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Periodic Trends Lesson (2-Day) By Erik Haigler Day1 Purpose a. Students will be able to identify the trends of the periodic table b. Students will be able to understand the concepts of each periodic trend c. Students will be able to explain how the trend increases or decreases across and up and down the periodic table d. Students will be able to show and understand how understanding the concept and trend are connected Virginia S.O.L’s CH.2 The student will investigate and understand that the placement of elements on the periodic table is a function of their atomic structure. The periodic table is a tool used for the investigations of d) families or groups; e) periods; f) trends including atomic radii, electronegativity, shielding effect, and ionization energy; Materials • Periodic Table • Alien Cards • March Madness Bracket Science Safety Students should be cleanup table at the end of class and throw all trash away in the nearest trash can. No Horseplay! Procedure Engage (5 minutes) Show video and highlight the key points made about properties and trends. https://www.youtube.com/watch?v=O-48znAg7VE#t=226 Explore (20 minutes) Reconnect to the Alien Periodic table, but this time instead of focusing on the table layout focus on trends between the aliens. Draw a connection on how the trends between the aliens and the trends between the elements are not that different. Experiment Overview: In cooperative activity, you will use the 40 cards and construct an Alien Periodic Table. You will arrange the Aliens in some logical pattern so that they form an organized regular block. The resulting table is visually impressive and clearly the meaning of periodic trends. Questions: 1. What multiple trends (Key Similarities and Varying Traits) did you use to distinguish the eight families? 2. What multiple trends (Key Similarities and Varying Traits) did you use to distinguish the five periods? 3. What is at least one trend that you already know on the periodic table? 4. Try to name at least 3 other trends you might know or make up three others? 5. Draw the missing alien from your periodic table! Explain (10-15 minutes) The following trends will be briefly covered and students will take notes then students will draw how the trend moves across period and group on their own periodic table Effective nuclear charge The effective nuclear charge is the net positive charge experienced by an electron in a multielectron atom. The term "effective" is used because the shielding effect of negatively charged electrons prevents higher orbital electrons from experiencing the full nuclear charge by the repelling effect of inner-layer electrons. The effective nuclear charge experienced by the outer shell electron is also called the core charge. It is possible to determine the strength of the nuclear charge by looking at the oxidation number of the atom. - Increase across a period (due to increasing nuclear charge with no accompanying increase in shielding effect). - Decrease down a group (although nuclear charge increases down a group, shielding effect more than counters its effect). Atomic Radius Trends For atoms, the atomic radius is one-half the distance between the nuclei of two atoms is (just like a radius is half the diameter of a circle). However, this idea is complicated by the fact that not all atoms are normally bound together in the same way. Some are bound by covalent bonds in molecules, some are attracted to each other in ionic crystals, and others are held in metallic crystals. Nevertheless, it is possible for a vast majority of elements to form covalent molecules in which two like atoms are held together by a single covalent bond. The covalent radius of these molecules is often referred to as the atomic radius. This distance is measured in picometers. Going through each of the elements of the periodic table, patterns of the atomic radius can be seen. - Atomic radius decreases from left to right within a period. This is caused by the increase in the number of protons and electrons across a period. One proton has a greater effect - than one electron; thus, a lot of electrons will get pulled towards the nucleus, resulting in a smaller radius. Atomic radius increases from top to bottom within a group. This is caused by electron shielding. Ionization Energy Trends Ionization Energy is the amount of energy required to remove an electron from a neutral atom in its gaseous phase. Conceptually, ionization energy is considered the opposite of electronegativity. The lower this energy is, the more readily the atom becomes a cation. Therefore, the higher this energy is, the more unlikely the atom becomes a cation. Generally, elements on the right side of the periodic table have a higher ionization energy because their valence shell is nearly filled. Elements on the left side of the periodic table have low ionization energies because of their willingness to lose electrons and become cations. Thus, ionization energy increases from left to right on the periodic table. Another factor that affects ionization energy is electron shielding. Electron shielding describes the ability of an atom's inner electrons to shield its positively-charged nucleus from its valence electrons. - The ionization energy of the elements within a period generally increases from left to right. This is due to valence shell stability. - The ionization energy of the elements within a group generally decreases from top to bottom. This is due to electron shielding. Elaborate (30 minutes) March Madness is upon us! Your students are probably already working on their next assignment in bracketology, predicting the field for the NCAA Basketball Tournament. Let’s apply the principles of bracketology to the properties of the elements. The competition among the 64 elements is stiff, and there is a wealth of information for students to research, in this “elementary” version of March Madness! Define each of the following properties of the elements and briefly describe any periodic trend in the property across a row or down a column in the periodic table. - Ionization energy, Atomic radius, Effective nuclear charge Evaluate (10 minutes) I will actively evaluate students throughout the bracket exercise. After I will give students an exit slip where they will have give me a definition in their own words of the each trend and be able to draw each trends arrow on a periodic table. Day 2 Purpose a. Students will be able to identify the trends of the periodic table b. Students will be able to understand the concepts of each periodic trend c. Students will be able to explain how the trend increases or decreases across and up and down the periodic table d. Students will be able to show and understand how understanding the concept and trend are connected Virginia S.O.L’s CH.2 The student will investigate and understand that the placement of elements on the periodic table is a function of their atomic structure. The periodic table is a tool used for the investigations of d) families or groups; e) periods; f) trends including atomic radii, electronegativity, shielding effect, and ionization energy; h) chemical and physical properties; and Materials • Periodic Table • Think Pair Share Activity Sheet • 1 die for each group • Index cards with main group element symbols • Periodic Trend War Activity Sheet Science Safety Students should be careful not to lose any of the elements cards or other material used in the game. When finished student should return all items back to the station bucket in which they were found. Students should be cleanup table at the end of class and throw all trash away in the nearest trash can. No Horseplay! Procedure Engage (5 minutes) Show video http://education-portal.com/academy/lesson/electronegativity-trends-among-groupsand-periods-of-the-periodic-table.html#lesson Explore (5 minutes) Students will play a tug of war game and show how the number of valence electrons creates a high electronegativity by adding more students for each electron. Explain (10 minutes) The following trends will be briefly covered and students will take notes then students will draw how the trend moves across period and group on their own periodic table Electron affinity Like the name suggests, electron affinity describes the ability of an atom to accept an electron. Unlike electronegativity, electron affinity is a quantitative measure that measures the energy change that occurs when an electron is added to a neutral gas atom. When measuring electron affinity, the more negative the value, the more of an affinity to electrons that atom has. - With Electron affinity increases from left to right within a period. This is caused by the decrease in atomic radius. - Electron affinity decreases from top to bottom within a group. This is caused by the increase in atomic radius. Chemical Reactivity METALS DOWN a Group: In METALS reactivity INCREASES as you go DOWN a Group because the farther down a Group of metals you go, the easier it is for electrons to be given or taken away, resulting in higher reactivity. ACROSS a Period: In METALS reactivity DECREASES as you go ACROSS a Period because though they still want to give away valence electrons they have more of them to get rid of, which requires more energy. Not as easy to blow off a little steam! NON-METALS UP a Group: In NON-METALS reactivity INCREASES as you go UP a Group because the higher up and to the right atoms are, the higher the electronegativity, resulting in a more vigorous exchange of electrons. Fluorine? A greedy, impatient beast when it comes to electron exchange manners. ACROSS a Period: In NON-METALS reactivity INCREASES as you go ACROSS a Period because (notice how trends repeat?) the closer you get to filling your s- and porbital’s the more motivated you are to do so. Show Cool video of this in action https://www.youtube.com/watch?v=uixxJtJPVXk Elaborate (20 minutes) Think Pair Share Reactivity Video Lab Students are to write down what they thing about the periodic trends, reactivity, then get with partners to discuss Show Cool video of this in action https://www.youtube.com/watch?v=uixxJtJPVXk and then get students to discuss what they saw and how it alters their views. Evaluate (50 minutes) Periodic Table Trend War Purpose: To teach students periodic trends regarding the properties of elements. Materials: 1 die, index cards with main group element symbols written on them (one element per card), a list of trends written on the board numbered from 1 -6. Trends should include such things as ionization energy, electronegativity, atomic radius, electron affinity, reactivity etc... A "wild" category can be included which allows the roller of the dice to choose the trend. Quiz will follow on all trends