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THE PETROLOGY OF THE PYROXENE-GRANULITE FACIES ROCKSOFJOTUNHEIMEN,NORWAY M. HUGH BATIEY & W. DAVID McRITCHIE Battey, M. H. & McRitchie, W. D.: The petrology of the pyroxene-granulite facies rocks of Jotunheimen, Norway. Norsk Geologisk Tidsskrift, Vol. 55, pp. 1-49. Oslo 1975. The petrography of the peridotites, plagioclase-pyroxene-gneisses, jotunites and mangerites and chemical analyses of the rocks and their constituent minerals are presented. An original differentiation by fractional crystallisation of a melt of generally basaltic composition, in the olivine + plagioclase stability field, can be inferred from bulk chemistry considerations and ele ment partitioning between present assemblages. Later thorough recrystallisa tion under stress produced strong foliation and lineation with progressive elimination by reaction of coexisting olivine and plagioclase in favour of pyroxene. Initial pressures of recrystallisation exceeded 8 kb (above olivine + plagioclase stability limit) and the main metamorphism was concluded 4 kb to preserve granulite facies mineralogy. Partial under pressures > melting of the feldspathic fraction during a pressure drop in the later stages resulted in the formation of transgressive mesoperthosites and assisted meta morphic segregation. Finally the massif was more or less passively uplifted. M. H. Battey, Geology Department, University of Newcastle upon Tyne, Newcastle upon Tyne, NEJ 7RU, England. W. D. McRitchie, Geological Survey of Manitoba, Box 20, 139 Tuxedo Boulevard, Winnipeg 29, Manitoba, Canada. The igneous rocks of Jotunheimen were grouped by Goldschmidt (1916) into the Jotun kindred, ranging in silica percentage from ultrabasic to acid, and characterised by a persistence of pyroxene in the more acid members and by a notable richness in potassium feldspar associated with relatively calcic plagioclase in basic and intermediate members. Goldschmidt's studies have formed the foundation of all later work. Subsequent petrological studies by C. W. Carstens tites and by Hødal (1945) (1920) on the perido on the anorthosites of Vossestrand have con siderably expanded our knowledge of particular aspects. Gjelsvik (1946) has given a careful account of the gamet-bearing anorthosite-magnerite-pyrox enite group of the neighbouring Heidal area in terms of Eskola's facies clas sification. Dietrichson (1953, 1955, 1958, 1960) studied pseudotachylytes, lamprophyres and recrystallised cataclasites, and concluded from chemical analyses and variation diagrams that the Jotunheim massif was originally a stratiform igneous body. Observations on the ultramafic bodies and on the layered structure of the massif were reported by Battey ping are summarised by Battey (1960, 1965), and results of geological map & McRitchie (1973). In this paper it is pro- 2 M. H. BATfEY & W. D. McRITCHIE posed to separate the rocks of Jotunheimen into a marginal group of gabbros with relict igneous textures, associated with thrust sheets of a wide range of composition metamorphosed in the amphibolite facies, from a central tract of layered and unlayered pyroxene-granulite facies rocks. The present paper gives an account of the petrology of the pyroxene granulite facies rocks of the central high mountain tract of Jotunheimen between the Tyin-Gjende Fault on the south and the N.W. Boundary Fault on the north (Battey & McRitchie 1973: figs. 2 & 3). Throughout this area the prevailing rock is a gneiss with dark folia, or spindle-shaped lines, of granular orthopyroxene, clinopyroxene, magnetite and more or less biotite, in a grey mosaic of plagioclase or plagioclase and potash feldspar. Porphyroblasts of a mesoperthitic intergrowth of inter mediate plagioclase and potash feldspar are often present. Apatite is a con stant accessory and zircon appears in the more feldspathic members. The colour index of these gneisses extends continuously from almost wholly feldspathic members to melanocratic types in which the layers or streaks of dark minerals attain centimetre thickness and tend to coalesce. Over wide areas, especially around Mjolkedalsvatn, Saga, Uranostind and Falketind, layering of rocks of different colour index, parallel to the foliation, pro duces conspicuous topographic featuring (Figs. 1-2). At the melanocratic limit of the feldspar-bearing gneisses, a mineralogical discontinuity enters. Heralded by an increasing thickness of mafic mineral Fig. 1. Uranostind: view southeastward from Uranosi ridge, showing mineralogical layering. Photo: Ulrik Lunn. PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 3 Fig. 2. Saga: view eastwards from Uranosi across Skogadalsbreen, showing folded mineralogical layering. Photo: Ulrik Lunn. layers, olivine enters in the cores of the mafic streaks. With its entry the rock becomes ultramafic, because feldspar is not found in contact with oli vine. These two minerals are always separated by a reaction rim resulting from metamorphic conversion of olivine + plagioclase to pyroxene + spinel (Battey 1960: 204, Griffin 1971b). The existence of the rim relationship implies an earlier conjunction of olivine and plagioclase established at lower pressure followed by re-equilibration above 8 to 11 kb (Emslie & Lindsley 1969, Green & Hibberson 1970). The ultramafic bodies are sheet-like, commonly stratified with olivine- and pyroxene-rich layers, and reach thicknesses of tens of metres. The sheets lie parallel with the foliation of the pyroxene-feldspar gneisses and, as they are particularly resistant to erosion and weather to a rusty brown colour, they contribute notably to the display of the layered structure in the gneisses as a whole. Fig. 3 shows features of the lensoid body on Mjølkedalstind for which modal mineral compositions are given in Table l. The rock types mentioned in the last two paragraphs are the principal con stituents of the complex. The petrography and mineralogy of these will now be described, beginning with the ultrabasic members. Homblende-rich amphibolites, which are widespread but occur in zones of shearing, are re garded as retrogressively metamorphosed derivatives and will not be dealt with here. A table setting out the rock classification used in the descriptions appears as an Appendix to this paper. M. H. BATIEY & W. D. McRITCHIE 4 Table 1. Modal analyses (vol. %) of ultramafic body on MjØlkedalstind. Height Spee. No. above base (m) Olivine Ortho- Clino- pyroxene pyroxene Hornblende Spinel Ore 1.5 4.3 (Top 21) Ml 19.5 M2 M3 61.9 12.9 18.4 1.0 16.5 62.3 12.6 10.1 5.4 13.5 58.0 12.0 20.6 3.9 M4 10.7 65.6 11.8 9.9 5.5 MS 7.5 15.8 15.7 66.6 0.3 0.9 M6 4.5 38.9 19.0 32.4 4.8 5.0 9.6 5.5 7.2 Ultramafic rocks MINERALOGICAL COMPOSITION The ultramafic rocks include mineral assemblages definitive of dunite, harz burgite, wehrlite, lherzolite and websterite, interstratified in more or less regular layers. Modal analyses of rocks collected on traverses across two ultramafic bodies (Tables l, 2 & 3) show the range in proportions of the minerals. The principal constituents are olivine and clinopyroxene in vary ing proportions. Orthopyro:xene is present in most rocks, but is subordinate to clinopyroxene: it does not exceed 25 vol. per cent except where plagio clase is present. The ore content is lower in pyroxene-rich rocks. The Langs kavlen body (Table 3) is exceptional in having olivine + plagioclase. Table 2. Modal analyses (vol. %) of ultramafic body S.E. of Uranosvatn. Spee. No. Height above base (m) Olivine OrthoClinopyroxene pyroxene Hornblende Spinel Ore 64/79 69 14.8 14.2 58.7 11.3 64/78 60 81.3 6.8 2.0 4.6 5.3 64/77 53 82.8 9.0 1.7 5.0 1.5 64176 45 81.0 7.0 3.1 2.4 6.5 64/75* 39 85.9 4.2 1.3 4.3 4.3 1.1 64/74 30 86.5 2.9 2.0 5.9 2.7 64/73 27 86.5 2.4 2.3 4.7 4.1 64/72 22.5 85.4 2.0 2.6 3.3 64/71 18 69.4 5.4 24.0 O.l 64170 15 7.5 85.6 6.9 64/69 13.5 64/68 9 9.3 82.3 8.2 64/67 5.7 5.6 89.4 5.0 64/66** o 14.2 67.8 8.0 * trace of biotite ** O.l of biotite 92.0 8.1 5.3 6.7 1.2 0.4 2.3 0.2 2.0 PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 5 Table 3. Modal analyses (vol. %) across a belt including an ultramafic layer, S. end Langskavlen. Distance Spee. No. Spinel E. from Plagio- datum elase Olivine Ortho- Clinopyroxene pyroxene Hornblende Biotite (m) Ore Apatite 1.3 0.3 plectite 63/128 o 49.5 19.8 7.2 22.0 63/129 2.7 53.1 26.6 0.5 19.1 63/130 6.0 12.0 13.6 31.3 2.3 24.6 63/131 9.1 7.0 34.6 24.6 1.6 27.1 34.0 9.2 4.0 25.3 13.1 6.6 63/132* 10.6 28.7 24.2 5.1 31.5 63/133 16.5 52.0 20.5 0.8 24.3 63/136 + Sym- 0.2 2.4 O.l O.l O.l 0.6 15.8 l.O 2.4 0.4 13.8 3.4 l.O O.l 2.4 0.4 tr O.l O.l O.l * also 6.2 sphene The only systematic change that is observed across the ultramafic bodies is the tendency for the marginal zones to be pyroxene-rich and, in some cases, for these zones to contain plagioclase in addition to ferromagnesian minerals. Conspicuous marginal zones of clinopyroxenite up to a metre or more wide border some ultramafic bodies and have sharp contacts with olivine-rich rock on one side and feldspathic gneiss on the other. In other cases centimetre scale reaction rims with the sequence olivine-pyroxene rockforthopyroxene spinelf (amphibole-) clinopyroxene-spinel symplectitefplagioclase-pyroxene rock separate peridotite from feldspathic gneiss. Ultramafic bodies may show regular dyke-like form (Fig. 4), but in other cases interfingering relations are seen and pyroxenite layers only a few centi- Fig. 3. Sharp contact between ultramafic rock and pyroxene-feldspar gneiss inter fingering with it, in the lens SE of MjØlkedalstind. 6 M. H. BATIEY & W. D. McRITCHIE Fig. 4. Sharply-bounded sheet of ultramafic rock in pyroxene-feldspar gneiss cut by a typical flat-lying lag fault with a pegmatite vein along it. metres thick occur (Fig. 5). In some examples strong deformation has pro duced a complex relationship between ultramafic and feldspathic gneiss, with layers and pods of the one lying in a matrix of the other (Fig. 6: see also Fig. 5. Pyroxenite layers a few cm thick in pyroxene-feldspar gneiss. Ridge 1.5 km N of Skauthøe. PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 7 Battey 1960). In such examples, pyroxenic reaction zones always separate olivine from plagioclase-bearing rock. An example of one of these reaction zones has been studied in detail by Griffin (1971b), who attributes the ab sence of garnet to an episode of rapid uplift and pressure-drop during cooling. Garnet is, in fact, present in small amounts in pyroxenite border zones of ultramafic bodies (Fig. 9B) and in dark feldspathic gneisses near them. It forms around ore grains, and biotite is very often associated with it. Its status is uncertain, in as much as garnet also forms in retrograde assemblages in cluding amphibole, biotite, epidote and scapolite, produced by late shearing movements. Along these movement planes pegmatites often form and pegmatitic feldspar rocks with garnet porphyroblasts are occasionally seen. Garnet also replaces plagioclase in the igneoustextured marginal gabbros and rare dykes within the massif. Tentatively we may separate the retrograde paragenesis from the garnet iferous rocks near ultramafic contacts. In the latter, the reaction by which garnet forms between ore and plagioclase in the feldspathic gneisses may be analogous to that in garnetiferous basic gneisses with less than 5 per cent of garnet described from Scourie by O'Hara (1961). It does not appear to be the reaction of aluminous pyroxene + spinel + plagioclase to give low-A1 pyroxene + garnet. Within the ultramafic border zones themselves it is not certain whether pyroxene enters into the reaction or not. Fig. 6. Detached slivers of pyroxene-feldspar gneiss in ultramafic rock. W. flank of ridge N. of Skauthøe. 8 M. H. BATIEY & W. D. McRITCHIE TEXTURES Uncrushed ultramafics consist of a mosaic of anhedral, equigranular olivine and pyroxene grains ranging up to 4 mm in diameter, united by simple curving junctions. A typical rock has pyroxene plates about 2 mm across. Magnetite and hercynite granules are disposed along the margins of the sili cate grains. Cataclastic effects are widespread, indeed almost universal, and have produced a range of grainsize down to 20 microns. The , crushing begins around grain margins and extends as lanes between relict crystal cores. Olivine is more readily crushed than pyroxene and, beginning with the development of translation lamellae of slightly differing extinction position, it is ruptured and reduced to a paste of fine fragments. Fig. 7 shows a boulder of peridotite breccia with lumps of unreduced pyroxenite in a matrix of crushed olivine. The same preferential crushing of olivine is seen on the microscopic scale. The pervasive cataclasis has not been accompanied by retrograde meta morphism and the high temperature minerals, olivine and pyroxene, persist with hardly any serpentinisation in most places. On the other hand, there is also localised shearing along discrete planes in many places, where the minerals dose to the plane of movement have been converted to an epidote amphibolite facies assemblage (Battey & McRitchie 1973: fig. 6). Whereas the first type of mechanical break-down must have taken place above 400°C Fig. 7. Tectonic conglomerate of pyroxenite lumps in a matrix of dunite. SW side of Store MiØlkedalsvatn. PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 9 or in the virtual absence of water, the second represents a late-stage high leve! shearing episode in the history of the rocks. DETAILED MINERALOGY OF ULTRAMAFICS Olivine Olivine is in rounded equant grains, clear except for specks of magnetite along cracks, and is rarely serpentinised except in one or two localities near the Tyin-Gjende Fault. Olivine is usually separated from associated clino pyroxene by a thin rim of orthopyroxene. Replacement of olivine by ortho pyroxene has been observed, with trails of relict olivine passing into the orthopyroxene. The olivines have a rather narrow range of composition, mostly between Fa1s and F�5· Table 4 presents data on olivines from rocks of one ultramafic body some 2.5 km north-east of Spiterstulen Hotel. Compositions have been determined from the refractive index � using the curves of Deer et al. ( 1966: fig. 3). Averages of 2V measurements generally support the values given, but indicate a wider spread of composition: they are regarded as subject to much greater experimental errors than refractive index measurements. The ranges of both, however, suggest that there is some local variation in composition. Compositions determined from the d174 X-ray spacing (Jambor & Smith 1964) are in reasonable agreement with those from optical data, though generally a little more iron-rich (McRitchie 1965). Of 20 olivines from widely separated ultramafic bodies determined by X-ray, 16 lie in the range Fa1s to Fa25, the extremes being Fa14 and Fa29. Checks of measurements on film by diffractometer measurements and by using other powder lines gave satis factory agreement suggesting that the range of compositions is not due to experimental error. A chemical analysis of one olivine, Fa21, is given in Table 5, anal. 1. Grif fin {1971b) reports that numerous electron-probe analyses of olivines in 58{63 (2.5 km on bearing 32° from Spiterstulen) varied little from Fa23• (Numbers refer to specimens in the collection of the University of Newcastle upon Tyne Department of Geology.) No strong evidence has been found of systematic differences between the olivines of different ultramafic bodies. It may be noted that the three most magnesian examples (Fa14, Fa15, Fa16) all come from specimens taken across a body at the south-west end of Uranosvatn, approximately 7.5 km on a bearing of 285° from Eidsbugarden Hotel. This is the most westerly mass sampled. However, the Koldedalsnosi body, along strike, has more ferri ferous olivine. Nor is there any systematic change within a single body. Indeed, the re fractive index range in one rock (J32, Table 4) is as great as that of the whole body of which it is a part. The olivine compositions fall within the range of those forming cumulates from gabbroic magmas (Fig. 8). But olivine in Jotunheimen has, in general, l l l l l l l l l J32 J33 J34 J35B 141 142 146 147 l J30 Rock No. (6) 19 18 - 19 24 24 23 25 d174 Fa % Mol. l 1.692 (7) 1.690 (11) 1.693 1.689- 1.690 (12) 1.690 (6) 1.692 (7) 1.692 (6) 1.689 (7) 1.689 (5) 1.691 av. 1.688- 1.691 1.689- 1.693 1.690- 1.694 1.690- 1.690 1.688- 1.690 1.687- 1.692 1.690- range y Orthopyroxene Number of determinations in brackets Fa16 (little present) (5) 1.692 = 1.691 1.689- 2V90° 21 20 22 22 21 21 Fa % Mol. (traccs only) 1.694 1.694 ( 7) 1.693- 1.692 1.693 (7) 1.692- 1.695 1.694- (6) 1.696 1.697 1.695 (6) 1.694- 1.694 1.690 (5) 1.691 1.697- 1.694 av. 1.695- range � Olivine 20 20 20 21 21 19 19 21 Fs % Mol. l l (2) 1.687 av. 1.683- 1.687 (7) 1.6861.688 (6) 1.686 56 1.684 1.682- 55 (4) (5) (6) 1.688 (lO) 1.686 1.686 1.689 (l) 1.684- (5) 59 (3) 1.685 (4) 55 1.687 1.6841.689 55 (l) 1.687 (little present) 1.687 1.686- range ( 4) (1) 55 (4) 5672 av. � 39-41 40--44 40-46 39-43 36-43 Z:c range Mg41 Fe12 Ca47 Mg/Fe = 77123 General composition of clinopyroxene 54-58 54-55 56-64 55-56 54-55 56-57 range 2Vy Clinopyroxene Table 4. Optical properties of minerals from the ultramafic body 2.1 km on 50° from Spiterstulen Hotel. (5) 40 (4) 42 (5) 43 (5) 41 (4) 40 av. l l 1.649 � 1.656 y 1.670 1.649 � 1.660 y 1.668 beige Y, Z pinkish brown 2Vy 85° Z: c 20° X pale 2Vy 87° � 1.658 X pale beige, Y, Z greenish yellow-brown Z:c 19° X pale yellow, Y pale beige, Z pinkish beige a brown Z:c 1772 ° X pale yellow, Y pinkish yellow-brown, Z green- a Amphibole ..... � ...... ..., () ::r: tTl � � (") � Ro �><: > t:l:l t:r.: � o PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 11 Jotun heim nf---Scourie 32 (HT- •HA) -------+ to 96 30 -toiOO 28 26 nf- ---•to96 nf -- nf--f nf --- 20 18 ------ - - - -- - 16 6 4 2 ---- ---- ----to 83 nf 12 8 - nf-- 14 ro ? nfnf nfnf nf -nfnf nf-if nf 10 20 40 30 50 60 Mol. per cent fayalite Fig. 8. Olivine compositions from some igneous intrusions compared with those from Jotunheim ultramafics. nf = non-feldspathic, if = interstitial feldspar, f = feldspathic. 1. SE Alaska ultramafics: Taylor & 20. Cuillins, Skye, Hebrides: ibid., p. 415 Noble 1960 2. Stillwater, Montana: Jackson 1961 21. Belhelvie, Aberdeenshire: Wadsworth, 3. Dun Mt. etc. New Zealand: Challis 22. Kapalagulu, Tanzania: Wager & 1965 4. Gt. Dyke, S. Rhodesia: Worst 1958 5. Webster-Addie, N. Carolina: Miller 23. Duke I. Alaska: op. cit., p. 512 24. Muskox, Canada: Smith, C. H. 1962 1953 6. Red Hills, New Zealand: Walcott 1968 7. Hebridean picrites: Drever & Johnston 1958 8. Union Bay, Alaska: Ruckmick & Noble 1959 9. Troodos, Cyprus: Wager & Brown 1968, p. 508 10. Bay of Islands, Newfoundland: op. c:t., p. 453 Stewart & Rothstein 1966 Brown 1968, p. 469 25. lnsch, Aberdeenshire: Clarke & Wadsworth 1970 26. Kaerven, E. Greenland: Wager & Brown 1968, p. 435 27. Carlingford, Eire: Le Bas 1960 28. Kap Edvard Holm, E. Greenland: Wager & Brown 1968, p. 427 29. Skaergaard, E. Greenland: op. cit., pp. 27, 35 30. Phenai Mata (lowermost 250 ft), 11. Lizard, Cornwall: ibid., p. 505 Gujarat, India: Sukheswala & Sethna 12. Rhum, Hebrides: ibid., p. 255 1969 13. Stjernøy, Norway: ibid., p. 506 14. Baltimore, Maryland: ibid., p. 509 31. Ashland, Wisconsin: Wager & Brown 1968, p. 510 15. Huntly, Aberdeenshire: Weedon 1970 32. Kiglapait, Labrador: op. cit., p. 457 16. Moxie, Maine: Wager & Brown 1968, 33. Duluth, Minnesota: ibid., p. 447 Scourie (metamorphic), Sutherland: p. 509 17. Ard Mheall, Rhum: Wadsworth 1961 18. Insizwa, S. Africa: Wager & Brown 1968, p. 525 19. Bushveld (Basal Zone), S. Africa: op. cit., p. 358 O'Hara 1961, p. 269 HT Hawaiian tholeiite, HA Hawaiian alkali basalt 12 M. H. BATfEY & W. D. McRITCHIE Table 5. Chemical analyses of olivine and orthopyroxenes. Si02 Ti02 Al20a F�Oa FeO Mn O MgO CaO Na20 Sum l 2 3 4 5 6 7 8 9 39.10 0.01 n.d. 3.92 15.48 0.60 40.30 0.80 0.20 100.41 53.72 0.06 2.78 2.74 9.72 0.20 29.40 1.40 0.30 100.32 53.01 0.16 4.49 0.03 13.62 0.45 28.20 0.20 0.10 100.26 55.60 0.03 2.00 4.54 10.10 0.75 26.05 1.00 0.60 100.67 52.89 0.14 3.56 0.02 13.70 0.28 28.07 0.61 0.16 99.77 51.69 0.10 4.57 0.32 15.88 0.44 25.80 1.40 0.20 100.40 51.60 0.13 3.72 1.30 16.51 0.65 25.23 1.44 0.16 100.74 52.30 0.12 5.37 0.20 16.29 0.68 23.24 1.86 0.35 100.41 49.90 0.21 6.30 0.25 17.68 0.73 23.90 1.28 0.15 100.40 Cation proportions to 4 oxygens Si Al lO 50.87 0.05 6.05 3.10 15.46 0.65 22.02 1.15 0.004 99.35 Cation proportions to 6 oxygens 0.992 1.900 0.100 1.806 0.114 1.972 0.028 1.903 0.097 1.862 0.138 1.878 0.122 1.900 0.100 1.821 0.179 1.863 0.137 0.992 2.000 2.000 2.000 2.000 2.000 2.000 2.000 2.000 2.000 0.015 0.074 0.006 0.057 0.054 0.002 0.039 0.004 0.035 0.501 0.020 1.373 0.057 0.013 0.131 0.004 0.004 0.493 0.022 1.269 0.072 0.026 0.093 0.006 0.009 0.539 0.022 1.308 0.050 0.009 0.127 2.021 2.036 0.076 0.328 0.012 1.532 0.021 0.009 0.072 0.286 0.006 1.560 0.053 0.021 0.403 O.D15 1.504 0.009 0.009 0.119 0.298 0.023 1.385 0.038 0.043 0.410 0.009 1.514 0.024 0.013 0.056 0.002 0.009 0.475 0.013 1.392 0.054 0.013 1.978 2.015 2.020 1.963 2.026 2.014 2.042 Atomic ratios 78.7 Ca 2.7 Mg 21.3 Mg 79.1 Fe Fe 18.2 0.4 78.4 21.2 2.0 1.2 3.9 2.6 2.5 77.7 69.9 69.0 68.6 66.0 21.7 21.0 2.8 72.1 25.1 2.8 76.3 27.3 27.0 28.8 31.5 Cell dimensions (A) a b c 18.279 8.830 5.195 18.259 8.828 5.198 18.290 8.878 5.203 18.277 8.844 5.197 18.292 8.879 5.201 Al Ti Fe3+ Fe2+ Mn Mg Ca Na 18.262 8.828 5.194 l. Olivine from hornblende-bearing harzburgite 621112, E. side of Langeskavlen (Includes P205 0.01). 2.-10. Orthopyroxenes from the following: 2. Lherzolite 63/M6b, S.E. MjØlkedalstind; 3. Hornblende-pyroxenite 62143, near summit of HøgbrothØgdi; 4. Hornblende-harzburgite 621112, E. side of Langeskavlen; 5. Hornblende-harzburgite 133, 2.1 km on 50° from Spiterstulen Hotel; 6. Pyroxene-gneiss 62140, HØgbrothØgdi; 7. Pyroxene-rich jotunite 62147, HøgbrothØgdi; 8. Pyroxene-gneiss 62/53, HØgbrothØgdi; 9. Jotunite 62/36, Høgbrothøgdi; 10. Jotunite 62/48, HøgbrothØgdi summit. Analyst: W. D. McRitchie, except no. 5, M. H. Battey. only survived the metamorphism where it is in feldspar-free rocks. On the as sumption that the ultramafics are cognate with the surrounding gneisses, we are denied knowledge of the full composition range that may once have existed, because the olivine possibly once present in gabbroic rocks would 0.084 0.473 0.021 1.211 0.046 1.962 PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 13 have disappeared in the metamorphism. Comparisons should therefore be made with non-feldspathic cumulates of gabbroic magma, or non-feldspathic peridotites of other origins. When this is done, the Jotunheimen olivines are seen to be unusually ferriferous (cf. Goldschmidt 1916: 24-25). They are of a composition that would be expected to occur in feldspar-bearing rather than non-feldspathic cumulates. McRitchie (1965), however, finds a similar range of olivine compositions in ultramafics south of the Tyin-Gjende Fault, which have not been subjected to granulite facies metamorphism. The olivine-bearing rocks of Langskavlen (Table 3) appear to represent rocks from which plagioclase is being eliminated by reaction, as witnessed by the high proportion of symplectite, though it has not yet been entirely destroyed. Such rocks may represent the original mineralogical composition of other ultramafics now free of feldspar. Fig. 9 shows interstitial patches in a pyroxenite of the border zone of an ultramafic body illustrating the elimi nation of basic plagioclase feldspar and the development of garnet b)l meta morphic reaction. Garnet is never abundant but is often found in small amounts in dark rocks transitional to feldspathic gneisses near the margins of ultramafic bodies. Fig. 9. Stages in border reactions of ultramafics. A. Interstitial plagioclase (striped), hypersthene (stippled), hornblende (cross-hatched) and ore (black), in plates of clinopyroxene enclosing a few apatites. Garnet only as a thin pellicle around the plagioclase tongue and ore granule in the extreme south. B. Garnet (stippled) surrounding ore + green spinel (black) amidst plates of clino pyroxene (cpx). h = hypersthene, pl = residual plagioclase, hb = hornblende. Section JJ37 (72133 Harker Coll. Camb.) marginal pyroxenite, ultramafic body 1100 m on 320° from Juvasshøe. M. H. BATTEY & W. D. McRITCHIE 14 The proportion of spinel in the main masses of ultramafic rock is not great enough, however, to suggest the elimination of any large amount of original plagioclase. The importance of the reaction phenomena is their indication that olivine + plagioclase was originally the stable assemblage, presumably under magmatic conditions (cf. Rothstein 1964). Orthopyroxene This mineral occurs in widely varying amounts in the ultramafic bodies. There seems to be no regularity in its proportions relative to the other major minerals (Tables 1-3). Orthopyroxene in olivine-rich rocks is interstitial to olivine and somewhat less pleochroic than in pyroxenites and feldspathic gneisses. Occasionally it poikilitically encloses olivine. Perfectly spherical crys tals (Fs24) with smooth, finely-pitted surfaces, but no sign of marginal altera tion, have been separated from one specimen (62/112). Their shape is perhaps 30 20 Q) c > ,. l c / / � / o u.. 10 / «"" ·· '<o ,.c l l v ""' / / /. / " / l l l l l ""' 10 20 Fs % 30 in orthopyroxene Fig. 10. Content of iron silicate in coexisting olivine and orthopyroxene in ultramafic rocks. Broken line shows main field of olivine-orthopyroxene pairs from layered gab broic intrusions, after O'Hara (1963). PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 15 due to same kind of resorption, but no records of such spherical forms have been found in the literature. In the pyroxenites, orthopyroxene is rather more pleochroic, and carries regularly arranged, rectangular, red-brown inclusions supposed to be rutile. Clinopyroxene is aften exsolved in crude lamellae parallel to (100) and sometimes in more irregular fashion. Small clear crystals of secondary ortho pyroxene develop in streams running between the larger crystals and passing through cracks in the larger grains. Table 4 gives values of the refractive index for orthopyroxenes of rocks collected across the body 2.5 km north-east of Spiterstulen, with com positions, Fs19-21, read from the curves of Deer et al. (1966: fig. 41). The composition range is very small, with no systematic change across the body. Chemical analyses of four orthopyroxenes from other ultramafic bodies are presented in Table 5, anals. 2 to 5. They yield ratios of Fs1s to Fs-æ. Using the microprobe, Griffin (1971b) finds orthopyroxene from a reaction zone between peridotite and gneiss to be Fs21• Optical determinations on orthopyroxenes from other ultramafics give values in the range Fs18 to Fs26• Table 5 gives the cell dimensions of the analysed orthopyroxenes. The composition range of the orthopyroxenes, like that of the olivines, is rather restricted. Comparison of the molecular ratio FeOfFeO + MgO of coexisting olivines and orthopyroxenes (Table 6) reveals only small differ ences between the members of each pair. Fig. 10 (cf. O'Hara 1963) shows the relationship of this 1:1 ratio of Fa per cent to Fs per cent to the equi librium ratio determined by Bowen & Schairer (1935). OlivinejCa-poor pyroxene pairs of igneous rocks show either the 1:1 ratio, or a greater concentration of FeO in pyroxene than in olivine, a feature at- Table 6. Compositions of coexisting olivine and orthopyroxene. 130 132 133 134 135B J41 J46 58/63 62/194 63/M6b 62/ 181 63/137 62/1 12 Olivine Fa% Orthopyroxene Fs% Difference 21 21 22 22 20 21 19 19 20 19 21 29 22 21 19 19 21 21 20 20 19 18 19 18 26 22 o -2 -3 -l +l -l +l o -2 o -3 -3 o The first 12 determined by optics or d174 of olivine. Orthopyroxene checked in some cases by electron microprobe. 621112 by wet chemical analysis. 16 M. H. BATfEY & W. D. McRITCHIE tributed to lack of equilibrium in cooling melts. In metamorphic rocks, like those of Jotunheimen, a doser approach to the equilibrium ratio would be expe�ted. Since this is not observed, it may be concluded either that the as semblage is a disequilibrium igneous one and that the metamorphism has not been high enough to allow the attainment of equilibrium: or that the equilib rium ratio of Bowen and Schairer is inappropriate to natural conditions. In any case it may be said that the partition of Fe and Mg between olivine and orthopyroxene in the Jotunheim ultramafics is no different from that found in slowly cooled mafic igneous rocks. Clinopyroxene Widely varying amounts of clinopyroxene are present in different layers of the ultramafic bodies. Little regularity in its change of proportion relative to other phases is shown by Tables 1-3. Nevertheless, it has been observed that clinopyroxene-rich rocks tend to occur at the margins of the bodies (cf. Carstens 1920) though the thickness of these marginal layers is extremely variable. There is, however, always a pyroxenic rim of some kind between olivine-bearing and feldspathic rocks. The clinopyroxene of the ultramafics is in equant grains which are very commonly full of opaque and brown inclusions, often zonally arranged and concentrated centrally. Orthopyroxene is exsolved in pools and occasionally along the 100 planes (including the twin plane in the limited number of cases where twinning is shown). 0·1 mm Fig. 11. Plagioclase and ore granules enclosed along the 100 partings of clinopyroxene. Section J29B/1, hornblende-websterite, E side of Visdalen, NNE of Spiterstulen. • PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 17 Table 7. Chemical analyses of clinopyroxenes. l 2 3 4 5 6 Si0 2 49.02 44.00 47.00 47.60 46.29 46.00 Ti02 0.37 0.52 0.15 0.50 0.51 0.36 A120a 6.88 9.46 6.77 6.34 4.92 6.57 2.51 3.60 3.59 3.85 3.87 2.80 4.61 5.31 6.16 6.46 0.16 0.19 0 30 Fe<&Oa FeO 3.14 4.63 Mn O 0.30 0.27 MgO 16.14 16.20 15.70 15.00 15.67 15.50 Ca O 20.56 21.10 21.30 20.60 21.30 21.70 0.74 0.60 1.30 0.50 0.50 0.05 0.10 99.91 99.51 Na20 K20 0.10 99.67* • 100.48 nil nil 100.42 . 1.00 nil 100.69 includes P205 0.01 Cation proportions to 6 oxygens Si 1.808 1.638 1.747 1.770 1.750 1.721 Al 0.192 0.362 0.253 0.230 0.218 0.279 2.000 2.000 2.000 2.000 1.968 2.000 Al 0.104 0.044 0.037 0.046 0.000 0.004 Ti 0.011 0.016 0.004 0.027 0.014 0.011 Fe3+ 0.071 0.103 0.098 0.107 0.109 0.081 Fe2+ 0.097 0.143 0.143 0.165 0.195 0.202 Mn 0.009 0.009 0.004 0.007 0.009 Mg 0.891 0.904 0.876 0.836 0.890 0.871 Ca 0.812 0.841 0.848 0.821 0.864 0.871 Na 0.004 0.045 0.094 0.036 0.036 0.072 K 0.004 0.005 1.999 2.109 Ca 43.4 42.0 43.1 42.5 41.7 42.9 Mg 47.5 45.2 44.5 43.3 43.0 42.9 9.1 12.8 12.4 14.2 15.3 14.2 Fe 2.100 2.042 2.120 2.121 Cell constants a sin � 9.334 9.349 9.351 9.353 9.354 9.363 b 8.874 8.888 8.890 3.900 3.899 8.915 c sin� 5.0098 5.0166 5.0219 5.0256 5.0202 5.0280 Source rocks 1. Peridotite 63/M6b, S.E. slope MjØlkedalstind. 2. Pyroxenite 62143, near summit of HØgbrothØgdi. 3. Pyroxene-rich pyroxene-feldspar gneiss 62140, HøgbrothØgdi. 4. Ditto, 62153, HøgbrothØgdi. 5. Mangerite-jotunite 62136, HøgbrothØgdi. 6. Jotunite, 62151, W. foot of HØgbrothØgdi. Analyst: W. D. McRitchie. 18 M. H. BAITEY & W. D. McRITCHIE In rare cases plagioclase may occur in the heart of a pyroxene grain, as a nest of rounded blebs enclosing dactylitic granules of pyroxene in optical continuity with the surrounding crystal. Plagioclase may occur along the 100 parting of clinopyroxene, as thin plates and beaded streaks associated with magnetite and granules of pleochroic hypersthene (Fig. 11). Table 4 gives the optical properties of clinopyroxenes from a series of rocks collected across one ultramafic body. Analyses 1 and 2 of Table 7 re present the compositions of clinopyroxenes from ultramafic rocks deter mined by conventional chemical analysis, while analyses 7, 8 and 10 of Table 8 are partial analyses by electron microprobe. The microprobe results give slightly higher CaO values which agree hetter with the 2V measure ments. As the microprobe analyses were made on selected homogeneous grains they should be free from interfering effects of included exsolution lamellae of a lime-poor phase which may affect the bulk analyses. Griffin (1971b) analysed clinopyroxenes from a peridotite, 58/61, and its reaction zone with the surrounding gneiss. The two are virtually identical, their composition being C145Mg44.sFe10.5 in reasonable agreement with the other results. The relationship between coexisting clinopyroxenes and orthopyroxenes on these rocks is considered below in conjunction with analyses of pyroxene pairs from feldspathic pyroxene-gneisses. Amphibole Many of the ultramafic rocks carry a pinkish-brown hornblende forming anhedral to subhedral crystals with sharp boundaries towards the other minerals and of comparable grain-size with them. They show every appear ance of primary grains. The optical properties of examples of these amphi boles are given in Table 4 and an analysis of one of them in Table 9. Marginal zones of ultramafic bodies and the whole of some small ultra mafic lenses may sometimes be recrystallised to greenish-black amphibolite. The amphibole replacing the clinopyroxene and orthopyroxene is normally pleochroic in greens. This change is restricted to zones of shearing traversing the granulite facies rocks and is regarded as representing a late retrograde metamorphic event. Spinel Green spinel is a common accessory mineral of the ultramafic rocks. It becomes particularly conspicuous in the reaction zones between ultramafic and feldspar-bearing rocks. Its refractive index is between 1.78 and 1.79 and the cell-edge a FeOfMgO 1.8, so that on the diagram of Deer et al. (1966: 431) it falls = = 8.132, while Griffin's (1971b) microprobe analysis gives between hercynite and the field of pleonaste. The spinel usually forms composite grains with magnetite. The two phases occur as separate portions of the composite grain, united along a smoothly curving boundary. No regular crystallographically controlled intergrowths 45! 38! 16 21.6 13.1 9.9 Cpx 56.35 0.61 2! 56! 41 1.2 18.1 23.9 1 2 58 40 2 45 39 16 21.4 13.2 9.8 Cpx 56.79 0.63 1.0 19.0 23.3 Opx 3 47 38 15 21.3 12.6 8.9 Cpx 52.68 0.59 2 64 34 1.0 20.2 19.2 Opx 4 Cpx 2 65 33 - - 42 41 17 0.75 18.9 21.5 13.3 9.6 19.4 Opx 5. 4. 3. 2. tind. 58/21 Mangerite Eidsbugarden-Olavsbu track at beginning of descent to Rauddalen. 58123 Jotunite Rauddalen valley floor S.E. of Olavsbu on Eidsbugarden track. 58124 Jotunite Semmeldalsmunnen, Olavsbu-Leirvassbu track, 0.5 km S.S.W. of Langvatn. 58/26 Pyroxene-gneiss Presten Ridge, N. of Leirvassbu. 1. 58/20 Mangerite 350 m E. of ultramafic body E. face MjØlkedals- Whole Rock Si02 FeO/ (MgO+FeO) Atomic ratios Ca Mg Fe Weight per cent CaO MgO Total Fe as FeO Opx 2 60 38 5 6 46 39 15 21.3 12.9 8.6 Cpx 49.81 0.56 2 64 34 1.1 21.1 20.0 Opx 1 73 27 0.5 24.8 16.7 Opx - 7 47 43 10 22.5 14.6 5.7 Cpx 1 78 21 8 44 44 12 20.4 14.6 6.7 Cpx 38.73 0.33 0.5 27.0 13.0 Opx 1 68 31 - 0.6 22.8 18.7 Opx 9 48 39 13 22.3 12.9 7.5 Cpx - 1 77! 21! 0.7 27.3 13.3 Opx Cpx 46 45 9 2 1.8 15.1 5.5 10 Analyst: M. H. Battey. 6. 58/38 Mafic jotunite N.E. ridge of GaldhØpiggen. 7. 120 Biotite-pyroxenite N. ridge of Skauthøe, E. of Visdalen. 8. 133 Homblende-harzburgite E. side Visdalen, N.N.E. of Spiterstulen. 9. 62/53 Mafic pyroxene-gneiss W. face of HØgbrothøgdi N. of Eidsbugarden. 10. 134 Wehrlite E. side Visdalen, N.N.E. of Spiterstulen. 45 40 15 21.5 13.3 9.0 Cpx 48.00 0.53 0.9 19.4 22.0 Opx Table 8. Partial analyses of related pyroxenes (analysed by electron microprobe). \0 ...... Cll :;.;; o (") � Cll "'1 > (") ...... 1:!1 > z c::: 1:"" ...... ..., 1:!1 6:;.;; -< :;.;; o :>< 1:!1 z "Ø o "'1 1:!1 ..., :;.;; o 1:"" o o -< "Ø 20 M. H. BATIEY & W. D. McRITCHIE Table 9. Analysis of amphibole. Si02 Ti02 Al20:J F�O:J FeO MgO CaO Na20 K20 H20+ H2o P205 41.20 2.04 14.83 2.41 7.21 15.08 11.85 2.70 1.24 1.07 n.d. 0.18 99.81 From hornblende-harzburgite, 133, E. wall of Vis dalen, N.N.E. of Spiterstulen (cf. Table 12). Analyst: M. H. Battey. are observed, and the relationship suggests metasomatic change rather than exsolution at the solvus known from experiments in the system hercynite magnetite (Turnock 1959). Biotite Usually sparsely distributed in shreds between the other minerals, biotite may sometimes form more prominent flakes 1 to 2 mm in length. It is a pale brown phlogopitic variety, in contrast to the darker biotite of the feldspathic gneisses discussed below. Carbonate Traces of carbonate in shapeless interstitial crystals occur in some of the ultramafic rocks. The presence of this mineral is presumably due to a slight degree of alteration by weathering, though on the whole the primary minerals are remarkable for their freshness, and it is not clear which of them has pro vided the materials of the calcite. Pyroxen�-feldspar gneisses (pyroxene-granulites) Rocks of this group are overwhelmingly dominant in the area under con sideration. The ultramafic layers and lenses are conspicuous but quantita tiv�ly quite subordinate. A recent discussion (Behr et al. 1971) has shown considerable divergence of opinion on the meaning to be attached to the term granulite. In particular, a number take the view that granulites, strictly speaking, should contain platy aggregates of quartz. The question of definition is not yet resolved, but as the Jotunheim rocks do not usually contain quartz they are referred to here as pyroxene-feldspar gneisses belonging to the granulite facies. PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 21 MINERALOGICAL COMPOSITION They are typically composed of feldspar, orthopyroxene, clinopyroxene, bia tite and opaque ore, with accessory apatite in most specimens and accessory zircon in the more feldspathic examples. Hornblende is often present, more notably in the less feldspathic rocks, but it is replacing pyroxene and is regarded as a product of retrograde metamorphism. Traces of garnet may sometimes be seen. Four varieties of feldspar may be distinguished, namely, plagioclase: plagioclase with sparse antiperthitic lamellae: mesoperthite in which plagio clase (andesine) is intergrown with a roughly equal amount of potash feid spar: and homogeneous, or weakly perthitic, orthoclase. Micrometric analysis of 130 feldspar-bearing rocks gave the following result: plagioclase only orthoclase + perthite < plagioclase orthoclase + perthite > plagioclase orthoclase + perthite only 59 37 29 5 In a further 64 examples examined qualitatively 23 have plagioclase only, 34 have plagioclase + potash feldspar and none have potash feldspar only. Two feldspar gneisses thus predominate over gneisses with plagioclase only in the ratio of about 5:4. As the colour index of the rock falls, the proportion of potash feldspar usually rises; but this is not always so, and there are some quite leucocratic rocks (colour indices 0.3, 6, 11, 13, 16) in which the feldspar is all plagio clase. Large bodies of anorthosite have not been found, however, and in this respect the area contrasts with that farther west around the head of Sogne fjorden (Hødal 1945, Griffin 1971a). In the direction of increasing colour index, neither orthoclase nor con spicuous perthite have been seen in rocks with a colour index greater than 44. McRitchie (1965) finds, moreover, that potash feldspar is incompatible with hornblende. Most of the rocks in this group contain both clinopyroxene and ortho pyroxene, though the fine-granular texture of the spindle-shaped pyroxene clusters makes distinction between them difficult at times. Micrometric mea surement gave the following distribution in 130 rocks: clinopyroxene > orthopyroxene orthopyroxene > clinopyroxene clinopyroxene only orthopyroxene only 58 39 33 4 In a further qualitative sample 45 rocks have both pyroxenes, 9 have clino pyroxene only and l has orthopyroxene only. Biotite is usually present and may occur in amounts as high as 35 vol. per cent. Though variable, it is present on average to about half the amount of 22 M. H. BA TIEY & W. D. McRITCHIE the total pyroxene and makes up less than a third of the dark minerals when ore is counted. Ore averages 3.4 vol. per cent, ranging from a few tenths of a per cent to 7 per cent, with exceptional values of 9, 11 and 22 per cent. Apatite is often relatively coarse and occurs in bluntly oval, anhedral grains. Garnet is a mineral occurring in accessory or trace amounts, in a small proportion of the rocks. It is recorded in 32 out of 130 micrometrically analysed rocks and in 16 out of 56 others. It is always associated with ore and nearly always with biotite. Within the range of these generalisations, the gneisses show a continuous variation in mineralogy. Formal subdivision can be made by micrometric analysis, but it is difficult to recognise macroscopically the varieties so estab lished. Colour index is the chief parameter that can be used to separate the rocks in the field. Fig. 12 shows the proportions of dark minerals plotted against feldspar content for a sample of olivine-free rocks. This presentation shows: the break in continuity between feldspar-free rocks and those with more than 15 vol. per cent feldspar; the relative scarcity of feldspar-bearing rocks with less than 50 vol. per cent feldspar; the fairly steady diminution, on average, of both types of pyroxene and biotite with increase in feldspar beyond 50 vol. per cent; the uneven distribution of hornblende; and that, in any set of classes by feldspar content, the variation of the biotite content of a class is likely to be greater than that of the clinopyroxene or orthopyroxene content. The fairly well-marked break in the trend of mineralogical variation at 50 vol. per cent feldspar seems to be significant. A rock containing 50 per cent feldspar, 15 per cent clinopyroxene, 12 per cent orthopyroxene and 20 per cent biotite (all of compositions corresponding to those determined from these rocks) would contain about 50 wt. per cent Si0.2• There is thus a smooth mineralogical variation, matched by the chemical variation described below, that extends from an acid composition to that of basalt and may re present a liquid line of descent. The scatter of more basic mineralogical compositions in Fig. 12 would represent accumulative rocks. TEXTURES Texturally the rocks are made up of either folia or spindle-shaped aggregates of anhedral pyroxene grains, passing by attenuation into trains of granules, separated by layers or lanes of anhedral feldspar. The foliation may be well marked, but often it is rather crude, and a linear structure defined by trains of dark minerals is dominant. There is rarely any fissility along the folia (except along late-formed movement planes with retrogressive minerals), but the outcrops as a whole weather into ledges controlled by mineralogical layering. PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 30 Zircon present Biotite (93/130} z z z z z z zz o o 10 � lO o o å t 50 4Q Hornblende o o o o 20 ; QO 10 � fo b 50 �o � o Clinopyroxene 30 � o o Orthopyroxene o o o 20 o o oo 8 c:Po q, o�o'b o 0 Oo � o o cfl 0 o o 00� O 0Cb O �c{?.� � o Cl;fb ciJ o oo o o o O o o o o o o oo n o o o o 00 oo o oo oocfP o c€ o o ooo �oo o . o o 0 o o�Oo8 oo o 0 o g;,'?l o oao oOo o �o o o 20{) 1 o Do 191/1301 o o o o o o o z z z zz zzz z z zz zzz z z zzz z z z z zzz zzz z z o o o o oi 10 c:P (1231130) � o ol 40 o 00 o o oO o o g 40 {P o 30 o 20 � o n o o o o (47/130) o o 30 ; o 10 o o o o oo o o 20 z z z zzz 23 oo � m-l: h:Jo 00 o o o o o 40 Vol. n percent o o (B O o O O QO 0 o � cfJ 3-g�n · �l '-"' -' 0 fJ 80 ex;> 0 c&:Pcf�.-�a 60 feldspor Fig. 12. Mineral composition of olivine-free gneisses. Percentages (by vol.) of dark minerals plotted against vol. per cent feldspar. Fractions (e.g. 91/130) denote number of rocks, out of 130 measured, that contain the mineral in question. Within the pyroxenic streaks, clinopyroxene and orthopyroxene may occur as independent grains. Sometimes, however, the orthopyroxene occurs as granules margining clusters of clinopyroxene crystals. A remarkable texture of clinopyroxene aften observed may be called festoon texture (Fig. 13). This consists of rings of tiny dactylitic clinopyro xene granules surrounding areas (like lagoons) of clear plagioclase feldspar, while outside the rings a mosaic of plagioclase and orthoclase occurs, or plagioclase and mesoperthite coexist. Often the dactylitic pyroxene forms what might be called a barrier reef around islands of pyroxene, the lagoon represented by plagioclase and the ocean by a mosaic of plagioclase and 24 M. H. BATTEY & W. D. McRITCHIE orthoclase. The granules are so small that optical determination is difficult, but sometimes they are seen in near-continuity with identifiable clinopyro xene, and Griffin (1971b) has analysed some by microprobe and determined them as clinopyroxene. Ore forms amoeboid blots always closely associated with pyroxene clusters, generally around their borders. Biotite is, in turn, often moulded upon ore, though it also occurs inde pendently. Garnet, when present, forms narrow pellicles around ore grains in dose association with biotite. The feldspar grains are invariably anhedral and equant. When plagioclase and mesoperthite or plagioclase and orthoclase are present together, the mesoperthite or orthoclase sometimes seems to shun the pyroxene spindles or folia, being separated from them by zones of plagioclase alone. l mm. Fig. 13. Festoon texture in pyroxene-feldspar gneiss. Clinopyroxene (stippled), ore (black), plagioclase (blank) and mesoperthite (wavy lines). Section JS 23, 1100 m on 7° from Skauthøe, and 50 cm from a l m thick pyroxenite sheet. PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 25 In the plagioclase-orthoclase mosaic, viewed microscopically with re stricted illumination, the orthoclase appears as lanes and angular cuspate embayments amongst plagioclase crystals, like leads of open water in dispers ing pack ice. The larger porphyroblasts of mesoperthite are commonly found in the centres of the feldspathic lanes or folia between the pyroxene trains. They are anhedral and generally oval in shape. Apatite and zircon, when present, are found in the feldspathic !anes and folia. DETAILED MINERALOGY OF THE PYROXENE-FELDSPAR GNEISSES Pyroxenes Tables 5, 7 and 8 present data on the composition of pyroxenes from ultra mafic and feldspathic rocks of the Jotun-kindred. Both ortho- and clino pyroxenes are commonly clouded by minute particles of opaque exsolved minerals. The bulk analyses thus represent an original pyroxene composition before this exsolution took place. In Fig. 14 coexisting orthopyroxene-clinopyroxene pairs from the whole rock series are plotted together. The small difference, shown in this figure, between wet-chemical and microprobe values of CaO has already been men tioned. The trend of iron-enrichment shown by the pyroxenes correlates with in creasing feldspar content, increasing Si� and increasing FeOjFeO + MgO in the whole rock composition. Though it covers only a short range of iron enrichment, this trend is consistent with differentiation by fractional crystal lisation. On the basis of the CaO contents determined by rnicroprobe (on the right hand section of Fig. 14) a wider solvus is indicated than that given by bulk compositions of pyroxene pairs in plutonic igneous rocks (e.g. Wager & Brown 1968: fig. 214, p. 391). This suggests that the Jotunheim pyroxenes equilibrated at low temperatures during metamorphism, to compositions comparable with those resulting from exsolution in plutonic pyroxenes de scribed by Boyd & Brown (1969: 86). The implied temperatures are a little lower than those of Boyd & Brown's examples from the Bushveld Complex. The AW3 contents of both pyroxenes are high and the high content of CaAklSi06 and low NaAlS�06 place them clearly in the granulite facies (White 1964). The Ab03 content of the orthopyroxene appears to increase with increasing feldspar content of the rock, with the exception of specimen 62/43. This tendency is not shown, however, in the clinopyroxene. In the special texture, described above, in which festoons of fine-granular pyroxene encircle folia of coarser pyroxene, Griffin (1971b) has shown that the festoon pyroxenes have lower AW3 than the islands of pyroxene within. He attributes this to a partial recrystallisation of the rock after a drop in pressure from the conditions of deep seated metamorphism.The symplectitic 26 M. H. BAITEY & W. D. McRITCHIE Co· existing pyroxenes. Jotunheimen 50 /l 40 /lo cJ Mg 2 3 45 lO Atoms% 20 Fe+Mn- Mg 14 10 Atoms% 'J {'\'\ 40 50 Fe- Fig. 14. Compositions of co-existing pyroxenes, Jotunheimen. Key to rock specimens: 1, 63/M6b (Table 5 no. 2 & 7 no. 1) - 2, 62/43 (5 no. 3 & 7 no. 2) - 3, 62/40 (5 no. 6 & 7 no. 3) - 4, 62/53 (5 no. 8 & 7 no. 4) - 5, 62/36 (5 no. 9 & 7 no. 5) - 6, J34* (8 no. 10) - 7, J33* (8 no. 8 & 5 no. 5) - 8, J20 (8 no. 7) - 9, 62/53 (8 no. 9) - 10, 58/24 (8 no. 4) - 11, 58/38 (8 no. 6) - 12, 58/23 (8 no. 3) - 13, 58/26 (8 no. 5) - 14, 58/21 (8 no. 2) - 15, 58/20 (8 no. 1). * co-existing olivine measured by X-ray. character of the fine-granular pyroxene suggests to him rapid reaction follow ed by chilling in a shallower environment. It may be observed, however, that the plagioclase within the festoons, also presumably a product of the reac tion, is not conspicuously fine-grained. While it seems to the present writers very doubtful whether the proportions of plagioclase and symplectitic pyro xene in the festoons are appropriate to a simple breakdown reaction of the earlier pyroxene, the lower AbOs of the symplectitic pyroxene must be ac cepted as indicating a lower pressure regime during its crystallisation. The partition coefficient for magnesium and ferrous iron between coexisting pyroxenes has been used by Kretz (1961, 1963) and Bartholome (1961) as an index of PT conditions of crystallisation and to discriminate between igneous and metamorphic pyroxenes. Kretz (1963) finds values of his distri bution function Kn of 0.86 to 0.65 for igneous rocks and 0.65 to 0.51 in metamorphics. Fig. 15 shows the values for coexisting pyroxenes from Jotunheimen which, on this basis, have equilibrated under metamorphic conditions. It has been noted above that the pyroxenes show clouding which is attributed to exsolution of Fe, Ti and Mn. When the function �Kn is cal culated, using (Fe2+ + Fe3+ + Mn) in place of Fe2+, its value is greater in most cases than Kn and lies close to the curve of Kn 0.73 in Fig. 19. It may be concluded that original crystallisation probably took place under igneous conditions, with subsequent re-equilibration under a metamorphic regime. = PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 27 The evidence of the pyroxenes, therefore, suggests a primary segregation by fractional crystallisation. If the rocks were differentiated by other means (e.g. if they were originally sedimentary), it is difficult to see why the ratio FejFe + Mg should increase with feldspar and Si0-2 content. This differ entiation was followed by recrystallisation under stress, to produce the meta morphic textures. Equilibration during this process led to a more complete segregation of Ca into clinopyroxene than has occurred in the bulk clino pyroxene fraction of annealed, igneous-textured plutonic bodies. The di stribution of magnesium and ferrous iron between coexisting pyroxenes, and their high AW3 content will have been established (or preserved) in the phase of high pressure recrystallisation. Symplectitic, low Al20a, festoon pyroxene is then believed by Griffin to have formed during partial recrystal lisation at lower pressure. 1·0 0·9 Q) c: Q) )( o ... >.. Q. o .J::. ... o i"" 0·8 Q) I.L. + Cl � Cl � 0·7 0·6 Mg/(Mg + Fe2+) clinopyroxene Fig. 15. Distribution of Mg and Fe between co-existing pyroxenes (after Kretz 1963). M. H. BATTEY & W. D. McRITCHIE 28 Feldspars Optical study of the gneisses shows that, broadly speaking, the anorthite content of the plagioclase decreases with increase in feldspar content, and that rocks with potash feldspar in addition to plagioclase have more sodic plagioclase than those from which potash feldspar is absent. Detailed optical study of the plagioclase seemed likely to be inconclusive, however, because shadowy extinction is common, whether due to strain or compositional change. The former is often to be suspected, but there is also a suggestion that plagioclase is more calcic near pyroxene clusters than in the feldspathic lanes and folia. In rocks with corona structures around the pyro xene clusters it seems clear that equilibrium has not been attained. The variation in plagioclase composition would in these circumstances, probably be progressive and would be best studied by microprobe as part of a study of the corona reaction. The frequent occurrence of mesoperthite or antiperthite and the intimate mosaic of plagioclase and potash feldspar prevents separation of represen tative feldspar for bulk chemical analysis. From the point of view of petrogenesis, the structural state of the average feldspars of the rocks should indicate temperature limits within which other reactions have taken place, and information on this was sought be X-ray powder methods. The feldspars were separated from a sample of 8 gneisses, and the bulk feldspar separated further into a light and a heavy fraction, representing potash feldspar and plagioclase respectively. The parameters d201 and axial obliquity from the 130 and 131 reflexions (MacKenzie 1954) were determined for the potash feldspar and the functions r and B (Smith & Gay 1958) for the plagioclase, by X-ray diffractometer. The results are given in Table 10. Table 10. K feldspar Rock 58/20 58/21 58/23 58/24 28 201 Obliquity Cu Ka. from 130 from 131 20.97 21.02 20.99 20.99 Nil Nil Nil Nil 58/26 None present 58/38 64/2 62/120 None present 20.97 Nil 20.97 ?** * Nil Nil Nil Nil Nil Nil Plagioclase 2Vx r B 45 ( 7) 44!(16) 42 (12) 0.46 0.50 0.65 0.54 0.55 0.54 0.54 0.10 0.36 0.88 0.91 0.89 0.86 0.90 0.86* 0.90 0.96 0.91 { % An (ext. angles) Ana6 Ana5-37 An50-58 An43-45 An4s An50 Value obtained before biotite and doubtless some calcic feldspar were sunk out of the sample in heavy liquid. ** A slight shoulder on the high angle side of the peak. PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 29 The potash feldspar proves to be free of any sodium component with d101 = 0.423 nm (Bowen & Tuttle with no splitting of 130 or 131 1950) and is monoclinic in symmetry reflexions. Measurement of 2V gives varying results partly because of the low birefringence and partly because of undu lose extinction. The range of values (Table 10) indicates compositions of Orso to Or10o with a mean of Or9i�· The values agree with those reported by Heier ( 196 1: 133 and fig. 3a) for granulite facies rocks. The absence of any obliquity in feldspar of this composition indicates crystallisation at a tem perature above 500°C (MacKenzie & Smith 1961). For the plagioclase, an approximate idea of the An content can be ob tained from extinction angles (Table 10) . The measured values of r and B may then be plotted on the diagrams of Smith & Gay where they (1958) fall in the region occupied by plutonic and metamorphic plagioclases. The structural state indicated is one of relatively high cation ordering, though somewhat less than complete order. Perhaps no doser approach to the fully ordered state can be expected above the orthoclase-microcline inversion. THE PROBLEM OF MESOPERTHITIC INTERGROWTHS The distinguishing features of mesoperthite are that the plagioclase com ponent is not albitic, as in ordinary perthite, but is an intermediate or acid intermediate plagioclase; and that the plagioclase and orthoclase components of the intergrowth are roughly equal in volume. The coexistence of plagioclase of intermediate anorthite content with potassium feldspar places a strict lower limit on the temperature of meta morphism, if the two feldspars are in equilibrium (Morse (1967) 1968). De Waard uses the presence of mesoperthite as an indicator of the minimum temperature of granulite facies metamorphism, on the assumption that the mesoperthite represents exsolution of originally homogeneous feldspar. Table 11 gives the modal and normative feldspar compositions of some gneisses in which modal feldspar is over 80 vol. per cent. Allowance has been made for the presence of biotite in calculating the normative feldspar. The results are plotted in Fig. 16 along with the normative feldspar for other rocks in which the rather small biotite correction has been neglected. From Fig. 16 it may be seen that the total feldspar is comparable with, though more calcic than, the Kiglapait mesoperthite studied by Morse (1968), and would yield a mean solvus, projected from anorthite, similar to the Kiglapait example. This does not, however, constitute evidence that the Jotunheim feldspar was originally a single homogeneous phase, and we have to turn to textural evidence (as indeed Morse does in the Kiglapait example) to try to decide this question. Though the textural relations are complicated and variable, the following statements apply to many examples. In the more mafic rocks, plagioclase is the sole feldspar, or is over whelmingly predominant. In some examples the crystals may contain thin 2.77 2.76 2.73 2.72 2.70 2.79 2.72 62/56 62162 62/27 62130 62/35 62/41 62/49 69.9 48.8 56.7 45.2 91.0 50.3 71.8 Or.+ perth. Analyst: W. D. McRitchie. S.G. Rock 17.8 35.7 27.9 45.6 0.5 34.3 18.9 87.7 84.5 84.6 90.8 91.5 84.6 90.7 Modes (vol. %) Plag. Tot.fsp. 8.1 3.4 2.2 0.5 2.1 1.5 0.9 Cpx. - 6.4 11.6 3.4 O.l 4.3 - Bio. Table 11. Feldspar compositions from whole rock chemical analyses. 81.4 79.5 80.1 86.8 86.4 71.5 85.7 Mod.fsp. (wt. %) 24.4 24.5 26.1 19.9 27.2 15.7 21.1 Or 35.6 35.6 38.8 45.6 44.5 39.5 44.0 Ab 17.5 20.6 20.3 17.8 13.3 22.2 20.3 An 77.5 80.7 85.2 83.3 85.0 77.4 85.4 � Norm. feldspar (wt. %) 33 37 34 28 23 36 32 An % Plag 31.5 30.4 30.6 23.9 32.0 20.3 24.7 45.9 44.1 45.5 54.7 52.4 51.0 5 1.5 22.6 25.5 23.8 21.4 15.6 28.7 23.8 Norm. fsp. to 100 An Ab Or æ g � � � n � ....:: fi:o � l:l:l ;z: � w o PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 31 An l • l • <50 wt.0/0 norm. feidspor o 50-80 .. 6. >80 .Å >80vol (o-75 wt) '}o feldspar corr'd for biotite • l .o l . o o o • L Op C?o r: 0: C,.OJ �P o pi:;)Op l 0 0 p oP 0oP ,A; P p �f:€P .1Ji. P .Åp p OP ..t.P ,AP P_� ��p p '62/35 p LI .Å Fig. 16. Normative feldspar components of Jotun rocks. p indicates conspicuously perthitic feldspar. The boundary of the equilibrium feldspar field and the line of the low-melting trough (after Kleeman 1965) are also shown. parallel antiperthitic lamellae, indicating unusually high solubility of potas sium in intermediate plagioclase: A large dass of more feldspathic gneisses has both orthoclase and plagioclase. In these, the common relationship is an even-grained mosaic of the two feldspars in independent crystals (Fig. 17). In the mosaic some plagioclase crystals may have sparse orthoclase lamellae, while the orthoclase may sometimes contain small blocks or shreds of plagio clase. The plagioclase in orthoclase has the appearance of relics left after a process of replacement by orthoclase. Large, shapeless, indefinitely-bounded crystals of mesoperthite Iie in the centres of the feldspathic lanes or layers of feldspar mosaic (Fig. 18). The two components of the mesoperthite may be intergrown in several ways. Some crystals are divided into wavy, but broadly parallel lamellae of the two feldspars (Fig. 19); others have two sets of orthoclase lamellae approximately at right angles, following (010) and (001) (Fig. 20); and others again have a more irregular intergrowth in which the components form lobate masses, rounded masses or curving streaks, rather than regular lamellae (Figs. 27). 21, 22, These different textures may coexist in the same rock. The boundaries 32 Fig. M. H. BATI'EY & W. D. McRITCHIE 17. Jotunite, 58/40, Breagrovein, Spiterstulen. Plagioclase-orthoclase mosaic between pyroxene grains (dark). Plane polarised light with restricted illumination. Scale bar Fig. = l mm. 18. Jotunite, 58/40, NE ridge of GaldhØpiggen. Mesoperthite intergrowths in centres of feldspar areas merge into plagioclase-orthoclase mosaic. Pyroxene is sur rounded by plagioclase only. Plane polarised light. Scale bar = l mm. PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 33 Fig. 19. Jotunite, 58/30, Breagrovein, Spiterstulen. Mesoperthite crystal with parallel lamellae of orthoclase in plagioclase. Crossed polars. Scale bar 0.5 mm. = Fig. 20. Jotunite, 58/49, ridge crest 3.5 km E of GaldhØpiggen. Mesoperthite crystal with orthoclase lamellae intersecting at right angles. Section approximately normal to u of host plagioclase (about An35). Crossed polars. Scale bar 0.5 mm. = 34 M. H. BATTEY & W. D. McRITCHIE Fig. 21. Jotunite, 58/71, Skautflye, NE of Leirtjern. Mesoperthite with irregular blebs of orthoclase, as well as regular lamellae. Section normal to 010 of host. Crossed polars. Scale bar = 0. 5 mm. of the intergrown crystals are vague, the orthoclase component passing out into the surrounding mosaic (Fig. 23). Moreover, in the same rocks there may be zones of plagioclase against the pyroxene clusters that are free of mosaic or intergrown orthoclase (Fig. 18). Such orthoclase-free plagioclase may also Iie inside the festoons of pyroxene granules already described: The rocks called mesoperthosites by McRitchie (1965) have mesoperthite porphyroblasts from 3 mm to 30 mm in length. They develop in streams, parallel to the main foliation of the rocks, the units · varying from a few centimetres to metres in thickness. The coarser meso perthosites are lilac-pink in colour and the fractured crystals show schiller lustre. Some mesoperthosite layers, that carry quartz as well as mesoperthite, occur near the contacts of ultramafic layers with feldspathic gneisses. Other mesoperthosites form discordant lenses and some show intrusive relations, extending amongst broken-up fragments of pyroxenic gneisses to produce agmatite. Examples of this are seen on the south end of Langeskavlen. Cata clastic margins are characteristic of the large mesoperthite crystals of the mesoperthosites. From these features the following deductions may be made: The general porphyroblastic habit of the mesoperthites seems to imply the growth of large crystals of a temary feldspar followed by unrnixing; for it is unlikely that large plagioclases grew in the centres of feldspathic lanes and were then preferentially replaced by orthoclase in lamellar fashion while PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 35 the finer-grained material formed a mosaic of independent crystals; the presence of crystals with two sets of lamellae at right angles, and irregular lobate intergrowths suggests the cooperation of a process of replacement and migration of potash feldspar in producing the present textures. The same conclusion is suggested by the plagioclase relict blocks in orthoclase. The discordant mesoperthosite lenses and veins indicate a degree of partial melt ing of the feldspathic component of the gneiss after the main layering had formed, but under depth and temperature conditions that would yield a temary feldspar. The plagioclase-orthoclase mosaic presumably represents the products of complete unmixing and recrystallisation of the original temary feldspar of which the large mesoperthite crystals are relics. In any attempt to estimate temperature of crystallisation of these temary feldspars the anorthite content is critical, because the solvus crest rises rapidly with increasing anorthite. The use of normative bulk feldspar composition of rocks will lead to erroneous results because of the presence within the folia of regions with plagioclase alone, which may have formed independently of the original temary feldspar. Of the samples plotted in Fig. 16, 62f35, a mesoperthosite, is likely to be most nearly representative of the temary feid spar, and it is one of the least calcic examples. Future work should concen trate on analysing regularly-lamellated mesoperthite crystals only, perhaps with a defocused electron microprobe. The probability is, however, that the mesoperthite crystallised at a tem perature of the order of 900°C and the environment must have been exceed ingly deficient in water to permit solidification at this temperature. Fig. 22. Jotunite, 58/40, NE ridge of GaldhØpiggen. Irregular orthoclase lamellae in outer zone of a plagioclase crystal. Crossed polars. Scale bar 0.5 mm. = 36 M. H. BATIEY & W. D. McRITCHlE Fig. 23. The same crystal as in Fig. 20, showing merging of lamellae with surrounding plagioclase-orthoclase mosaic (cf. also Fig. 18). Plane polarised light. Scale bar = 0.5 mm. BULK COMPOSITIONS OF THE ROCKS The rocks of central Jotunheim are highly differentiated; yet, as the fore going account shows, they possess a close mineralogical and textural affinity. Available for study we have 60 new analyses of rocks from the relatively restricted area defined above (A selection of analyses typical of the various petrographic types is presented in Table 12. The full analytical data is avail able on request from M. H. Battey). Dietrichson (1958) assembled 18 anal yses from a much wider region of rocks assigned to the Jotun kindred, but this collection lacked the close spatial, textural and probable genetic homo geneity of the set presented here. MAJOR ELEMENT VARIATION The variation diagram (Fig. 24), shows a scattered distribution of the major eletnent oxides in rocks with less than about 53 wt. per cent Si02, attribut able to large concentrations of pyroxene, olivine and sometimes hornblende. There is a small overlap in Si02 content between this group and the series beginning at about 50 wt. per cent Si02 and extending to 64 per cent Si02 in which CaO, MgO and total iron (as Fe20a) decline, while Na20 and K20 increase, in the manner typical of igneous rock series. A third group with PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 37 Table 12. Chemical analyses of typical Jotunheim rocks. 133 137 199 58126 62120 58/20 62/18 62135 58/50A 62121 38.70 44.0 51.1 48.00 52.64 56.35 58.80 60.4 63.42 68. 8 Al20a 3.88 2.1 4. 3 14.83 18.73 17.02 19.01 19.0 17.28 15.2 Fe20a 1.88 1.40 2.19 6.49 5.46 3.20 2.85 1.9 2.39 0.57 6.55 6.13 4.17 4.77 2.78 2.3 2.06 0.44 Si02 FeO 19.1 12.60 MgO 31.38 29.0 14.57 6.94 2.77 3.11 1.52 2.2 1.28 0.30 CaO 2.48 8.12 18.34 11.44 9.16 6.54 4.38 3.0 3.73 1.30 Na20 0.44 0.24 1.03 2.90 4.90 4.19 4.51 5.25 4.61 3.95 K20 0.26 0.03 0.10 0.80 0.92 3.28 5.69 4.63 4.32 9.05 H20+ 0.58 1.83 0.38 0.25 0.24 0.59 0.15 0.13 0.22 0.11 Ti02 0.47 0.27 0.55 0.94 0.78 0.60 0.75 0.50 0.40 0.10 MnO 0.32 0.27 0.21 0.18 0.18 0.15 0.10 0.12 0.12 0.02 P205 0.10 Sum 99.59 0.30 99.8 99.3 0.6 98.90 99.95 4.7 5.4 100.54 99.7 19.4 33.6 27.4 99.80 99.8 99.83 CIPW Norms 2.3 1.5 Q 1.5 0.2 ab 2.7 2.0 8.7 24.5 41.4 35.4 38.1 44.4 39.0 an 7.8 4.6 6.8 25.1 26.4 18.0 14.8 13.1 13.7 ne 0.5 di hy C 0.5 0.9 di 2. 9 3.4 1.9 1.3 wo 1.2 0.8 en 1.1 10.5 25.2 9.5 5.5 fs 0.4 3.2 6.7 2.6 1.8 en 6.3 4.1 2.1 1.4 4.3 1.6 5.5 1.9 fs 1.9 1.1 0.6 0.4 3.0 0.7 2.1 0.8 6.0 0.6 fo 54.0 38.8 4.9 4.0 fa 25.4 13.1 1.4 1.2 mt 2.7 2.0 3. 2 9.4 7.9 4.6 4.1 2.8 3.5 il 0.9 0.5 1.0 1. 8 1.5 1.1 1.4 1.0 0.8 ol 1.6 ns 2.4 35.1 7.9 27.8 ac 2.0 14.9 13.2 54.5 2. 9 1.6 wo 13.1 10.6 25. 5 or 0.2 O.l 0. 2 0.7 ap 133 Hornblende-harzburgite, E. side of Visdalen, N.N.E. of Spiterstulen. 137 Wehrlite, slightly serpentinised, same locality. 199 Pyroxenite (fine-grained), at ultramafic margin, same locality. 58126 Pyroxene-gneiss, Presten ridge, Leirvassbu. 62/20 Jotunite, head of tarn in Øvre MjØlkedalen, S.E. of Storegut. 58/20 Jotunite, E. flank MjØlkedalstind, 400 m E. of ultramafic body. 62/18 Mangerite, head of tarn in Øvre Mjølkedalen, S.E. of Storegut. 62135 Mesoperthosite, W. face of HØgbrothØgdi. 58/50A Pyroxene-granite, E. end of ridge from GaldhØpiggen to Spiterstulen. 62121 Pyroxene-granite, W. side of Øvre MjØlkedalen corrie. Analysts: M. H. Battey, W. D. McRitchie, P. J. Oakley. over 67 wt. per cent Si02 shows a scattering of Na20, K20 and Al20a values due to variation in the content of plagioclase and potash feldspar and the entry of quartz. This third group represents quartz-feldspar layers of limited extent. The break between it and the preceding group may be exaggerated by incomplete sampling, but field observation suggests that quartzose members of the series are relatively rare. M. H. BATTEY & W. D. McRITCHIE 38 l) 20 • • o • o •o o o• • • e o 0 8 o o oO 0 cPO AI203 • • • • • • 10 .. V " V �" V 20 V "" 6 ,. "'" " .. • Fe2 03 " Uotall .. • "" 10 • "l • • l\)" o •'O • Illl"!� o o o o g o oooo 0 o V l-" " V JO " • •• t. V " .. • " . o 20 .. • • " .. • Wehrlite Harzburgite Pyroxenite Pyroxene -gneiss )alun ile o Man gerite • Pyroxene- granite 0 .. • KEY Mesoperthosite Mg O f-10 • • • • e • "� '21 g 20 8 (}rP cf>Ore 0 • ... Ca O .. " .. .. 10 . " " .. " l • El " t.V • •• !fo • 00 oo - �o q,oo o 00 V 5 • t.Vv .. "" !JB \!i o• o •• • • o • • • .. . .. " " o o CbD:> 5 0 8 0 o � o . .� . . -t. . ..J. .. --- t. Y,L--t..!... .. · . 50 'CP percent • • Na20 o O o 0 • � • K20 o o - - .. Wt • • • • o& • ��" 40 0 ooo0o • Si02 60 70 PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 39 Table 13. Si� Al20:! I 51.5 Il 52.5- 17.553.25 18.25 I 6.12 31.96 28.91 or 18.0 ab an Fe<.!Oa FeO MgO CaO Na20 K20 3.5 6.0 5.0 10.0 3.{}3.5 6.{}6.6 4.{}5.0 9.{}- 2.4510.0 3.15 hy(en di(wo en fs) 8.70 5.00 3.30 1.0 3.8 0.35 0.75 fs) ol(fo fa) mt 2.51 1.00 3.92 2.65 5.10 FRACTIONAL CRYSTALLISATION HYPOTHESIS The most reasonable interpretation of this series of compositions is that they represent a sequence of liquids developed by fractional crystallisation from a parent liquid with about 51 per cent Si02, associated with a group of ac cumulative rocks (pyroxenites and peridotites) produced by segregation of early-formed crystals. The composition of the parent magma, on this inter pretation, would be roughly that given as I in Table 13. Such a composition would precipitate olivine and could give rise to the sequence of rocks observed. The great predominance of intermediate rocks in the observed sequence would be in accord with the operation of such a process. The parent material suggested does not correspond closely to any of the proposed basaltic partial melts of mantle origin. On the other hand, its oxide percentages conform with the maxima of Chayes's (1964) distribution curves for Cenozoic 'basalts' (volcanics with Si02 less than 54 wt. per cent) from the world's circum-oceanic regions, Il in Table 13). The only differences are the lower Si� and somewhat higher alkalis. The suggested parent com position is thus comparable with a widespread eruptible mixture found on the continental side of the great circum-oceanic trenches of the Cenozoic. These lines of evidence lead to the view that the layered metamorphic series of central Jotunheim is of originally igneous origin and the range of composition within it can be ascribed to differentiation by fractional crystal lisation. A special feature of the differentiation is the high soda content of rocks with more than 50 wt. per cent of Si� and the very steep rise in pot ash between 50 and 60 per cent Si02, reflecting the increase in alkali feid spar especially orthoclase. The pervasive distribution of the feldspar, and the fact that it is partly in the form of mesoperthite makes its introduction by a process of partial melting difficult to accept, though it may have been to some extent redistributed by this means. Apparently a high temperature and pressure of original equilibration al lows the intermediate rocks to store K� as a temary feldspar. Important Fig. 24. Major oxide percentages of chemically analysed rocks plotted against silica. 40 M. H. BATTEY & W. D. McRITCHIE local concentrations of K can thus exist in lower crustal rocks, like those of Jotunheimen, to be released for upward migration during later retrograde metamorphism or igneous action. This could represent a staging point in the progressive upward concentration of K in the continental crust disclosed by the work of Lambert & Heier (1968) and others. The role of K in orogenic igneous events is gradually being elucidated (Moore 1959, Jakes & White 1970, Ewart & Bryan 1973) and the existence of K stores emplaced in the deep structure of ancient fold mountain beits may help to explain some features of its distribution. If the hypothesis of crystallisation differentiation is accepted to explain the main compositional features of the massif, the implication is clear that it was originally a plutonic body, since the extreme ultrabasic products and those formed from residual liquids are still associated. Oftedahl (1961), accepting Hamilton's (1960) revival of Daly's old concept of an areal erup tion, has suggested that the massif is the result of an areal eruption taking place on the sea floor. Criteria are lacking to identify such a body with cer tainty, though a distant connexion might be traced between this hypothesis and the imagined events at constructive plate boundaries. Such a model does not seem to be applicable to the Jotunheim, however, and the idea of plutonic emplacement is preferred. The layered arrangement of the rock types, and the persistent zone of ultrabasic layers from Rusteggi to Gravdalen (Battey & McRitchie 1973) suggests an original stratiform plutonic complex. However, the smaller bodies of peridotite and pyroxenite scattered elsewhere throughout the area testify to drastic disruption of any system of gravitational layering that may once have existed. Intense small-scale folding of pyroxene-rich laminae also in dicates that any original layering has been much modified. The distribution of N a� and �20 at the acid end of the series is irregular and indicates segregation of the two alkalis, due probably to the meta morphism. Such segregation does not seriously conflict with the hypothesis of crystallisation differentiation for the series as a whole. DISCUSSION It may be argued that any series of analyses of rocks varying in the propor tion of light to dark minerals will have the basic oxides decreasing as in Fig. 24, and hence an original sedimentary differentiation is not excluded. However, the increase in alkalis, without any depletion in Na20, and the rarity of quartzose representatives contradict the sedimentary hypothesis. Moreover, as shown in discussion of the pyroxenes, the increase of Fe{Fe + Mg with decreasing colour index is a typical igneous feature. One peculiar rock (62{29, Table 12) must, however, be mentioned here, that might be suspected of being sedimentary. This forms a pale-coloured rusty-weathering layer on the south-western slope of Høgbrothøgdi and, PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 41 because of its distinctive colour it is easily visible from the Eidsbugarden Olavsbu track. It consists of a mosaic of millimetre-sized perthite grains with marginal cataclasis, some plagioclase (An10), sutured quartz, pale biotite in centimetre-long parallel streaks and granular sillimanite. Rounded zircons are common, arranged in lines reminiscent of heavy mineral layers in a sediment and associated with leucoxene grains, pyrite is concentrated along the biotite-sillimanite streaks and tiny needles of probable rutile are present. Small amounts of iron sulphide are associated with this layer, which is slightly transgressive to the layering in the rocks above and below. The exact relations of this limited occurrence to the other layers are not clear and would repay further study. It is near the Tyin-Gjende fault-zone and may be some kind of tectonic inclusion or raft. Its occurrence does not seem to war rant wholesale reinterpretation of the other members of the Jotunheim series. The conclusion from the study of the bulk chemical compositions is that the series was originally differentiated by processes in a melt and has, since this prim·ary differentiation, undergone extensive disruption coupled with some remobilisation and segregation of the feldspathic portion. This subsequent metamorphic history has been complex. There has un doubtedly been thorough-going recrystallisation under shearing stress pro ducing strong foliation or lineation. We have clear evidence of the following reactions taking t=Cace during metamorphism: Reaction between olivine and plagioclase to yield orthopyroxene, clinopyro xene and spinel; exsolution of iron from the pyroxenes, especially clino pyroxene; reaction producing hercynite from magnetite; crystallisation of biotite; exsolution of ternary feldspar to produce mesoperthite and plagio clase-orthoclase mosaic; reaction between ore and plagioclase to produce garnet; late amphibolisation of pyroxene, crystallisation of garnet and zoisite, and the segregation of pegmatite veins. More uncertain, but strongly suggested in many thin sections, is a reaction leading to the corrosion and break-up of larger pyroxene crystals into small granules in a sea of feldspar, as an extension of the process shown in Fig. 13. Griffin (1971b) puts this down to the reaction aluminous clinopyroxene -+ plagioclase + Al-poor clinopyroxene a reaction which requires the addition of silica. This may be part of the story. However, examination of a large number of thin sections suggests that pyroxene is being greatly diminished in some rocks, and that alkalis and alumina, as well as silica, may well have been added, as part of a process of metamorphic segregation. The existence of transgressive mesoperthosite bodies shows that late partial melting of feldspar components has occurred, at least locally, in the metamorphic history. Migration of feldspathic material may also have taken place on a more limited scale to help produce the rocks with festooned pyroxenes. The process envisaged is akin to the limited partial fusion suggested by Tuttle & Bowen (1958: 122 ff.) in connection with the advanced metamorphism of sediments. It would undoubtedly assist in the 42 M. H. BATIEY & W. D. McRITCHIE deformation and extreme attenuation of the pyroxene folia and linear trains shown in some of these rocks (see Pl. Ill, fig. 2 of Battey 1965). Such a process would fit reasonably into the cooling scheme discussed below. COMPARISON WITH SEILAND The Seiland gabbro province in Finnmark, north Norway, offers many points of comparison with Jotunheimen. In this region there is an extensive series of layered gabbros with igneous textures associated with two-pyroxene granu lites (gabbro-gneisses) lying to the east in the direction of increasing meta morphic grade (Hooper 1971). On the island of Stjernøy, in the Caledonides of Finnmark, Oosterom (1963) has described two contiguous rock series. The first includes peridoti tes, olivine-melagabbros and layered gabbros which he compares with suc cessions from the Stillwater and Bushveld complexes (1963: 188-199, 271277) and regards as of igneous origin. This group differs from the Jotunheim series in that it has a much more limited range of Si0.2 content (34 to 47 wt. per cent) and in the coexistence of olivine and plagioclase in some of its members. This last feature suggests that the rocks have been metamorphosed under lower pressures than the Jotunheim set (Green & Hibberson 1970). The second series described by Oosterom (p. 199) comprises dominant gabbro-gneisses and amphibolites with hypersthene-plagioclase gneiss, sye nite-gneiss ( mesoperthosite ), various gamet granulites and some calc silicate layers. The rocks of this group have many resemblances to those of Jotunheimen, but ultramafic members are absent on Stjernøy. The range of Si02 content is 45 to 71 per cent. Though most of the mafic rocks could well be of igneous origin, because of the presence of the calc-silicate layers Oosterom (p. 202) is reluctantly constrained to accept the view of Krauskopf (1954) that the gabbro-gneiss group represents the metamorphic product of an immense pile of volcanic ash, with interbedded calcareous sediments. Oosterom emphasises the long and complex metamorphic history of the Stjernøy metamorphic complex, including the gabbro-gneiss group, compared with the group of ultramafics and layered gabbros. It is interesting to note that, in a similar way, in Jotunheimen, there is a gabbro group with relict igneous texture which is peripheral to the much more highly metamorphosed rocks of the central Jotunheim described in this paper (cf. Battey & McRitchie 1973). The chemical and mineralogical features of the Stjernøy metamorphic group and the Jotunheim rocks suggest that they represent tectonically elevated parts of a deep-seated crustal layer that may extend widely below the Scandinavian Caledonides. More basic than estimates of the average continental shield composition (Holland & Lambert 1972), such rocks may form an important element in the make-up of the deep crust in the fold mountain belt. = PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 43 Hooper (1971) dealing briefly with the Seiland two-pyroxene granulites (gabbro-gneisses) south of Oosterom's area suggests that, in their formation, meta-sediments and plutonic mafic rocks have been folded together in a process of intrusion at depth during tectonic movement. Of particular interest, within the Seiland province, is the concentrically zoned, but also layered, ultrabasic intrusion of Reinfjord (Bennett 1971, 1974). This body, about 4 km by 6 km across, intrudes earlier layered gab bros and bears many resemblances to the zoned ultramafic complexes of S.E. Alaska and the Ural Mountains (Taylor 1967). Comparing the relations of the Reinfjord mass and its surrounding gab bros with the Jotunheim rocks, it is not difficult to conceive that, if the Rein fjord body and its envelope were intensely metamorphosed and folded, something very like the Jotunheim complex could be produced. It seems quite likely that these two areas represent the results of similar magmatic events at different crustal levels and with different subsequent metamorphic histories. The hypothesis, presented above, of a simple gravity differentiation as the early stage in Jotunheimen may well be over-simplified; but the heavy metamorphic overprint hampers any attempt to greatly refine the original spatial and temporal relationships. In the Seiland province, where individual bodies can be separately mapped and their time relations worked out, there is still an overall unity of mag matic process that makes it a distinctive plutonic province. If the suggested analogies between that area and Jotunheimen are valid, the gabbroic inva sion into the roots of the Caledonian fold belt was indeed on an immense regional scale. Emphasis is aften placed upon granitic invasion of fold mountain beits. Here, in the Norwegian Caledonides, we see that, at deeper levels, there may also be a massive uprise of basic (and same would say ultrabasic) magma, as well. Summary and conclusions The chemistry of the granulite facies rocks of Jotunheimen suggests that they have formed by fractional crystallisation from a melt. A layered structure is inferred to have developed during this process. The structural disposition of the differentiated rocks indicates extensive internal disruption of the rock units formed by the fractionation, but the fact that the extreme members are still associated with one another indicates a plutonic site of differentiation and the tectonic upthrusting of the differentiated body as a large scale unit. The original fractionation took place under conditions where the plagio clase-olivine assemblage was stable, that is at pressures below 10 kb at temperatures of 1100° to 1200°C. Subsequently, metamorphic reactions at high pressure led to the elimination of this assemblage and to the widening of the solvus between orthopyroxene and Ca-rich clinopyroxene. Original 44 M. H. BATTEY & W. D. McRITCHIE temary feldspar that had crystallised at high pressure exsolved to give either mesoperthite or, on further segregation, a mosaic of intermediate plagio clase of relatively ordered structure with monoclinic potash feldspar. At a later stage, partial melting has permitted local transgressive move ment of feldspathic material and sometimes with agmatitic breakup of the layered structure, and this partial melt also crystallised to yield a temary feldspar that gave rise to mesoperthosite. Fig. 25 illustrates a path through the probable stability fields of critical mineral assemblages that could lead to the observed products. The scheme involves high-pressure fractional crystallisation, followed either by isobaric cooling through the olivine-plagioclase reaction, eliminating this assemblage, or by a rise in pressure, regardless of temperature, to carry the system across the boundary from olivine + plagioclase to spinel + clinopyroxene + pla gioclase. Herzberg (1972) insists that the boundary is parallel to the temper ature axis and that a rise in pressure is essential, but geological evidence (e.g. Gardner & Robins 1974) does not support this and isobaric cooling is con sidered more probable. This is succeeded by a drop in pressure, at more or less constant temperature, leading to local partial melting of feldspar-rich fractions, at temperatures depending upon the water content, within the PT region where mesoperthite would be precipitated on renewed cooling. This accounts for the transgressive mesoperthites. The 9 kb pressure of initial crystallisation shown in Fig. 25 is indicated by the demonstration that the presence of Na and Fe in the system stabilises olivine + plagioclase to higher pressures than forsterite + anorthite (Emslie 1970). Apart from questions of the absolute P and T scales, the scheme outlined is consistent with Griffin's suggestion of a relatively rapid uplift and fall in pressure during the formation of the gneiss complex. In the sequence of events suggested for the Jotunheim in our earlier paper (Battey & McRitchie 1973), the uplift of the granulite facies rocks is regarded as taking place relatively rapidly, during the Caledonian orogeny. The reason for this view is that, had the granulite facies rocks been uplifted in the Precambrian, buried by the Valdres Sparagmite and then participated in the Caledonian movements, they would in all probability have undergone exten sive retrogressive metamorphism. It does not seem possible that granulite facies rocks can survive such a long history in the near-surface zones of an orogenic belt. Moreover, rocks of gabbroic composition peripheral to the granulite facies rocks have been recrystallised in the amphibolite facies. As the Valdres Sparagmite is now believed to be Eocambrian in age, the hypothesis of late, rapid, tectonic uplift of the granulites during the Cale donian orogeny means that the mesoperthite grains of the Valdres Sparagmite were not derived from the jotunites of the granulite facies group, or at least not from the part of them now exposed in the axis of the fold-belt. It seems preferable to abandon this long-held view of the source of the Valdres meso perthite grains rather than to claim a persistence of pyroxene-granulite facies PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 45 40 l 10 --- o\�p --l : 14 :1 1 l �Il (l 3!� l f ; l l l kb Gl 6 l l 2 900 l ll l l l E JO l l Gl - - �-� l l :l 8 \ l km l 1 1/" l/:: l l+ l l l l 20 "O :;) .!! V � o Q. "' ::2 Gl ... 1100 10 1300° c Fig. 25. Possible cooling path of Jotun gneisses. l. Limit of olivine + plagioclase stability, after Emslie (1970). 2. Limit of forsterite + anorthite stability, after Herzberg (1972). 3. 3'. Possible limits of homogeneous temary feldspar, after Morse (1968). K is the experimental solvus crest for Kiglapait mesoperthite. 4. 4' etc. Schematic curves of the solidus minimum for alkali feldspar solid solutions, dry and with increasing H20 content. The short-dashed line is a possible cooling path. rocks at shallow depth throughout the lang run-up to the Caledonian oro geny. Briefly, in order to preserve the central Jotunheimen rocks in their won derfully fresh condition, it seems necessary to keep them at depth as lang as possible and to conceive of most of their extensive deformation as having taken place at pressures greater than 4 kb - that is, at a depth of 12 km or more. In an earlier stage, pressures must have exceeded 8 kb. 46 M. H. BATIEY & W. D. McRITCHIE The work on which this paper is based has been supported by grants from the Geology Department, University of Newcastle upon Tyne, the Royal Society of London, Norges Almenvitenskapelige Forskningsråd and Norges Geologisk Undersøkelse. McRitchie's work was carried out during tenure of a Research Student ship of the United Kingdom Department of Scientific & lndustrial Research. To all these organisations the authors express their grateful thanks. Mr. P. Oakley has carried out some of the chemical analyses. To Mr. Ulrik Lunn the authors extend their thanks for his pleasant companionship in the field and for two excellent photographs used as illustrations. October 1973 Acknowledgments. - APPENDIX Scheme of rock classification Main Granulite Facies Stem Leucocratic types Clinopyroxene dominant Orthopyroxene dominant l DUNITE (>90% olivine) l Without feldspar L HERZOLITE HARZ BURGITE WE HRLITE (>5% olivine) PYROXENITE C< 5% olivine) Plagioclase 90% of feldspar Plagioclase + orthoclase Quartz < 10% PYROXENE-GNEISS Plag. > Orthoclase (incl. mesoperthite) JOTUNITE Orthoclase > Plag. (incl. mesoperthite) MANGERITE MESO PERTHO SITE PYROXENE-GRANITE Plagioclase + orthoclase Quartz > 10% ANORT HO SITE (>50% An in plagioclase) HYPER ST HENE GRANITE VALLE VARITE PETROLOGY OF PYROXENE-GRANULITE FACIES ROCKS 47 REFERENCES Bartholome, P. 1961: Coexisting pyroxenes in igneous and metamorphic rocks. Geol. Mag. 98, 346-348. Battey, M. 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