. Arrange them in the decreasing order of their atomic radii. Ans. Ans. Ans. Na Mg Al Si P S Cl 190 160 143 132 128 127 99 2. Are they arranged as in the periodic table ? Yes. 3. Which are the atoms of highest and lowest atomic radii ? Highest atomic radius = Na (190 pm) Lowest atomic radius = Cl (99 pm) SCHOOL SECTION 19 MT SCIENCE & TECHNOLOGY Ans. Q. Ans. EDUCARE LTD. 4. What trend is observed in the atomic radii in a period from left to right ? Atomic radii decreases from left to right in a period. Atomic radii of group 17 are given below : Group 17 elements I F Cl Br Atomic radius (pm) 133 72 99 114 1. Arrange them in the increasing order of thier atomic radii. Ans. Ans. Ans. Ans. 20 F (72) Cl (99) Br (114) I (133) 2. Are they arranged as in the periodic table ? Yes. 3. Which are the atoms of highest and lowest atomic radii ? Highest atomic radii = Iodine (133). Lowest atomic radii = Fluorine (72). 4. What trend is observed in the atomic radii down the group ? Atomic radii increases down the group. Atomic number Elements configuration Symbol electrons Electronic 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 Hydrogen Helium Lithium Beryllium Boron Carbon Nitrogen Oxygen Flurine Neon Sodium Magmesium Aluminium Silicon Phosphorus Sulphur Chlorine Argon Potassium Calcium H He Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca 1 2 2,1 2, 2 2, 3 2, 4 2, 5 2, 6 2, 7 2, 8 2, 8, 1 2, 8, 2 2, 8, 3 2, 8, 4 2, 8, 5 2, 8, 6 2, 8, 7 2, 8, 8 2, 8, 8, 1 2, 8, 8, 2 Valence Valency electrons 1 2 1 2 3 4 5 6 7 8 1 2 3 4 5 6 7 8 1 2 1 0 1 2 3 4 3 2 1 0 1 2 3 4 3 2 1 0 1 2 SCHOOL SECTION SCIENCE & TECHNOLOGY MT EDUCARE LTD. HOTS QUESTIONS & ANSWERS 1. Ans. 2. Ans. 3. Ans. 4. Ans. 5. Ans. 22 X, Y, Z are the elements of Dobereiner’s triad. If the atomic mass of X is 7 and that of Z is 39. What should be the atomic mass of y ? In the triads, the atomic mass of the middle element is approximately the mean of the atomic masses of the other two elements. Hence, 7 39 46 = = 23 Y= 2 2 Atomic mass of Y = 23. Read the following descriptions and decide whether the element belongs to metal or non-metal. Justify your answer. (a) Element ‘X’ has atomic number 11. (b) Element ‘Y’ has atomic number 16. (a) Element X is a metal. Its electronic configuration is (2, 8, 1). The element has a tendency to loose one electron making it metallic in nature. (b) Element Y is a non-metal. Its configuration is (2, 8, 6). Therefore there is a tendency to accept the electrons rather than to loose, making it non-metallic in nature. The atomic number of an element X is 17. Predict : (a) Its valency. (b) Whether it is a metal or non-metal. (c) Its relatively atomic size with respect to other members in the group. (a) Valency is 1 (Electronic configuration 2, 8, 7). (b) It is a non-metal. (Tendency to accept electron as the outermost orbit has 7 electrons.) (c) Atomic size is relatively smaller with respect to the other members in a group. (Electrons in the outer shell are not released easily.) Inert gases are neutral because ...................... . (a) they do not combine with other elements under normal circumstances. (b) the number of electrons in their outer shell is 8. (c) they do react with other elements, but the process remains incomplete. The number of electrons in their outer shell is 8. Identify the main characteristic of the elements given below from their description. (a) Element P is in O group element. (b) Element Q is in group 1 with atomic number 19. (c) Element R is a d-block element and its two outermost shells are incomplete. (d) Element S is f-block element. (e) Element T has two different atomic masses. (a) It is an inert gas. (b) It is a metal with one electron in the outer shell. (c) It is called a transition element and is metallic in nature. (d) They are either lanthanides or actinides with three incomplete outermost shells and metallic in nature. (e) They are isotopes of element T. SCHOOL SECTION MT SCIENCE & TECHNOLOGY EDUCARE LTD. GLOSSARY Alkali metals : Alkali Alkaline earth metal : : Atomic number : Atomic mass number : Electronic configuration Electrostatic force of attraction Element : : Isotopes : Halogens : Noble gases : Metals Non-metals Metalloids : : : Valency : Periodicity Cations Anions Nuclear charge Ionisation potential : : : : : : Elements of group IA are most reactive. They are called alkali metals as they form alkali on reaction with water. Soluble bases which produce OH– ions in water. Elements belonging to group II A. They form alkali on reaction with water and their oxides are found in earth. So, they are called alkaline earth metals. Number of protons (in nucleus) or extra nuclear electrons. the total number of protons and neutrons in the nucleus of an atom. Distribution of electrons shell wise. A strong force of attraction between particles of opposite charges. A substance that cannot be divided further into simpler substances. They are different atoms of same element having same atomic number but different mass number Elements belonging to group VII A. The elements of this group form salts and are called as salt formers. Elements of group 18 also called as rare gases/ noble gases. Electron donors, hence electro-positive. Electron acceptors, hence electro-negative. Elements showing properties of both metals and non-metals. Combining power of an atom or number of electrons donated/accepted/shared to attain the nearest inert gas configuration. A phenomenon occurring at regular intervals. Positively charged ions. Negatively charged ions. The positive charge on the nucleus of an atom. The energy required to remove a loosely bound electron from the outermost shell of an isolated gaseous atom is called as ionization potential. AMAZING FACTS The noble gas Xenon lasers can cut through materials that are so tough even diamond tipped blades will not cut. Astatine is the rarest element on Earth (approx 28g in the Earth's entire crust.) SCHOOL SECTION 23 S.S.C. Marks : 20 CHAPTER 1 : SCHOOL OF ELEMENTS Duration : 1 hr. SCIENCE Q.I 1. 2. 3. 4. Q.I 1. 2. 3. 4. [A] Fill in the blanks : Noble gases have valency as ....................... . Group 1A is called ....................... . The formula of chloride of metal is MCl 2, the metal M belongs to ....................... group. The element eka-Aluminium is called as ....................... . 2 [B] Match the columns : Column A Alkali metals Alkaline earth metals Halogens Noble gases 2 (a) (b) (c) (d) Column B II A group I A group zero group VII A group Q.I 1. 2. [C] State whether True or False : Eka boron is known as Germanium. Isotopes have same atomic masses. 1 Q.II 1. 2. 3. [A] Give scientific reasons : (Any Two) Atomic size decreases across a period. The family of noble gases is called as zero group. Chlorine is placed in VII A group in the modern periodic table. 4 Q.II 1. 2. [B] State the following : Dobereiner’s triads law. Modern periodic law. 4 Q.III 1. 2. 3. [A] Answer the following in details : (Any One) Explain the demerits of Mendeleevs periodic table. Explain the four blocks of periodic table. Explain the zig-zag line in the periodic table. 4 Q.III 1. 2. 3. 4. [B] Answer in one sentence each : (Any Three) Name elements having single electron in their outermost shell. Name halogens, to which group do they belong ? Give two names of Member of 3rd period. What are lanthanides ? 3 Best Of Luck