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Lecture Lecture 33 :: ultracold ultracold Fermi Fermi Gases Gases The ideal Fermi gas: a reminder Interacting Fermions BCS theory in a nutshell The BCS-BEC crossover and quantum simulation Many-Body Many-Body Physics Physics with with Cold Cold Gases Gases Diluteness: atom-atom interactions described by 2-body (and 3 body) physics. At low energy: a single parameter, the scattering length a Control of the sign and magnitude of interaction Control of trapping parameters: access to time dependent phenomena, out of equilibrium situations, 1D, 2D, 3D n(k) Simplicity of detection Sherson et al., MPQ 2010 n(k) Comparison with quantum Many-Body theories: 1 Gross-Pitaevskii, Bose and Fermi Hubbard models, 1 search for exotic phases, dipolar gases disorder effects, Anderson localization, … Link with condensed matter (high Tc superconductors), astrophysics (neutron stars), Nuclear physics, k/kF high energy physics (quark-gluon plasma), 1 k/kF 1 Quantum simulation with cold atoms « a la Feynman » The The ideal ideal Fermi Fermi gas: gas: aa reminder reminder Zero temperature Fermi sea: E(p) 2 kF2 EF kBTF 2m EF k F (6 2 n)1/ 3 ~ (particle distance) 1 p 1 2m Fermi pressure: 15 2 2 3/ 2 EF5/ 2 Approximation valid as long as T<<TF Electrons Electrons vs vs cold cold atoms atoms Electrons in metal Ultra cold atoms Density 1030 /m3 1020 /m3 Mass 10-30 kg 10-26 kg Fermi temperature 104 K 1µK T/TF <10-5 ~ 10-2 Lifetime Infinite ~10s Size 1cm 10 µm Particle number 1024 105 Pauli Pauli Exclusion Exclusion Principle Principle and and evaporative evaporative cooling cooling of of ultra-cold ultra-cold Fermi Fermi gases gases Collision between two atoms. Effective potential in the l-wave: ( 1) Veff (r ) V (r ) 2mr 2 2 Interatomic potential (long range~-1/r6) l >0 l=0 centrifugal potential At low temperature, atoms cannot cross the centrifugal barrier: only s-wave collisions. Symmetrization for identical particles: even l-wave collisions forbidden for polarized fermions. Suppression Suppression of of elastic elastic collisions collisions in in aa spin spin polarized polarized Fermi Fermi gas gas Sp i n po la riz ed (p -w av e) Spin mixture (s-wave) B. DeMarco, J. L. Bohn, J.P. Burke, Jr., M. Holland, and D.S. Jin, Phys. Rev. Lett. 82, 4208 (1999). Use spin mixtures or several atomic species (eg 6Li-7Li, K-Rb, different spin states…) Quantum Quantum gases gases in in harmonic harmonic traps traps Bose-Einstein statistics (1924) Bose-Einstein condensate Fermi-Dirac statistics (1926) Fermi sea EF Bose enhancement Pauli Exclusion h TC = (0.83 N)1/3 kB h 1/3 T << TF = (6N) kB Dilute gases: 1995, JILA, MIT Dilute gases: 1999, JILA Absorption Absorption imaging imaging in situ: cloud size Bose -Einstein condensate Bose-Einstein condensate and and Fermi Fermisea sea Lithium 7 2001 ENS Lithium 6 104 Li 7 atoms, in thermal equilibrium with 104 Li 6 atoms in a Fermi sea. Quantum degeneracy: T= 0.28 K = 0.2(1) TC= 0.2 TF Now: T=0.03 TF The The non-interacting non-interacting Fermi Fermi gas gas Gaussian Fit Fermi-Dirac T/TF<0.05 Atom number~105 Quantum Quantum simulation simulation of of strongly strongly interacting interacting Fermions Fermions Quantum Quantum fluids fluids Bose Einstein condensates Superconductivity and helium 3 4He High Tc and 3He Dilute gas BEC BEC BECof ofstrongly stronglybound boundfermions fermions Connecting the two regimes ? Theory since 80’: Leggett, Randéria, Nozières,Schmidt-Rink, Holland, Kokkelmans, Levin, Ohashi, Griffin, Strinati, Falco, Stoof, Bruun, Pethick, Combescot, Giorgini…. intermediate intermediateregime regime Near Feshbach resonance, interactions in cold Fermi gas can be enhanced Tc ~TF/5 Fermions Fermions with with two two spin spin states states with with attractive attractive interaction interaction Tc TF e BEC of molecules Bound state / 2 k F a BCS fermionic superfluid Interaction strength No bound state Dilute gases: Feshbach resonance Cooper Cooper Pairing Pairing Bardeen, Cooper, Schrieffer, 1957 100 years of supraconductivity. Naive interpretation: Take a homogeneous T=0 Fermi gas, kF, EF Add two fermions, 1 et 2, which display attractive interaction V ( r1 r2 ) V ( r1 r2 ) a< 0 avec V < 0 Then these particles will always form at state with an energy lower than EF , a bound state. Pairs k, k at Fermi surface: | k | kF These pairs form a superfluid phase TBCS 0.3 TF e 2 k F |a | k F a 1 Mean-field Mean-field Theory Theory (BCS) (BCS) at at T=0 T=0 Bardeen, Cooper, Schrieffer, 1957 Many-body hamiltonian: Hˆ 3 3 3 ˆ ˆ ˆ ˆ ˆ (r ') ˆ (r ) d ( ) h ( ) d d ' ( ) (r ')V (r r ') r r r r r r 0 ˆ d r 3 ˆ (r ) g d 3r ˆ (r ) ˆ (r ) ˆ (r ) ˆ (r ) (r )h0 b 2 h0 2m ˆ (r ) In momentum space: k gb ˆ H k aˆk aˆk 3 L k aˆ eik .r 3 L aˆk , k q k ' q k ' k k ,k ',q aˆ aˆ aˆ 2k 2 k 2m Mean-field Mean-field Theory Theory (2) (2) Search for a solution in the form: N N ck ak† a† k ck c k k (ri rj ) Fourier components of spatial function N /2 | vac Assumption: zero momentum for BCS pairs: k aˆk aˆk ~ order parameter for a gas of bosonic molecules with zero center of mass momentum. BCS order parameter Hˆ cte k aˆk aˆk * aˆ k aˆk aˆ k aˆ k ... k k gb 3 L gb k k L3 k k aˆ k aˆk Gap equations Excitation Gap Excitation Gap In the ground state, no excitation of the Bogoliubov modes Ek k2 | |2 Ek |D| BCS wavefunction: | xk 2k 2 k 2m BCS (| uk | | vk | ei ak† a† k ) | vac k | uk |2 | vk |2 1 Tuning Tuning interactions interactions in in Fermi Fermi gases gases Lithium Lithium 66 scattering length [nm] 200 a>0 100 BEC-BCS Crossover 0 a<0 -100 -200 0,0 Bound state 2 EB ma 2 0,5 1,0 1,5 Magnetic field [kG] condensate of molecules 2,0 No bound state BCS phase The The Equation Equation of of State State of of aa Fermi Fermi Gas Gas with with Tunable Tunable Interactions Interactions Cold atoms, Spin ½ Dilute gas : 1014 at/cm3, T=100nK BEC-BCS crossover Spin imbalance, exotic phases Neutron star, Spin ½ a = -18.6 fm, n~2 1036cm-3 •Tc=1010 K , T=TF/100 • kFa ~ -4,-10,… • kFre<<1 Experimental Experimental sequence sequence - Loading of 6Li in the optical trap - Tune magnetic field to Feshbach resonance - Evaporation of 6Li - Image of 6Li in-situ Suppression Suppression of of vibrational vibrational relaxation relaxation for for fermions fermions W(r) a a EB r Re C6 / r 6 Pauli exclusion principle Inhibition by factor (a/Re)2 >>1 Re h2/ma2 Binding energy: EB= Momentum of each atom: h/a G~ 1/as with s = 2.55 for dimer-dimer coll. 3.33 for dimer-atom coll. D. Petrov, C. Salomon, G. Shlyapnikov, ‘04 Unitary Unitary Fermi Fermi Gas Gas :: a Optical Density (a.u) Pixels Direct Direct proof proof of of superfluidity: superfluidity: classical classical vs. vs. quantum quantum rotation rotation Rotating classical gas velocity field of a rigid body Rotating a quantum macroscopic object macroscopic wave function: In a place where , irrotational velocity field: The only possibility to generate a non-trivial rotating motion is to nucleate quantized vortices (points in 2D or lines in 3D) with quantized circulation around vortex core. Feynman, Onsager to keep single-valued Vortices now all have the same sign, imposed by the external rotation MIT 2005: Vortex lattices in the BEC-BCS Crossover Energy [MHz] 1 Direct proof of superfluidity 0 BEC side BCS side M. Zwierlein A. . Schirotzek C. Stan C. Schunk P. Zarth W. Ketterle Science 05 -1 650 834.15 Magnetic Field [G] Direct Direct proof proof of of superfluidity superfluidity Critical SF temperature = 0.19 TF MIT 2006 Superflow Superflow in in fermionic fermionic superfluids superfluids Landau criterion: dissipation for V>wk/k Theory: Combescot, Kagan and Stringari. Experiment: MIT, 2008. strongly strongly interacting interacting Fermions Fermions thermodynamic thermodynamic properties properties Thermodynamics Thermodynamics PV Nk BT Is a useful but incomplete equation of state ! Complete information is given by thermodynamic potentials: Grand potential n(k) n(k) 1 1 PV E TS N Pressure Volume Temperature Entropy Chemical potential Atom number Internal energy We have measured the grand potential of a tunable Fermi gas S. Nascimbène et al., Nature, 463, 1057, (2010), arxiv 0911.0747 N. Navon et al., Science 328, 729 (2010) 1 NJP (2010) k/kk/k F S. Nascimbène et al., F S. Nascimbène et al.,1arXiv 1012.4664: normal phase, to appear PRL 2011 M. Horikoshi et al., Science, 327, 442 (2010) The ENS Fermi Gas Team S. Nascimbène, N. Navon, F. Chevy, A. Ridinger, T. Salez, S. Chaudhuri, K. Gunther, B. Rem, A. Grier, I Ferrier-barbut, D. Wilkowski, F. Chevy, F. Werner, U. Eismann, K. Magalhães, K. Jiang Y. Castin, M. Antezza, D. Fernandes Theory collaborators: D. Petrov, G. Shlyapnikov , D. Papoular, J. Dalibard, R. Combescot, C. Mora C. Lobo, S. Stringari, I. Carusotto, L. Dao, O. Parcollet, C. Kollath, J.S. Bernier, L. De Leo, M. Köhl, A. Georges Useful Useful thermodynamic thermodynamic quantities quantities • Gibbs –Duhem relation: • Density: VdP SdT Nd P n P T • Free energy in canonical ensemble: • Entropy density: S /V P F (T , ,V ) V 2 F • Isothermal Compressibility: 1/ T V 2 V T , N 2 F • Specific heat: CV T 2 T N ,V • Legendre transform between grand canonical and canonical variables Thermodynamics Thermodynamics of of aa Fermi Fermi gas gas The Equation of State of a uniform Fermi gas can be written as: ( , T ; a ) E TS N P ( , T ; a ) V Pressure contains all the thermodynamic information Variables : scattering length temperature chemical potential a T µ We build the dimensionless parameters : Interaction parameter Fugacity (inverse) Canonical analogs Measuring Measuring the the EoS EoS of of the the Homogeneous Homogeneous Gas Gas Local density approximation: gas locally homogeneous at Measuring Measuring the the EoS EoS of of the the Homogeneous Homogeneous Gas Gas Extraction of the pressure from in situ images Ho, T.L. & Zhou, Q., Nature Physics, 09 S. K Yip, 07 • doubly-integrated density profiles equation of state measured for all values of Derivation Derivation LDA: 1 1 2 2 2 ( x, y, z ) mr ( x y ) m z 2 z 2 2 2 0 Cylindrical symmetry Gibbs-Duhem: dP SdT nd nd Integrating over x and y between 0 and + at constant temperature 1 P( z ) mr2 n( x, y, z )2 rdr 2 0 2 2 mr mr P( z , T ) n( x, y, z )dxdy n ( z) 2 0 2 Directly relates the pressure at abscissa z to the doubly integrated absorption signal at z Unitary Unitary Fermi Fermi Gas Gas a Doubly integrated Density Pressure of the locally homogeneous gas Position / Chemical potential z S. Nascimbène et al., Nature, 463, 1057, (2010) Next Next lecture: lecture: measurement measurement of of the the Equation Equation of of State State P( , T )