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Course Schedule Model (meeting two times a week) Week # Date Topic Introduction to the course 1 2 Energy levels and atomic orbitals. Electronic Configuration Structure and properties of Organic Compounds Structure and properties of Organic Compounds Organic Chemistry& the Structural Theory Classical concept of Chemical Bonding The relationship between the Orbital hybridization and molecular geometry. Names &Structures of common Functional Groups Bond dissociation energy.Homolysis & heterolysis. 3 Fundemental laws of Organic Chemistry . Hybridization &Classification of Organic Compounds Saturated hydrocarbons(Alkanes), IUPAC Preparation & Reactions of alkanes 4 Structure &Physical properties &Nomenclature of alkenes Geometric Isomers, Preparation of Alkenes.,Elimination Reactions Dehydrohalogenatn of alkyl halide,Dehydratn of Alcohol. 5 Dehalogenation of vicinal alkyl halide,Reductn of alkynes Orientation of [dehydrohalogenation& dehydration],Rearrangement of carbonium ion Reactions of alkenes, Addition reactions, mechanism of electrophilic addition reaction , mechanism of free radical addition, ozonolysis of alkenes 6 Preparations & reactions of alkynes ,keto-enol tautomerism Cyclic Aliphatic Compounds [nomenclature,preparation, reactions, reactions of small-ring compounds [cyclopropene&cyclobutane ] Week # Date Topic Alcohols (nomenclature,classification), preparation of alcohols[reduction of carbonyl compounds-hydrolysis of alkyl halide – Grignard reactions-effect of nitrous acid on amines-hydration of olefins Reactions of alcohols[ formation of alkoxide- formation of ethers 7 formation of esters-dehydration –oxidation of alcohol-formation of alkyl halideLucas test Aromatic Compounds,structure of benzene,M.F.,Isomer number,Kekule structure, stability of benzene,Heat of hydrogenation&combustion Resonance structure of benzene.Aromatic character [The Huckel 4n+2 rule]. Nomenclature of benzene. Electrophilic aromatic substitution reaction , introduction , Effect of substituent , groups 8 Determination of orientation . Classification of substituent groups. Orientation in disubstituted benzene. Mechanism of nitration,sulphonation, Friedel-Crafts alkylation Mechanism of halogenation.Reactivity and orientation.Theory of reactivity&orientation 1st Exam 9 Aromatic-Aliphatic compounds [Arenes and their derivatives],structure,nomenclature,preparation, reactions [oxidation,reduction,decarboxylation,Wurtz-Fittg reaction,nitration,sulphonation,halogenation] Aromatic Nitro Compounds [nitrobenzene ,nitrotoluene] reactions&preparations Aromatic Amino compounds[preparation,reactions] Diazonium Salts[preparation&reactions]- Azo-compounds 10 Phenols [structure,nomenclature,acidic character of phenolic compounds,preparations] 11 Reactions of phenols[ (I) Reaction on OH group,salt formation,ether formation,formation of esters .,(II) Electrophilic substitution reactions ,halogenation, nitration,sulphonation,Friedel-Crafts reactions,Kolbe reaction,Ledrer-Manasse reaction,Reimer-Tieman reaction [ Aromatic Alcohols,Aldehydes and Ketones [preparation&reactions] Aliphatic Amines [structure&physical properties] Classification,nomenclature&basicity of amines Week # 12 Date Topic Preparation of amines [reduction of nitro compound , Reductive amination]Reactions of amines. 2nd Exam Aliphatic Aldehydes and Ketones (nomenclature,general methods for preparation of aldehydes -Reactions of aldehydes and ketones (addition reactions) 13 Condensation reactions(condensation with :hydroxyl amine –hydrazine and phenyl hydrazine)-Substitution reactions. Stereochemistry -Isomerism- Classification constitutional isomerism( chainposition-functional) isomerism)- Stereoisomer(configurational-conformational) isomers 14 General Revesion Final Exam