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© CBSEPracticalSkills.com Edulabz International CHEMICAL REACTION AND CHEMICAL EQUATIONS 1 TEXTBOOK QUESTIONS AND THEIR ANSWERS Q.1. Why should magnesium ribbon be cleaned before burning in air? Ans. Magnesium ribbon is coated with a thin layer of magnesium oxide. Thus, in order to burn it, it is scrubbed with sandpaper, so that fresh layer of magnesium metal is exposed. Q.2. What happens when dilute hydrochloric acid is added to iron filings? Tick the correct choice. (a) Hydrogen gas and iron chloride are hydroxide are produced. (b) Chlorine gas and iron produced. (c) No reaction takes place. (d) Iron salt and water are produced. CBSEPracticalSkills.com 1 © Edulabz International © CBSEPracticalSkills.com Edulabz International Ans. (a) is correct choice. Q.3. Potassium iodide solution is added to lead nitrate solution, then a yellow precipitate formed. The yellow precipitate is : (a) Potassium nitrate. (b) (c) Lead nitride Lead iodide. (d) None of the above. Tick the correct choice. Ans. (b) is the correct choice as lead iodide is yellow in colour. Q.4. Balance the following chemical equations. (a) HNO3 + Ca(OH) 2 Ans. Ca(NO3) 2 + H2O (b) NaOH + H2SO4 Na2SO4 + H2O (c) NaCl + AgNO3 AgCl + NaNO3 (d) BaCl2 + H2SO4 BaSO4 + HCl (a) 2HNO3 + Ca(OH)2 (b) 2NaOH + H2SO4 (c) NaCl + AgNO3 CBSEPracticalSkills.com 2 Ca(NO3)2 + 2H2O Na2SO4 + 2H2O AgCl + NaNO3 © Edulabz International © CBSEPracticalSkills.com (d) BaCl2 + H2SO4 Q.5. Edulabz International BaSO4 + 2HCl Write a balanced chemical equation with state of symbols for the following reactions : (i) Solutions of barium chloride and sodium sulphate in water react to give insoluble barium sulphate and the solution of sodium chloride. (ii) Sodium hydroxide solution (in water) reacts with hydrochloric acid solution (in water) to produce sodium chloride solution and water. Ans. (i) Barium chloride (Sol) + Sod. sulphate (sol) Barium Sulphate (ppt) + Sod. Chloride (sol) ...... Word equation. BaCl2(aq) + Na2SO4(aq) BaSO4(s) + NaCl(aq) ........... Skeletal equation. BaCl2(aq) + Na2SO4(aq) BaSO4(s) + 2NaCl(aq) ......... Balanced equation. (ii) Sodium hydroxide (aq) + Hydrochloric acid (aq) Sod. chloride (aq) + Water. ....... Word equation. CBSEPracticalSkills.com 3 © Edulabz International © CBSEPracticalSkills.com NaOH(aq) + HCl(aq) Edulabz International NaCl(aq) + H2O(l) ........ Balanced equation. Q.6. What is a balanced chemical equation? Why should a chemical equation be balanced? Ans. A chemical equation in which number of atoms of each element is same on the side of reactants and products is called balanced chemical equation. A chemical equation in which the number of each element is not same on the side of reactants and products contradicts law of conservation of mass, as matter can neither be created nor be destroyed. Thus, such an equation is not true chemical equation and hence it should be balanced. Q.7. Translate the following statements into chemical equations and then balance them. (a) Hydrogen gas combines with nitrogen gas to form ammonia gas. (b) Hydrogen sulphide gas burns in air to give water and sulphur dioxide gas. (c) Barium chloride reacts with aluminium CBSEPracticalSkills.com 4 © Edulabz International © CBSEPracticalSkills.com Edulabz International sulphate to give aluminium chloride and a precipitate of barium sulphate. (d) Potassium metal reacts with water to give potassium hydroxide and hydrogen gas. Ans. (a) H2(g) + N2(g) NH3(g) ...... Skeletal equation 3H2(g) + N2(g) 2NH3(g) ...... Balanced equation. (b) H2S(g) + O2(g) H2O(l) + SO2(g) ...... Skeletal equation 2H2S(s) + 3O2(g) 2H2O(l) + 2SO2(g) ........ Balanced equation (c) BaCl2(aq) + Al2(SO4)3(aq) BaSO4(s) + AlCl3(aq) ...... Skeletal equation 3BaCl2(aq) + Al2(SO4)3(aq) 3BaSO4(s) + 2AlCl3(aq) ..... Balanced equation. (d) K(s) + H2O(l) KOH(aq) + H2(g) ..... Skeletal equation 2K(s) + 2H2O(l) CBSEPracticalSkills.com 5 2KOH(aq) + H2(g) ..... © Edulabz International © CBSEPracticalSkills.com Edulabz International Balanced equation. Q.8. Write balanced chemical equations for the following reactions. (a) Calcium hydroxide + Carbon dioxide Calcium carbonate + Water. Zinc nitrate + (b) Zinc + Silver nitrate Silver. (c) Aluminium + Copper chloride Aluminium chloride + Copper. (d) Barium chloride + Potassium sulphate Barium sulphate + Potassium chloride. Ans. (a) Ca(OH)2(aq) + CO2(g) CaCO3(s) + H2O ...... Balanced equation (b) Zn(s) + AgNO3(aq) Zn(NO3)2(aq) + Ag(s) ...... Skeletal equation Zn(s) + 2AgNO3(aq) Zn(NO3)2(aq) + 2Ag(s) ...... Balanced equation (c) Al(s) + CuCl2 AlCl3 + Cu ...... Skeletal equation. CBSEPracticalSkills.com 6 © Edulabz International © CBSEPracticalSkills.com 2Al(s) + 3CuCl2 Edulabz International 2AlCl3 + 3Cu ..... Balanced equation. (d) BaCl2(aq) + K2SO4(aq) BaSO4(s) + KCl .... Skeletal equation BaCl2(aq) + K2SO4(aq) BaSO4(s) + 2KCl ....... Balanced equation Q.9. Which of the statements about the reaction below are incorrect ? 2Pb(s) + CO2(g) 2PbO(s) + C(s) (a) Lead is getting reduced. (b) Carbon dioxide is getting oxidised (c) Carbon is getting oxidised. (d) Lead oxide is getting reduced. (i) (a) and (b) (ii) (a) and (c) (iii) (a), (b) and (c) Ans. Q.10. (iv) all. (iv) is the answer, as all other choices are incorrect. Fe2O3 + 2Al CBSEPracticalSkills.com Al2O3 + 2Fe. 7 © Edulabz International © CBSEPracticalSkills.com Edulabz International The above reaction is an example of a (a) combination reaction. (b) double displacement reaction. (c) decomposition reaction. (d) displacement reaction. Ans. Q.11. (d) displacement reaction is the correct choice. Why does the colour of copper sulphate solution change, when iron nail is dipped? Ans. The blue colour of copper sulphate is due to Cu2+ ions. These copper ions are discharged and the Fe2+ ions are added in solution, which result in the change in colour. Q.12. In the refining of silver, the recovery of silver from silver nitrate solution involved displacement by copper metal. Write down the reaction involved. Ans. Q.13. 2AgNO3(aq) + Cu(s) Cu(NO3)2(aq) + 2Ag. Why respiration in living beings is called an CBSEPracticalSkills.com 8 © Edulabz International © CBSEPracticalSkills.com Edulabz International exothermic process? Ans. The food taken by the living beings is ultimately broken down to glucose by the digestive system. The glucose so formed is slowly oxidised to carbon dioxide and water with the release of heat energy. Thus, respiration is an exothermic process. Q.14. Identify the substances that are oxidised and the substances that are reduced in the following reactions. (i) 4Na(s) + O2(g) (ii) CuO(s) + H2(g) Ans. 2Na2O(s) Cu(s) + H2O(l). (i) Sodium is oxidised and oxygen is reduced. (ii) Hydrogen is oxidised and copper oxide is reduced. Q.15. What does one mean by exothermic and endothermic reaction? Give examples. Ans. A chemical reaction which proceeds with the evolution of heat energy is called exothermic reaction. CBSEPracticalSkills.com 9 © Edulabz International © CBSEPracticalSkills.com Example : 2Mg(s) + O2(g) Edulabz International 2MgO(s) + heat. A chemical reaction which proceeds with the absorption of heat energy is called endothermic reaction. Example : CaCO3(s) ¾ heat ¾ ® CaO(s) + CO2(g). Q.16. What is the difference between displacement and double displacement reactions? Write equations for these reactions. Ans. In a displacement reaction only an active metal displaces less active metal from its aqueous ionic salt solution as shown in the following equation. FeSO4(aq) + Zn(s) ZnSO4(aq) + Fe(s) However, in double displacement reaction the aqueous ionic solutions of two salts react by exchanging their ions/radicals to form two new compounds as shown in the following equation. BaCl2(aq) + Na2SO4(aq) Q.17. BaSO4(s) + 2NaCl(aq) A shiny brown coloured element ‘X’ on heating in air becomes black in colour. Name the element CBSEPracticalSkills.com 10 © Edulabz International © CBSEPracticalSkills.com Edulabz International ‘X’ and the black compound formed. Ans. The shiny brown element is metal copper. The black compound formed is copper (II) oxide. Q.18. Explain the following terms with one example each. (a) Corrosion Ans. (b) Rancidity (a) Formation of layers of undesired compounds, such as metallic oxides and hydroxides on the surface of metals is called corrosion of metals. Copper metal when exposed to moist air containing carbon dioxide gets covered with a greenish layer of basic copper carbonate. (b) The oxidation of food materials, such that they become stale and start smelling is called rancidity. Any kind of cooked food gets rancid, if kept at room temperature (above 25°C) in 24 hours, due to its oxidation with air. Q.19. Why are decomposition reactions called opposite CBSEPracticalSkills.com 11 © Edulabz International © CBSEPracticalSkills.com Edulabz International of combination reactions? Write equations for these reactions. Ans. During decomposition reaction a single chemical compound breaks down into two or more different elements or compounds, whereas during chemical combination reaction, two or more elements or compounds react to form a single chemical compound. Thus, we can say that chemical decomposition reaction is opposite of chemical combination reaction. Following examples will illustrate the point. 2Mg(s) + O2(g) 2MgO(s) ....... Combination reaction 2CO(g) + O2(g) 2CO2(g) ....... Combination reaction ¾ ® PbO(s) + CO2(g) ....... PbCO3(s) ¾ heat Decomposition reaction ¾ ® 2NaNO2(s) + O2(g) ....... 2NaNO3(s) ¾ heat Decomposition reaction Q.20. Write balanced chemical equation for the following and identify the type of reaction in each case. CBSEPracticalSkills.com 12 © Edulabz International © CBSEPracticalSkills.com Edulabz International (a) Potassium bromide (aq) + Barium iodide (aq) Potassium iodide (aq) + Barium bromide (s). (b) Zinc carbonate (s) Zinc oxide (s) + Carbon dioxide (g) (c) Hydrogen (g) + Chlorine (g) Hydrogen chloride (g) (d) Magnesium (s) + Hydrochloric acid (aq) Magnesium chloride (aq) + Hydrogen (g). Ans. (a) 2KBr(aq) + BaI2(aq) 2KI(aq) + BaBr2(s). It is a double displacement precipitation reaction. (b) ZnCO3(s) ZnO(s) + CO2(g) It is a chemical decomposition reaction. (c) H2(g) + Cl2(g) 2HCl(g) It is a chemical combination reaction. (d) Mg(s) + 2HCl(aq) MgCl2(aq) + H2(g). It is a chemical displacement reaction. CBSEPracticalSkills.com 13 © Edulabz International © CBSEPracticalSkills.com Q.21. Edulabz International Write an equation each for decomposition reactions, where energy is supplied in the form of heat, light, or electricity. Ans. (a) Energy is supplied in the form of heat, during the decomposition of ferrous sulphate crystals. 2FeSO4(s) ¾ heat ¾ ® Fe2O3(s) + SO2(g) + SO3(g) (b) Energy is supplied in the form of light, when silver iodide decomposes to form silver and iodine. ¾ ® 2Ag(s) + I2(s) 2AgI(s) ¾ heat (c) Energy is supplied in the form of electricity, when molten lead bromide decomposes to lead and bromine. PbBr2(l) ¾ elect ¾ ricity ¾¾ ® Pb + Br2 Q.22. What do you mean by precipitation reaction? Explain by giving examples. Ans. Precipitation reaction is basically double displacement reaction. It is defined as under : When the aqueous solutions of two ionic compounds CBSEPracticalSkills.com 14 © Edulabz International © CBSEPracticalSkills.com Edulabz International react by exchanging their ions/radicals, to form two new compounds, such that one of the products formed is insoluble in water, and hence form precipitate, it is said to be precipitation reaction. Examples : 1. 2NaOH(aq) + FeSO4(aq) Na2SO4(aq) + Fe(OH)2(s) 2. Pb(NO3)2(aq) + Na2SO4(aq) 2NaNO3(aq) + PbSO4(s). 3. AgNO3(aq) + HCl(aq) HNO3(aq) + AgCl(s) Q.23. Explain the following in terms of gain or loss of oxygen with two examples each : (a) oxidation, (b) reduction Ans. (a) Oxidation of a substance takes place when there is : (i) addition of oxygen, (ii) removal of hydrogen from a substance. Examples : 1. 2Mg(s) + O2(g) CBSEPracticalSkills.com 15 2MgO(s) © Edulabz International © CBSEPracticalSkills.com Edulabz International Oxidation of magnesium takes place as oxygen is added to it. 2. H2S(g) + Br2(aq) 2HBr(aq) + S(s) Oxidation of hydrogen sulphide takes place as hydrogen is removed from it. (b) Reduction of a substance takes place when there is : (i) addition of hydrogen, (ii) removal of oxygen from a substance. Examples : ¾ ¾® 2HCl(g). 1. H2(g) + Cl2(g) ¾ sunlight Reduction of chlorine takes place as there is addition of hydrogen. heat 2. CuO(g) + H2(aq) ¾ ¾ ® Cu(s) + H2O(s) Reduction of copper oxide takes place as oxygen is removed from it. Q.24. Write the balanced equation for the following chemical reactions. (i) Hydrogen CBSEPracticalSkills.com + 16 Hydrogen Chlorine © Edulabz International © CBSEPracticalSkills.com Edulabz International chloride (ii) Barium chloride + Aluminium sulphate Barium sulphate + Aluminium chloride Sodium hydroxide + (iii) Sodium + Water Hydrogen Ans. (i) H2 + Cl2 2HCl (ii) 3BaCl2 + Al2(SO4)3 (iii) 2Na + 2H2O Q.25 3BaSO4 + 2AlCl3 2NaOH + H2 A solution of substance X is used for white washing. (i) Name the substance X and write its formula. (ii) Write the reaction of the substance X named in (i) above with water. Ans. (i) The substance X is calcium oxide and its formula is CaO. (ii) CaO(s) + H2O(l) Calcium Water oxide Q.26. Ca(OH)2(aq) Calcium hydroxide Why is the amount of gas collected in one of the CBSEPracticalSkills.com 17 © Edulabz International © CBSEPracticalSkills.com Edulabz International test-tubes in electrolysis of water is double of the amount collected in the other? Name this gas. Ans. When electric current is passed through acidulated water, water decomposes to form hydrogen and oxygen. The reaction takes place is 2H2O(l) 2H2(g) + O2(g) Thus, hydrogen and oxygen are produced in the ratio of 2 : 1 by volume. Hence, the amount of gas collected in one test tube is double the amount collected in the other. This gas is hydrogen. Q.27. Give an example of a double displacement reaction other than the one given in Activity 11.0 (of the text book). Ans. Barium chloride reacts with aluminium sulphate to form barium sulphate and aluminium chloride 3BaCl2 + Al2(SO4)3 Q.28. Ans. 3BaSO4 ↓ + 2AlCl3. Why do we apply paint on iron articles? When iron articles are kept in air, then after CBSEPracticalSkills.com 18 © Edulabz International © CBSEPracticalSkills.com Edulabz International sometime they get corrode due to the formation of reddish brown powder which is called rust of iron. So, we paint on iron articles to protect them from rusting. Q.29. Oil and fat containing food items are flushed with nitrogen. Why? Ans. Nitrogen prevents the oil and fat containing food items from getting oxidised. So, these food items are flushed with nitrogen. CBSEPracticalSkills.com 19 © Edulabz International