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Lithographic masks and photoresist that are made from programmable polymers such as DNA with embedded optical defect metrology BSU File Reference #147 Abstract Central to the phenomenal success of the semiconductor industry is the ability to detect, classify, and eventually eliminate defects during high volume manufacturing. Precise metrology is the cornerstone for quality control in the industry. Surface analysis techniques such as AFM, TEM, SEM, and X-ray scattering are commonly used to identify near level details of mask features, such as critical dimensions and roughness. These techniques are also employed to inspect mask defects. However, process variability during directed self-assembly (DSA) requires real-time, online metrology to identify mask defects and alignment errors between the mask and lithographically defined substrates. Although DSA of block copolymers demands new metrology, efficient wafer scale techniques have not been developed. Boise State University has developed technology that improves efficiency in wafer scale techniques that allows defects to be self-identified by fluorescence, without affecting the properties of the mask. As a result, defect metrology can be performed at a relatively high resolution and in real-time. This new technology can be rationally designed with atomic precision, allows for features to be readily programmed into the rectilinear coordinate system used by the semiconductor industry, can form periodic, aperiodic, and random patterns, be enthalpically driven in material systems with the potential for low defect concentrations, have a resolution of ~2.5 nm perpendicular to the DNA axis and 0.34 nm along the DNA axis, be conjugated with a host of functional groups to increase their functionality, allows for the use of embedded optical metrology through conjugation of molecular dyes, molecular quenchers, fluorescent metal clusters or other optical readout-technologies, and allows defect locations to be mapped with dSTORM at a resolution of 20 nm for super-resolved defect images. Boise State is looking for a Licensee for this technology. For More Information Contact: Katy Ritter Director, Office of Technology Transfer Division of Research and Economic Development (208) 426-5765 [email protected] Boise State University ● Research and Economic Development ● Office of Technology Transfer http://research.boisestate.edu/ott/