Download Brake Away - Krystal Kleen Detail

Krystal Kleen Detail Safety Data Sheet according to REACH Regulation (EC) No. 1907/2006
Product: Brake Away
Reference: A-102-MSDS
Version: 1.1
Revision date: 15/05/13
Section 1:
IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Identification of the
substance or preparation
Brake Away
Use of the
substance/preparation
Non-Acid Wheel Cleaner
Company/undertaking
identification
Krystal Kleen Detail
Address
Unit 3b Staplehurst Farm, Weston-On-The-Green, Oxford, OX25 3QU
Telephone
07932-402424
Email
[email protected]
Emergency telephone
Section 2:
HAZARD IDENTIFICATION
Corrosive
Causes severe burns
Section 3:
COMPOSITION/INFORMATION ON INGREDIENTS
Substances classified as dangerous according to Directive 67/548/EEC, if present (individually, or
in combination) in concentrations exceeding those defined under 1907/2006.
Name
EC Number
215-185-5
203-905-0
CAS
Number
1310-73-2
111-76-2
Content
(% W/W)
>5
1-25
Hazard
Symbol(s)
C
Xn, Xi
Sodium Hydroxide
Butyl Glycol
Alkyl ethoxy sulphate
Ethylenediaminetetracetic acid sodium
salt
200-573-9
68585-34-2
64-02-8
1-25
1-20
Xi
Xn
R-Phrase(s)
R35
R20/21/22,
R36/38
R38, R41
R22, R36
Additional substances, listed according to 648/2004.
0.1% or more but less
Alkyl Amido Propyl Dimethylamine Betaine (61789-40-0)
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Print date: 16/05/2013
This product is intended for professional use.
Krystal Kleen Detail Safety Data Sheet according to REACH Regulation (EC) No. 1907/2006
Product: Brake Away
Reference: A-102-MSDS
Version: 1.1
Revision date: 15/05/13
than 1%
Section 4:
FIRST AID MEASURES
***** Speed is essential. Obtain immediate medical attention*****
Inhalation
If patient feels unwell, remove from exposure and keep warm and at rest. If symptoms persist,
seek medical attention.
Contact with skin
Immediately remove contaminated clothing and wash the affected area with plenty of water. If
redness/irritation develops/persists, seek medical attention.
Contact with eyes
Immediately irrigate with eyewash solution or clean water. Continue to irrigate until medical
attention can be obtained.
Ingestion
Wash out mouth and dilute ingested chemicals with plenty of milk or water. Do not induce
vomiting. Seek immediate medical attention.
Section 5:
FIRE FIGHTING MEASURES
*****This product is not flammable*****
Extinguishing media
Water, foam, carbon dioxide, dry powder or water fog.
Hazardous
decomposition
products
No specific decomposition products are noted.
Special fire fighting
measures
There is no specific risk resulting from toxic fumes derived from this product. However, it is
advisable that fire-fighters wear self-contained positive pressure breathing apparatus and full,
chemical proof, turnout gear.
Section 6:
ACCIDENTAL RELEASE MEASURES
Personal precautions
Suitable personal protection should be worn whilst dealing with spillage/accidental release.
Refer to section 8 for further details.
Environmental
precautions
Wash spillage area with water to dilute. Do not discharge into natural waters without pretreatment at a water waste/sewage/biological processing plant.
Methods for cleaning
up
Small spills (<25L)
May be washed down the drain with water
Large spills (>25L)
Should be contained with absorbent material and disposed of
professionally.
Section 7:
HANDLING AND STORAGE
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Print date: 16/05/2013
This product is intended for professional use.
Krystal Kleen Detail Safety Data Sheet according to REACH Regulation (EC) No. 1907/2006
Product: Brake Away
Reference: A-102-MSDS
Version: 1.1
Revision date: 15/05/13
Handling
Eye and skin protection should be worn at all times.
At all times, observe good hygiene and working practices.
Storage
Store in original, closed containers and avoid sharp edges and other potential sources of
puncture.
Ensure product is stacked safely.
Section 8:
EXPOSURE CONTROLS/PERSONAL PROTECTION
Short term (15 mins)
2 mg/m3
Long term (8 hour TWA) 123 mg/m3
Short term (15 mins)
246 mg/m3
Occupational
exposure limits
Sodium Hydroxide Butyl Glycol
Hand/Eye/Skin
Protection
Hand, eye and skin protection should be worn at all times. In case of spillage, rubber boots and
PVC suit should be worn.
Respiratory
Protection
Not normally required due to low volatility.
Section 9:
PHYSICAL AND CHEMICAL PROPTERIES
Colourless to Pale Yellow Liquid
Slight solvent
> 100 ˚C
na
> 13 (1% aqueous)
~ 1.1
Miscible with water in all proportions
Appearance:
Odour:
Boiling point:
Flash point:
pH:
Relative density:
Solubility:
Section 10:
STABILITY AND REACTIVITY
Stability
Stable under normal conditions.
Materials to avoid
Acids. Ammonia. Ammonium salts. Alcohols. Peroxides. Halogenated solvents. Nitroalkanes.
Acid anhydrides. Aluminium. Zinc. Tin. Magnesium. Aldehydes. Ketones. Unsaturated oils.
Sugars. Phosphorous.
Conditions to avoid
Excessive heat and cold. Direct sunlight.
Hazardous reaction
products
Attacks many metals liberating hydrogen gas.
Section 11:
TOXICOLOGICAL INFORMATION
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Print date: 16/05/2013
This product is intended for professional use.
Krystal Kleen Detail Safety Data Sheet according to REACH Regulation (EC) No. 1907/2006
Product: Brake Away
Reference: A-102-MSDS
Version: 1.1
Revision date: 15/05/13
Acute toxicity:
Sodium Hydroxide - Estimated lowest lethal dose in man is 5g
LD50 (oral, rat)
365mg/kg
Inhalation:
Low risk – not volatile.
Prolonged inhalation of vapours may lead to irritation of respiratory pathways and other ill
effects.
Skin:
High risk.
Will cause irritation and redness followed by blistering and severe dermal damage.
Eye:
High risk.
Will immediately cause severe irritation followed by ocular lesions with a high risk of
permanent damage.
Ingestion:
High risk.
Will immediately cause severe irritation of mouth, throat, oesophagus and stomach. If not
immediately diluted with milk/water, severe internal damage and burns may be experienced.
Section 12:
ECOLOGICAL INFORMATION
Ecotoxicity
Concentrations greater than 100ppm, especially in fresh water, or with a pH value greater than
10.5, may be fatal to fish and other aquatic organisms. Can also damage aquatic plants and
vegetation.
Persistence and
degradability
Easy to eliminate.
Biological degradability > 90%
Bioaccumulative
potential
Does not bioaccumulate.
Other adverse effects
Effluent treatment: - Concentrations sufficient to render effluent alkaline may cause damage to
effluent treatment organisms.
Section 13:
DISPOSAL CONSIDERATIONS
Empty containers should be rinsed with water prior to disposal or recycling. Uncontaminated packaging may be
returned and re-used. If necessary, quantities greater than 25 Litres/Kilograms should be treated by a professional
disposal company.
Section 14:
TRANSPORT INFORMATION
UN Number
Proper shipping name
Class
Packing group
Hazard identification number
Other information
1824
SODIUM HYDROXIDE SOLUTION
8
II
80
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Print date: 16/05/2013
This product is intended for professional use.
Krystal Kleen Detail Safety Data Sheet according to REACH Regulation (EC) No. 1907/2006
Product: Brake Away
Reference: A-102-MSDS
Version: 1.1
Revision date: 15/05/13
Section 15:
REGULATORY INFORMATION
Hazard symbol(s)
Corrosive
Hazard determining component(s)
Sodium Hydroxide
R-phrase(s):
R35
Causes severe burns.
S-phrase(s):
S1/2
S26
S27/28
S36/37/39
S45
Keep locked up and out of reach of children.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
After contact with skin, take off immediately all contaminated clothing and wash immediately with
plenty of water.
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident, or if you feel unwell, seek medical advice immediately. (Where possible, show
this label)
Guiding information:
This product is classified, labelled and packaged according to the Chemicals (Hazard Information and Packaging for
Supply) Regulations (Northern Ireland) 2009 and to the Approved Classification and labelling Guide (Sixth Edition).
Additional reference has also been made to EC Directive 67/548/EEC.
The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in
Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent
authorities of the Member States and will be made available to them, at their direct request or at the request of a
detergent manufacturer.
The information within this data sheet has been collated from EC regulation 790/2009 (amended 1272/2008), the
CESIO recommendations for Anionic and Non-ionic surfactants (2006), the EH40/2005 Workplace Exposure limits, the
Detergent Ingredients Database (DID-list, maintained by Ecolabelling Norway on behalf of the European Commission),
CESIO recommendations for the classification and labelling of surfactants as “Dangerous for the Environment” and
from ingredient safety data sheets.
The data should be considered when making any assessment under the Control of Substance Hazardous to Health
(COSHH) Regulations.
Section 16:
OTHER INFORMATION
Full text of hazard symbols and R-phrases, if mentioned as hazardous components in section 3.
C
Xi
Corrosive
Irritant
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Print date: 16/05/2013
This product is intended for professional use.
Krystal Kleen Detail Safety Data Sheet according to REACH Regulation (EC) No. 1907/2006
Product: Brake Away
Reference: A-102-MSDS
Version: 1.1
Revision date: 15/05/13
Xn
R22
R35
R20/21/22
R36
R36/38
R38
R41
Harmful
Harmful if swallowed
Causes severe burns
Harmful by inhalation, in contact with skin and if swallowed
Irritating to eyes.
Irritating to eyes and skin.
Irritating to skin
Risk of serious damage to eyes
PLEASE NOTE: the above risk phrases refer to the full strength ingredients, not to the formulated product.
Revision history:
Revision
1.1
Author
CAH
date
15/05/13
notes
MSDS Created
Checked
If you have any queries relating to this MSDS, its contents or any other safety related questions,
please write to: [email protected]
The information contained herein is believed to be accurate and is given in good faith. No warranty
or guarantee is implied. Recipients must take responsibility for observing existing laws and
regulations.
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Print date: 16/05/2013
This product is intended for professional use.