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ATOMIC STRUCTURE Democritus believed that all matter consisted of small particles that could not be divided. He called these particles atoms from the Greek word atamos meaning “uncut” or “indivisible” He thought there were different types of atoms for example atoms in liquids were round and smooth. Aristotle did not think there was a limit to the number of times matter could be divided. He thought that all substances were built from four elements: Element-matter that is made of one type of atom. Ex. Hydrogen is only made of hydrogen atoms John Dalton, English teacher that studied the behavior of gases in the air. Based on the way gases exert pressure, he correctly concluded that a gas consists of individual particles. Dalton measured the masses of elements that combine when compounds form. He noticed that the ratio of masses is always the same, they have a fixed composition. He proposed the theory that all matter is made up of individual particles called atoms, which cannot be divided. 1. 2. 3. 4. All elements are composed of atoms. All atoms of the same element have the same mass, and atoms of different elements have different masses. Compounds contain atoms of more than one element. In a particular compound, atoms of different elements always combine in the same way. Dalton used solid spheres to represent atoms….. Incorrect! “All atoms of the same element have the same mass” - what about isotopes? Matter is composed of indivisible particles – atoms can be divided (nuclear reaction) “different elements have different masses” - Correct! “elements always combine in the same way.” - Correct! Theory was widely accepted just revised once new discoveries were made. Objects such as amber and glass can attract and repel other objects…remember that opposites _________. JJ Thomson used an electric current to learn more about atoms. He discovered first subatomic particles – electronsnegatively charged particles!!!! (add to notes) He hypothesized that a stream of charged particles that interacted with air in the tube would cause air to glow. He observed that the beam was repelled by the negatively charged plate- Anode and attracted by the positively charged plate.- cathode Thomson concluded that the particles in the beam had a - charge because they were attracted to the + plate. This changed the way scientists thought about atoms (remember they thought an atom was a solid ball of matter) Thomson’s experiments provided the first evidence that atoms are made of even smaller particles, he revised Dalton’s model. In his model, negative charges were evenly scattered throughout an atom. “Plum pudding” model, chocolate chip ice cream model. 1. Who said there • A. Aristotle • B. Democritus • C. Dalton • D. Thomson 2. Negative charges evenly scattered throughout. • • • • were only 4 elements? A. Aristotle B. Democritus C. Dalton D. Thomson 3. Matter is made up of atoms which are solid spheres. • • • • A. Aristotle B. Democritus C. Dalton D. Thomson 4. Termed small particles atoms from Greek word atamos. • • • • A. Aristotle B. Democritus C. Dalton D. Thomson His student, Ernest Marsden, set up gold foil experiment to find out what happens to particles as they pass through a thin sheet of gold. Rutherford predicted that most particles would travel in a straight path from their source. During the gold foil experiment, a beam was aimed at the gold, which would produce a flash of light when it struck the screen. By observing the flash, he could figure PROBLEM!!!!!!!!!!! •More particles were deflected out the path of the than expected! particle. •Some even bounced straight back! Rutherford concluded that the positive charge of an atom-proton is not evenly spread throughout the atom. It is concentrated in a very small, central area that Rutherford called the nucleus. The nucleus is a dense, positively charged mass located in the center of the atom. According to Rutherford’s model, all of an atom’s positive charge is concentrated in its nucleus. The particles that were reflected back came close to the nucleus and those that went through passed through space surrounding nucleus. If an atom had the same volume as a football stadium, its nucleus would have the volume of a marble!!! Total volume of an atom is about a trillion times that of the nucleus. (1,000,000,000,000) QUICK REVIEW – USE CARDS 1. One of the first people to state that matter is made up of atoms was • • • • A. Aristotle B. Democritus C. Dalton D. Thomson 2. Thomson’s model of an atom is best described as a(n) ____ a. solar system b. solid sphere c. plum pudding 3. Who provided the first evidence that atoms contain subatomic particles? • A. Aristotle B. Democritus • C. Dalton D. Thomson 4. Who discovered electrons? • A. Aristotle B. Democritus • C. Dalton D. Thomson 5. Which scientist experimented with gold foil? • A. Aristotle B. Democritus • C. Rutherford D. Thomson 6. What was one incorrect concept in Dalton’s model? A. used solid spheres to represent atoms B. States that all atoms of the same element have the same mass C. Matter is composed of indivisible particles D. All of the above Niels Bohr was a Danish physicist who expanded Rutherford’s Atomic Model Bohr focused his arrangement around the positioning of electrons In Bohr’s model, electrons move with constant speed in fixed orbits around the nucleus, much like planets orbit a sun. The possible energies that electrons have in an atom are called energy levels. If an atom gains or loses energy, the energy of an electron can change. Scientists can measure the energy gained when electrons absorb energy and move to a high level Example: • Heat produced by an explosion causes some electrons to move to higher energy levels. When the electrons move back to lower energy levels, they emit some energy in the form of light. (Not all energy is lost, it has to go “somewhere” and in this case it is released in the form of light) Building from Bohr’s Model scientists now know that electrons move in a much more unpredictable manner than Bohr proposed. An Electron Cloud is a visual model of the most likely locations for electrons in an atom. Scientists use the electron cloud model to describe the possible locations of electrons around the nucleus. Electro ns move so quickly they are a blur THE STRUCTURE OF AN ATOM PARTICLE SYMBOL CHARGE RELATIVE LOCATION MASS PROTON p+ + 1 Nucleus e- 1/1836 n 1 ELECTRON NEUTRON* Electron cloud – orbiting nucleus Nucleus * James Chadwick concluded that neutrons are neutral because a charged object did not deflect the paths of the particle. Atoms of an element always have the same number of protons. Atomic # = number of protons Since electrons = protons, atomic # also tells you the # of electrons For example: Sulfur has an atomic # of 16 so it has 16 protons and 16 electrons. How many protons does Carbon have? 6 How many electrons does Carbon have? 6 Mass number is the sum of the protons and neutrons in the nucleus. To find the # of neutrons = Mass # minus # of protons For example: Sulfur has a mass # of 32.06 Subtract # of protons 32.06-16 = 16 neutrons How many neutrons does Lithium have? Mass # of 7-3 protons = 4 neutrons Every atom of the same element has the same number of protons and electrons. For example all atoms of Carbon have 6 electrons and 6 protons. Every atom of an element does not have the same number of neutrons. Isotopes are atoms of the same element that have different numbers of neutrons and therefore different mass numbers. Isotopes of an element have the same atomic number but different mass numbers because they have different numbers of neutrons. For example Carbon 14 is a radioactive isotope. Usually, carbon has a mass number of 12, but Carbon 14 has a mass number of 14 due to the 2 extra neutrons. 6 protons + 8 neutrons = mass number of14 How many neutrons are in Carbon 13? Mass of 13-6 protons = 7 neutrons ISOTOPE ATOMIC # # OF NEUTRONS Nitrogen-15 7 8 Iodine-131 53 78