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Chapter 2 Sec 2.3 Scientific Measurement Vocabulary 14. accuracy 15. precision 16. percent error 17. significant figures 18. scientific notation 19. directly proportional 20. inversely proportional 2.3 Measurements and Their Uncertainty A measurement is a quantity that has both a number and a unit Measurements are fundamental to the experimental sciences. For that reason, it is important to be able to make measurements and to decide whether a measurement is correct. International System of Measurement (SI) typically used in the sciences Accuracy and Precision Accuracy is the closeness of a measurement to the correct value of quantity measured Precision is a measure of how close a set of measurements are to one another To evaluate the accuracy of a measurement, the measured value must be compared to the correct value. To evaluate the precision of a measurement, you must compare the values of two or more repeated measurements Accuracy and Precision Accuracy and Precision Which target shows: 1. 2. 3. 4. an accurate but imprecise set of measurements? a set of measurements that is both precise and accurate? a precise but inaccurate set of measurements? a set of measurements that is neither precise nor accurate? A. Determining Error 1. Error = experimental value – accepted value *experiment value is measured in lab (what you got during experiment) * accepted value is correct value based on references (what you should have gotten) 2. Percent error = [Value experimental – Valueaccepted] x 100% Valueaccepted Significant Figures in Measurement all known digits + one estimated digit What is the measured value? What is the measured value? What is the measured value? 2.3 Practice Problems – Accuracy and Precision B. Rules of Significant Figures 1. Every nonzero digit in a measurement is significant (1-9). Ex: 831 g = 3 sig figs 2. Zeros in the middle of a number are always significant. Ex: 507 m = 3 sig figs 3. Zeros at the beginning of a number are NOT significant. Ex: 0.0056 g = 2 sig figs B. Rules of Significant Figures 4. Zeros at the end of a number are only significant if they follow a decimal point. Ex: 35.00 g = 4 sig figs 2400 g = 2 sig figs Sig Fig Practice #1 How many significant figures in the following? 1.0070 m 5 sig figs 17.10 kg 4 sig figs 100,890 L 5 sig figs 3.29 x 103 s 3 sig figs These all come from some measurements 0.0054 cm 2 sig figs 3,200,000 mL 2 sig figs 5 dogs unlimited This is a counted value C. Significant Figures in Calculations 1. A calculated answer can only be as precise as the least precise measurement from which it was calculated 2. Exact numbers never affect the number of significant figures in the results of calculations (unlimited sig figs) a) counted numbers Ex: 17 beakers b) exact defined quantities Ex: 60 sec = 1min Ex: avagadro’s number = 6.02 x 1023 C. Significant Figures in Calculations 3. multiplication and division: answer can have no more sig figs than least number of sig figs in the measurements used. 4. addition and subtraction: answer can have no more decimal places that the least number of decimal places in the measurements used. (not sig figs) Rounding Sig Fig Practice #1 Calculation Calculator says: Answer 3.24 m x 7.0 m 22.68 m2 100.0 g ÷ 23.7 cm3 4.219409283 g/cm3 4.22 g/cm3 23 m2 0.02 cm x 2.371 cm 0.04742 cm2 0.05 cm2 710 m ÷ 3.0 s 240 m/s 236.6666667 m/s Rounding Practice #2 Calculation Calculator says: Answer 3.24 m + 7.0 m 10.24 m 10.2 m 100.0 g - 23.74 g 76.26 g 76.3 g 0.02 cm +2.378 cm 2.398 cm 2.40 cm 710 m -3.4 m 706.6 m 707 m Sec 2.3 Practice Problems – Significant Figures R61 Appendix C (1-7) Sec 2.3 Practice Problems – Significant Figures Sec 2.3 Practice Problems – Significant Figures Scientific Notation An expression of numbers in the form m x 10n where m (coefficient) is equal to or greater than 1 and less than 10, and n is the power of 10 (exponent) D. Rules of Scientific Notation 1. Multiplication – multiply the coefficients and add the exponents Ex: (3x104) x (2x102) = (3x2) x 104+2 = 6 x 106 2. Division – divide the coefficients and subtract the exponent in the denominator from the exponent in the numerator Ex: (3.0x105)/(6.0x102) = (3.0/6.0) x 105-2 = 0.5 x 103 = 5.0 x 102 D. Rules of Scientific Notation 3. Addition – exponents must be the same and then add the coefficients Ex: (5.4x103) + (8.0x102) (8.0x102) = (0.80x103) (5.4x103) + (0.80x103) = (5.4 +0.80) x 103 = 6.2 x 103 4. Subtraction – exponents must be the same and then subtract the coefficients Sec 2.3 Practice Problems – Scientific Notation Chapter 2 Section 3 Using Scientific Measurements Direct Proportions • Two quantities are directly proportional to each other if dividing one by the other gives a constant value. • yx • read as “y is proportional to x.” Chapter 2 Section 3 Using Scientific Measurements Direct Proportion Chapter 2 Section 3 Using Scientific Measurements Inverse Proportions • Two quantities are inversely proportional to each other if their product is constant. 1 • y x • read as “y is proportional to 1 divided by x.” Chapter 2 Section 3 Using Scientific Measurements Inverse Proportion Vocabulary 14. accuracy 15. precision 16. percent error 17. significant figures 18. scientific notation 19. directly proportional 20. inversely proportional