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Chemistry Chapter 1 The Science of Matter 1.1 Objectives • Students will be able to… – Understand matter, its phases, and composition – Know the differences quantitative and qualitative expressions – Explain the if something is a substance or a mixture – Know the differences between homogeneous and heterogeneous mixtures I. What is Chemistry? The study and investigation of the structure and properties of matter II. A Picture of Matter A. composition, structure, and behavior 1) matter— a substance that takes up space and has mass 2) mass— the amount of matter in an object 3) properties of matter— characteristics and behavior; can be physical or chemical III. Using Models in Chemistry Scientific model— tools to help you understand the relationship between the macroscopic and submicroscopic views of matter II. A Picture of Matter B. examining matter 1) macroscopic view— matter large enough to be seen 2) submicroscopic view— dealing with atoms 1.5 x10-10 m IV. Classifying matter A. classification by composition: 1) qualitative —verbal description, no exact figures 2) quantitative —description by numbers IV. Classifying matter B. Pure substance vs. Mixture 1) pure substance—matter with the same definite composition and properties examples of elements and compounds: C H2O NaCl NH3 2) mixture—physical blend of two or more substances IV. Classifying matter C. Mixed matter 1) Mixtures heterogeneous— not uniform -has different “phases” homogeneous—uniform -has one “phase” -a called a solution What Kind of Mixture is it? Review Questions • What three characteristics of matter does chemistry deal with? • The population of India is…. Is this a quantitative or qualitative expression? Why? • How does a mixture differ from a substance? • Select a common item and describe chemically using the proper terms. IV. Classifying matter 2) Phase -solid, liquid, gas, plasma IV. Classifying matter States of matter solid a) matter with a definite, fixed shape and volume IV. Classifying matter States of matter liquid a) matter with variable shape and fixed volume b) exhibits flow c) takes the shape of its IV. Classifying matter States of matter gas a) matter with variable shape and volume b) exhibits flow c) takes the shape and volume of its container d) normally stable as a gas at room temperature e) vapor is a gas even though the normal state is not f) volatile—changing to a gas easily at room temperature IV. Classifying matter States of matter Plasma- ??? - low-density ionized gas IV. Classifying matter 3) Solutions solute— the substance being dissolved solvent— the substance doing the dissolving aqueous solutions (aq)—water containing dissolved materials Can be separated by physical means: evaporation, filtration, distillation, etc. Evaporation Filtration Distillation IV. Classifying matter D. Separation of matter into pure substances physical change a) alterations that do not change the substance’s identity and composition b) boil, freeze, melt, condense, dissolve, crush, break, cut… physical properties conductivity density solubility melting point ductility boiling point malleability odor refractive index IV. Classifying matter Intensive property- does not depend on the amount of matter Extensive property- depends on the amount of matter V. Substances: Pure Matter V. Substances: Pure Matter A. elements simplest form of matter retaining the properties of that matter examples : Ag Pb O W COMMON ELEMENTS TO KNOW: Ag, Al, Ar, As, Au, B, Ba, Be, Bi, Br, C, Ca, Cl, Co, Cr, Cs, Cu, F, Fe, Fr, H, He, Hg, I, K, Kr, Li, Mg, Mn, N, Na, Ne, Ni, O, P, Pb, Ra, Rb, S, Sb, Si, Sr, Sn, U, W, Zn B. chemical symbols: -each element has a different symbol -capitalize the first letter only -word roots from English and other languages (Latin) Periodic Table of Elements V. Substances: Pure Matter C. compounds -more than one element in a type of matter -can only be separated by chemical methods examples: NaHCO3 CO H2CO CaCO3 D. formulas of compounds -formula—correct combination of chemical symbols H2O H2SO4 Jimmy took a drink but he will drink NO MORE, because what he thought was H2O was H2SO4!!! Review Questions • What three characteristics of matter does chemistry deal with? • How does a mixture differ from a substance? • How does a compound differ from a mixture? • Select a common item and describe chemically using the proper terms. Homework • Read section 1.1 and 1.2 • Copy Vocabulary into your notebooks 1.1 Objectives • Students will be able to… – Understand the law of the conservation of matter Review Questions • Is milk a homogeneous or heterogeneous mixture? Why? • Forms of energy like sunlight and heat are not matter. Why? Ch. 1 The Science of Matter Section 1.2 1.2 Objectives • Students will be able to… – Distinguish between physical and chemical properties – Contrast physical and chemical changes – Apply the law of conservation of matter – Complete density and dimensional analysis calculations Warm Up Questions • What is the difference between and element and a compound? • Describe the picture. Are these quantitative or qualitative descriptions? • What is the chemical formula of the chemical model? – Black= Carbon (C) – White= Hydrogen (H) – Red= Oxygen (O) VII. Chemical Properties and Changes A. Atoms and chemical change 1) chemical properties—ability to form new substances as a result of chemical reactions 2) chemical changes—alterations that changes a substance’s identity and composition to something new, through a chemical reaction VII. Chemical Properties and Changes 3) chemical reactions—the changing of substance(s) into new ones a) reactants—starting substances in a rxn. b) products—new substances formed in a rxn. c) clues that a chemical rxn. has occurred energy is given off (gets hotter) color change production of a gas energy is absorbed (gets colder) odor change production of a solid (precipitate; ppt.) A Chemical Reaction H2SO4 + 2NaOH -> Na2SO4 + 2H2O Reactants Products VII. Chemical Properties and Changes 4) Law of Conservation of Mass— matter cannot be created nor destroyed, it merely changes form (burn a candle) a) reactant mass = product mass b) exceptions are nuclear rxns. VII. Chemical Properties and Changes B. chemical reactions and energy 1) energy—the capacity to do work 2) some types of energy a) potential—energy at rest; energy of position b) kinetic—energy of motion c) thermal—heat energy d) radiant—light energy e) chemical—energy in chemical bonds VII. Chemical Properties and Changes 3) Law of Conservation of Energy: in a physical or chemical change, energy cannot be created nor destroyed, it merely changes form 4) energy changes in reactions a) exothermic - giving off heat b) endothermic - absorbing heat SI Units • SI stands for “le Systeme International d’Unites” • France, 1789. • There are two types of units: – base units; – derived units. • There are 7 base units in the SI system. • Scientific (Exponential) Notation is used for convenience with smaller or larger units in the SI system. SI Base Units SI Prefixes VI. Identifying Matter by its Properties B. Density 1) density = mass (g) / volume (ml) 2) D = M / V 3) density usually decreases as temp. increases (due to increased volume) Derived Units • Derived units are obtained from the 7 base SI units. • The are combined by multiplication or division • Examples: km/hr g/mL m/s cal/g/oC Density Problems: • A metal bar has a mass of 35.50 g and a volume of 262 cm3. What is its density in g/cm3? D=M/V D= 35.50 g / 262 cm3 D= 0.135g/ cm3 Density Problems: • 500.0 mL of a liquid has a density of 0.447 g/mL. What is its mass? D=M/V M= DV M= (0.447g/ml )(500ml) M= 224g Density Problems: • 4.2 g of a substance has a density of 0.89 g/m3. How much space, in m3, does it occupy? D=M/V V=M/D V=4.2g / (0.89g/m3) V=4.7m3 Volume • The units for volume are given by (units of length)3. SI unit for volume is 1 m3. • We usually use 1 mL = 1 cm3. • Other volume units: 1 L = 1 dm3 = 1000 cm3 = 1000 mL. Volume Uncertainty in Measurement • All scientific measures are subject to error. • These errors are reflected in the number of figures reported for the measurement. • These errors are also reflected in the observation that two successive measures of the same Precision and Accuracy (often confused) • Measurements that are close to the “correct” value are accurate. • Measurements that are close to each other are precise. Precision and Accuracy Significant Figures (sig-figs) • The number of digits reported in a measurement reflect the accuracy of the measurement and the precision of the measuring device. • Report the fewest significant figures • Fewest number for multiplication and division • Fewest decimal places for addition and subtraction • • • • • Significant Figures (sig-figs) Non-zero numbers (e.g. 1, 2, 3…9) are significant. Zeros between non-zero numbers are always significant. (e.g. 204 ml) (the sandwich rule) Zeros before the first non-zero digit are not significant. (e.g. 0.0003 has one.) Zeros at the end of the number after a decimal place are significant. (e.g. 123.00 g) Zeros at the end of a number before a decimal place are ambiguous (e.g. 10,300 g). Examples: How many sig-figs are in each of the following? 4 10 m = 3; 5.23 x 2. 0.000487 kg = 6; 4.87 x 10-4kg 3. 29.0400 s = 7; 2.90400 x 10s 4. 507 people = 3; 5.07 x 102 people 5. 230,050 cm = 5; 2.30050 x 105 cm = 5; 4.5600 x 10 L 6. 45.600 L 1. 52300 m Scientific Notation • Numbers written in scientific notation include a numeral with one digit before the decimal point, multiplied by some power of ten (6.022 x 1023) • All digits are significant. 1. Convert to scientific notation: a. 450 000 000 b. 0.000 000 047 c. 46.04 2. Convert to non-scientific notation: a. 7.09 x 10-6 b. 3.39 x 105 c. 8.00 x 106 • • • • • • Dimensional Analysis Method of calculation using a knowledge of units and some basic algebra. Given units can be multiplied or divided to give the desired units. Conversion factors are used to manipulate units Treat units just like you would treat numbers Given unit (conversion factor) = Desired unit The conversion factors are ratios equal to “1” Using Two or More Conversion Factors • To convert length in meters to length in inches: • Given: 1 m = 100 cm and 1 inch = 2.54 cm • What are the conversion factors for these two? • How many inches are in 1.5 m? Using Two or More Conversion Factors • In dimensional analysis ask three questions: • What data are we given? (where are we?) • What quantity do we need? (where do we want to be?) • What conversion factors are available to take us from what we are given to what we need? (how do we get there?) Examples: Convert the following: 1. 240 000 000 cm to km. 2. 0.00657 m3 to cm3. 3. 2.57 years to s. 4. 4.98 feet to mm. Homework • Read Chapter 2 • Copy Vocabulary into your notebooks • Worksheet 1.1 Stuff to add