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ANALOG FEEDBACK Li-Ion Cells Build Better Batteries for Power Tools By David Morrison, Editor, Power Electronics Technology A substantial, vendors are using the technology to market their new products. For example, Milwaukee Electric refers to its battery pack as the V28 Lithium-Ion cordless technology and its end products as the V28 line of tools. Cells based on the V28 technology employ manganese-oxide cathodes rather than the cobalt-oxide cathodes commonly used in low-power applications. To create a 28-V pack requires seven of these 4-V, 3-Ah Li-ion cells. To serve the power tool applications, Li-ion batteries have been modified to operate at high discharge rates. So, while the standard Li-ion batteries specify their capacity at a 1C (or even lower) discharge rate, high-power Li-ion batteries typically specify performance at a 10C or higher rate. Low-power and high-power Li-ion cells differ with respect to rated capacity and the variation in capacity as a function of discharge rate. In general, the cells developed for high discharge rates sacrifice some of the energy density achievable at lower discharge rates to obtain lower impedance in the cell. For example, in the 18650 cylindrical format, Sanyo now offers a high-power cell with 1500-mAh capacity at 10C, while one of its low-power cells currently offers 2600 mAh at a 0.2C rate in the same package.[1] Typically, conventional Li-ion cells have limited ability to deliver high power. In contrast, the high-power Li-ion cells offer nearly the same capacity at high and low discharge rates. fter becoming the dominant rechargeable chemistry in cell phones, PDAs and a host of other mobile applications, Li-ion batteries are just starting to prove their metal in highpower portable applications such as power tools. Just as in the lower-power applications, high-power Li-ion cells offer higher energy density than the NiCd and NiMH cells they replace. Recently developed Li-ion cells offer two to three times the gravimetric energy density of the nickel-based chemistries—an advantage that can be exploited either to build lighter battery packs or to extend battery run times. One equipment manufacturer, Milwaukee Electric Tool, collaborated with an established battery manufacturer to develop a 28-V Li-ion battery pack that offers greater power and up to twice the run time of conventional 18-V NiCd models. Despite its higher performance, the 28-V pack weighs slightly less than the 18-V pack. As a result, the company is able to create some of the first cordless versions of professional-grade power tools (see the figure). One example is a cordless bandsaw that is described as “powerful enough for everyday use.” Latest Offerings Sanyo (www.sanyobatteries) continues to develop cells with a high discharge rate/higher power capability. A recent example is Sanyo’s UR18650W, a cell that specifies a typical capacity of 1600 mAh and a minimum capacity of 1500 mAh. The cell achieves this minimum capacity at a 10C (15-A) discharge rate (see the table). The cell is constructed with a manganese-oxide cathode to improve safety over what would be obtained with the cobalt-oxide cathode typically used in standard Li-ion cells. Despite its safer cathode, a combination of risk factors such as the possibility of overcharge and an internal short made it necessary to incorporate overcharge protection into the UR18650W. This circuitry protects against voltage imbalance during normal cell use and abnormal charging conditions. The latter can occur when the battery encounters a broken charger or the wrong charger, or when a battery is charged manually. The UR18650W follows two power cells previously In its V28 line of power tools, Milwaukee Electric Tool is replacing 18-V NiCd battery packs with slightly lighter 28-V Li-ion packs that deliver higher power and up to twice the run time of the NiCd packs. Along with offering greater power and run time, Li-ion cells offer better performance at temperature extremes. This advantage includes greater cycle life than NiCd batteries under extreme conditions. The impact of Li-ion batteries on power equipment is so Power Electronics Technology February 2006 52 www.powerelectronics.com ANALOG FEEDBACK Vendor/Model Capacity at 1C or Less (mAh) Capacity at 10C (mAh) Internal Impedance (m) at 1 kHz Charge Voltage (V) Discharge Voltage (V) Cycle Life Sanyo UR18650W 1600 at 1C 1500 — 4.2 3.7 700 cycles to 75% initial capacity Sony 18650VT 1080 avg. 1000 (rated capacity) at 1C 1030 avg. 25 4.1 3.76 500 cycles to 90% of initial capacity, 2-A discharge Sony 26650VT 2500 avg. 2400 (rated capacity), at 0.2C 2400 avg. 13 4.1 3.75 Same as above, but at 5-A discharge Valence Technology Saphion IFR18650p 1100 at 1C (rated capacity) 1050 <20 3.65 3.2 at 1C >600 cycles to 70% capacity at 10 A Table. High-power Li-ion cells. pacities at 10C, 4C and 1C discharge rates (see the table). As these specifications reveal, the capacities of the high-power cells vary only slighty across a range of discharge rates. For example, the 18650VT specifies an average capacity of 1030 mAh at 10C versus an average capacity of 1080 mAh at a 1C rate. Similarly, the 26650VT specifies a 2400-mAh developed by Sanyo. The UR18650H/V offer 2000 mAh of capacity, but at a lower discharge rate (5C). Another cell manufacturer, Sony (www.sony.com/energy) describes its VT series of Li-ion cells as the first developed for power tool use.[2] The 18650VT and 26650VT, which were introduced early last year, are cylindrical cells that specify ca- MULTILAYER MULTILA TILAYER POLYMER POL (MLP) CAPA CAP CITORS Ultra Low ESR and ESL High Ripple Current Handling Stable Under AC & DC Voltage V T Telecom Grade - No Aging Low Profile For Surface Mount Robust Mechanical and Electrical Design 50 to 500 Volts V APPLICA APPLICATIONS • • • • • Made In The USA 48 Volt V T Telecom/Datacom 42 Volt V Automotive SMPS Off-Line PFC Front Ends RFI/EMI Suppression MLP Capacitors @ 500KHz Max I rms • • • • • • • Max RMS Current vs. Capacitance 20.0 18.0 16.0 14.0 12.0 10.0 8.0 6.0 4.0 2.0 0.0 1 5 10 15 20 Cap Value (microfarads) V Max RMS Current vs. Capacitance Value P.O. Box 4539 • 1205 McConville Road • Lynchburg, VA 24502 434-239-4730 TEL 434-239-6941 • FAX F [email protected] Available through these distributors: • Atlantic Components (1-800-433-6600) • Future (1-800-388-8731) • Gopher (1-800-592-9519) • Cornell Dubilier/Mallory (1-508-996-8561) www.paktron.com www.powerelectronics.com 53 Power Electronics Technology February 2006 ANALOG FEEDBACK average capacity at 10C versus a 2500-mAh average capacity battery in its Vitz, a minivan sold in Japan, to provide power PETech at a 0.2C rate. within a stop-start system. Although these cells were originally developed using cobalt-oxide cathodes, newer cells incorporate manganese References and nickel, which is said to eliminate the need for an over1. “New Concept Lithium Ion Batteries in Sanyo” by Masacharge protection circuit. toshi Takahashi, Sanyo Electric Co., Power Solutions Group, Although these cells exhibit about half the enerpresented at Portable Power Conference, Sept. 20, 2005. gy density of the convention Li-ion cells for low2. “R&D Activities & Results for Sony Batteries,” by Kenji power applications, their performance is still signifiOgisu, R&D Division, Energy Group, Sony, presented at cantly better than the chemistries they are replacing. Portable Power Conference, Sept. 20, 2005. The VT series cells offer 94 Wh/kg gravimetric en3. Valence Technology Datasheet, available online at www. ergy density versus 47 Wh/kg for NiMH and 35 Wh/kg valence.com/solutions.asp. for NiCd. Last year, Valence Technology (www. valence.com) targeted power tool applications when it introduced its Power Cell in an 18650 cylindrical format. Like other Li-ion batteries offered by the company, the Power Cell employs the Saphion chemistry, which incorporates phosphate-based cathodes rather than cobalt-oxide. The phosphatebased cathodes offer greater safety and less susceptibility to thermal runaway than cobalt oxide. The Power Cell offers nearly a 1.1 Ah of capacity at a 10C rate but can deliver higher current pulses.[3] For instance, the cell can supply a 30-A pulse for 30 sec. Valence is working on the next revision of the Saphion power cell, improving the product’s cycle life and power density. The company expects the Saphion power cell revision to be in production within six months. Although Li-ion cells developed for ��������������������������������������������� power-tool applications are relatively new, we can expect that their development will ���������������������������������� follow some of the same trends as their low-power counterparts. With consumers ��������������������������� always wanting longer run times for their ������������������������������������ batteries, cell vendors will likely strive to offer higher energy densities at the higher �������������������������������������������� ���������� discharge rates. �������� Vendors will strive to improve cell safety and lower material costs to enable high-power �������������������������������������� Li-ion cells to be adopted in more applications. To that end, cell makers are already ���������������������� developing Li-ion cells for even higher discharge rates. ������������������ Hybrid electric vehicles (HEVs) rep���������������� resent one of the most promising target applications for such batteries, and several battery suppliers and at least one automaker �������������� (Toyota) are developing Li-ion cells to power ���������������� ������������������������������������������������ HEVs. Although most of these batteries ������������� ����������������������������������� ������������� may be years away from use in commercial ��������������������������������������������� ����������� vehicles, Toyota is already using a Li-ion ���������������������������� ������������������������������ Power Electronics Technology February 2006 54 www.powerelectronics.com