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Pulsed Superconducting Magnets (for accelerators) Plan of the Lectures Martin N Wilson (Rutherford Lab Oxford Instruments consultant) 1. Introduction to Superconductors • where to find more information • properties of superconductors, critical field, critical temperature & critical current density • screening currents and the critical state model 2. Magnetization, AC Losses & Filamentary Wires 4. AC Losses in Magnets - and Training • • • • summation of ac loss and refrigeration load temperature rise and temperature margin measurement of ac loss training - energy releases in the magnet conductor design for stability • • • • irreversible magnetization and hysteresis loops field errors and flux jumping 5. Quenching and some other Accelerators ac losses in terms of magnetization • the quench process fine filaments & composite wires, coupling & twisting • decay times and temperature rise 3. Cables and Materials Manufacture • propagation of the resistive zone • why accelerators need cables • quench protection schemes • coupling currents in cables: anisotropy • case study: LHC protection • interstrand resistance • pictures of superconducting accelerators • manufacture of wire and cable Martin Wilson Lecture 1 slide 1 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Pulsed Superconducting Magnets- why bother? Superconductivity Abolishes Ohm’s Law ! no Ohm's law • no power consumption (except refrigeration) lower power bills • ampere turns are cheap, so don’t need iron (except shielding) higher magnetic fields higher energies and /or smaller rings reduced capital cost • high current density compact windings high gradients higher luminosity but • superconductors suffer losses when the field changes rise in temperature (and there's not much margin) increase in refrigeration load Martin Wilson Lecture 1 slide 2 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Some useful references Superconducting Magnets • Superconducting Accelerator Magnets: KH Mess, P Schmuser, S Wolf., pub World Scientific, (1996) ISBN 981-02-2790-6 • High Field Superconducting Magnets: FM Asner, pub Oxford University Press (1999) ISBN 0 19 851764 5 • Case Studies in Superconducting Magnets: Y Iwasa, pub Plenum Press, New York (1994), ISBN 0-30644881-5. • Superconducting Magnets: MN Wilson, pub Oxford University Press (1983) ISBN 0-019-854805-2 • Proc Applied Superconductivity Conference: pub as IEEE Trans Applied Superconductivity, Mar 93 to 99, and as IEEE Trans Magnetics Mar 75 to 91 • Handbook of Applied Superconductivity ed B Seeber, pub UK Institute Physics 1998 Cryogenics • Helium Cryogenics Van Sciver SW, pub Plenum 86 ISBN 0-0306-42335-9 • Cryogenic Engineering, Hands BA, pub Academic Press 86 ISBN 0-012-322991-X • Cryogenics: published monthly by Butterworths • Cryogenie: Ses Applications en Supraconductivite, pub IIR 177 Boulevard Malesherbes F5017 Paris France Martin Wilson Lecture 1 slide 3 Materials Mechanical • Materials at Low Temperature: Ed RP Reed & AF Clark, pub Am. Soc. Metals 1983. ISBN 0-87170-146-4 • Handbook on Materials for Superconducting Machinery pub Batelle Columbus Laboratories 1977. • Nonmetallic materials and composites at low temperatures: Ed AF Clark, RP Reed, G Hartwig pub Plenum • Nonmetallic materials and composites at low temperatures 2, Ed G Hartwig, D Evans, pub Plenum 1982 • Austenitic Steels at low temperatures Editors R.P.Reed and T.Horiuchi, pub Plenum1983 Superconducting Materials • Superconductor Science and Technology, published monthly by Institute of Physics (UK). • Superconductivity of metals and Cuprates, JR Waldram, Institute of Physics Publishing (1996) ISBN 0 85274 337 8 • High Temperature Superconductors: Processing and Science, A Bourdillon and NX Tan Bourdillon, Academic Press, ISBN 0 12 117680 0 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Materials data web sites • Cryogenic properties (1-300 K) of many solids, including thermal conductivity, specific heat, and thermal expansion, have been empirically fitted and the equation parameters are available free on the web at www.cryogenics.nist.gov. • Plots and automated data-look-up using the NIST equations are available on the web for a fee from www.cpia.jhu.edu. • Other fee web sites that use their own fitting equations for a number of cryogenic material properties include: www.cryodata.com (cryogenic properties of about 100 materials), and www.jahm.com (temperature dependent properties of about 1000 materials, many at cryogenic temperatures). • Commercially supplied room-temperature data are available free online for about 10 to 20 properties of about 24,000 materials at www.matweb.com. Cryodata Software Products GASPAK properties of pure fluids from the triple point to high temperatures. HEPAK properties of helium including superfluid above 0.8 K, up to 1500 K. STEAMPAK properties of water from the triple point to 2000 K and 200 MPa. METALPAK, CPPACK, EXPAK reference properties of metals and other solids, 1 - 300 K. CRYOCOMP properties and thermal design calculations for solid materials, 1 - 300 K. SUPERMAGNET four unique engineering design codes for superconducting magnet systems. KRYOM numerical modelling calculations on radiation-shielded cryogenic enclosures. thanks to Jack Ekin of NIST for this information Martin Wilson Lecture 1 slide 4 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 The critical surface of niobium titanium • Niobium titanium NbTi is the standard ‘work horse’ of the superconducting magnet business Jc • it is a ductile alloy qc Bc2 Current density (kA.mm-2) • picture shows the critical surface, which is the boundary between superconductivity and normal resistivity in 3 dimensional space • superconductivity prevails everywhere below the surface, resistance everywhere above it • we define an upper critical field Bc2 (at zero temperature and current) and critical temperature qc (at zero field and current) which are characteristic of the alloy composition • critical current density Jc(B,q) depends on processing Martin Wilson Lecture 1 slide 5 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Critical current density A.mm-2 The critical line at 4.2K • because magnets usually work in boiling liquid helium, the critical surface is often represented by a curve of current versus field at 4.2K 104 Nb3S n 103 • but it is brittle intermetallic compound with poor mechanical properties NbTi • note that both the field and current density of both superconductors are way above the capability of conventional electromagnets 102 10 • niobium tin Nb3Sn has a much higher performance in terms of critical current field and temperature than NbTi Conventional iron yoke electromagnets Magnetic field (Tesla) Martin Wilson Lecture 1 slide 6 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Filamentary composite wires • for reasons that will be described later, superconducting materials are always used in combination with a good normal conductor such as copper • to ensure intimate mixing between the two, the superconductor is made in the form of fine filaments embedded in a matrix of copper • typical dimensions are: • wire diameter = 0.3 - 1.0mm • filament diameter = 10 - 60mm • for electromagnetic reasons, the composite wires are twisted so that the filaments look like a rope (see Lecture 3 on filamentary conductors and cables) Martin Wilson Lecture 1 slide 7 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Critical properties: temperature and field 1 Critical Temperature qc 3.5k Bq c 2D(0) where kB is Boltzmann's constant and D(0) is the energy gap (binding energy of Cooper pairs) of at q = 0 Critical Field Bc: Type 1 superconductors show the Meissner effect. Field is expelled when sample becomes superconducting It costs energy to keep the field out. Critical field happens when the condensation energy of the superconducting state is just equal to the energy penalty of keeping the field out. Bc 2 Gn Gs 2m o where G is the Gibbs Free Energy of the normal/superconducting state. BCS theory says Gn (0) Gs (0) 1 / 2 N F (D(0)) 2 where NF is the density of states at the Fermi surface of metal in normal state calculate it from: 2 / 3 2 N F k B 2 where is Sommerfeld coefficient of electronic specific heat C q Aq 3 Martin Wilson Lecture 1 slide 8 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Critical properties: temperature and field 2 combining the previous equations: 1 3m 0 2 1 1 3.5 2 Bc (0) q c 7.65x10 4 2q c 2 2 'thermodynamic critical field' Bc so like the critical temperature, Bc is defined by the 'chemistry' typically for NbTi ~ 103 J m-3 K-1 so if q = 10 K Bc = 0.24T Conclusion: Type 1 superconductors are useless for magnets! Note however: Meissner effect is not total, the magnetic field actually penetrates a small distance l the London Penetration Depth. Another characteristic distance is the coherence length z - the minimum distance over which the electronic state can change from superconducting to normal Martin Wilson Lecture 1 slide 9 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Critical properties: type 2 superconductors Theory of Ginsburg, Landau, Abrikosov and Gorkov GLAG kl/x defines the ratio If k > 1/2 the magnetic field can penetrate in the form of discrete fluxoids - Type 2 a single fluxoid encloses flux I o h / 2e h 2 1015Webers 2e where h = Planck's constant, e = electronic charge upper critical field Bc 2 2k Bc thus the upper critical field for NbTi: in the ‘dirty limit' Bc 2 3.1 10 3 nq c ~ 900 J m -3 K-2 Martin Wilson Lecture 1 slide 10 k 2.4 10 6 1 2 n ~ 65 x10 -8 W m qc = 9. K n where n is the normal state resistivity - best superconductors are best resistors! hence Bc2 = 18.5 T 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Critical properties: current density Fluxoids consist of resistive cores with supercurrents circulating round them. precipitates of a Ti in Nb Ti spacing between the fluxoids 1 o 2 2 d 3 B 22nm at 5T a uniform distribution of fluxoids gives no net current, so Jc= 0, but a gradient produces a net current density CurlB mo J • gradients must be produced by inhomogeneities in the material, eg dislocations or precipitates • process is known as flux pinning • flux pinning is an irreversible lossy process Martin Wilson Lecture 1 slide 11 fluxoid lattice at 5T on the same scale 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Critical properties: a summary • Critical temperature: choose the right material to have a large energy gap or 'depairing energy' • Critical field: choose a Type 2 superconductor with a high critical temperature and a high normal state resistivity • Critical current density: mess up the microstructure by cold working and precipitation heat treatments - this is the only one where we have any control Similar effects in high temperature superconducting materials : fluxoid lattice in BSCCO Martin Wilson Lecture 1 slide 12 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Upper critical fields of metallic superconductors Note: of all the metallic superconductors, only NbTi is ductile. All the rest are brittle intermetallic compounds 2000 Jc (A/mm2) MgB2 at 5K MgB2 at 5K NbTi at 5K 1000 0 0 B (T) 4 MgB2 Martin Wilson Lecture 1 slide 13 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 8 High temperature superconductors 80 • many superconductors with critical temperature above 90K - BSCCO and YBCO 70 • operate in liquid nitrogen? Upper critical field Bc2 (T) 60 50 YBa2Cu3O7 40 'YBCO' B2212 30 NbTi 20 10 0 0 20 40 60 80 100 Critical temperature Tc (K) Martin Wilson Lecture 1 slide 14 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 High temperature superconductors YBCO structure Conduction layers consist of two CuO2 layers separated by yttrium atoms. The charge layer consists of copper, barium and oxygen atoms Note: this structure makes the properties highly anisotropic Martin Wilson Lecture 1 slide 15 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Irreversibility line - a big disappointment Unlike the metallic superconductors, HTS do not have a sharply defined critical current. At higher temperatures and fields, there is an 'flux flow' region, where the material is resistive - although still superconducting The boundary between flux pinning and flux flow is called the irreversibility line q metallic q Oxide HTS M agnetic Field Normal Resistivity Flux Flow Flux Pinning Temperature Martin Wilson Lecture 1 slide 16 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Engineering current density In designing a magnet, what really matters is the overall 'engineering' current density Jeng J eng current J supercon lmetal lwinding unit cell area lmetal fill factor in the wire insulation NbTi Cu 1 1 mat ) where mat = matrix : superconductor ratio typically: for NbTi mat = 1.5 to 3.0 ie lmetal = 0.4 to 0.25 for Nb3Sn mat ~ 3.0 ie lmetal ~ 0.25 for B2212 mat = 3.0 to 4.0 ie lmetal = 0.25 to 0.2 lwinding takes account of space occupied by insulation, cooling channels, mechanical reinforcement etc and is typically 0.7 to 0.8 So typically Jeng is only 15% to 30% of Jsupercon Martin Wilson Lecture 1 slide 17 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Importance of (engineering) current density: (1) solenoids • the field produced by an infinitely long solenoid is B mo J e t • in solenoids of finite length the central field is B mo f J e t where f is a factor less than 1, typically ~ 0.8 • so the thickness (volume, cost) of a solenoid to produce a given field is inversely proportional to the engineering current density Je Martin Wilson Lecture 1 slide 18 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Importance of (engineering) current density: (2) dipoles I II Je = 37.5 Amm-2 field produced by a perfect dipole is B B mo J e t 2 LHC dipole Je = 375 Amm-2 120mm 660mm 9.5x105 Amp turns 9.5x106 Amp turns =1.9x106 A.m per m =1.9x107 A.m per m Martin Wilson Lecture 1 slide 19 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Some engineering current densities 600 Nb3Sn at 4.2K NbTi at 1.9K 500 Je A/mm 2 NbTi at 4.2K B2212 at 4.2K 400 B2212 at 35K 300 200 100 0 0 Martin Wilson Lecture 1 slide 20 5 10 B Tesla 15 20 25 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Measurement of critical current • • this sample holder is placed in the bore of a superconductin g solenoid, usually in liquid helium boiling at 4.2K at each field level the current is slowly increased and voltage across the test section is measured Martin Wilson Lecture 1 slide 21 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Resistive transition 1 When measured sensitively, the boundary between superconducting and resistive states is not sharp, but slightly blurred. If we measure Jc with voltage taps across the sample, we see that the voltage rises gradually. To define Jc, we must therefore define a measurement sensitivity in terms of electric field or effective resistivity. Commonly used definitions are 10-14 Wm or E = 1 mV.m-1 Overall Current density 10 8 A.m-2 Martin Wilson Lecture 1 slide 22 Critical current defined at this level is about what you would expect the conductor in a resin impregnated solenoid to achieve. At higher resistivity, self heating starts to raise the internal temperature and reduce the critical current 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Resistive transition 2 It has been found empirically that the resistive transition may be represented by a power law J ( J ) o Jo n a) perfect filament b) mid sausaging c) bad sausaging where n is called the resistive transition index. The effect is partly intrinsic and partly geometrical. 'Sausaging of the filaments, forces current to cross the copper matrix as critical current is approached. resistive transition can be the main source of decay in persistent magnets 'n' is often taken as a measure of quality - look for n > 50 HTS conductors so far have low n ~ 5 - 10 Martin Wilson Lecture 1 slide 23 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Screening currents and the critical state model • when a superconductor is subjected to a changing magnetic field, screening currents are induced to flow • screening currents are in addition to the transport current, which comes from the power supply • they are like eddy currents but, because there is no resistance, they don't decay • usual model is a superconducting slab in a changing magnetic field By • assume it's infinitely long in the z and y directions - simplifies to a 1 dim problem • dB/dt induces an electric field E which causes screening currents to flow at critical current density Jc • known as the critical state model or Bean model • in the 1 dim infinite slab geometry, Maxwell's equation says J B y x J B x Martin Wilson Lecture 1 slide 24 m o J z m o J c • so uniform Jc means a constant field gradient inside the superconductor • everywhere in the superconductor the current density is either Jc or zero 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 The flux penetration process plot field profile across the slab B fully penetrated field increasing from zero field decreasing through zero Martin Wilson Lecture 1 slide 25 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 The flux penetration process plot field profile across the slab B fully penetrated field increasing from zero field decreasing through zero Martin Wilson Lecture 1 slide 26 'Pulsed Superconducting Magnets' CERN Academic Training May 2006 Lecture 1: concluding remarks • superconducting magnets burn no power (dc); they produce high fields and high gradients - but in changing fields they suffer ac losses • three types of superconductor - type 1: unsuitable for high field - type 2: good for high field - but must work hard to get current density - HTS: good for high field & temperature - but current density still a problem in field • all superconducting accelerators to date use type 2, usually NbTi (45 years after its discovery) • performance of type 2 superconductors is described by the critical surface in B q J space, - properties in B and q space are reversible properties determined by the chemistry - properties in J space are irreversible and lossy, determined by flux pinning inhomogeneities • engineering current density is what counts for magnet performance • changing magnet fields induce persistent currents in superconductors • persistent currents may be described by the Bean critical state model, - we shall see they are a major cause of ac losses Martin Wilson Lecture 1 slide 27 'Pulsed Superconducting Magnets' CERN Academic Training May 2006