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Chapter 5: Electrons in Atoms
Bohr’s Model
•Niels Bohr
•Changed Rutherford’s model because it lacked
the ability to describe chemical properties.
•Rutherford’s also did not account for atomic
collapse.
•Changed the model based upon how atoms
absorb/emit light.
•Hydrogen atom
Bohr’s Contributions
•Bohr discovered that electrons are not
free, random-motion particles.
•Major Contribution:
•Electrons are found in circular paths, or
orbits, around the nucleus.
•Fixed Energy
Bohr (cont.)
•Energy levels are like
rungs of a ladder.
Energy Levels
•Higher energy level = further from
nucleus
•Quantum → Move between energy
levels.
Energy Levels
Bohr’s Ladder
(Increasing Energy)
6th Level
5th Level
4th Level
3rd Level
2nd Level
1st Level
•Energy levels are not
equidistant.
Electrons in Energy Levels
•Degenerate vs. Excited Energy Levels
• Electrons are lazy.
• Emission of light.
Energy → Lazy = Happy
n=4
n=3
n=2
n=1
Flaws with the Bohr Model
•Bohr’s Model:
•Showed electrons in controlled orbits.
(like planets) – often called “Planetary
Model”.
•Experiments greater than 1 electron
systems failed to reproduce this motion.
Oversights of Bohr
•Electrons are not only moving around the
nucleus but then are spinning as they move.
•2 types of spin (more later)
•Uncertainty of location of e-
Heisenberg’s Uncertainty
•Werner Heisenberg – you cannot know both
the momentum and the location of an e-, you
either know one or the other.
•“Heisenberg’s Uncertainty Principle”