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LP-CH2201 LESSON PLAN LP Rev. No: 00 Date: 25.06.2012 Sub Code & Name : CH2201 – ORGANIC CHEMISTRY Unit: I Branch: Chemical Engineering Page 1 of 6 Semester : III DOC/LP/01/24.01.09 Objective: To impart the students the knowledge of preparation of various organic compounds, reaction mechanisms, types and the reagents involved. Unit syllabus: Definitions – reagents – mechanism – catalyst – illustration of the following unit processes: nitration – halogenation - oxidation & reduction – esterification. Session No Time Topics to be covered Ref Teaching Aids 1 2 3 4 Introduction and concept of IUPAC nomenclature Common aspects of organic compounds and reactions Types of reactions – illustration with examples. Catalyst and its influence on the type of reaction. 50 minutes 50 minutes 50 minutes 50 minutes T1,R1 T1, R2 T1, R3 R1,R2 BB& C BB &C BB&C BB &C 5 6 7 8 9 Mechanism of nitration in detail with examples. Mechanism of halogenation in detail with examples. Mechanisms of redox reactions with examples. Mechanism of esterification in detail with examples. Revision and supplementary aspects in Unit I 50 minutes 50 minutes 50 minutes 50 minutes 50 minutes R2,R3 R1,R3 T1,R1 T1, R2 T1, R3 BB&C BB &C BB&C BB &C BB&C LP-CH2201 LESSON PLAN LP Rev. No: 00 Date: 25.06.2012 Sub Code & Name : CH2201– ORGANIC CHEMISTRY Unit: II Branch: Chemical Engineering Page 2 of 6 Semester : III DOC/LP/01/24.01.09 Objective: To impart the students the knowledge on the concepts of nucleophile, electrophile, substitution, condensation and addition reactions. Unit syllabus: Electrophilic reaction – Friedel craft reaction – Riemer –Tiemenn reaction – Nucleophilic reactions – aldol condensation – benzoin condensation – Free radical reaction: Halogenation of alkane – Addition of HBr on alkene in presence of peroxide. Session No Time Topics to be covered Ref Teaching Aids 50 minutes T1,R1 BB& C 11 12 13 Concept of nucleophiles and electrophiles; +I and –I groups – Electrophilic and nucleophilic reactions illustration with examples. Salient aspects of Friedel craft reactions – examples. Salient aspects of Riemer-Tiemann reaction- illustration. Mechanism of aldol condensation reactions – cross aldols. 50 minutes 50 minutes 50 minutes T1, R2 T1, R3 R1,R2 BB &C BB&C BB &C 14 15 16 17 18 Mechanism of benzoin condensation reaction – details. Mechanism of halogenation of alkanes – details. Addition of HBr to alkenes - Markovnika rule. Peroxide effect on HBr addition to alkenes; Revision. CAT – I 50 minutes 50 minutes 50 minutes 50 minutes 50 minutes R2,R3 R1,R3 T1,R1 T1, R2 T1, R3 BB&C BB &C BB&C BB &C BB&C 10 LP-CH2201 LESSON PLAN LP Rev. No: 00 Date: 25.06.2012 Page 3 of 6 Sub Code & Name : CH2201– ORGANIC CHEMISTRY Unit: III Branch: Chemical Engineering Semester : III DOC/LP/01/24.01.09 Objective: To impart the students the knowledge of various halogenation, condensation, polymerization and redox reactions and estimation of important organic compounds. Unit Syllabus: Allylic halogenation using N.Bromo Succinimide (NBS) – thermal halogenation of alkene (CH3-CH=CH); condensation and polymerization reactions – oxidation and reduction reactions – estimation of some organic compounds – phenol – aniline – acetone – glucose. Session No Topics to be covered Time 19 20 21 22 General aspects of halogenation reactions in detail. Allylic halogenation using N.Bromo Succinimide (NBS) Thermal halogenation of alkane / alkene (CH3-CH=CHR) Condensation and polymerization reactions in detail. 23 24 25 26 27 Oxidation and reduction reactions in detail. Estimation of phenol – principle and practice. Estimation of aniline – principle and practice. Estimation of acetone – principle and practice. Estimation of glucose – principle and practice. Ref Teaching Aids 50 minutes 50 minutes 50 minutes 50 minutes T1,R1 T1, R2 T1, R3 R1,R2 BB& C BB &C BB&C BB &C 50 minutes 50 minutes 50 minutes 50 minutes 50 minutes R2,R3 R1,R3 T1,R1 T1, R2 T1, R3 BB&C BB &C BB&C BB &C BB&C LP-CH2201 LESSON PLAN LP Rev. No: 00 Date: 25.06.2012 Sub Code & Name : CH2201– ORGANIC CHEMISTRY Unit: IV Branch: Chemical Engineering Page 4 of 6 Semester : III DOC/LP/01/24.01.09 Objective: To impart the students the knowledge of synthesis of important organic compounds. Unit Syllabus: Synthesis of different types of compounds like alcohol, aldehyde, amine, acids – dicarboxylic acids – unsaturated acids – synthesis of azodyes – methyl orange and congo dye – synthesis of triphenyl methane dyes – malachite green – synthesis of alizarin. Session No Time Topics to be covered Ref Teaching Aids 28 29 30 31 Synthesis of alcohols – detailed approach. Synthesis of aldehyde – detailed approach. Synthesis of amine – detailed approach. Synthesis of acids – dicarboxylic and unsaturated acids. 50 minutes 50 minutes 50 minutes 50 minutes T1,R1 T1, R2 T1, R3 R1,R2 BB& C BB &C BB&C BB &C 32 33 34 35 36 Synthesis of azodyes – methyl orange – details. Synthesis of azodyes – congo red – details. Synthesis of triphenyl methane dyes – malachite green. Synthesis of alizarin dye and its uses as mordant dyes. CAT - II 50 minutes 50 minutes 50 minutes 50 minutes 50 minutes R2,R3 R1,R3 T1,R1 T1, R2 T1, R3 BB&C BB &C BB&C BB &C BB&C LP-CH2201 LESSON PLAN LP Rev. No: 00 Date: 25.06.2012 Sub Code & Name : CH2201– ORGANIC CHEMISTRY Unit: V Branch: Chemical Engineering Page 65 of 6 Semester : III DOC/LP/01/24.01.09 Objective: To impart the students the knowledge of synthesis and properties of aminoacids and proteins. Unit Syllabus: Aminoacids and proteins – classification – synthesis of aminoacids – reactions of carboxyl and amino group – peptide linkage – end group analysis – colour reaction of proteins – denaturation. Session No Topics to be covered Time 37 38 39 40 Aminoacids and proteins – introduction / salient aspects. Classification of aminoacids and proteins in detail. Synthetic aspects of aminoacids in detail. Reactions of aminoacids – those of COOH & NH2 groups 41 42 43 44 45 Reactions of aminoacid –COOH & NH2 groups-combined Peptide linkage in proteins – detailed discussion. Colour reactions of proteins – detailed aspects. Denaturation of proteins – concepts; overall revision. CAT – III Ref Teaching Aids 50 minutes 50 minutes 50 minutes 50 minutes T1,R1 T1, R2 T1, R3 R1,R2 BB& C BB &C BB&C BB &C 50 minutes 50 minutes 50 minutes 50 minutes 50 minutes R2,R3 R1,R3 T1,R1 T1, R2 T1, R3 BB&C BB &C BB&C BB &C BB&C Sub Code & Name : CH2201– ORGANIC CHEMISTRY Semester : III Branch: Chemical Engineering DOC/LP/01/24.01.09 Course Delivery Plan: Week 1 2 3 4 5 6 7 8 9 10 11 12 I II I II I II I II I II I II I II I II I II I II I II UNIT I UNIT Units II UNIT III UNIT CAT I I IV UNIT V CAT II CAT III Text Book: 1. Tiwari K.S., Vaishnoi N.K. and Marhotra S.N., A Textbook of Organic Chemistry, II edition, Vikas Publishing House Pvt. Ltd., (1998), New Delhi. [T1] References: 1. P.H.Groggins, Unit Processes in Organic Synthesis, III Edition, McGraw-Hill, New York, 1947. [R1] 2. Finar I.L. Organic Chemistry – The Fundamental Principles [R2] 3. Morrison R.T. and Boyd , Organic Chemistry [R3] Prepared by Signature Name Designation Date Dr. S. Jegannathan & Dr.G.Baskar Asst. Professors 25.06.2012 Approved by Staff HOD Student HOD Dr. R.Parthiban / Dr.G.Devasagayam Prof. & Head 25.06.2012 Dr. R.Parthiban Prof. & Head 25.06.2012