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Petrologic processes that generate the intermediate to felsic plutonic core of island arcs Susan DeBari & Michael Johnsen, Department of Geology, Western Washington University, Bellingham, WA In exhumed arc sections worldwide, the upper mid-crust is composed dominantly of hornblende-bearing tonalite, quartz diorite, diorite, and gabbro (49-76 wt.% SiO2) whose compositions would correspond to an in situ Vp in the range of 6.0-6.3 km/s. This is in contrast to a more mafic, cumulate lower crust composed dominantly of two-pyroxene gabbro (±hornblende, ±garnet) and pyroxenite, (43-52 wt.% SiO2) whose compositions would correspond to an in situ Vp ~7.0 km/s. This grossly simplified crustal structure is surprisingly similar to many modern arcs whose seismic velocity structures have been determined (IBM, Tonga, Kurile, Aleutians, North Honshu, Cascades). In all of these modern arcs, an upper mid-crust with Vp 6.0-6.5 km/s is present, corresponding to velocities calculated for exhumed arc upper mid-crust lithologies. If we presume that modern arcs and exhumed arcs all contain upper mid-crust with intermediate to felsic plutonic rocks (an unsubductable nucleus), we must be able to model how these rocks are generated. In general, we have discerned two chemically distinct groups of tonalite/diorite in the exhumed arc sections. The first compositional group (Type I) typically has flat to slightly LREE enriched rare earth element patterns where REE abundances increase with increasing SiO2. The second compositional group (Type II) shows trends of LREE enrichment and HREE depletion, where both LREE and HREE abundances decrease with increasing SiO2. They are also depleted in Y and enriched in Sr. The more felsic members of this group generally exhibit concave-up patterns of HREE depletion. Most exhumed arcs show one or the other of these trends, but some, including Talkeetna, show both, but at different times in the arc’s history. In the Talkeetna arc, least squares calculations and REE Rayleigh fractionation modeling indicate that Type I tonalite/diorite (55-76 wt.% SiO2) form via fractional crystallization from basalt to dacite. Type II tonalite/diorite (56-74 wt.% SiO2) must be produced by more complicated means that involve some component of cannibalization of lower crust, either by partial melting, or by assimilation. Type II tonalites in the Talkeetna arc can be effectively modeled as a result of magma mixing between an andesitic parental liquid (presumably formed by fractional crystallization) and felsic partial melts of hornblende-bearing mafic rock (amphibolite, hornblende gabbro cumulates). In the Talkeentna arc, these Type II rocks post-date the Type I rocks, and were formed after the arc had matured and (presumably) thickened. These mechanisms provide a testable hypothesis for modern arcs. If the arcs are relatively young and thin, then tonalite/diorite should have geochemical characteristics of Type I (fractionation only). If the arcs are more mature and thicker, then tonalite/diorite may have geochemical characteristics of Type II (some component of lower crustal melting). S. Coast Plutonic Cplx (Washington) Kohistan arc (Pakistan) Jurassic x-section Jurassic x-section Cretaceous x-section Cretaceous x-section Depth 0 granitoid batholith + mingled mafic + mingled mafic Interlayered intermediate plutons 5 kb amphibolite (~15 km) crustal melting • Crustal melting • Crustal melting • Crustal melting • Older oceanic basement • Older oceanic basement • Older oceanic basement • Unknown bulk composition • Int. bulk composition to ~30 km depth • Unknown bulk composition • Mafic bulk composition These sections have been color-coded to their expected seismic velocities based on lithology (velocities calculated using formulation of Behn and Kelemen, 2003) 6 100 (60% SiO2) (58% SiO2) A Cascade volcano with a similar pattern: Glacier Peak volcano (56% SiO2) (65% SiO2) 92-274 66% SiO2 (69% SiO2) Type 2 concentration / C1 chondrite plutonic samples (observed) volcanic samples (observed) modeled REE (melting) gabbroic rock (5710J10B) felsic end-member (5711J01) 10 Residual Cpx 10% Opx 5% Plag 45% Amphibole 35% Magnetite 5% 15 120 Sr/Y Cc/Cm La Ce 20% partial melt of 5710J10B compared to 5711J01 Example 2: Bonanza arc (field exposure of leucosome & melanosome) 92-274 66% SiO2 Type 2 40 20 0 0 50 55 60 65 70 75 45 50 SiO2 (wt %) 55 60 65 70 75 (69% SiO2) Decreasing SiO2 Lu Yb Ho Dy Tb Gd Eu Sm Nd La Ce Pr Nd Sm Eu Gd Tb Dy 10 plutonic samples (observed) volcanic samples (observed) modeled REE (mixing) interm. end-member (5721J03) felsic end-member (5711J01) 1 10 90 % of felsic end-member Felsic end-member (5711J01) 71.2 wt % SiO2 Nd Sm Eu Gd Tb Dy Ho Er Yb Lu 20% 5721J03 80% 5711J01 compared 65.8 wt SiO2 to%5712J07 1.1 0.9 0.7 0.5 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Yb Lu Concluding hypothesis: 35% amphibole 45% plagioclase 10% magnetite 10% clinopyroxene 37c (melanosome) 10 10 Type 2 (dacite) 37c - 'residue' 1 - leucocratic diorite model results 1 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Yb Lu Intermediate end-member (5721J03) RESIDUE ~25% melting 1 Pr 60.4 wt % SiO2 In the Talkeetna Arc, the older plutonic rocks are Type 1. The youngest rocks are Type 2 (thicker, more mature crust?) Batch modal melting 100 60 5 100 Pr Nd Sm Eu Gd Tb Dy Ho Er Yb Lu 80 Type 2 also have high Sr/Y with Felsic end-member (5711J01) 71.2 wt% SiO2 Pr Nd Sm Eu Gd Tb Dy Ho Er Yb Lu 1.1 1.0 0.9 0.8 100 10 ~20% fractional melting Example: Talkeetna arc (see Johnsen et al poster) 44.8 wt% SiO2 Gabbroic composition (5710J10B) 1 Mafic lavas that backmix with Type 2) (65% SiO2) 1 REE normalized to C1 chondrite (Sun & McDonough, 1989) [La/Yb]N 100 100 Lu Yb Ho Dy Tb Gd Eu 1 Sm 1 >54 wt.% SiO2 (diorite/tonalite) Increasing SiO2 10 Ce 10 REE/Chondrite 10 Type 1 REE/Chondrite Increasing SiO2 Nd REE/Chondrite REE/Chondrite Bonanza arc migmatite Example 1: Talkeetna arc (see Johnsen et al poster) La Ce Diorites, Tonalites & Leucotonalites (65% SiO2) (56% SiO2) Mixing of the crustal melts with mantle-derived magmas can produce the Type 2 trend of decreasing REE with increasing SiO2 Bonanza Arc La Kohistan arc migmatite 7 Cc/Cm (60% SiO2) (58% SiO2) Produce a Si-rich, Type 2 magma by crustal melting La Ce Diorites, Tonalites & Leucotonalites Type 1 Moho pyroxenite, dunite +/- garnet • No obvious exposure of crustal melting • Type 2 - REE abundances decrease with increasing SiO2 content (and decreasing Mg#). This cannot be modeled as fractional crystallization (even taking into account observed quantities of apatite). This is best modeled as melting of a distinct low LREE source (cumulates?) coupled with mixing. (65% SiO2) 10 kb (~30 km) • Intermediate plutonic layer • Type 1 - REE abundances increase with increasing SiO2 content (and decreasing Mg#). This can be easily modeled as fractional crystallization, typically involving cpx + plag + amphibole + Fe-Ti oxide (see Johnsen et al. poster for Talkeetna detailed example). Western Talkeetna Arc 10 kb (~30 km) • Intermediate to >30 km (10 kbar)! The intermediate to felsic plutonic rocks of the mid crust display distinct REE patterns that fall into two categories 100 garnet gabbro • Intermediate plutonic layer How is the intermediate-felsic mid crust generated? Using geochemical signatures to discern magmatic processes: 100 layered 2-px gabbros Questionable stratigraphy…… (bottom and top may actually be two sections based on ages) • Intermediate plutonic layer • No oceanic basement • What lithologies make up this upper crust? Can we make generalizations based on arc crustal sections? 2. Crustal melting - snapshots of this process observed in the Bonanza arc and the Kohistan arc in the mid-crust to upper parts of the lower crust ? tonalite, diorite hornblende gabbro Crust at least 60 km thick • Even Izu Bonin and Aleutians are not that different in the upper crust. Close to homogenization? ? 2-px gabbro amphibolite crustal melting Mafic plutonic rocks 10 kb garnet gabbro (~30 km) Moho pyroxenite duniteharzburgite • Modern arcs in a gross sense have similar seismic velocity structures person for scale 5 kb (~15 km) Intermediate-felsic plutonic rocks Uppermid crust Fine-scale mingling and Volcanic and volcaniclastic rocks Upper crust 5-~7 km Shillington et al (2004) 5 kb (~15 km) metamorphic rocks (schist/ amphibolite) layered 2-px gabbro Iwasaki Nakanishi et al. et al. (2001) (2007) Parsons et al. (1998) volcanic rocks tonalite diorite 5 kb (~15 km) Suyehiro et al. (1996) 0 ? volcanic rocks ? 5 45 0 tonalite diorite +mingled mafic Crawford et al. (2003) Depth Depth volcanic rocks Physical mixing of crystals Mingling on the large scale Bonanza arc (Vancouver Island) 0 1. Magma mingling (and mixing) is pervasive in the middle crust in all arc sections. Extreme heterogeneity at all scales. Break-up and mingling of basaltic sill Talkeetna arc (Alaska) Depth Ce 4 Common processes observed in the mid crust of exposed arc sections 3 The crustal sections concentration / C1 chondrite 2 ABSTRACT La 1 Seismic stratigraphy of modern arcs - more similarities than differences? La Ce Nd Sm Eu Gd Dy Ho Yb Lu Type 1: Increasing REE with increasing SiO2. Process is fractionation (young thin arcs?) Type 2: Decreasing REE with increasing SiO2. Process is crustal melting and is often coupled with mixing with mantlederived magmas and fractionation (older thicker arcs?) Both processes produce the nonsubductable nucleus of continental crust La Ce Pr Nd Sm Eu Gd Tb Dy