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Chapter 3 Fill-in-the blank 1. The water molecule is a______________________ covalent molecule: The opposite ends of H2O have opposite charges. 2. Since oxygen is very ________________________________________, it attracts the shared e- more than hydrogen does….so, the e- spend more time near the oxygen nucleus than the hydrogen nucleus. 3. Because the electrons are held closer to the oxygen, it has a partial _______________________ charge and the hydrogen has a partial _______________________ charge. 4. ___________________________ allows water molecules to form hydrogen bonds with each other. 5. List 4 emergent properties of water (these are ALL a result of ______________________ bonding between H 2O molecules): 6. Hydrogen bonds hold water molecules close together, a phenomenon called __________________________. 7. ________________________ is an attraction between different substances, for example, between water and plant cell walls. 8. ________________ ______________________________ is a measure of the force necessary to stretch or break the surface of a liquid, and is related to cohesion. 9. Water can absorb or release a large amount of heat with only a _____________________ change in its own temperature. 10. Atoms and molecules are always in motion. ________________________ energy is the energy of motion. _____________ is a measure of the total amount of kinetic energy due to molecular motion. 11. _______________________________ measures the intensity of heat due to the average kinetic energy of molecules. 12. When two objects of different temperatures come together, heat passes from the ____________ object to the ______________ object until the two are the ______________________- temperature. 13. The ______________________ _____________________ of a substance is the amount of heat that must be absorbed or lost for 1 g of that substance to change its temperature by 1ºC. 14. Water resists changing its temperature because of its ______________ specific heat. 15. A liquid that is a completely homogeneous mixture of two or more substances is called a ________________________. In an ____________________________ solution, water is the solvent. 16. A substance that has an affinity for water is ________________________ (water-loving). Hydrophilic substances are dominated by _________________ or _______________________- bonds. 17. Substances that have no affinity for water are ________________________ (water-fearing). Hydrophobic substances are non____________ and have nonpolar covalent bonds. 18. The actual number of molecules in a mole is called Avogadro’s number, _________________________________. A mole of one substance has the same number of molecules as a mole of any other substance. 19. ________________________is the number of moles of solute per liter of solution. A one-molar (1 M) solution has 1 mole of a substance dissolved in 1 liter of a solvent. 20. Concentrations of H+ and OH– are ________________ in pure water. 21. An __________________ is any substance that increases the H+ concentration of a solution and a ______________ is any substance that reduces the H+ concentration of a solution. 22. Strong acids and bases, like ________________(acid) and ______________________ (base), dissociate completely when mixed with water. 23. [___________] [_________] = 10−14 In a neutral solution, [H+] = ____________ M and [OH−] = ____________ M. 24. Solutions with more OH− than H+ are _________________ solutions; solutions with more H+ than OH- are ______________; solutions in which the concentrations of OH- and H+ are equal are ________________________. 25. The pH (scale = 1 to 14) of a solution is defined by the negative logarithm of H+ concentration, written as: 26. Acidic solutions have pH values __________ than 7, and basic solutions have pH values ___________________ than 7. 27. _________________________ are substances that minimize changes in concentrations of H+ and OH– in a solution. Chapter 4 Fill-in-the blank 1. With _______________valence electrons, carbon can form four covalent bonds with a variety of atoms. Carbon’s tetravalence makes large, complex molecules possible. 2. Hydrocarbons contain only _____________ and _______________ . 3. ____________________ are compounds with the same molecular formula but different structures and properties 4. _______________________ isomers have different covalent arrangements of their atoms, ___________________ isomers have the same covalent arrangements but differ in spatial arrangements, ________________________are isomers that are mirror images of each other. 5. _______________ ____________________ are the components of organic molecules that are most commonly involved in chemical reactions. 6. List the seven chemical groups are most important to the chemistry of life: 7. List the six chemical groups are functional groups. (They are hydrophilic and increase the solubility of organic compounds in water): 8. _____________________________ groups are not reactive but add 3-D shape in organic molecules. 9. Organic compounds with hydroxyl groups (_________) are ______________________, and their names typically end in -ol. 10. A carbonyl group (____________) consists of an oxygen atom joined to the carbon skeleton by a double bond. If the carbonyl group is on the end of the skeleton, the compound is an _______________________. If the carbonyl group is within the carbon skeleton, the compound is a _____________________ 11. A carboxyl group (_______________________) consists of a carbon atom with a double bond to an oxygen atom and a single bond to the oxygen atom of a hydroxyl group. Compounds with carboxyl groups are carboxylic _________________. 12. An amino group (__________________) consists of a nitrogen atom bonded to two hydrogen atoms and the carbon skeleton. 13. Organic compounds with amino groups are ________________________. The amino group acts as a ____________ because it can pick up a hydrogen ion (H+) from the solution. 14. Amino acids, the building blocks of proteins, have _______________ and _____________________ groups . 15. A sulfhydryl group (________________) consists of a sulfur atom bonded to a hydrogen atom and to the backbone. Organic molecules with sulfhydryl groups are _________________. 16. A phosphate group (__________________________) consists of a phosphorus atom bound to four oxygen atoms (three with single bonds and one with a double bond). 17. One function of phosphate groups is to _______________ ______________________ between organic molecules. 18. Adenosine triphosphate, or _________________________, is the primary energy transfer molecule in living cells. 19. A ____________ group (________________) is a chemical group, but it is not a functional group because it is not reactive.