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HYDROCARBONS
I & II
PHENOLS
ALCOHOLS &
ETHERS
1. During electrophilic substitution of
benzene the intermediate species
benzene,
involved is
a) Carbanion
b) Carbocation
c)) Free radical
d)) none of these
Carbocation, since benzene
is electron rich
ANSWER: b
2 In the reaction
2.
FeCl3
C6H6 + Cl2 ⎯⎯⎯→ C6H5Cl + HCl
( chlorobenzene)
The attacking reagent is
a) Cl2
b) Cl+
c) Cl
d) FeCl4
Chorination of benzene takes
place through the attack by Cl+
(chloronium ion)
ANSWER: b
3. Methyl bromide when heated with
zinc in a closed tube produces
a) methane
b) ethane
c)) ethyne
th
d) methanol
th
l
This iis a W
Thi
Wurtz
t type
t
reaction.
ti
Instead of sodium, other metals
such as Ag, Cu, Zn can also be
used in finely divided state.
ANSWER: b
4. During
g the preparation of ethane by
y
Kolbe’s electrolytic method using inert
electrodes the pH of the electrolyte
a) increases progressively as the
reaction proceeds
b) decreases progressively as the
reaction
ti proceeds
d
c) remains constant throughout the
reaction
d) may decrease if the concentration of
the electrolyte is not very high
During
D
i the
th preparation
ti off ethane
th
by
b
Kolbe’s electrolytic method using inert
electrodes the pH of the electrolyte
2CH3COONa
COONa+ 2H2O
O⎯Electrolysis
Electrolysis →
CH3 – CH3 + 2CO2 + H2 + 2NaOH
Since NaOH is formed, the pH increases
p
As the proceeds.
ANSWER: a
5. Nitrobenzene can be prepared from
benzene by using a mixture of conc.
HNO3 and conc.
conc H2SO4 In the
nitrating mixture, HNO3 acts as a
a) base
b) acid
c) reducing agent d) catalyst.
HNO3 acts as base as it provides–OH¯
H2SO4 ⎯→H
→H+ + HSO4¯
O2N – OH + H+ ⎯⎯⎯→NO2+ + H2O
ANSWER: a
6 When
6.
Wh a mixture
i t
off methane
th
and
d
oxygen is passed through heated
molybdenum
l bd
oxide,
id the
th main
i
product formed is
a)) methanoic
th
i acid
id b) ethanal
th
l
c) methanol
d) methanal
MoO
CH4 + O 2 ⎯⎯→ HCHO + H2O
550K
ANSWER: d
7. which of the following can’t be
used in Friedal-Crafts
Friedal Crafts reactions?
a) FeCl3
b) BF3
c) AlCl3
d) NaCl
Friedal-Crafts
Friedal
Crafts alkylation reaction
require Lewis acid catalysts and
but NaCl is not a Lewis acid
acid.
ANSWER: d
8. Which one of the following has
the minimum boiling point?
a) n-Butane
b) Isobutane
c) 1-Butene
d) 1- Butyne
Boiling points follow the order
alkyne > alkene > n-alkane >
branched alkane
alkane.
ANSWER: b
9 On mixing certain alkane with chlorine
9.
and irradiating it with ultraviolet light,
it forms only one monochloroalkane.
The alkane is:
a) isopentane b) neopentane
c)) p
propane
p
d)) p
pentane
Neopentane (CH3)4C is a symmetrical
alkane
lk
and
d gives
i
only
l one
monoalkane derivative.
ANSWER: b
10. Pure methane can be produced by
a) Wurtz reaction
b) Kolbe’s electrolytic method
c)) Soda-lime
S d li
d
decarboxylation
b
l ti
d) reducetion with H2
sodalime
CH3COONa
COON + NaOH
N OH ⎯⎯→ CH4+ Na
N 2CO3
∆
ANSWER: c
11 Which of the following species
11.
participate in sulphonation of
b
benzene
ring?
i ?
a) H2SO4
b) HSO3
c) SO3
d) SO2
In sulphonation of benzene,
the species which attack benzene
ring is SO3
ANSWER : c
12. A gas decolourises alkaline
KM O4 solution
KMnO
l ti but
b t does
d
nott
give precipitate
g
p
p
with AgNO
g
3. It is
a) CH4
b) C2H4
c) C2H2
d) C2H6
ANSWER: b
As C2H4 (alkene) is not acidic in
nature therefore,
nature,
therefore it does not give
any precipitate with AgNO3.
However it is oxidized with dilute
However,
alkaline KMnO4 (Baeyer’s reagent)
to glycol
CH2
Alk KMnO4
Alk.KMnO
+ H2O + O ⎯⎯⎯⎯→
CH2
CH2OH
⎪
CH2OH
13. In its reaction with silver
nitrate
it t acetylene
t l
shows
h
a)
b))
c)
d)
Oxidising property
Reducing
g property
p p y
Basic proerty
Acidic property
The reaction of silver nitrate with
acetylene shows its acidic nature
CH
⎪⎪⎪ + 2AgNO3 + 2NH4OH ⎯→
→
CH
C Ag
C.Ag
⎪⎪⎪ + 2NH4NO3+2H2O
C Ag
C.Ag
Silver acetylide
ANSWER d
ANSWER:
14. Benzene is obtained by
fractional distillation of
a) Heavy oil
b) Anthracene oil
c) Middle oil
d) Light oil
Benzene is obtained by the
Fractional distillation of light oil.
oil
Answer: d
15 The function of AlCl3 in Friedal
15.
Craft’s reaction is
a) to absorb water
b) to absorb HCl
c) to produce electrophile
d) to produce nucleophile
AlCl3 produces attacking electophile
as follows
o o s AlCl
C 3+Cl-Cl
C C ⎯⎯→
→ AlCl
C 4+ C
Cl+
ANSWER: c
16 Benzene
16.
B
d
does nott undergo
d
addition reaction easily because
a)) It has
h a cyclic
li structure
t
t
b) Double bonds in it are very strong
c)) Resonance
R
stabilised
t bili d system
t
iis to
t
be preserved
d) It has
h six
i hydrogen
h d
atoms
t
Benzene is resonance stabilised and as
such resistant to addition reactions.
ANSWER: c
17. The presence of unsaturation in
17
organic compounds can be tested with
a) Schiff
Schiff’s
s reagent
b) Tollen’s reagent
c)) Fehling’s
F hli ’ reagentt
d) Baeyer’s reagent.
Presence of unsaturation in organic
compounds can be tested with Baeyer
Baeyer’s
s
reagent.
ANSWER d
ANSWER:
18. Reactions of alkanes with halogens
is explosive in case of
a) F2
b) Cl2
c) Br2
d) I2
Reaction of alkanes with F2 is explosive.
ANSWER: a
19. Most common reactions of benzene
and its derivatives are
a) Elecrophilic addition reactions
b) Electrophilic stustitution reactions
c) Nucleophilic addition reactions
d) Nucleophilic substitution reactions.
Benzene give electrophilic
substitution reactions.
ANSWER: b
20 The most reactive hydrocarbon is
20.
a) Ethene
b) Ethyne
c) Ethane
d) Methane
Alkynes are less reactive than alkenes.
ANSWER: a
21 To a mixture of fuming HNO3 and
21.
conc. H2SO4, benzene was added.
This mixture was heated for
f long
time at 100°C. The main product is
a) C6H5NO2
b) C6H5SO3H
c) 1,3,5-trinitrobenzene
d) m-Dinitrobenezene
m Dinitrobenezene
ANSWER: c
22 Vulcanized
22.
V l
i d rubber
bb resists
i t
a) Jerking motion
b) cold temperature
c)) chemical corrosion
d) wear and tear due to friction.
Vulcanized rubber has lot of cross
bonding between polymer chains by
sulphur cross links
links. Hence it becomes
strong and resistant to wear and tear.
ANSWER d
ANSWER:
23. In Buna-S, the symbol Bu
stands for
a) 1-Butene
b) n-Butane
c) 2-Butene
d) Butadiene
In Buna-s,, Bu stands for butadiene
and S stands for styrene.
ANSWER: d
24 The catalyst used in the manufacture
24.
of polyethene by Zeigler method is
a)) Titanium
Tit i
tetrachloride
t t hl id and
d
triphenyl aluminium
b) Titanium tetrachloride and
triethyl aluminium
c) Titanium dioxide
d)) Titanium isoperoxide
p
ANSWER: b
25. Which is most strained cycloalkane?
y
a) Cyclohexane
b) Cyclopropane
C l
c) Cyclobutane
d) Cycloctane
ANSWER: b
26 Most stable conformation of
26.
cyclohexane is
a) Planar chair conformation
b)) Non p
planar chair conformation
c) Planar boar conformation
d) Non planar board conformation.
conformation
To minimize the angle strain
cyclohexane assumes two non planar
structures-Boat and Chair forms. In
chair form there is least repulstion.
Hence most preferred conformation of
cyclohexane is chair conformation
which is non planer.
ANSWER: b
27 According to Baeyer
27.
Baeyer’s
s strain
theory which among the
f ll i is
following
i highly
hi hl stable?
t bl ?
a) Cyclohexane
b) Cycloheptane
c) Cyclopentane
d) None of these
Angle stain in cyclopentane is
minimum and hence is highly stable.
ANSWER c
ANSWER:
28. Which of the following
reagents
g
can react with phenol
p
to produce phenolphthalein ?
a) phthalic anhydride / H2SO4
b) ethanoic anhydride / H2SO4
c) CO2, CCl4
d) Potassium phthalimide
Phthalian fusion test
ANSWER: a
29. The most acidic compound
among
g the following
g is
a) phenol
b) m
m-cresol
cresol
c) p-Nitrophenol
d) Picric acid
Picric acid
ANSWER: d
30. Identify
y the p
product Z in the
following sequence of reaction
NaOH
Phenol ⎯⎯⎯→ X
CO2, 4
4-7atm,
7atm,
⎯⎯⎯→
410 K
H3O +
Y
⎯⎯⎯→ Z
a) aspirin
b) salicylaldehyde
c) benzoic acid d) salicylic acid
acid.
Kolbe’s Schmidt reaction.
ANSWER d
ANSWER:
31 Phenol,
31.
Phenol p-Methyphenol,
p Methyphenol m-Nitrophenol
m Nitrophenol
and p-Nitrophenol follows order
of increasing acidic strength
a) Phenol, p-Methylphenol, p-Nitrophenol,
m-Nitrophenol
b) p-Methylphenol, Phenol, m-Nitrophenol,
p
p-Nitrophenol,
p
,
c) p-Methylphenol, m-Nitrophenol,Phenol,
p-Nitrophenol,
d) m-Nitrophenol
Nit
h
l p-Nitrophenol,
Nit
h
l Phenol,
Ph
l
p-Methylphenol,
ANSWER: b.
32.
Inorder to get Bakelite from
phenol which of the following
p
g
reagent is required?
a)
b))
c)
d))
HCHO
CHCl3 / NaOH
CCl4 / NaOH
HCHO / H+ or OH
HCHO / H+ or OH
ANSWER: d
33. Phenol is more readily soluble in
a) dil. HCl
b) Both
B th NaOH
N OH and
d HCl
c) NaOH sol
d) Sodium
Sodi m bicarbonate solution.
sol tion
since it is very weak acid is
soluble in NaOH solution.
ANSWER: c
34 Carbolic acid is
34.
a)) aqueous
q
solution of phenol
p
b) phenyl benzene
c) phenyl acetate
d) Salol
aqueous solution
l ti off phenol
h
l
ANSWER: a
35. Organic acid without a
carboxylic
ca
bo y c g
group
oup is
s
a)
b)
c)
d)
ascorbic acid
vinegar
i
oxalic acid
picric
i i acid
id
Picric acid is 2
2,4,6-Trinitrophenol.
4 6-Trinitrophenol
ANSWER: d
36 Salicylaldehyde can be prepared
36.
from
a) Phenol and chloroform
b) Phenol, chloroform and
sodium hydroxide
c) Phenol, carbon tetrachloride
and NaOH
d) None
Phenol,
Ph
l chloroform
hl
f
and
d sodium
di
hydroxide , Reimer – Tiemann’s reaction.
ANSWER: b
37 Phenol is treated with bromine water
37.
and shaken well to get white
precipitate.
i it t The
Th white
hit precipitate
i it t is
i
a) 1-Bromophenol
b) 2,4,6-Tribromophenol
2 4 6 T ib
h
l
c) 2,4-Dibromophenol
d) Mixture of o- and p-bromophenol
Bromination of phenol in aqueous
medium gives 2,4,6-Tribromophenol.
ANSWER: b
38. Cumene is the compound used
for commercial preparation of
phenol. Chemically cumene is
a) Isopropyl benzene
b) ethyl benzene
c) n-propylbenzene
n propylbenzene
d) None of above
isopropyl benzene
ANSWER: a
39. Hybrid state of central
oxygen atom in ether is
a)
2
sp
c) sp
ANSWER : b
b)
3
sp
d) sp3d
40 Oxygen atom in ether is :
40.
a)
b)
c)
d)
very active
replaceable
active
comparatively inert.
The divalent oxygen is linked
g y to C–atoms on both sides
strongly
and there are no active sites like OH,
C=O etc. in it.
ANSWER: d
41. Which of the following
p
is used as
compounds
an anesthesia?
a)
b)
c))
d)
ethyl alcohol
acetic acid
di th l ether
diethyl
th
acetic anhydride
ANSWER: c
42. When diethyl ether is treated
with excess of Cl2 in the
presence of sunlight,
sunlight the
product formed is :
a) CH3CHCl–O–CH2CH3
b) CH3CHCl
CHCl–O–CHClCH
O CHClCH3
c) CCl3CCl2–O–CCl2CCl3
d) CH3CCl2 –O– CHClCH3.
ANSWER: c
ANSWER
43. An ether is more volatile than an
alcohol having the same molecular
formula. This is due to
a)
b)
c)
d)
dipole character of ethers
alcohols having resonance
structure
inter-molecular hydrogen
bonding in ethers
inter- molecular hydrogen
bonding in alcohols.
Alcohols have stronger
g inter
molecular bonding ( H-bonding)
and
d ethers
th
have
h
weaker
k
intermolecular bonding
(vander Waals).
ANSWER: d
44. All alcohols are
a)
b)
c)
d)
completely soluble in water
ionized in water
not soluble in water
soluble organic solvents
All alcohols are not soluble in water.
Alcohols with large size of RR are
almost immiscible with water.
ANSWER: c
45. Power alcohol is a mixture of
petrol and alcohol in the ratio of
a))
4:1
b) 1 : 4
c)
2:1
d) 1 : 2
4 : 1 ( 80% petrol and 20 % alcohol)
ANSWER: a
46. Widespread deaths due to liquor
poisoning is because of
a)
b)
c)
d)
presence of bad compound
in liquor
presence of methyl alcohol
presence of ethyl alcohol
presence of carbonic acid.
ANSWER: b
47.
The dehydration of butane–1–ol gives
a)
b)
c)
1 – butene as the main product
2 – butene as the main product
equal amounts of 1 – butene
and 2 – butane
d) 2 – methyl propene.
propene
The dehydration of 1–butanol gives
2 b t
2–butene
as the
th main
i product
d t
because 2° carbocation is stabler than 1°
ANSWER b
ANSWER:
48.
Rectified spirit can be converted
into absolute alcohol by
a) Fractional distillation
b) steam distillation
c)) cannott be
b converted
t d
d) by putting rectified spirit in
contact with quick lime
followed by
y distillation.
Quick lime has stronger affinity for water.
ANSWER: d
49. Which one is primary alcohol ?
a)
b)
c)
d)
Buten –2–ol
propan–2–ol
Butan–1– ol
2,3–Dimethylhexane–4–ol.
H3C–CH2–CH2–CH2–OH
Butan–1–ol.
ANSWER: c
50 In reaction of alcohols with alkali
50.
metal, which of the following
alcohol will react fastest ?
a) secondary
b) tertiary
c) primary
d) all equal
Primary alcohol because the reaction
Involves cleavage of strongest acidic
group (O – H) of various types of
alcohols
alcohols.
ANSWER: c
51. Primary and secondary alcohols
on action of red hot copper give
a) Aldehydes and ketones
respectively
b) Ketones and aldehydes
respectively
c)) Only
O l aldehydes
ld h d
d) Only ketones.
51. Primary and secondary alcohols
on action of red hot copper give
RCH2OH with Cu at 573K gives
RCHO and R2CHOH gives R2CO
ANSWER: a