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Fall 2012 Chem106 Final Review Name: Test 1 Materials Question 1. How Many significant figures does each of the following numbers have? 34.22 0.030345 2.0030 5.04x103 34030 Question 2. Which label on the periodic table best represents the following: A C B D Alkali Metals Metalloids Halogens F G E Nonmetals Noble Gases Question 3. Fill in the Symbol, Atomic Number (AN), Number of Protons(NP), Number of Neutrons(NN), Mass Number (MN) and Number of Electron (NE) for each of the following? Symbol AN NP NN MN NE 15 N 20 26 238 U 96 44 Question 4. What’s the half-life of a material that decays to 12.5% of its original mass in 24 days? a) 3 days b) 8 days c) 16 days d) 12 days Question 5. The half-life for the radioactive decay of barium-137 is 2.5 minutes. If a sample of has an initial activity of 10564.0 μCi, what is the activity of the sample after 15 minutes? a) 82.5313μCi b) 165.063 μCi c) 0 μCi d) 330.125 μCi Question 6. If the half-life of a radioactive element is 8 years, what percentage of the original sample would be left after 32 years? a) 6.25% b) 3.125% c) 12.5% d) 0.064% Question 7. If Pu-238 loses an alpha particle what element is formed? 234 242 a) U b) Cm 238 238 c) U d) Pu Question 8. Absorbing a neutron will have what affect on the nucleus? a) increase atomic mass # by 2 a) increase atomic mass # by 1 a) decrease atomic mass # by 2 a) decrease atomic mass # by 1 Question 9. If the density of a liquid is 1.07g/mL, what volume does 32.4 g of it have? a) 30.28 mL b) 30.3 mL c) 34.7 mL d) 0.0330 mL Question 10. Which element has the smallest Atomic Radius? a) Ti b) V c) Mn d) Zn Question 11. What is the density of a liquid that has a volume of 34.6 mL and a mass of 39.67 g? a) 1.147 g/mL b) 1.00 g/mL c) 1.15 g/mL d) 0.872 g/mL Question 12. What does the metric prefix μ mean? a) 103 b) 10-3 c) 106 d) 10-6 Question 13. Which form of radiation is the most dangerous? a) alpha particle b) beta particle c) positron d) gamma radiation Question 14. Given that TF= 1.8TC +32, what is 344.8◦F in Kelvin and Celsius? Question 15. Write the long form electron configuration, abbreviated electron configuration, the number of valence electrons, and the electron dot symbol for the following: a) P b) N c) C Question 16. Convert the following: a) Given that 2.20 lbs. are in 1 kg, and there are 16 ounces in a lb., how many kg are in 242.3 oz? b) Convert 5.657x105 mL to ML. c) 4.65x107 sec to years. Question 17. How many Cal. and kJ are in a food item that has 2.5g of fat, 8.5g of carbohydrates, and 3.5g of protein(Fat = 9Cal/g, Prot and Carb = 4 Cal/g)? Question 18. What will the final temperature be if 237500 Joules are used to heat 685.0g of water initially at 2.5◦C (Heat = Mass x ∆T x Specific Heat; Specific Heat of water = 4.184J/g◦C)? Test 2 Materials Question 1. Draw the electron dot formulas for the following: a) NCl2H (N is central atom) b)CO2 (1 N is central atom) c) For the compounds in question #5, give the number of electron groups, the electronic geometry and the molecular shape of the molecules. Compound Electron Groups Electron Molecular Group Shape Arrangement SCl2H CO2 Question 2. Write the molecular formula for the following names: a) Lead (IV) Sulfide b) Molybdenum (V) Phosphate c) Barium Phosphide d) Ruthenium (III) sulfide Question 3. Name the following covalent compounds: a) PO3 b) F2S3 Question 4. The combustion of natural gas, CH4 is very important in energy production: a) What is the balanced chemical equation for the combustion of natural gas? b) If 25.5g of CH4 and 65.2g of O2 are burned, what is the limiting reactant? c) How much water is produced(in grams)? d) What is the percent yield if only 18.5g of H2O are collected? Question 5. Consider the reaction: Zn(s) + 2HCl(aq) → H2(g) + ZnCl2(aq) a) What type of reaction is it? b) What species is being reduced and what is being oxidized? Question 6. Consider the Molecule VO(H2PO4)2: a) What is its Molar Mass? b) How many moles are in 234.5g of it? c) How many moles are 8.36x1022 molecules? d) How many H atoms are in 1 molecule of it? e) How many O atoms are in 7.35 moles? Question 7. Write the Balanced Formulas for the following Anions and Cations: O2CO32N3FSr2+ Mo4+ V5+ Na+ Fe3+ Question 8. What is the pressure (in mmHg) of a gas that occupies 1.345x108μL, has a temperature of 67.3◦C and contains 1.76 moles of N2? Question 9. At standard temperature and pressure (STP), how many moles of N2 occupy 5.83x10-3ML? Question 10. A container of Xe gas at -23◦C occupies 3.45L at a pressure of 2.45atm. What volume (in L) does it occupy at 72◦C at a pressure of 657mmHg? Question#11 How many moles of oxygen can be produced from one mole of KClO3 in the reaction: 2KClO3→2KCl + 3O2? a) 1 mol c) 2 mol b) 1.5 mol d) 3 mol Question#12 The number of C atoms in 0.500 mole of C is_______. a) 2.50 × 1023 C atoms b) 3.01 × 1023 C atoms c) 5.01 × 1023 C atoms d) 6.00 × 1023 C atoms Question#13 How many moles of O atoms are there in 2 moles of glucose: (C6H12O6)? a) 2 moles b) 24 moles c) 6 moles d) 12 moles Question#14 What is the molar mass of S3 if the molar mass of sulfur is 32.0? a) 64 g b) 32 g c) 96 g d) 10.7 g Question#15 What is the percent yield if 50 g of CO2 were collected and 200g were expected? a) 50% b) 25% c) 75% d) 100% Question#16 Which of the following reactions can be classified as decomposition? a) CuCO3 (s) → CuO (s) + CO2 (g) b) 4Fe (s) + 3O2 (g) → 2Fe2O3 (s) c) Mg (s) + 2AgNO3 (aq) → Mg(NO3)2 (aq) + 2Ag (s) d) NaOH (aq) + HCl (aq) → NaCl (aq) + H2O (l) Question#17 What is the correct name of the ionic metal compound: AuCl3? a) gold chloride b) gold trichloride c) gold (III) chloride d) gold (III) trichloride Question#18 What is the name of the covalent compound: S3Cl5? a) Sulfur chloride b) Sulfur hexachloride c) Trisulfur chloride d) Trisulfur pentachloride Question#19 What is the correct formula for Chromium (VI) hydroxide? a) Cr(OH)3 b) Cr(OH)6 c) CrOH6 d) Cr6OH Question#20 How many electrons were lost by Pb in Lead (IV) chloride? a) 4 b) 5 c) 0 d) 6 Test 3 Materials 1. A patient receives 250 mL of a 4% (m/v) mannitol solution every hour. The number of grams of mannitol is_______. a) 8 b) 10 c) 15 d) 20 2. Write the balanced equation for dissociating the following solid ionic salts in water: a) Na2CO3(s) b) (NH4)3PO4(s) 3. (15pts) Which of the following reaction has a precipitate. Use the solubility rules and predict the products, if there is an insoluble product then write the total ionic equation and the net ionic equation for the reaction. a) KNO3(aq) + Na2SO4(aq) or b) (NH4)2SO4(aq) + Ca(NO3)2(aq) 4. How many grams of a solution of 1.760%(m/m) Na2S can be made with a starting Na2S mass of 6.278 g? 5. How many liters of a 1.250 M HCl solution will react with 13.68g of Na? Na(s) +2HCl(aq) → H2 (g) + 2NaCl(aq) 6. Write the balanced equation for the neutralization reaction between the following acid/base pairs: a) Mg(OH)2 + H2SO4 b) Al(OH)3 + H2CO3 7. Calculate the [H3O+] or the pH of the following solutions, and say wither the solution is acidic, basic, or neutral: a) pH= 5.352 b) [H3O+] = 0.006001 M 8. What volume of a 0.0150M HCl solution would be neutralized by 32.25 mL of a 0.020M NaOH solution?