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Why does a Potentiostat have three electrodes? We would like to study the electrochemical events taking place at one specific electrodeâ¦the Working Electrode. The use of a three-electrode potentiostat with a separate Reference and Counter Electrode allows the potential at the WE and the current at the WE to be measured with little or no âinterferenceâ or âcontributionâ from the other electrodes.