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The First Atomic Theory- John Dalton • Began teaching Chemistry at 12! • English school teacher, but never a trained chemist • Used the laws to prove that atoms existed by making meticulous notes. He kept a diary with 200,000 scientific entries! • Many of his unpublished documents were destroyed by the bombing of England in WWII- “War does not only kill the living.”Asimov Dalton’s Atomic Theory- 5 Postulates 1. All matter is composed of extremely small, indivisible particles called atoms. 2. Atoms of the same element are identical to each other and have the same properties. 3. Atoms of different elements have different properties. 4. Atoms of different elements combine in whole-number ratios to form compounds. 5. In chemical reactions, atoms are combined, separated, and rearranged but never created or destroyed. We know now… • Atoms can be divided into smaller parts called electrons, protons, and neutrons • Atom of one element can change into another element- creating a new atom (nuclear energy) • Atoms of the same element can have different properties isotopes- an atom of the same element, with a different # of neutrons Ex: C12 C13 C14 What Dalton’s Atom looks like • A solid sphere- no electrons, neutrons, or protons, because he believed it was indivisible The Indivisible, Solid Sphere Model (1808) • This Model was the first model of what was once believed to be the look, shape, and form of an atom. • This model was created by John Dalton. The Cathode Ray Tube Experiment • 1897: The cathode ray tube experiment • Done by J.J. Thomson- also an Englishman and colleague of Dalton • Discovery of Electrons Cathode Ray Tube (J. J. Thomson) The Plum-pudding Model (1904) • This was the next model to come after John Dalton’s model of the atom. • This model was created by J.J Thomson. • Rutherford in 1901 created the first human “nuclear reaction” – led to the discovery of the proton James Chadwick- discovered the neutron Niels Bohr- created a stable, quantum version of Rutherford’s atomic model (energy levels) 1909 Rutherford’s Gold Foil Experiment Rutherford’s Atomic Model • Electrons are less heavy than protons or neutrons and electrons orbit around the nucleus- like the planets orbit the sun • The nucleus is positively charged and contains protons and neutrons • The electron orbits are not defined- they can be anywhere Rutherford Nuclear Atom Model (1911) • This was the next model to come after J.J Thomson’s version of the atom. • This model was created by Ernest Rutherford. The models we have seen so far Dalton’s Atomic model Think of as many words as you can relating these models • Atomic number= # of protons Neutral atom has the same number of electrons as protons • Mass number = # protons and neutrons; different for different isotopes • Atomic Mass / Atomic Weight= average atomic mass of all isotopes of the element • Rutherford’s model is inherently unstable • If the electron can orbit at any distance from the nucleus, the atom would collapse in on itself!!! The Bohr Model • Niels Bohr determined that there are discrete (fixed) energy levels in an atom • The Bohr model stabilizes Rutherford’s model • In Bohr’s model, the electrons in the farthest orbit are the highest energy level; electrons in the closest orbit are in the lowest energy level Bohr’s Energy Levels • Electron Energy Level spacings are affected by nearness to the nucleus Planetary System Model (1913) • This was the next model to come after Rutherford’s version of the atom. • This model was created by Neils Bohr. What we think an atom looks like • Orbitals = region where the electron is, we don’t know exactly where, but we know it is in this general region • Nucleus= where the protons and neutrons are • Energy Levels= discrete and increase as the electron goes farther from the nucleus Electron Cloud Model (1900’s but after 1913) • This was the next model to come after Bohr’s version of the atom. • This model was created by Erwin Schroedinger.