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Weakly nonlocal fluid mechanics Peter Ván Budapest University of Technology and Economics, Department of Chemical Physics – One component fluid mechanics - quantum (?) fluids – Quantum potential • Why Fisher information? – Two component fluid mechanics – sand (?) – Conclusions Why nonequilibrium thermodynamics? Thermodynamics Thermodynamics Thermodynamics (?) science of temperature science of macroscopic energy changes general framework of any macroscopic (?) continuum (?) theories General framework: – fundamental balances – objectivity - frame indifference – Second Law reversibility – special limit Phenomenology – minimal or no microscopic information universality Second Law – “super-principle” – valid for all kind of dynamics – like symmetries Beyond local equilibrium – memory and inertia Beyond local state – nonlocality weak – short range - not gravity – higher order gradients Non-equilibrium thermodynamics a ja a basic balances – basic state: – constitutive state: – constitutive functions: a (, v,...) a C (a, a , a,...) ja (C) weakly nonlocal Second law: s(C) js (C) s 0 (universality) Constitutive theory Method: Liu procedure, Lagrange-Farkas multipliers Special: irreversible thermodynamics Origin of quantum mechanics: motivation – interpretation – derivation (?) Is there any? (Holland, 1993) – optical analogy – standard (probability) – stochastic – quantized solutions – de Broglie – Bohm – de Broglie-Bohm – stochastic – hydrodynamic – Kaniadakis Justified by the consequences. – Frieden-Plastino (Fisher based) – Points of views – Hall-Reginatto “The Theory of Everything.” – Equivalent (Laughlin-Pines, 2000) (for a single particle) Schrödinger equation: i V ( x) t 2m iS R e Madelung transformation: 2 v 0 : R 2 v : S m de Broglie-Bohm form: v (U QM V ) Hydrodynamic form: v PQM V R 2 2m R 2 U QM Fundamental questions in quantum mechanics: – Why we need variational principles? (What is the physics behind?) – Why we need a wave function? (What is the physics behind?) – Where is frame invariance (objectivity)? One component weakly nonlocal fluid (, v ) basic state v 0 C ((,,, v,, v) , v, v) v P(C) 0 Cwnl constitutive state s(C) js (C) 0 s(C), js (C), P(C) constitutive functions Liu procedure (Farkas’s lemma): 2 2 v v ss((, ,vv, ) )se (se (), ) 2 2 js v P ... r P reversible pressure 2 1 2 s P s s I s : v 0 2 2 Pv P P r Potential form: P UQ r U Q ( se ) ( se ) Euler-Lagrange form Variational origin Schrödinger-Madelung fluid (Fisher entropy) 2 SchM v 2 sSchM ( , v, ) 2 2 2 r SchM P 1 2 2 I 8 eiv Bernoulli equation Schrödinger equation Landau fluid sLan ( , ) Lan r Lan P Lan ( ) 2 2 2 2 I 2 2 1 U Lan Lan 2 2 Alternate fluid s Alt ( , ) Alt ( ) 2 Alt 2 P (I ) 4 r Alt Alt U Alt 2 Korteweg fluids: r Kor P p ( ) I 2 2 Origin of quantum potential – weakly nonlocal statistics: Unique under physically reasonable conditions. – Extensivity (mean, density) – Isotropy s( , ) s ( , ( ) 2 ) – Additivity s( 12 , D( 12 )) s( 1 , 1 ) s( 2 , 2 ) ( ) 2 s ( , ( ) ) k ln 2 2 Fisher Boltzmann-Gibbs-Shannon Extreme Physical Information (EPI) principle (Frieden, 1998) – Mass-scale invariance (particle interpretation) s( , ) s( , ) Two component weakly nonlocal fluid 1 1 2 2 0 v 0 v P(C) 0 s(C) js (C) 0 density of the solid component volume distribution function ( , , v ) basic state C ( , , , , v, v) constitutive state s(C), js (C), P(C) constitutive functions Constraints: (1), (1), (2), (2), (3) s 1 , s 2 , Liu equations s 3 , s 4 , vs 5 , vs 0, ( js 5 P)s 0, ( js 5 P)s 0, ( v js 4I 5 v P)s 0. s 0, s 0, s 0, s 0. isotropic, second order Solution: v2 ( )2 s(, , , , v) se (, ) m(, ) (, ) 2 2 js (C ) m( , ) v P(C ) j1 ( , , v). (mv) : P ( sI) : v 0 Simplification: p m 1, j1 (, , v) 0, se 2 . Entropy inequality: ()2 P (p )I : v 0 2 Pr Coulomb-Mohr P P r P v Lv isotropy: Navier-Stokes like + ... Properties 1 Other models: a) Goodman-Cowin P r (p ()2 2)I 2 h b) Navier-Stokes type: configurational force balance somewhere 2 Coulomb-Mohr N : n P r n S : P r N S 2 (N t ) 2 s 2 s ( ) 2 t p ( ) 2 2 1 t p 1 (ln ) s 2 S unstable s t stable N Conclusions − Weakly nonlocal statistical physics − Universality (Second Law – super-principle) − independent of interpretation − independent of micro details phenomenological background behind any statistical-kinetic theory (Kaniadakis - kinetic, Frieden-Plastino - maxent) − Method - more theories/models − Material stability Thermodynamics = theory of material stability e.g. phase transitions (gradient systems?) What about quantum mechanics? – There is a meaning of dissipation. – There is a family of equilibrium (stationary) solutions. v0 U SchM U E const. – There is a thermodynamic Ljapunov function: v 2 1 2 U E dV L( , v) 2 2 2 semidefinite in a gradient (Soboljev ?) space