Survey
* Your assessment is very important for improving the workof artificial intelligence, which forms the content of this project
* Your assessment is very important for improving the workof artificial intelligence, which forms the content of this project
Isotopic labeling wikipedia , lookup
Two-dimensional nuclear magnetic resonance spectroscopy wikipedia , lookup
Nuclear fission wikipedia , lookup
Nuclear transmutation wikipedia , lookup
Radioactive decay wikipedia , lookup
Nuclear fusion wikipedia , lookup
Valley of stability wikipedia , lookup
Nuclear binding energy wikipedia , lookup
Plan for Today (AP Physics 2) • Lecture/Notes on Decay Rates and HalfLife • Half life multiple choice practice Size of Nuclei • Rutherford first investigated • Using conservation of energy – how close an alpha particle could get to the nucleus before being turned around (KE to electrical PE) Size of Nuclei New Unit • Femtometer (fm) AKA Fermi • 1 fm = 10^-15 m Radius of Nuclei • All nuclei have nearly the same density Nuclear Force • AKA strong force • It’s what’s holding the nucleus together (protons would want to repel each other) • Short range (around 2 fm) • Protons and neutrons attract each other via this nuclear strong force • Much stronger than coulomb repulsive force at short distances Stable Nuclei • Around 260 stable nuclei • Light nuclei most stable if they have about equal numbers of protons and neutrons (N = Z), heavy nuclei need more neutrons than protons • More neutrons needed to “dilute” nuclear charge density • With Z = 83, no more stable nuclei – repulsive forces between protons can’t be compensated for by neutrons Stability Curve A stable nucleus remains forever, but as the ratio of N/Z gets larger, the atoms decay. Elements with Z > 82 are all unstable. 140 Neutron number N Nuclear particles are held together by a nuclear strong force. 120 100 Stable nuclei 80 60 40 Z=N 20 20 40 60 80 100 Atomic number Z Mass • It is convenient to use unified mass units, u, to express masses – 1 u = 1.660 559 x 10-27 kg – Based on definition that the mass of one atom of C-12 is exactly 12 u • Mass can also be expressed in MeV/c2 – From ER = m c2 – 1 u = 931.494 MeV/c2 Atomic Mass Unit, u One atomic mass unit (1 u) is equal to onetwelfth of the mass of the most abundant form of the carbon atom--carbon-12. Atomic mass unit: 1 u = 1.6606 x 10-27 kg Common atomic masses: Proton: 1.007276 u Neutron: 1.008665 u Electron: 0.00055 u Hydrogen: 1.007825 u Exampe 2: The average atomic mass of Boron-11 is 11.009305 u. What is the mass of the nucleus of one boron atom in kg? 11 5 B = 11.009305 Electron: 0.00055 u The mass of the nucleus is the atomic mass less the mass of Z = 5 electrons: Mass = 11.009305 u – 5(0.00055 u) 1 boron nucleus = 11.00656 u 1.6606 x 10-27 kg m 11.00656 u 1 u m = 1.83 x 10-26 kg Mass and Energy Recall Einstein’s equivalency formula for m and E: E mc ; c 3 x 10 m/s 2 8 The energy of a mass of 1 u can be found: E = (1 u)c2 = (1.66 x 10-27 kg)(3 x 108 m/s)2 E = 1.49 x 10-10 J When converting amu to energy: Or E = 931.5 MeV c 931.5 2 MeV u Example 3: What is the rest mass energy of a proton (1.007276 u)? E = mc2 = (1.00726 u)(931.5 MeV/u) Proton: E = 938.3 MeV Similar conversions show other rest mass energies: Neutron: E = 939.6 MeV Electron: E = 0.511 MeV Example 3: What is the rest mass energy of a proton (1.007276 u)? E = mc2 = (1.00726 u)(931.5 MeV/u) Proton: E = 938.3 MeV Similar conversions show other rest mass energies: Neutron: E = 939.6 MeV Electron: E = 0.511 MeV Summary of Masses Masses Particle kg u MeV/c 2 Proton 1.6726 x 10-27 1.007276 938.28 Neutron 1.6750 x 10-27 1.008665 939.57 Electron 9.109 x 10-31 5.486x10-4 0.511 The Mass Defect The mass defect is the difference between the rest mass of a nucleus and the sum of the rest masses of its constituent nucleons. The whole is less than the sum of the parts! Consider the carbon-12 atom (12.00000 u): Nuclear mass = Mass of atom – Electron masses = 12.00000 u – 6(0.00055 u) = 11.996706 u The nucleus of the carbon-12 atom has this mass. (Continued . . .) Mass Defect (Continued) Mass of carbon-12 nucleus: 11.996706 Proton: 1.007276 u Neutron: 1.008665 u The nucleus contains 6 protons and 6 neutrons: 6 p = 6(1.007276 u) = 6.043656 u 6 n = 6(1.008665 u) = 6.051990 u Total mass of parts: = 12.095646 u Mass defect mD = 12.095646 u – 11.996706 u mD = 0.098940 u Mass and Energy • Total mass of a nucleus is always less than the sum of the masses of nucleons • Total energy of the nucleus is less than the combined energy of the separated nucleons • Binding energy – difference in these energies, energy that must be added to break a nucleus apart The Binding Energy The binding energy EB of a nucleus is the energy required to separate a nucleus into its constituent parts. EB = mDc2 where c2 = 931.5 MeV/u The binding energy for the carbon-12 example is: EB = (0.098940 u)(931.5 MeV/u) Binding EB for C-12: EB = 92.2 MeV Binding Energy per Nucleon An important way of comparing the nuclei of atoms is finding their binding energy per nucleon: Binding energy EB = MeV per nucleon A nucleon For our C-12 example A = 12 and: EB 92.2 MeV MeV 7.68 nucleon A 12 Formula for Mass Defect The following formula is useful for mass defect: Mass defect mD mD ZmH Nmn M mH = 1.007825 u; mn = 1.008665 u Z is atomic number; N is neutron number; M is mass of atom (including electrons). By using the mass of the hydrogen atom, you avoid the necessity of subtracting electron masses. Example 4: Find the mass defect for the He nucleus of helium-4. (M = 4.002603 u) 4 2 Mass defect mD mD ZmH Nmn M ZmH = (2)(1.007825 u) = 2.015650 u Nmn = (2)(1.008665 u) = 2.017330 u M = 4.002603 u (From nuclide tables) mD = (2.015650 u + 2.017330 u) - 4.002603 u mD = 0.030377 u Example 4 (Cont.) Find the binding energy per nucleon for helium-4. (mD = 0.030377 u) EB = mDc2 where c2 = 931.5 MeV/u EB = (0.030377 u)(931.5 MeV/u) = 28.3 MeV A total of 28.3 MeV is required To tear apart the nucleons from the He-4 atom. Since there are four nucleons, we find that EB 28.3 MeV 7.07 A 4 MeV nucleon Curve shows that EB increases with A and peaks at A = 60. Heavier nuclei are less stable. Green region is for most stable atoms. Binding Energy per nucleon Binding Energy Vs. Mass Number 8 6 4 2 50 100 150 200 250 Mass number A For heavier nuclei, energy is released when they break up (fission). For lighter nuclei, energy is released when they fuse together (fusion). Radioactive Materials The rate of decay for radioactive substances is expressed in terms of the activity R, given by: Activity N R t N = Number of undecayed nuclei One becquerel (Bq) is an activity equal to one disintegration per second (1 s-1). One curie (Ci) is the activity of a radioactive material that decays at the rate of 3.7 x 1010 Bq or 3.7 x 1010 disintegrations per second. Units • The unit of activity, R, is the Curie, Ci – 1 Ci = 3.7 x 1010 decays/second • The SI unit of activity is the Becquerel, Bq – 1 Bq = 1 decay / second • Therefore, 1 Ci = 3.7 x 1010 Bq • The most commonly used units of activity are the mCi and the µCi The Decay Constant • The number of particles that decay in a given time is proportional to the total number of particles in a radioactive sample – ΔN = -λ N Δt • λ is called the decay constant and determines the rate at which the material will decay • The decay rate or activity, R, of a sample is defined as the number of decays per second N R N t The half-life T1/2 of an isotope is the time in which onehalf of its unstable nuclei will decay. 1 N N0 2 n Where n is number of half-lives Number Undecayed Nuclei The Half-Life No N0 2 N0 4 1 2 3 4 Number of Half-lives Decay Curve • The decay curve follows the equation – N = No e- λt • The half-life is also a useful parameter – The half-life is defined as the time it takes for half of any given number of radioactive nuclei to decay T1 2 ln 2 0.693 Half-Life (Cont.) The same reasoning will apply to activity R or to amount of material. In general, the following three equations can be applied to radioactivity: Nuclei Remaining 1 N N0 2 n Mass Remaining 1 m m0 2 n Activity R 1 R R0 2 n Number of Half-lives: t n T12 Example 6: A sample of iodine-131 has an initial activity of 5 mCi. The half-life of I-131 is 8 days. What is the activity of the sample 32 days later? First we determine the number of half-lives: t 32 d n T1/ 2 8d n 1 1 R R0 5 mCi 2 2 n = 4 half-lives 4 R = 0.313 mCi There would also be 1/16 remaining of the mass and 1/16 of the number of nuclei. Conservation Laws For any nuclear reaction, there are three conservation laws which must be obeyed: Conservation of Charge: The total charge of a system can neither be increased nor decreased. Conservation of Nucleons: The total number of nucleons in a reaction must be unchanged. Conservation of Mass Energy: The total massenergy of a system must not change in a nuclear reaction. Example 7: Use conservation criteria to determine the unknown element in the following nuclear reaction: 1 1 H Li He X energy 7 3 4 2 A Z Charge before = +1 + 3 = +4 Charge after = +2 + Z = +4 Z=4–2=2 (Helium has Z = 2) Nucleons before = 1 + 7 = 8 Nucleons after = 4 + A = 8 1 1 (Thus, A = 4) H Li He He energy 7 3 4 2 4 2 Summary (Radioactivity) The half-life T1/2 of an isotope is the time in which one-half of its unstable nuclei will decay. Nuclei Remaining 1 N N0 2 n Mass Remaining 1 m m0 2 n Activity R 1 R R0 2 n Number of Half-lives: t n T12