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Lecture 12 Semiconducting junctions The PN-Junction One of the simplest bipolar devices, important for the understanding of more complex devices (bipolar = both electrons and holes contribute to device characteristics). Semiconductor devices: Inhomogeneous semiconductors All solid-state electronic and opto-electronic devices are based on doped semiconductors. In many devices the doping and hence the carrier concentrations are non-homogeneous. In the following section we will consider the p-n junction which is an important part of many semiconductor devices and which illustrated a number of key effects Diode Nonlinear I-V characteristics Forward bias n + I + + + + + + + + + + + + + -- - - p A Reverse bias V - -- - The p-n semiconductor junction: p-type / n-type semiconductor interface We will consider the p-n interface to be abrupt. This is a good approximation. n-type ND donor atoms per m3 p-type NA acceptor atoms per m3 Consider temperatures ~300K Almost all donor and acceptor atoms are ionised. p-n interface at x=0. impurity atoms m-3 ND NA p-type n-type x=0 xa ND (x) = ND (x>0) = 0 (x<0) NA (x) = NA (x<0) (x>0) = 0 (x>0) (x<0) p-type semiconductor Electron and hole transfer n-type semiconductor Electrons EC m EC m EV EV Holes Consider bringing into contact p-type and n-type semiconductors. n-type semiconductor: Chemical potential, m (Fermi level) below bottom of conduction band p-type semiconductor: Chemical potential, m above top of valence band. Electrons diffuse from n-type into p-type filling empty valence states. EC Electrons Band Bending EC m EV Holes e0 EV p-type semiconductor n-type semiconductor Electrons diffuse from n-type into p-type filling empty valence band states. The p-type becomes negatively charged with respect to the n-type material. Electron energy levels in the p-type rise with respect to the n-type material. A large electric field is produced close to the interface. Dynamic equilibrium results with the chemical potential (Fermi level) constant throughout the device. Note: Absence of electrons and hole close to interface -- depletion region Junction At equilibrium the Fermi level gradient equals zero! dE F 0 dx p-n junction IV characteristics : I The principle working of a pn-junction P-doped N-doped Positively charged holes + negatively charged immobile acceptors Negatively charged electrons + positively charged immobile donors N-doped P-doped holes - + electrons No electrons or holes, only charged donors/acceptors (DEPLETION LAYER) The principle working of a pn-junction No Voltage IV characteristics : - + holes electrons Current I N-doped P-doped Forward bias current + -+ holes electrons - Voltage “No” current (Leakage current) Reverse bias “no” current - holes - + electrons + Circuit symbol: Large current Ec No bias Ev Forward bias Ec Drift (thermally exc.) Diffusion (E-field) ee- jdrift jdiffusion jdiffusion jdrift j V Reverse E c bias V jdiffusion jdrift 0 0 V I-V Characteristics Hole current: • diffusion Ipd = C1Npexp (-eVbi/(kT)) • drift Ipu = CNpn = Ipd = C1Npexp (-eVbi/(kT)) • at forward bias IpF = C1 Np exp (-e(Vbi- V) /(kT)) • Ip = IpF - Ipu = C1Np exp (-e(Vbi- V) /(kT)) – C1Np exp (-eVbi/(kT)) = C1Npexp [-eVbi/(kT)][exp(eV/(kT)-1] =Ipd [exp(eV/(kT))-1] Electron current: In = Ind [exp(eV/(kT))-1 with Ind = C2Nn exp (-eVbi/(kT)) I = Io [exp(eV/(kT)-1] Io = Ind + Ipd = (C1 Np + C2Nn) exp (-eVbi/(kT)) Rectifier Ac transfers into dc b) a) I t photodiode Based on the photovoltaic effect -solar cell -photodetectors Avalanche diode • Powielanie lawinowe (Vprzebicia>6Eg/e) - elektrony p uzyskują energię - aby kreować pary elektron-dziura przez zderzenie nieelastyczne + n Zener diode Wykład VI photodiode Light is absorbed if hf Eg ; EHP are created; electric field separates carriers • Short-circuit (U = 0) E ID (A) C hf E EF E C V VD (V) 0 E V - Isc Isc = q Nph(Eg) photodiode • Open circuit ID (A) EC EC qVOC Voc EV qVbi EV Id = Io [exp(eVoc /kT)-1] This current balances photogenerated current, Isc Isc – Id = 0 I sc kT kT I sc Voc ln( 1) ln q Io q Io VD (V) Solar cell Transfers solar energy into electric energy P = I x U=I2 x R= U2/R LED Ge Si GaAs Semiconductor laser EFC EFV 0