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Unit 6a Question Packet Chemical Formulas & Equations Name …………………KEY……………………… Period …………. SKILLS 1. NAMES TO FORMULAS 2. FORMULAS TO NAMES 3. identifying MOLECULAR & EMPIRICAL FORMULAS 4. BALANCING EQUATIONS 5. applying the LAW OF CONSERVATION OF MASS 6. identifying TYPES OF REACTIONS SKILL #1: NAMES TO FORMULAS – refer to your notes & RB p. 75-78 1. Complete the table for the following IONIC substances. Name Criss-Cross, Formula Electron-dot diagram Reduce +1 potassium fluoride –1 K +1 lithium bromide Li –1 Sr barium iodide gallium nitride LiBr Br +2 strontium chloride KF F –1 Cl +2 –1 Ba I +3 –3 Ga N +2 zinc sulfide –2 Zn SrCl2 BaI2 GaN ZnS S 2. How many elements are in each ionic compound in #1? How are they named? They all contain two elements only. Metal: always first (element name) Nonmetal: element root w/ -ide ending 3. Write formulas for the following IONIC substances. Use Table E. Criss-Cross, Criss-Cross, Name Formula Name Reduce Reduce +1 –2 sodium sulfate Na (SO4) aluminum chromate Al (CrO4) magnesium hydrogen carbonate +3 +2 Mg (HCO3) +1 Li (MnO4) rubidium oxalate Rb (C2O4) +1 Ba (PO4) Al2(CrO4)3 calcium hydroxide Ca (OH) Mg(HCO3)2 potassium hydrogen sulfate –1 lithium permanganate –3 barium phosphate –2 –1 +2 Na2SO4 –2 LiMnO4 Rb2C2O4 ammonium chloride sodium acetate +2 Ba3(PO4)2 –1 +1 Ca(OH)2 –1 KHSO4 K (HSO4) +1 –1 NH4Cl (NH4) Cl +1 Formula –1 Na (C2H3O2) NaC2H3O2 4. What do the ionic compounds in #3 all have in common? How are they named? They all contain polyatomic ions. + ion: always first (element name or ammonium) - ion: second (name on Table E) 5. What two types of bonds are found in all the compounds in #3? ionic & covalent 6. Write formulas for the following ionic substances. Use Table E if needed. Criss-Cross, Criss-Cross, Name Formula Name Reduce Reduce +2 –1 +3 –2 lead(II) manganese(III) PbI2 Mn O Pb I iodide oxide +1 –1 +2 –1 copper(I) copper(II) CuNO3 Cu (NO ) Cu (NO ) 3 3 nitrate nitrate +3 –2 +3 –2 iron(III) gold(III) Fe 2(SO4)3 Fe (SO4) Au O sulfate oxide Formula Mn2O3 Cu(NO3)2 Au2O3 +5 –1 +4 –3 chromium(V) titanium(IV) CrCl Ti3P4 5 Cr Cl Ti P chloride phosphide +2 –2 +2 –1 platinum(II) iron(II) PtO Fe(OH)2 Pt O Fe (OH) oxide hydroxide 7. What do the ionic compounds in #6 all have in common? How are they named? They all contain metals w/ more than 1 possible charge (oxidation state). + ion: always first (element name or ammonium Charge of metal ion goes as Roman numeral in ( ) - ion: second (name on Table E or root / ide ending) 8. Write formulas for the following molecular substances. Underline the Greek prefixes in the name. Name Formula Name Formula dinitrogen trioxide N2O3 silicon tetrafluoride SiF4 diphosphorus pentoxide P2O5 carbon tetrachloride sulfur dioxide SO2 boron triiodide BI3 silicon dioxide SiO2 carbon disulfide CS2 xenon pentafluoride XeF5 phosphorus pentabromide PBr5 dihydrogen monoxide H2O boron trihydride BH3 CCl4 SKILL #2: FORMULAS TO NAMES – refer to your notes & RB p. 75-78 9. Write IUPAC names for the following molecular substances. Name Formula Name Formula dinitrogen pentoxide N2O5 dihydrogen monosulfide H2S sulfur pentafluoride SF5 boron trifluoride BF3 phosphorus tribromide PBr3 phosphorus trihydride PH3 sulfur trioxide SO3 dihydrogen monoxide (water) H2O diboron tetrahydride B2H4 chlorine Cl2 10. Write IUPAC names the following ionic compounds. Formula How MANY oxidation states listed for the Metal? One Two or more* Name Show work here: LiBr X lithium bromide Ag2O X silver oxide X SnO tin(II) oxide Ba3N2 X barium nitride AgBr X silver bromide X Cu3P Mg(NO3)2 SnO +1 –3 Cu3P magnesium nitrate X NaNO3 sodium nitrate KI X potassium iodide NaClO X sodium hypochlorite Fe(OH)3 X iron(III) hydroxide PbSO4 X lead(II) sulfate X +3 –2 cobalt(III) oxide X NaHCO3 +2 –2 copper(I) phosphide X Co2O3 *Use charge of NONmetal to figure out charge of metal Co2O3 +3 Fe(OH)3 +2 sodium hydrogen carbonate Ni2(SO4)3 X nickel(III) sulfate Ti2O3 X titanium(III) oxide Al2(SO3)3 X aluminum sulfite Al(CN)3 X aluminum cyanide NH4Cl X ammonium chloride KNO3 X potassium nitrate CaCO3 X calcium carbonate (NH4)2CO3 X ammonium carbonate NaS2O3 X sodium thiosulfate YBr3 X yttrium bromide –1 –2 Pb(SO4) +3 –2 Ni2(SO4)3 +3 –2 Ti2O3 11. Write the formulas of the ionic compounds in #11 that have BOTH ionic and covalent bonds. Circle the polyatomic ion in each formula. Mg(NO3)2 NaNO3 NaClO Fe(OH)3 PbSO4 NaHCO3 Ni2(SO4)3 Al2(SO3)3 Al(CN)3 NH4Cl KNO3 CaCO3 (NH4)2CO3 NaS2O3 SKILL #3: – refer to your notes & RB p. 74 identifying MOLECULAR & EMPIRICAL FORMULAS 12. Below are a list of formulas. Write the empirical formula (if not already empirical) and identify the type of substance & type of bonds inside the substance. Type of Empirical Type of Bonds Electrons are… Substance Formula formula (ionic and/or (shared and/or (ionic or (simplest ratio) covalent) transferred) covalent) a. C4H10 C2H5 covalent covalent shared b. C3H6 CH2 covalent covalent shared c. N2O4 NO2 covalent covalent shared Na2SO4 Already empirical (ionic) ionic BOTH BOTH C6H10 C3H5 covalent covalent shared ionic ionic transferred ionic BOTH BOTH d. e. f. g. h. Al2O3 NH4NO3 Already empirical (ionic) Already empirical (ionic) C11H22O11 CH2O covalent covalent shared K2S2O3 Already empirical (ionic) ionic BOTH BOTH j. S2O4 SO2 covalent covalent shared k. CH4 CH4 covalent covalent shared l. C6H12Cl2O2 C3H6ClO covalent covalent shared i. SKILL #4: – refer to your notes & RB p. 79, 81 BALANCING EQUATIONS 13. Balance the following equations using the smallest, whole-number coefficients. a. __3__Mg *Start w/ O + ____Mn2O3 __3__MgO + __2__Mn b. _____C6H12O6 ___2__C2H5OH + ___2__CO2 *Start w/ H c. _____C3H8 + __5__ O2 __4__ H2O + __3__ CO2 *start w/ C or H d. __2__FeCl3 + ____Be3(PO4)2 *Start w/ Be, Cl, or (PO4) __3__BeCl2 + __2__FePO4 e. __4__NH3 + *Start w/ H __3__O2 __2__N2 + __6__H2O f. __3__ C2H4O2 + ____ PCl3 __3__ C2H3OCl + ____ H3PO3 *start w/ Cl *g. _____Fe2O3 + __3___CO __2__Fe + __3__CO2 * must start w/ O, want an EVEN # of O’s on both sides, so CO gets a 3 in front 14. Given the following incomplete equations, write the formula of the molecule represented by X. a. X + Cl2 C2H5Cl + HCl b. 4Fe + 3O2 2X C2H6 Fe2O3 15. Which equation represents conservation of mass? (1) H2 + Cl2 HCl (2) H2 + Cl2 2HCl (3) H2 + O2 H2O SKILL #5: (4) H2 + O2 2H2O – refer to your notes & RB p. 81 applying the LAW OF CONSERVATION OF MASS 16. Given the reaction: 2H2 + O2 2H2O What is the total mass of water formed when 8 grams of hydrogen reacts completely with 64 grams of oxygen? 8 g + 64 g = X 72 g = X 17. When glucose is fermented, it produces ethanol and carbon dioxide. If 60.0 grams of glucose is fermented and produces 16.5 grams of carbon dioxide gas, what mass of ethanol is produced? Glucose ethanol + CO2 60 g = X + 16.5 g 43.5 g = X 18. A 4.86-gram sample of calcium reacted completely with oxygen to form 6.80 grams of calcium oxide. This reaction is represented by the balanced equation below. 2Ca(s) + O2(g) 2CaO(s) Determine the total mass of oxygen that reacted. 4.86 g + X = 6.80 g X = 1.94 g SKILL # 6: – refer to your notes & RB p. 80 identifying TYPES OF REACTIONS 19. Complete the table below. The first one is done for you. Equation Reactant(s) Product(s) Type of Reaction a. Cl2 + 2NaI 2NaCl + I2 Cl2 and NaI NaCl and I2 Single replacement b. HNO3 + LiOH H2O + LiNO3 HNO3 + LiOH H2O + LiNO3 Double replacement c. 2NaN3 2Na + 3N2 NaN3 Na + N2 decomposition d. Ba(NO3)2 + K2SO4 2KNO3 + BaSO4 Ba(NO3)2 + K2SO4 KNO3 + BaSO4 Double replacement e. BaO + SO3 BaSO4 BaO + SO3 BaSO4 synthesis f. 2Al + Fe2O3 Al2O3 + 2Fe Al + Fe2O3 Al2O3 + Fe Single replacement g. P4 + 6Cl2 4PCl3 P4 + Cl2 PCl3 synthesis