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Unit 5- Periodic Table Practice Review Name: _________________________________ 1. Which of the following scientists is credited with developing the modern periodic table? A) Le Châtelier C) Dalton E) Haber B) Rutherford D) Mendeleev A) atomic masses C) atomic numbers E) physical properties 2. In the modern Periodic Table, the elements are arranged according to A) B) C) D) E) 10. The Periodic Law states that the chemical properties of elements are periodic functions of their 11. The original format of the Periodic Table, as described by Mendeleev, is based on the arranging the elements atomic mass atomic number most common oxidation number maximum positive oxidation number atomic density A) B) C) D) E) 3. Which is not a periodic property? A) color C) atomic radius E) electronegativity B) ionization energy D) oxidation number A) sodium C) neptunium E) tin A) protons C) nucleons E) energy levels B) Li and Ne D) Si and P B) S C) Se D) I A) B) C) D) E) E) Ti 7. Similar properties for chemical elements recur at certain intervals of atomic number. Therefore, these properties are referred to as A) periodic C) electronegativity E) atomic number B) neutrons D) valence electrons 14. Elements in the same family 6. The element whose properties are most similar to those of tellurium is A) O B) gallium D) germanium 13. Each of the elements in a Main Group of the Periodic Table has the same number of B) neutron charge D) covalent radius 5. Two elements with similar orbital structures are A) Li and Ne C) Na and K E) Co and Ni in order of increasing density according to chemical properties with reference to nuclear stability in order of increasing number of neutrons according to physical properties 12. The Periodic Table, based on an octet pattern, led Mendeleev to predict the existence of the element referred to as eka–silicon, now known as 4. The periodic table position and the chemical properties of the elements arise from their A) atomic mass C) nuclear radius E) electron configuration B) isotopic masses D) number of neutrons are in the same horizontal row have similar chemical properties have the same number of protons have the same number of electrons have the same phase at room temperature 15. Which pair of atoms is expected to show the greatest chemical similarities? A) H and He C) Sr and Ba E) O and F B) shielding effect D) oxidation number B) K and Ca D) Na and Cl 8. Which is used as the basis for the atomic weights in the current Periodic Table? A) water C) oxygen E) carbon B) hydrogen D) nitrogen 9. What determines the order of elements in the Periodic Table? A) size of ions C) atomic mass E) number of protons H-Chem B) size of elements D) number of neutrons Page 1 Dr. Powell 16. The letters X, Y, and Z stand for three elements whose fluorides have the formulas XF, YF2 , and ZF3. Where could X, Y, and Z be located in the periodic table? 21. Consider the electron configurations: I 1s22s23s2 II 1s22s22p6 III 1s22s22p63s1 IV 1s22s22p63s23p63d84s2 V 1s22s22p63s23p63d104s24p6 A) The configurations that represent elements of the same Group of the Periodic Table are B) A) I and IV C) IV and V E) I, II and V C) B) II and V D) I, II and III 22. What similarity exists for the atoms of the Period 3 elements in the ground state? A) B) C) D) E) D) 17. Similar chemical properties of families of elements is a result of similar A) B) C) D) E) nuclear charges physical properties outer electron shells numbers of electron shells inner electron shells B) 7 A) 6 D) 12 A) B) C) D) E) H-Chem D) 4 E) 5 B) diagonal rows D) vertical columns B) 2 C) 3 D) 4 E) 5 a noble gas an alkali metal the eight element in the row the eighteenth element in the row a halogen 26. Which period in the periodic table contains the most nonmetals ? E) 19 20. In the periodic table elements with similar properties are grouped in A) periods C) horizontal rows E) horizontal families C) 3 25. A new row in the periodic table begins immediately after B) period 3, group IVA D) period 6, group IVA C) 9 B) 2 24. An atom with the outer electron structure 3d104s24p5 would be in which row of the periodic table? 19. An element with atomic number 11 is likely to have similar chemical properties to the element whose atomic number is A) 2 23. Which period contains elements which are all gases at standard temperature and pressure? A) 1 18. The ground state electronic configuration of the valence electrons for an element is 3s23p2 . This element belongs to A) period 3, group IIA C) period 4, group IIIA E) period 6, group VA 3 valence electrons the 3s sublevel contains 2 electrons the 3p sublevel contains 6 electrons 3 principal energy levels contain electrons the 3d sublevel is full A) 1 B) 2 C) 3 D) 4 E) 5 27. Which period in the Periodic Table contains the most metals? A) 2 B) 3 C) 4 D) 5 E) 6 28. Which element is correctly identified according to family and period? A) B) C) D) E) Page 2 Element 10 is a halogen in period 2 Element 11 is an alkaline earth metal in period 4 Element 17 is a halogen in period 3 Element 21 is a transition metal in period 3 Element 3 is a alkaline earth metal in period 1 Dr. Powell 29. To which families in the periodic table do the elements belong? 31. Elements X', Y' and Z' have the following atomic radii. Element M forms an M2+ ion Element N forms a N2– ion When atomic radii are correctly arranged, how might these elements appear in the periodic table? A) Both elements belong to the oxygen family B) Both elements belong to the alkaline earth family C) M belongs to the oxygen family and N belongs to the alkali metals D) M belongs to the alkaline earth family and N belongs to the oxygen family E) M belongs to the alkaline earth family and N belongs to the halogen family A) B) 30. An element has a ground state electron configuration for its valence electrons: C) The location of this element in the Periodic Table is A) Period 2, Family IA C) Period 3, Family IIIA E) Period 3, Family VIA B) Period 3, Family IIA D) Period 3, Family VA D) 32. Base your answer to the following question on the picture below. In which part of the Periodic Table are the elements with the smallest covalent radius found? A) B) C) D) E) H-Chem Page 3 A B C D None of the above are necessarily correct. Dr. Powell 33. Chlorine has a smaller atomic radius than bromine because the bromine atom has a greater A) B) C) D) E) number of protons number of neutrons number of energy levels number of valence electrons electronegativity B) Mg C) Na D) Na+ A) B) C) D) E) E) Be2+ A) B) C) D) E) 35. Which element has the largest diameter? A) Al B) Si C) P D) S E) Cl 36. The atomic radii of the atoms becomes larger from lithium to francium going down Group IA primarily as a result of A) B) C) D) E) the shielding effect increased nuclear charge the increased mass number decreased metallic character increasing number of neutrons A) Ar; Ca2+; Cl–; Cl. C) Cl–; Ar; Ca2+; Cl. E) Ca2+; Ar; Cl–; Cl. a greater nuclear charge more unpaired electrons a smaller atomic number a smaller oxidation number more neutrons 38. The variation in the radius of successive atoms in a period is primarily caused by the A) B) C) D) E) B) Ca2+; Ar; Cl; Cl–. D) Cl; Cl–; Ar; Ca2+. 43. Which is true regarding elements in the Periodic Table in the sequence shown? A) B) C) D) E) Si ® P ® Cl shows increasing metallic character Li ® Na ® K shows decreasing metallic character C ® N ® O shows decreasing atomic radius Ti, V, and Cr are nonmetals Cl ® Br ® F shows decreasing electronegativity 44. The atomic radii decrease from left to right in a period of the Periodic Table because the A) B) C) D) atomic mass increases number of protons decreases number of electrons increases electrostatic force between the nucleus and the electrons increase E) size of the nucleus increases increase in nuclear charge increase in number of neutrons change in metallic properties addition of a principal energy level increase in nuclear radius 39. Consider the covalent radii of the Nitrogen Family increases decreases stays the same increases and then decreases cannot be predicted 42. The atoms and ions in order of increasing radius are 37. An atom of fluorine is smaller than an atom of oxygen because fluorine has A) B) C) D) E) increase from bottom to top increase from top to bottom increase from left to right do not change in a regular manner changes according to the number of neutrons 41. Within a Main Group of the Periodic Table, such as the halogens, how does ionization energy change as atomic radius increases? 34. Which of the following atoms or ions is the largest? A) Mg2+ 40. In the Periodic Table, the radii of atoms 45. Which of the following statements apply when an atom of chlorine, Cl, becomes an ion in a chemical reaction? I Its charge is generally 1+. II Its charge is generally 1–. III The ion is larger than the atom. IV The ion is smaller than the atom. A) I and III only C) II and III only E) I only The atomic radius of antimony is approximately A) C) E) H-Chem B) D) Page 4 B) I and IV only D) II and IV only Dr. Powell 46. In which part of the periodic table are the elements with the largest ionic radius found? 50. Which has the smallest ionic radius? A) aluminum ion C) magnesium ion E) lead ion B) cesium ion D) sodium ion 51. The diameter of a sodium atom, Na, is larger than the diameter of a sodium ion, Na+, because the sodium ion has A) B) C) D) E) A) B) C) D) E) upper left lower left upper right lower right upper right or lower left. 47. Which graph best depicts the change in the size of an ion with increasing atomic number in a Period? A) B) C) more protons than the Na atom. fewer protons than the Na atom. a greater proton:electron ratio than its atom. a smaller proton:electron ratio than its atom. more neutrons than the Na atom. 52. Which is the element with the smallest ionic radius? A) (A) B) (B) C) (C) D) (D) E) (E) 53. An atom of a nonmetal generally becomes an ion by A) B) C) D) E) D) losing electrons gaining electrons losing protons gaining neutrons both losing protons and gaining electrons 54. Which electronic configuration represents atoms of the element having the highest second ionization potential? A) 1s2s22p4 C) 1s22s22p63s1 E) 1s22s22p63s23p1 E) B) 1s22s22p6 D) 1s22s22p63s2 55. The first ionization energy of each successive element decreases as the alkali metals, Group IA, are considered from the top to the bottom of the Periodic Table. One reason for this is that there is a A) B) C) D) decrease in the nuclear charge. increase in the number of neutrons. decrease in the number of principal energy levels. increase in the distance between the valence electrons and the nucleus. E) decrease in the shielding effect. 48. Four pairs of electrons in the outer level is referred to as a stable A) octet B) nuclear charge C) shielding effect D) electronegativity E) noble gas configuration 49. When an atom is changed to a negatively charged ion, A) B) C) D) E) protons are lost electrons are lost the radius increases the ion is a better electron acceptor the radius decreases H-Chem Page 5 Dr. Powell Base your answers to questions 56 through 59 on the data below. The data is the first four ionization energies, in kJ•mole -1, of four elements in the same period. 63. Which of the following elements has the greatest electron affinity A) Bismuth C) Fluorine E) Carbon B) Aluminum D) Nitrogen 64. The strength of an atom’s attraction for the electrons in a chemical bond is the atom’s A) electronegativity C) heat of reaction E) none of the above 56. Which is from Group IIIA ? A) A C) C E) None of the above B) B D) D 65. In which group of elements do the atoms gain electrons most readily? A) 1 57. Which is from Group VIIA ? A) A C) C E) None of the above A) B) C) D) E) B) B D) D periodic force gravitational attraction shielding effect electromagnetic attraction weak force H-Chem low first ionization energy, low electronegativity high first ionization energy, low electronegativity low first ionization energy, high electronegativity high first ionization energy, high electronegativity high first ionization energy, zero electronegativity B) sodium D) calcium 69. The valence electrons of metals are A) B) C) D) E) the nuclear charge the number of neutrons in the nucleus the number of energy levels in the atom the distance of the electron from the nucleus the number of filled valence orbitals loses an electron to form a negative ion gains an electron to form a negative ion loses an electron to form a positive ion gains an electron to form a positive ion none of the above B) nonmetals D) precious metals A) magnesium C) potassium E) lithium few in number and strongly held few in number and weakly held many in number and strongly held many in number and weakly held variable in number and strongly held 70. Atom X has 11 protons and 12 neutrons and atom Y has 12 protons and 12 neutrons. They are A) B) C) D) E) 62. Electron affinity is a measure of the amount of energy released when a neutral atom in the gaseous phase A) B) C) D) E) E) 18 68. The most metallic of these elements is 61. Which will not affect the ionization energy? A) B) C) D) E) D) 16 67. Which would correctly characterize a metal ? B) B D) D 60. The decreased effect of the attraction of a nucleus for valence electrons due to the presence of intervening electrons is the A) B) C) D) E) C) 14 A) metals C) noble gases E) transition elements 59. Which is from Group IA? A) A C) C E) None of the above B) 2 66. The electronegativity of elements is generally greater for B) B D) D 58. Which is from Group IIA ? A) A C) C E) None of the above B) ionization energy D) heat of formation both metallic in character isotopes of the same element both nonmetallic in character members of the same family in the Periodic Table members of different periods in the Periodic Table 71. Which neutral element will most easily form a positive ion? A) Page 6 B) C) D) E) Dr. Powell 72. Which list consists entirely of diatomic molecules under normal room conditions? A) B) C) D) E) helium, neon, argon, krypton hydrogen, helium, fluorine, neon carbon, oxygen, nitrogen, fluorine oxygen, sulfur, selenium, tellurium fluorine, chlorine, bromine, iodine 81. Which metal exists as a liquid at room temperature and standard pressure? A) aluminum C) mercury E) iodine 82. An oxide of the formula X2O would be formed if oxygen combined with any element in 73. Which would correctly characterize a nonmetal? A) B) C) D) E) A) Group IA. C) Group IIIA. E) Group VIIA. low first ionization energy and low electronegativity high first ionization energy and low electronegativity low first ionization energy and high electronegativity high first ionization energy and high electronegativity low first ionization energy and zero electronegativity Al is the only metal Cl is the only nonmetal Cl and O are the only nonmetals Ca and Na are the only metals Al is the most reactivie element A) halogens C) alkali metals E) chalcogens A) B) C) D) E) B) iodine D) fluorine formation of 2+ ions. oxides dissolve in water to yield acids. ionic radius is greater than the atomic radius. atomic radius decreases with increasing atomic number. large first ionization energy. 85. Among the elements of Group IA, which orbital provides the electron most used in bonding? 76. Which element is not a diatomic molecule at STP? A) iodine C) oxygen E) hydrogen B) noble gases D) alkaline earths 84. The characteristic typical of the elements in Group IIA of the Periodic Table is the 75. Which is not a gas at room temperature? A) xenon C) oxygen E) nitrogen B) Group IIA. D) Group IVA. 83. In which family (or Group) does the element beryllium, Be, belong? 74. Based on the properties of Ca, O, Na, Al and Cl, which of the statements is true? A) B) C) D) E) B) magnesium D) tin A) s B) p C) sp D) sp2 E) sp3 Base your answers to questions 86 and 87 on the graph below. B) carbon D) nitrogen 77. Chemical elements having both metallic and nonmetallic characteristics are called A) atoms C) metalloids E) semiconductors B) bi–metals D) semi–solids 78. Which group contains two metalloids? A) Group IIA C) Group IIB E) Group IA B) Group VA D) Group VB 79. Which element has the highest melting point? A) Ar B) Br C) Hg D) Si 86. Which are just beginning the pairing of electrons in the p–orbitals? E) Kr 80. Which Group of the periodic table contains only solid elements at room temperature and standard pressure? A) Group IA C) Group VA E) Group 0 H-Chem A) (A) B) (B) C) (C) D) (D) E) (E) 87. Which have exactly half–filled p–orbitals? B) Group IIA D) Group VIA A) (A) Page 7 B) (B) C) (C) D) (D) E) (E) Dr. Powell 88. Which element in the 5th period of the Periodic Table have the following electron configuration A) Bi B) Po C) Sb D) Te 95. The neutral atom of an element containing eight electrons in its outer shell A) B) C) D) E) E) I 89. Which is the element with a possible oxidation number of –2? A) (A) B) (B) C) (C) D) (D) 96. The Noble gases are characterized by completed outer shells of electrons. The outer shells of the Noble gases, with the exception of helium, consist of E) (E) A) s and d electrons C) p and d electrons E) d and f electrons 90. Which group in the Periodic Table contains solid, liquid and gaseous elements at room temperature and standard pressure? A) 0 B) IIA C) VA D) VIA E) VIIA 91. In which family on the Periodic Table would the element having an atomic number of 117 be placed? A) Noble gas C) Alkali metal E) Nitrogen group has a charge of 1+ is chemically inert is chemically active loses one electron when chemically reacting forms many compounds B) Halogen D) Alkaline earth metal B) s and p electrons D) s, p and d electrons 97. From which sublevel(s) will an atom of Ni in the ground state lose electrons to form the Ni3+ ion? A) the 3p, only C) the 4d, only E) both the 4s and 4p B) the 4s, only D) both the 3d and 4s 98. Which set has elements with atomic radii which are nearly identical? 92. Consider the melting points of Group VIIA elements. A) C, P, Se, I C) Cr, Mn, Fe, Co E) Ne, Ar, Kr, Xe B) Be, B, C, N D) Mg, Ca, Sr, Ba 99. The element with the electron structure [Rn] 7s 2 6d1 5f5 is a member of the series of elements called the A) rare earths. C) lanthinides. E) chalcogens. B) noble gases. D) transuraniums. 100. The most colorful solids are the Which value would be a reasonable prediction for the melting point of astatine, 85As? A) –150°C B) –50°C C) 50°C D) 100°C 93. The first ionization energy of 33As is 987 the first ionization energy for 34Se is A) B) C) D) E) kJ•mol–1. A) iodides C) chromates E) chlorides E) 200°C The expected 101. The radii of the atoms become smaller when comparing sodium to chlorine in Period 3. This is primarily as a result of equal to that of arsenic larger than that of arsenic smaller than that of arsenic unrelated to that of arsenic undeterminable from the information given 94. An atom in the ground state with eight valence electrons is most likely classified as a(n) A) halogen C) active metal E) chalcogen H-Chem B) bromides D) phosphates A) B) C) D) E) the shielding effect increased nuclear charge decreased metallic character the increased number of electrons increased number of filled orbitals 102. Which is a correct periodic trend in properties when comparing Group IA to Group VIIA elements? B) noble gas D) inactive metal A) B) C) D) E) Page 8 increase in atomic volume decrease in electronegativity decrease in ionization energy decrease in metallic character decrease in nuclear charge Dr. Powell 103. I. An aqueous solution of potassium chromate is colored 107. I. Aluminum and phosphorous exhibit different chemical properties BECAUSE BECAUSE II. a transition metal is present. II. they are in the same period. A) B) C) D) I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I A) B) C) D) I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I 104. I. Krypton is more likely than neon to react with fluorine 108. I. It is easier to remove the outermost electron from sodium than from magnesium BECAUSE II. Neon is a Noble gas. BECAUSE II. the magnesium atom has a larger radius. A) B) C) D) I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I A) B) C) D) I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I 105. I. Oxygen has a lower first ionization energy than fluorine BECAUSE 109. I. The second ionization energy is larger than the first for any given atom II. oxygen has fewer protons in its nucleus. BECAUSE A) B) C) D) I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I II. it is harder to remove a second electron from an atom. A) B) C) D) I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I 106. I. A sodium atom becomes a positive ion when it loses an electron BECAUSE 110. I. Ionic radii decrease across a period II. electrons have a positive charge. BECAUSE A) B) C) D) I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I H-Chem Page 9 II. atomic radii decrease across a period. A) B) C) D) I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I Dr. Powell