Download dental material_lec5_ 9_3_2011

Dental material
Lec. 5
9-3-2011
Dental Composite
Definition: tooth color restorative material
It has advantages and disadvantages we will talk about them later on.
Application of dental composite
1- Fractured tooth
2- Caries legion
3- Spacing between teeth
Scientifically, it defined as:
Products which consist of two distinct phases normally formed by blending
together result in a compound have different structures and properties.
*note that the sitting reaction of composite is
polymerization.
Composite mean more than one phase or material
*Why do we mix them together?
To achieve some properties this cannot be achieved from either of the
component by itself.
History
They were developed in the 1960s (relatively new) once they evolved they
replaced quickly over the tooth color restorative materials such as fabricate
restoration and acrylic resin restoration.
Fabricate and acrylic resin restoration can be near from normal tooth color
but they are not good as composite.
Nowadays, people turn to use composite than silver filling because they
want to look nicer.
Component of composite:
1-Matrix
2- Fillers
Matrix
- Its resin material
- Its main property is stickiness
- Just to bind the fillers togather
-Help to fix the composite on the tooth structure.
- Its not a cure chemical bonding its a micro-chemical bonding
Fillers
- They are added to the matrix just to reinforce the matrix.
Because the matrix by its self is a weak phase.
* The matrix by its self has 4 different elements:
1234-
principle monomer
diluents monomer
activator /initiator system
Celine coupling agent
* Principle monomer is one of two things:
1- bis GMA (bisphenol A glycidyl methacrylate)
2- UDMA (urethane dimethacrylate)
These the two main monomer we use for the composite
* diluent monomer:
- It dilutes the viscosity of the principle monomer.
Since the principle monomer is very viscous by its self, we need something
to reduce its viscosity. Thus, is achieved by the diluent monomer which is
commonly is TEG DMA (triethylene glycol dimethacrylate)
* The functional group of both the principle and the diluent monomer is
carbon-carbon double bond
Remember! When there is a monomer with
Carbon-carbon double bond, it will turn into single bond through
polymerization.
* Activator/ initiator system
They are 2 different ways to initiate the polymerization:
1- Light cure system
2- Chemical cure system
(we will talk about them later on)
* Celine coupling agents:
- Its aim is to bind the fillers to the matrix
*Polymerization reactions:
They are two types of reaction:
1- additional polymerization: the double bond is change into single bond
but there is no byproduct
2- condensation polymerization: the double bond is released with a
byproduct
advantages of the matrix;
1-it’s the moldable phase of the composite. Because it allow the filling
material to take the shape of the tooth or the shape we want it to be
So, the matrix can be shaped but the fillers can't be shaped
3- This moldability is happened at ambient temperature (room
temperature)
Disadvantages of the matrix:
1- matrix phase are many and it’s the weakest phase
2- it has low-wear resistance
Because inside the oral cavity, the teeth are moving against each other,
eating process and food bolus are there. This will affect the tooth and the
filling material
 If the amount of the matrix is big, there will be too much wear on the
composite and that will decrease the life time of the filling material inside
the oral cavity.
So, it should stayed dimensionally the same so that it can be durable
3- Another problem of the matrix is that it absorb water.
This will change its size, weak it and change the physical property of the
filling material.
4- its stain and discolor
Stain come form chocolate and coffee. It enter the matrix with water
More matrix phase  more discoloration
To avoid the discoloration of the matrix, manufacturer try to decrease the
matrix phase and increase the filler content
Type of fillers
1- naturally exciting fillers : quartz, its very hard, inert and it doesn’t
react in the oral environment (chemically stable)
2- synthesizing fillers: bio engineer glass
we manufacture them and modify them to a certain size and shape for
using in the oral environment
Advantages of fillers
1- decrease the negative properties of the matrix
adding more fillers more hardness of the composite and that hardness with
more wear resistance
2- decrease the co-efficient of thermal expansion
Co-efficient of thermal expansion is: a unit change in length of the filling
material related to the unit change in temperature
Because the temperature in the oral cavity is not static, we need a
material with co-efficient at least matching the tooth structure
If there were no matching, the tooth expansion and contraction in
different rate will result in gapping between the restorative material and
the tooth structure
Gaps mean space and microleakage like saliva and bacteria and that will
result in caries and sensitivity of the patient tooth.
3- decrease the setting contraction
during polymerization, composite material will decrease in mass
( contraction upon setting)
So, adding more fillers, will decrease the contraction
4- fillers particles can be modified to have the optimal characteristics, we
can make them more opaque or more translucent
Caries
Dental caries are either on the tooth structure or between the composite and
the tooth structure. No caries on the composite
Lactic acid for example, is a byproduct of bacteria. It demineralizes the tooth
structure but doesn’t do anything with the composite
* Composite come in tubes or syringes from the manufacturer that contain
monomers, diuent, coloring agents and other chemical substance participate
in the reaction
The only thing that we do at the clinic is to initiate the reaction.
The type, concentration, particle size and particle size distribution of the
fillers affect the physical and the mechanical properties of the composite.
Classifying of the composite
The finishability of the composite is determined by the filler content. So,
classifying of the composite is according to the size of the filler particle but
more less in the matrix
1- large size filler particle: affect the surface finish of the composite and
make it rough
2- Small size filler particle: make a very smooth surface finish of the
composite
we can add more filler to a composite with small size particle. Because,
the more the content, the good the physical property of the composite
*wear resistance
Also depend on the size of the particle
1- Big fillers particle on the surface : friction with the tooth structure
and/or food bolus will result in removing these large filler particle from
the matrix huge dimensional change
2- Small filler particle on the surface: because they are small and tightly
packed together, the wear developed is the same degree on all particles.
Thus, will not removed the particle from the matrix and will resist the
wear on the surface and the surface loss will be less than that of the 1st
case
.
Composite can be prepared by:
1- chemical cure system
2- light cure system
3- dual cure system(both chemical and light)
Chemical cure system
Comes in two jars or two different paste on have the activator and the
other have initiator
The activator is usually tertiary amine (dimethyl-p-toludine) and the
initiator is benzoyl peroxide
.
They come in two different color so that we can know if the proper
mixing happened or not and that is by getting a one homologous color
when mixing.
It’s a chair side mixing
chair side mixing mean that while the patient is on the chair and his/her
tooth is ready for filling, we do mixing the material and apply it in patient
mouth
We also have an inhibitor in the system to inhabit the polymerization
reaction
once we mix the two paste together, polymerization begins and the
material start to get harder that we will not be able to shape it or even put
it in the oral cavity
 So, we use the inhibitor to expand the working time so that we can put
it in the oral cavity and shape the way we want.
Both the inhibitor and the initiator produce free radicals. These radicals
will de stabilize the double bonds in the composite
.
The inhibitor doesn’t react with the double bond till the initiator come.
So, the affinity of the inhibitor is higher than the initiator
Disadvantages of chemical cure system
During mixing the two paste, there is a chance of the air bubble to be
incorporated in the reaction and this will weaken the material
Light cure system
Its one paste material and there is no chair side mixing
So, we directly use it from the tubes to the oral cavity and
Polymerization starts once we cure it with the light. So it has an expanded
working time
Since there is no mixing, the paste in this system is thicker(more fillers) and
that’s mean a stronger restoration
 light cure material are stronger than the chemical cure material because of
two reasons:
1- more fillers
2- no mixing(since mixing may be incorporated with air bubbles)
The light used in this system has a certain characteristics. The most
important is the weave length.
The wave length of the light should match the initiator in the light cure
system
the commonly used initiator in the light cure system is diketone
Anthraquinone which is activated by the blue visible light of a
wavelength of 470 nm
Visible light curing unit
As the light is very bright, direct viewing of the light source will damage
the human eye even indirect viewing is contraindicated. Avoiding the
light is achieved by the yellow protector and there are also specific type
of glasses the dentist can wear to avoid this kind of damage
We said before that the inhibitor expand the working time
In addition to that, it extend the storage life time
 most of the material are not used immediately but within 6 months to 1
year. So, as long as its stored, we don’t want any polymerization. This
would come from any accidental light that will not result in a complete
polymerization but it will decrease its plasticity
Notice that complete polymerization is only achieved with the proper light
curing
Depth of cure
It’s a certain depth of the composite that the light can penetrate through
If we were using too much composite, the light will not reach the deep part
of it.
The depth of cure is usually 2mm
It depends on:
1- Type of the composite we use
2- Time of light exposure
3- Shade of the composite (shade composite required more exposure
time because they are pigmented
We said before that the depth of cure is usually 2mm. So, Any depth is
more than 2mm will not be cured
Sometimes, we may have 6mm depth. This problem is solved by the
incremental addition of the composite (adding the composite layer by
layer)
The thickness of each layer is determined by the depth of cure and each
layer is cured with the light separately
Advantages of the incremental addition :
1- assure adequate polymerization
2- minimize polymerization shrinkage
the shrinkage of each layer is compensated from the next added layer
composite with much shrinkage develop more stress on the wall of the
tooth
composite shrinkage is approximately 2% and its occur after
polymerization takes place
No spacing result from the incremental addition as it happened in case
we put the composite as one piece
Air inhibition
When polymerization is completed , the surface layer(outer layer) of the
composite is in direct contact with the atmosphere and that will result in
inhabitation of polymerization of this layer because of the O2 in the
atmosphere
It occur in both system (chemical and light cure system)
The air inhabited layer help in bonding the layers together
How..?!
In incremental addition when we make a curing for the 1st layer, this will
result in an inhabited layer on the surface of this layer which will result in
a double bond still un reacted. Adding the 2nd layer which is also still
having the double bond unreacted will react with the previous one and
bind to it
The last layer added in incremental addition will still unreacted
( inhabited layer). So, to avoid that we cover it with a protective layer
that should be translucent (transmit light). This layer is usually known as
a miller strip.
The miller strip should be removed after polymerization. Because we
only want the filling material to be in the oral cavity and by doing that we
eliminate the inhabited layer
Another way to get rid off the inhabited layer, is by building the
composite slightly more and then we removed the extra inhabited layer so
that we only have a completely polymerized composite
We can differentiate the inhabited layer by feeling it which appear softer
because its un cure and sticky and slimy
In case we have a fracture in a very old filling and we want to repair it.
1st, we should know in polymerization not all the double bond in the
composite is turned into single bond. Only 50% of the double bond will
turn into a single bond and the other 50% will still unreacted.
As long as we have double bond in the composite, we still have the
ability to add more composite
Its one of the advantages of the composite being an additive material .
this known as a DGREE OF CONVERSION.
Shade of composite
Depending on the fillers product, there are two types;
1- more-opaque used to hide the natural tooth color
2- more-translucent  may result in blue color staining on the
composite
We usually use a translucent composite for the insical edge.
How to detect the composite restoration..??!
Clinically, it feels softer than the enamel
When Taking an x-ray photo of a tooth, we will see some areas are dark
(transmit light) and other areas are white (reflex light)
The white color area called radio-opaque
The black color area called radio-lucent
Usually, caries appear radio-lucent while composite appear radio-opaque
(by adding a barium and/or heavy element on the filler particles of the
composite)
Again, we should remember that the Fillers are the most important
determinant of the physical and chemical property of dental composite.
.....‫يتـــبع‬
Done by: Mohammad Al-Garalleh
Good luck