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Mathematical Operations in Chemistry Significant Figures 1. All non-zero digits are significant (2.45 has 3 SF) 2. Zeros between (sandwiched) non-zero digits are significant (303 has 3 SF) 3. Zeros to the left of all non-zero digits are NEVER significant (0.000025 has 2 SF and 00000125 has 3 SF) 4. Zeros to the right of all non-zero digits are only significant if they are also to the right of the decimal (250 has 2 SF and 250.00 has 5 SF) 5. A number ending in zero with a decimal place after it indicates the zero is significant (350. has 3 SF) 5. Counting numbers have infinite significant figures (21 students has infinite SF) 6. Exactly defined quantities and conversion factors have infinite significant figures (100 cm = 1 m – both terms have infinite SF) IMPORTANT NOTE Significant Figures are used ONLY for multiplication and division. Places are used for addition and subtraction. Mathematical Operations with Significant Figures Multiplying and Dividing The answer must be rounded to the same number of significant figures as the number in the problem with the least significant figures. 7.83 kg x2.1 kg 16.443 kg = 16 kg Mathematical Operations with Places Adding and Subtracting_ The answer should have no more places than the number in the problem with the least places. 10.21 cm +5.3 cm 15.51 cm = 15.5 cm