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Models of the Atom Model Greeks – 450 BC Democritus and Leucippus Dalton – 1803 John Dalton’s Atomic Theory Thomson – 1897 Positively charged matter Electron Rutherford – 1911 Bohr – 1913 • • • • • Characteristics The word "atom" comes from the Greek "a-tomos" and signifies indivisible. solid (no void inside) surrounded by an empty All matter consists of atoms, tiny indivisible particles of an element that cannot be created or destroyed. • Atoms of one element CANNOT be converted into atoms of another element. • Compounds form from the chemical combination of a specific ratio of atoms of different elements Scientist’s noticed that: • Cathode rays traveled in straight lines unless they were placed in a magnetic or electrical field • When placed in a magnetic field, the cathode rays bent • When placed in an electrical field, the cathode rays bent towards the positive plate • The cathode ray was identical regardless of the metal used as the cathode J.J. Thompson realized that this was evidence that the atom was divisible and he proposed his model of the atom “the raisin bun in a plum pudding” with electrons embedded in a positively charged sphere. . • Tiny positively charged alpha particles from radioactive radium were aimed like projectiles at a thin gold foil • 1 in 20,000 alpha particles was deflected back by more than 90 • Something small in the centre of the atom was repelling the alpha particles • Rutherford concluded that the atom was mostly empty space occupied by electrons but in the centre, a small “nucleus” contained all of the positive charge and essentially all the mass of the atom • Rutherford explained the nature of the atom but not the mass. In 1931 James Chadwick discovered the neutron which explained the mass • Bohr hypothesized that hydrogen only had certain allowable energy levels on which electrons could be found Modern – post 1932 • This is the model that is accepted today According to the Principles of Quantum Mechanics electrons are distributed around the nucleus in "probability regions". These probability regions are called "atomic orbitals". According to Quantum Mechanics, these orbitals are mathematically defined and are described by a uniquely different math function for each electron. Animations 1. Go to http://www.mhhe.com/physsci/chemistry/essentialchemistry/flash/ruther1 4.swf Watch the animation. 2. Go to http://www.wwnorton.com/COLLEGE/chemistry/gilbert/tutorials/ch3.htm Watch Section 3.2 Rutherford Experiment (p. 106-109) Click view tutorial.