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EÐL620M / Life in the Universe Astrophysics – chemistry – Biology – earth-/planetary sciences •Atoms - chemical bond •Carbon chemical bond •Atoms and molecules in space; Informations derived from spectroscopy •Molecules in the universe; Existance and formation •Interactions between light and matter ; photochemistry, photoionization, photofragmentation •Thermochemistry in the Universe •Biochemistry A l = 0/s E . l = 1/p : : l = 2/d : : l = 3/f : : : n=4 n=3 n=2 n=1 * ** * A=H l = 0/s l = 1/p E H. .H H:H or * n=2 n=1 H-H A>H l = 0/s l = 1/p e.g. E C(6e-) .H H. C .H 4 x sp3 H. n=2 n=1 * A>H l = 0/s l = 1/p H e.g. E C(6e-) 4x sp3 H C H H * n=2 n=1 A>H l = 0/s l = 1/p H E 4x sp3 H C H H H N O H H H H ** n=2 n=1 A>H l = 0/s H E 4x n=2 n=1 bonds: 1 H-H l = 1/p sp3 H C H H N O H H H 4 3 H H 2 A>H e.g. E C(6e-) l = 0/s H l = 1/p 4 x sp3 H 109.5o C H H 4en=2 * 2en=1 A>H l = 0/s l = 1/p e.g. E C(6e-) t.d.: H 4 x sp3 109.5o C H H H p H 4en=2 C 3 x sp2 120o H * 2en=1 A>H l = 0/s l = 1/p e.g. E C(6e-) t.d.: H 4 x sp3 H 109.5o C H H p 4en=2 t.d.: H H C 3 x sp2 H H * 2en=1 A>H l = 0/s l = 1/p e.g. E C(6e-) e.g.: 4x H e.g.: H sp3 109.5o H 3 x sp2 H C= H C ca 120o H H H p p C 4en=2 C 2x sp H * 2en=1 A>H l = 0/s l = 1/p e.g. E C(6e-) e.g.: 4x H e.g.: H sp3 109.5o H 3 x sp2 H C= H C ca 120o H H H p p t.d.: 4en=2 2x sp H C C H * 2en=1 A>H e.g. E C(6e-) l = 0/s l = 1/p e.g.: 4x H e.g.: H sp3 109.5o H 3 x sp2 H C= H C ca 120o H H H e.g.: 4en=2 2x sp H C 180o C H * 2en=1 A>H e.g. E C(6e-) l = 0/s l = 1/p e.g.: 4x H e.g..: H sp3 109.5o H 3 x sp2 H C= H C ca 120o H H H e.g.: 4en=2 2x sp H C 180o C H * 2en=1 Etc.: e.g.: 3x 3 x sp2 sp2 H H H C= p C= N H 4 x sp3 4 x sp3 H H C C C C C H H H H H H H H H C= p H C= N H H 05.02.12: O O C C C C N C O N O O O N sp3: C, O , N 3 x sp2 Adenine í DNA / RNA Tryptophane / aminoacid 3 x sp2 3 x sp2 4 x sp3 Aspirine Glycine/ aminósýra Large variety of structures: n-butane C4H10 Different isomers 2-methylpropane Large variety of structures: Chiral isomers /chirality: -O CH3 N Chiral isomers, Amino acids e.g. tryptophane: C containing molecules: large variety in structure. C-chemistry: organic- and bio-chemistry. Tryptophane / aminoacid Basic unit in proteins / enzymes C containing molecules: large variety in structure. C-chemistry: organic- and bio-chemistry. C containing molecules: large variety in structure. C-chemistry: organic- and bio-chemistry. Tryptophane / aminoacid Basic unit in proteins / enzymes C containing molecules: large variety in structure. C-chemistry: organic- and bio-chemistry. Adenine Basic unit in DNA / RNA C containing molecules: large variety in structure. C-chemistry: organic- and bio-chemistry. Adenine Basic unit in DNA / RNA C containing molecules: large variety in structure. C-chemistry: organic- and bio-chemistry. Adenine Basic unit in DNA / RNA C containing molecules: large variety in structure. C-chemistry: organic- and bio-chemistry. Bio-compounds / Macromolecules in life: DNA/RNA Próteins; enzymes Fat Carbohydrates :