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A BI V O EY BR I COLU M SH GE TI LO GICAL SUR British Columbia Geological Survey Geological Fieldwork 1993 GEOLOGY OF THE POTHOOK ALKALIC COPPER-GOLD PORPHYRY DEPOSIT, AITON MINING CAMP, BRITISH COLUMBIA (921/9,10) Clifford R. Stanley, Mineral Deposit Research Unit, U.H.C. (MDRLI Contribution # 035) KEYWORDS: Ecorlomic geology. porphyry, copper, gold, supergene, alkalic. Nicola, Pothook. Sugarloaf, Cherry Creek, diorite, monzonite, Iron Mask, Quesnellia. INTRODUCTlON The Pothwk deposit is one of several alkalic porphyry copper-gold ,deposits (Afton, Crescent, Ajax East, Ajax West) developed in the Afton mining camp, located 10 kilometres west of Kamloops, British Columbia. These deposits are,311 hosted by the Iron Mask batholith, a large composite alkalic inwsion of earliest Jurassic age that intrudes latest 'Triassic Nicola volcanic rocks of the Quesnellia oceanic island arc terrain (Souther. 1992). The Pothook deposit is located on the southwestern edge of the Iron Mask batholith. approximately 750 metres southeast of the much larger Afton copper--golddeposit (Figure 1). It contained a gcological reserve of 3.26 million tonnes grading 0.40% copper and 0.16 gram per tonne gold ($0.40 copper equivalent cut-off; Bond, 1985). Between October 1986 and September 1988, Afton Operating Corporation, a division of Teck Corporation, mined 2.60 million tonnes of ore with an average grade of 0.35% copper and 0.21 gram of gold per tonne froman open-pit, with a stripping ratio of I : I .9 (L. Tsang, personal communication, 1993). Detailed open-pit mapping ;at 1:300 stall , more rt?gional mapping of the area around the Potho lk deposit at 1:2400 scale, and drill-core logging carried 011 during; Ihe summer of 1993 have documented the compl cated geclogical history of the deposit. Art open-pit mi p of the P:sfhook deposit is presented in Figure 2. GEOLOGICAL HISTORY The geological history of the Pothook zc ne is summarized in Table I and a full description of tl e geolog,ir:al units and events is presented in chronologica order b+ low. LATE TRIASSIC Several different volcanic lithologies act as hostrocks for the Iron Mask batholith in the depo ,it area. These consist of: dark green tct black, aphyric to plagio. clase-phyric, massive basalt flows; maroon t( dark grf:): aphyric to sparsely plagioclase or augite-phy: ic, poorly bedded, ash to lapilli mafic tuffs and lesser blocky agglomerates; black, crowded, augite-phyric, massive &Isalt flows; dark grey, crowded plagioclase-pk yric andesite flows and feeder dikes; and dark gre :n to blacic, crowded augite-phyric picrite flows (Snyder md Russell, 1993b). These units comprise the Carnian to iorian (la:.. est Triassic) Nicola Group on t b a southweste. n edge of the Iron Mask batholith (Preto, 1977). EARLY JURASSIC The Nicola Group was intruded during 11 e earliest Jurassic (at approximately 2073 Ma; Ghosh, 993) by t ~ e Iron Mask batholith. Several iutrusivebodies comprise the batholith; all are exposed in the Pothook (,penpit. POTHOOK DIORITE The first to intrude wasthe Pothook dim te phase, predominantly fine to medium-grained, equig ranular, pyagioclase-augite diorite with late poikilitic hio ite conta.ining both plagioclase and augite inclusions (Suyder and Russell, 1993a). Disseminated magnetite in variable coocentrations up to 10%. and accessory potassil rn feldspsr Figure I . Generalized geological map of the Iron Mask batholilh, showing locationsof Ihe principle mineral deposits (after Kwong, and apatite also occur. The Pofhoek dioritein :orpOratal 1977). .% Geological Fieldwork 1993. Paper 1994-1 :!75 I , I Y ! Figure 2. Geological mapof the Pothook akalic porphyry copper-gold depositopen pit. 2 76 British Columbia GeologicalSurvey Branch TABLE 1 SUMMARY OF CHRONOLOGY OF INTRUSIVE, STRUCTURAL., ALTERATION/METAMORPHISMIWEATHERINGEVENTS IN THE POTHOOK ALRALIC PORI'HYRY COPPER-GOLD DEPOSIT Fdtlng Intrusion t 1 Fine to medium-grained Pothook diorite intruder NicolaVOIC~II~ES Medium-grained Pothook diorite intrudes fine 111 mcdiumgrained Pothook diorltr Steep N N W and ENE faulting disrupts intmsive conLIcu Cherry Creek mommite intrudes earlier Pothook diorite phase Steep N N W and ENE faulting disrupts intrusive contam Sugarloafdiorits dikes intrude volcanic$ and fine to mediumgrained Pothook diorite disrupts intrusive contacts 7 topsto sw with Kaml<?ops Group mag=magnetile; act= actinolite; plag-plagioclase; alb-albite; aug-augite; chi-chlorite; biot-biotite; cpy-chalcopyrite; chakchalcocite Geological Fieldwork 1993, Puper 1994-1 i!7? numerous blocksof volcanic rocks as xenoliths within the intrusion. In places, especially near the margins of the diorite, these xenolithsare sufficiently abundant to comprise an intrusion breccia. Apophyses of Pothook diorite also intruded along faults and steeply dipping depositional contacts in the volcanic hostrocks. A fine-grained chilled margin of the diorite occurs at the intrusive contacts with these volcanics. Volcanic rocks adjacent tothe diorite contact recrystallized to a biotite hornfels containing less than 1% disseminated pyrite cubesand disseminated magnetite. A medium-grainedvariety of Pothook diorite was intersected at depth in exploration drill-holes. This latervariety intrudes the fine tomedium-grained Pothook diorite variety, but is otherwise petrologicallysimilar. It is not observed to intrude, nor contain xenoliths of, Nicolavolcanic rocks. After the Pothook diorite intrusionhad cooled sumciently to allow brittle fracture, an episode of largely steep faulting disrupted the diorite-volcanic contact and juxtaposed volcanicrocks, without contact metamorphic recrystallization effects, and diorite. Displacements along these numerous, steeply dipping faults (mosthave dips >70)are probably vertical, appear tobe generally less than I 0 0 metres, and several sets of fault orientations were observed (NNWand E N E Figure 3). This faulting alteration deappears to predate the pervasive potassic scribed below. After and probably during this steep faulting, magnetite-apatite-actinolite veins, blebs, schleiren and breccias formed along dilatant fractures. These fractures also occasionally contain epidoteand chlorite, both within the structures and in alteration envelopes surroundingthem, Figure 3. Stereonet of poles to steeply dippingfaults cutting Pothook dioriteand Nicola volcanics (n = 97). 278 Blebs and schleiren tend to occur in large envelopes about major magnetite veins. The Magnet showing, and probably other magnetiteveins in the Iron Mask batholith, formed at this time (Cann, 1979). In the Pothook deposit area, all of these magnetite-bearing structures are hosted by the fine to medium-grained Pothook dioriteor by intrusion breccia with a fine to medium-grainedPothook diorite matrix. These magnetite-bearing structures may have formed from coalescing orthomagmatic hydrothermal fluids evolved from other, still molten, parts of the Pothook diorite during late stage crystallization. CHERRY CREEK MONZONITE The Cherry Creek monzonite phase of the Iron Mask batholith was next to intrude. In the Pothook area, it intruded only Pothook diorite (Stanleyet al., 1994, this volume). This intrusion is generally avery fine grained, equigranular, potassium feldspar-plagioclase-biotiteaugite monzonitewith accessory magnetiteand apatite, and trace quartz (Snyderand Russell, 1993a). It also contains small miarolitic cavities filledwith quartz, and locally exhibits an aplitic texture. Its emplacementwas apparently controlled by pre-existing structures within the Pothook diorite; it doesnot intrude Nicola volcanic rocks in the Pothook area(Stanley et al., 1994). No contact metamorphic effects were observedin Pothook diorite adjacent tothe Cherry Creek monzonite. A generally pervasive potassic alteration occurs within but near the margins of the Cherry Creekmonzonite and in Pothook diorite adjacent to exposuresof Cherry Creek monzonitein the open pit. This alteration involved the ‘selective pervasive’ replacement of plagioclase by potassium feldsparin both phases, and the partial destruction of disseminated magnetitein the Pothook diorite. Biotite remained stable, but augite was commonly replaced by epidote. At the margins, this ‘selective pervasive’ alteration grades outward into fractureswith potassic alteration envelopes, indicatingthat at least the outer parts of these alteration zones formed from coalescing alteration envelopes. The close spatial association between this alteration and the monzonite suggests that the alteration is probably deutericand was related to andoccurred duringthe late stages of cooling of the monzonite. The widespread nature of this alteration, and the pink colour imparted by the potassium feldspar, have causedpervasive, potassically alteredfine to medium-grained Pothook diorite tobe confused with the fine-grained Cherry Creek monzonitein the past (Stanley et al.. 1994, this volume). In the Pothook open-pit, this early pervasive potassic alteration is restrictedto the north wall, adjacent toand above the exposure of Cherry Creek monzonite. After intrusionof the Cherry Creek monzonite, additional steep faultingtook place. Displacements occurred largely along pre-existing structures,and this further disrupted intrusive contacts along the southwest edge of the batholith. British Columbia Geological Survey Branch SUGARLOAF DIORITE The second p+:riod of faulting was followed by the intrusion of the Sugarloaf diorite into carlierphases of the Iron Mask batholith and surrounding rocks. This diorite contains large, sparseto crowded, stubby hornblende phenocrysts, generally smaller augiteand commonly trachytically aligned plagioclase phenocrysts. These are set in an aphanitic groundmassof plagioclase and potassium feldspar with dissemirlated magnetite (Snyder andRussell, 1993a). TheSugarloaf diorite was emplaced as a setof northwest-trending, steeply dipping dikes along the southwestern edge of the batholith. These intrudeNicola volcanics more commonlythan Pothook diorite,do not intrude the Cherry Creek monzonite, and are widest, most abundant, and,in some casesradially oriented, around Sugarloaf Hill, which is thought to be a volcanic neck and intrusive:centre (Snyderand Russell, 1993b). As such, the intrusive formof the Sugarloaf diorite resembles the classic hypabyssalvolcanic neck at Shiprock, New Mexico (Press andSiever, 1978). Sugarloaf dioriteproduced contact metamorphismin adjacent volcanicrocks. This involvedthe completerecrystallization of mafic volcanic rocks to an actinoliteplagioclase hornfds with abundant disseminated magnetite. This contact metamorphismwas texturally destructive so the protoliths of amphiholitized Nicola volcanic rocks canno't be ascertained. No contact metamorphic effects are apparent in Pothook diorite where it isintrudad by the Sugarloaf diorite dikes, probably because of the low hydration state of the Pothook diorite and the stabilitiesof the minerals comprisingit under those metamorphic conditions. The more extensive recrystallization of volcanic hostrocksassociated with emplacement of the small Sugarloaf diorite dikesmay suggest that these dikes wereintruded at higher temperatures than the Pothook diorite.Alternatively, the probably higher volatile fugacityof the Sugarloaf phase, as indicated by its more porphyritic texture, may have more efficiently catalyzed recrystallization and metasomatism, forming the higher grade hornfels. Another stageof hydrothermal alteration t w k place after intrusion of the Sugarloaf diorite. Thistook the form of partial to pervasive albiticalteration and was confined to the intrusiverocks. This alteration becomes pervasive It probwhere envelopes surrounding fractures coalesce. during cooling of the Sugarloaf diorite. and occurred ably In tha alalso have been deuteric. Pothook diorite, may bite replaced plagioclase, augite andpotassium feldspar, and chlorifer e p l ~ e dbiotite. Moderate but subequal amounts of chalcopyrite and pyrite precipitation accompanied this alteration. This albitic alteration most is intense (pervasive) on the southeastwall of the open pit, below the ramp, where the Pothook diorite consists almost completelyof albite. Elsewhere, Pothook diorite is incompletely albitized, occasionallyin fracture envelopes, where plagioclaseis selectively but pervasively replaced by albite but chlorite hasnot replaced biotite, and augite and potassium feldsparremained stable. The Sugarloaf diorite is only'selective pervasively' albitized. AlGeological Fieldwork 1993, Paper 1994.1 bite replaced plagioclase and potassium feld ;par, but hornblende generally 1ernaine.dstable. Suga loaf diorilc: also containsblebs of epidote thought to be elated tcl \his alterahon event. The pervasive albitic alteration is oveq! inted by fracture-controlled potassic alteration repres :nted by through-going potassium feldspar-biotite-ep dote veins. These were strongly controlled by steeply d pping. n8z-hnorthwest-striking fractures (Figure4) and L re restric:tt:d to the Pothook dioriteand Cherry Creekmo lmnite i n n sions. These veins are not significantly dilat Int but are continuous across20 vertical and 30 horizo~)tal metre!: and in many places constitute 'sheeted' veir sets. During this hydrothermal alteration, different vein i nd envelopc alteration mineral assemblages were producsdin different lithologies. Specifically, in unaltered to nodera1e:l.ialbitized Pothook diorite andCherry Creek mmzonite, the veins are primarily filled by lmtassium feld: par and Ii.. otite and have epidote envelopes. In pervasively albitimtl Pothook diorite, the veins are commonly fil ed by epidotm: and have potassium feldspar and biotite en\ elopes. In :pe :vasive potassically altered Pothook diorite, he veins are generally filled only by epidote:. All of thesl, potassium feldspar - epidote veins contain smallbut SI bequal amounts of chalcopyrite andpyrite, and are well developed on the southeast wall of the open pit a lovethe ramp, and along the north wall of the open- Dit just a h v e the ramp on the lowerbenches. This slructlrally cor11~~31led potassic alteration introduced a small a1 lount of c o p per and gold mineralization, as, chalcopyritl and bornite, in the veins. Following the episodeof fracture-con1 olled potlosic alteration, further steep faulting dissected ntany o f t ! ~ : Sugarloaf diorite dikesand through-going 1 otassiunl feld- Figure 4. Stereonet of poles UI strucNrally COI trolled pot;iosium feldspar - epidote veins (n = 1, .). 2'79 spar-epidote veins, and further disruptedthe margin of the Iron Mask batholith. Much of this movementtook place along pre-existing structures. COPPER-GOLD MINERALIZATION None of the previously described pervasiveor fracture-controlled hydrothermal alteration events is characterized by the introductionof significant amountsof copper to the Pothook area. The copper ore-forming event is represented by iron oxide - sulphide veins. On the southwest sideof the open-pit, these veins are characterized by a chlorite-pyrite-chalcopyrite-magnetite(specular) hematite mineral assemblage, whereason the northeast sidethey contain chalcopyrite, borniteand magnetite. These veins, like the potassium feldspar-epidote veins that they cut, were not significantly dilatant. Similarly, they also have apreferred orientation approximately perpendicular to the orientation of the potassium west-southwest to feldspar - epidote veins, ranging from northwest with dips generally greaterthan 45 (Figure 5 ) . The density of these mineralized veins appears to control ore grade, and produced some very significant copper and gold concentrations (occasionallyup to 2%Cu and 2 glt Au in exploration drilling samples). Where these veins cut Nicola volcanic rocksor their metamorphosed equivalents, significant chlorite selvages and envelopes are developed. Where they cut intrusive rocks, epidote on the vein margins. envelopes and selvages predominate These veins are not through-goingand tend to dissipate into micro-fractureswith epidote orchlorite envelopes. Previously existing fault zones are also at least partially filled by theseiron oxide - sulphide veins. In the centre of the open pit, and seen only in drill core, there is alarge body of hydrothermal brecciathat contains rotated and clasts of Pothook diorite, Cherry \ e . EOCENE - Figure 5 . Stereonet of poles to iron oxide - sulphide veins (n = 112). 280 Creek monzonite, Sugarloaf diorite, and Nicola volcanics in a matrix of rock flour, chlorite and pyrite,with subordinate amounts of magnetite, chalcopyrite andbornite. In places, especially toward the centre of the breccia, these clasts are well rounded due to milling, range in size from 5 to 100 millimetres, and are clast supported.Toward the margins of the breccia, fragments are larger and more angular, and the breccia grades into a crackle zone with unrotated fragmentsin a disrupted stockworkof iron oxide sulphide veins. As such, the hydrothermal breccia and veins are interpreted to be geneticallyrelated. The mineralizing episode that produced the sulphidehearing veins and breccia was followed by, or possibly evolved into, a propylitic episode of chlorite veining without significant amountsof associated copperor gold mineralization. Chlorite veinlets fill narrow fractures at all scales, from large through-going joints down microto fractures, in both volcanic and intrusive rocks. They are responsible for the predominantly darkcolour of rock exposures in the open pit because blasting has broken the rocks along these veins, exposing dark green chlorite. This chlorite veining event involved no other alteration minerals, except for minor amountsof calcite and disseminated pyriteintergrown with the chlorite. Chlorite veins do not occur in pervasive albitically alteredPothook diorite. Rather, late kaolinite-calcite-filled microfractures are prevalent (Bond,1985). These veins may be the equivalent to the chlorite veins, but contain no chlorite because of the lackof iron and magnesium in intensely alhitized Pothook diorite. Calcite veins crosscut the propylitic chlorite veins. In the intrusive units, theseveins consist solely of calcite with no associated alteration envelopes.In the Nicola volcanic rocks, they are commonly associatedwith talc and serpentine, and have chlorite selvages. Calciteveins have no preferred orientation, andare not through-going.In general, wider calcite veins tend to be truncated by smaller, crosscutting calcite veins. Wider calcite veins are generally isolated from each other, and thus are rarely widespread and abundant enough to form crackle zones. of these calcite Nevertheless, the overall distribution veins suggest that the rocks have been intensively shattered, in spite of the relative absenceof large crackle zones. The calcite veins postdate the sulphide-bearing fluveins and probably formed from lower temperature ids. They also partially fill pre-existing fault zones. Another episodeof faulting followed the mineralizing and alteration events. Unlikethe earlier episodesof faulting, movement occurred along relatively shallow planes with southeasterly strikes and dips generally less than 30 to the southwest (Figure6). Numerous faults with this orientation cut the upper southwest wall of the open pit, and display spoon-like, concave-upward(lisuic) forms. The displacement directionis generally to the southwest, and movements of up to 50 metres are indicated on individual fault planes. Given the number of these faults,the main mass of Pothook diorite and SugarBritish Columbia Geological Survey Branch ment blanket. Instead, themeteoric fluids caused the destruction of primary copper sulphideminera ization ard the formation of secondary native copperan i chalcocite. This produced a supergene blanket without I opper enrichment (cJ Kwong, 1987). This weathering is Iredomi.. nantly fracture controlled, often occurring ir open spac:es thought to be originally filled by calcite, anc penetrates to depths of np to50 metres below the bedrc ck surfact: in unfractured rocks andto depths greaterthan 200 metre !; along faults. Finally, further movementon pre-existi: Ig, northusststriking faultsdown-dropped supergene weathered material into grabens where they were protected iom subsequent Pleistocene glacial erosion. ORE DISTRIBUTION Figure 6. Stereonet of poles to shallow listric faults with southwesterly directedthrow (n = 16). loaf diorite dikes above these faults may have been displaced significant ,distances from the margin of thebatholith (upto or exceeding250 m) ontounmetamorphosed Nicola volcanics. This stageof faulting may reflect unroofing of the batholith,possibly during a period of extensional tectonics that affected theregion during the Eocene (Souther, 1992). Late, relatively rare mafic dikesintruded the Pothook area during the Eocene. These are aphyric to sparsely plagioclase phyric and are unaltered. They may be feeder dikes to !.he mafic volcanic: rocks in the Eocene Kamloops Group, which fills grabens formedduring extension (Souther, 1992). Rare, late qualtz-calcite-chloriteveins cut through all lithologies in the open pit. They partially fill all faults, including those with shallow dips, and previously formed veins with open spaces. They also fill shallow-dipping fractures oriented parallel to the shallow-dipping 'detatchment' faults. These veins contain amethystine quartz and may be related to hydrothermal activity associated with Kamloops Group rnafic volcanic feeder dikes. During a period of lateTertiary supergene weathering, some ofthe chalcopyrite and bornite was destroyed and replaced by native copper, chalcocite and earthy hematite. Pyrite WBS also partially destroyed and replaced by earthy hematite and goethite during this supergene event. This weathering appears to have occurred without significant supergene enrichment, but local movements into adjacent fractclres undoubtedly occurred. This relative lack of coppermobility was probably due to the high calcite and low pyrite abundances in the deposit.The relative absence of pyrite limited the amountof acid that could be produced during weathering, and the of calcite neutralized any acid that wasproduced. This prevented descending meteoric fluids becoming sufticiently acidic to transport copper downward to form a supergene enrichGeological Fieldwork 1993, Paper 1994-1 Copper and gold grades in both explora ion drillholes and production blast-holes were exam ned to assess lithological and structural controlson miner,ilization. Scatterplots of copper and gold concentratio 1s are prn. sented in Figure 7. This demonstrates thatcc pper ancl gold concentrations are not well correlated, , md that, in general, high copper concentlations occurin samples with relatively low gold grades, and vice ve? FU. This lack of correlation between copper and gold grad: is differmt from most other alkalic porphyly copper-go1 d deposits, which commonly exhibit strongly correlatedcopper ard gold concentrations, and relatively constant :opper/go:d ratios within individual deposit!; (average ral ios in individual deposits range from 10 OW to 25 OOO Stanley,, 1993). Figures 8 and 9 are bubble plots of coprer and gold blast-hole assays from the 2340-foot bench i 1 the Polhook open pit. Higher copper grades exhibita strong structural control and define trends with vari Ible strike:;. Many of these trends can be traced directly i >tofault zones mapped on the 2340-fool bench (Figu e 2). Th1:re C" (PC11 Figure 7. Scatterplot of explorationdrill-hole md produilion blast-hole copper and gold assays from the 21(0, 2160, 222C, 2280,2340 and 2400-foot benches in the Pothoor open pit (n :: 3992). ;!81 c ” ! 10700 1osoo 1 10300 - - 11 100 117001150011300 1090010700 Figure8.Bubbleplotofproductionblast-holecopperassaysfromthe2340-footbenchofthePothookopenpit.Assaysbavebeentransformed andscaledtoenhancegeocbemicalcontract.Thesmalleslandlargestbubblescorrespondstocoppergradesof0.0l%and2.60%,respectively (n = 635). 10700 1 1oso0 1 1 10300 i 10100 I 11300 11100 10900 10700 ~ * I 8 1 1 1 1 1 Figure 9.Bubble plot of production blast-hole gold assays from the 2340-foot bench of the Pothook to enchance geochemical contract.The smallest and largest bubbles correspond to gold and scaled tonne, respectively (n = 635). 282 Geological Columbia British 1 1 1 open pit. Assays have been transformed grades of 0.034 28.972 and grams per Survey Branch fault zones are stecply dippingand were active before, during and after mineralization in the Pothook deposit. The distribution ofhigher gold concentrations, however, suggests that the gold and copper mineralization in the Pothook depor,it isnot identically controlled(Figure 9). In fact, there is little correspondence between the locations of high gold and high copper concentrations in blast holes. The lack of correlation between copper and gold, in terms of both magnitude and space, maybe duein part lo local mobility during supergene weathering, or to inaccuracies produced by nugget effects. However, given the relatively high density of blast-holes (approximately 20foot spacing), the spacingof assays in exploration drillcore samples (continuous, immediately adjacent intervals), and the masses of these samples ( >2 kg), it is more likely that copper and gold do not share an identical mineral paragenesis. Whereas thetiming of copper mineralization canbe d,:termined because the copperminerals are visible, the timing of gold mineralization remains unclear. Copper and gold may have been introduced at different times,or by the differentmeans, during the hydrothermal history of the deposit. CONCLUSIONS In the Pothook area, the Pothook diorite, Cherry Creek monzonite and Sugarloaf diorite all intruded latest Triassic Nicolavolcanics during the earliest Jurassic. These intrusionsand their host-rocks have been affected by several, largelypre-mineral, stages of hydrothermal alteration: rnagneti1.e veins and breccias controlled by fractures in the Pothook diorite;pervasive potassic alteration associated with the Cherry Creek monzonite; pervasive albitic alteration:associated with the Sugarloaf diorite; and late, potassium feldspar - epidote veins. Copper-gold mineralization in the Pothook area appears to hemost (closely related to Sugarloaf diorite dikes that cut Nicola volcanics along the southwest margin of the Iron Mask batholith. Mineralization occurs predominantly in hydrothermal breccia and steeply dipping, eaststriking veins that cut all three phases of the batholith and the surrounding Nicola volcanics. The Pothook orebody is characterized by abundant pyrite, magnetite, chlorite and minor (specular) hematite gangue and chalcopyrite, bornite and native copper ore minerals. Ore-stage mineral zoning is spatially consistentwith both the predominant orientation of the veins and a hydrothermal fluid source in the Sugarloaf diorite dikes. The zoning of pyrite-chalcopyrite and chalcopyritebornite mineral assemblages across the deposit suggests that copper andp l d mineralization may have precipitated under variable temperature andlor fluid sulphidation conditions (Einaudi, 1993) encountered as fluids migrated away from theSugarloaf diorite dikes. Precipitation of copperand goldoccurred after the pervasive albitic alteration event thataffected all intrusive rock types, and contact metamorphism of volcanics adjacent to Sugarloaf diorite dikes. Thehostrocks to mineralization appear to have been made more competent by Geological Fieldwork 1993, Paper 1994-1 these pre-mineral alteration events such that they fractured more brittley and acted as ready hosts for minerdization. Late, post-mineral chlorite veins cut un albitized rocks, whereas kaolinite veinleu cutalhitizc d rocks. Later calciteveins cut all lithol.3gies. During the Eocene, low-angle ’detachn ent’ faulting, mafic dike emplacement and graben format on reflect I b c . extensional tectonic episoIJe t h a t affected th :Pothook area. Latequartz-bearing veins are associatc d with this tectonic and intrusive episode. REFERENCES Bond, L. (1985): Geologyandb4ineralization of the P~~lhook Zone; Afton Operating Corporalion, inter la1 comp :I 1:port, 99 pages. Cann, R.M. (1979): Geochemist0 of Magnetite and the Cifneris of Magnetite-ApatiteLode!;intheIronflaskBalholith. British Columbia; unpublishedMSc. thesi i, The Un~v?rsity of British Columbia. 106 Ipa;:es. Einaudi. M.T. (1993): Anatomy oi‘Porphyry Co >perSystms. in VolcanocsandOreDeposits, Mineral Leposir Rts<rm:h Unir, The Universiry oJBriti,rh Columbia, ::hart Course No. 14, April. Ghosh. D. (1993): Uranium-LxadGeochronolrgy, in Pcr>hyry Copper-Gold Systems of British Columt ia; Mineral De- .I posir Research Unir, The L’niversiry of British Coiuaha, Annual Technical Report. pages 11.1-11.25. Kwong, Y.T.J. (1987): Evolution af the Iron M sk Batholilh aid its Associated Copper Mineralization; B.C. Minisrq I f E n epy, Mines and Perroleurn ,Qesources,Bu letin 77. Press, E and Siever, R. (1978): E,arth;WH.Fn eman and (7o.npany, San Francisco, 649 pages. Preto. V.A. (1977): The Nicola Group: Mesozoc Volcanisiu Related to Rifting in Southom British Colu~ibia; in Vol,:al!ic Regimes in Canada, Raragsr, W.R.A.,C, ‘leman.L C . and Hall, J.M.,Editors, Geoloqb-alAssociatior ofCanarl6, Specia1 PaperNo. 16, pages :39-57. Snyder, L.D.andRussell, J.K (1993a): Fie181 Constrailrts on Diverse IgneousProcesser in the Iron MaskBatholith (9219.10); in Geologicall3eldwork 1952, Grant, II. and Newell, J.M., Editors,E. C. Minisfryof E zergy, Mim:r ond Permleum Resources,Palm 1993-1, page i 281-286a. Snyder. L.D. and Russell,J.K. (1993b): Pebolo! y and GevchernicalAspectsofRocksinth~:I”onMaskBath,lith;inPotph!,ry Cu-Au Systems of British t:olumbia, Mir era1 Depxd I!esearch Unit, The Universily of Brirish Columbia, P.nnllal Technical Report, pages!i,Cl.O-5.2.15. Souther, J.G. (1992): Volcanic Regimes; in Ge, ‘logy of thc: C m dilleran Orogen in Canada, Gabrielse, H. and Yoratt, C.J., Editors, Geological Survey of Canada, lecade of I‘lonh American Geology Project, PaperNo. 4, )ages 457-450 Stanley, C.R.(1993): A ThermodynamicGeod :mica1 Model For the Co-precipitation of Gold and Chalcl pyrite in Alkidic Porphyry Cu-Au Deposits; in Porphyry ( u-Au Sy!;tmr of BritishColumbia’. Minsnd Deposir Re:earch Umt. ;“he Universiry ofBritish C o h b i a , Annual rechnical Repm, pages 12.1-12.17. Stanley, C.R., Lang, J.R. and Sn,yder, L.D. (19>4):Geolo:y ;md Mineralizationin the Nolthem Partofthe .ton Mask I’luton. ;!83 Kamloops British Columbia (92U9. IO); i n Geological Fieldwork 1993. Grant, B. and Newell, 1.M.. Editors, B.C. 284 Ministry oJEnergy, Mines 1994-1, this volume. and Petmleum Resoumes, Paper British Columbia Geological Survey Branch