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Oxidation Numbers
HV2O4-

V6+
Is the above equation oxidation or reduction?
Oxidation numbers are used to quickly determine if
oxidation or reduction has occurred in a redox reaction.
Rules for Oxidation Numbers
1.
All elements are zero:
Oxidation #
Rules for Oxidation Numbers
1.
All elements are zero:
N2
Oxidation #
Rules for Oxidation Numbers
1.
Oxidation #
All elements are zero:
N2
0
Rules for Oxidation Numbers
1.
Oxidation #
All elements are zero:
N2
Pb
0
Rules for Oxidation Numbers
1.
Oxidation #
All elements are zero:
N2
0
Pb
0
Rules for Oxidation Numbers
1.
Oxidation #
All elements are zero:
N2
0
Pb
0
Na
Rules for Oxidation Numbers
1.
Oxidation #
All elements are zero:
N2
0
Pb
0
Na
0
Rules for Oxidation Numbers
1.
Oxidation #
All elements are zero:
N2
0
Pb
0
Na
0
O2
Rules for Oxidation Numbers
1.
Oxidation #
All elements are zero:
N2
0
Pb
0
Na
0
O2
0
Rules for Oxidation Numbers
2.
Ions are their charge
Na+
Oxidation #
Rules for Oxidation Numbers
2.
Oxidation #
Ions are their charge
Na+
+1
Rules for Oxidation Numbers
2.
Oxidation #
Ions are their charge
Na+
Br-
+1
Rules for Oxidation Numbers
2.
Oxidation #
Ions are their charge
Na+
+1
Br-
-1
Rules for Oxidation Numbers
2.
Oxidation #
Ions are their charge
Na+
+1
Br-
-1
MgSO4
Rules for Oxidation Numbers
2.
Oxidation #
Ions are their charge
Na+
+1
Br-
-1
MgSO4
+2
Rules for Oxidation Numbers
2.
Oxidation #
Ions are their charge
Na+
+1
Br-
-1
MgSO4
+2
Al2O3
Rules for Oxidation Numbers
2.
Oxidation #
Ions are their charge
Na+
+1
Br-
-1
MgSO4
+2
Al2O3
-2
Rules for Oxidation Numbers
3.
The oxidation number of O
in a compound is –2.
Na2O
Oxidation #
Rules for Oxidation Numbers
3.
Oxidation #
The oxidation number of O
in a compound is –2.
Na2O
-2
Rules for Oxidation Numbers
3.
Oxidation #
The oxidation number of O
in a compound is –2.
Na2O
CO2
-2
Rules for Oxidation Numbers
3.
Oxidation #
The oxidation number of O
in a compound is –2.
Na2O
-2
CO2
-2
Rules for Oxidation Numbers
3.
Oxidation #
The oxidation number of O
in a compound is –2.
Na2O
-2
CO2
-2
O2
Rules for Oxidation Numbers
3.
Oxidation #
The oxidation number of O
in a compound is –2.
Na2O
-2
CO2
-2
O2
0
Rules for Oxidation Numbers
3.
Oxidation #
The oxidation number of O
in a compound is –2.
Na2O
-2
CO2
-2
O2
0
CH3COOH
Rules for Oxidation Numbers
3.
Oxidation #
The oxidation number of O
in a compound is –2.
Na2O
-2
CO2
-2
O2
0
CH3COOH
-2
Rules for Oxidation Numbers
3.
Oxidation #
The oxidation number of O
in a compound is –2 or in
peroxides -1.
Na2O
-2
CO2
-2
O2
0
CH3COOH
-2
HOOH
Rules for Oxidation Numbers
3.
Oxidation #
The oxidation number of O
in a compound is –2 or in
peroxides -1.
Na2O
-2
CO2
-2
O2
0
CH3COOH
-2
HOOH exception
-1
Rules for Oxidation Numbers
4.
The oxidation number for H
in a compound is +1.
Oxidation #
Rules for Oxidation Numbers
4.
The oxidation number for H
in a compound is +1.
H2O
Oxidation #
Rules for Oxidation Numbers
4.
Oxidation #
The oxidation number for H
in a compound is +1.
H2O
+1
Rules for Oxidation Numbers
4.
Oxidation #
The oxidation number for H
in a compound is +1
H2O
C12H24O11
+1
Rules for Oxidation Numbers
4.
Oxidation #
The oxidation number for H
in a compound is +1
H2O
+1
C12H24O11
+1
Rules for Oxidation Numbers
4.
Oxidation #
The oxidation number for H
in a compound is +1
H2O
+1
C12H24O11
+1
H2
Rules for Oxidation Numbers
4.
Oxidation #
The oxidation number for H
in a compound is +1
H2O
+1
C12H22O11
+1
H2
0
Rules for Oxidation Numbers
4.
Oxidation #
The oxidation number for H
in a compound is +1 or in
metal hydrides -1.
H2O
+1
C12H24O11
+1
H2
NaH
0
Rules for Oxidation Numbers
4.
Oxidation #
The oxidation number for H
in a compound is +1 or in
metal hydrides -1.
H2O
+1
C12H24O11
+1
H2
NaH
0
-1
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
SO4
2-
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
SO4
2-
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
-2
SO4
2-
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
-2
SO4
Total charge
2-
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
-2
SO4
Total charge
-8
2-
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
-2
SO4
Total charge
2-
-8 = -2
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
-2
SO4
Total charge
2-
+6 -8 = -2
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
+6 -2
SO4
Total charge
2-
+6 -8 = -2
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
+6 -2
SO4
Total charge
+6
2-
+6 -8 = -2
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
PO4
3-
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
PO4
3-
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
-2
PO4
3-
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
-2
PO4
Total charge
3-
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
-2
PO4
Total charge
-8
3-
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
-2
PO4
Total charge
3-
-8 = -3
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
-2
PO4
Total charge
3-
+5 -8 = -3
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
+5 -2
PO4
Total charge
3-
+5 -8 = -3
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
+5 -2
PO4
Total charge
+5
3-
+5 -8 = -3
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
Cr2O7
2-
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
Cr2O7
2-
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
-2
Cr2O7
2-
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
-2
Cr2O7
Total charge
2-
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
-2
Cr2O7
Total charge
-14
2-
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
-2
Cr2O7
Total charge
2-
-14 = -2
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
-2
Cr2O7
Total charge
2-
+12 -14 = -2
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
-2
2-
Divide by 2
Cr2O7
Total charge
+12 -14 = -2
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
+6
-2
Cr2O7
Total charge
2-
+12 -14 = -2
Rules for Oxidation Numbers
5.
All other oxidation numbers are assigned so that the
sum of all of the oxidation numbers is equal to the
charge on the chemical species.
Oxidation #
oxidation #s
+6
-2
Cr2O7
Total charge
+6
2-
+12 -14 = -2
Oxidation #
Ca(NO3)2
Oxidation #
+2
Ca(NO3)2
Oxidation #
+2
Ca(NO3)2
+2
Oxidation #
Na2C2O4
Oxidation #
+1
-2
Na2C2O4
+2
-8 = 0
Oxidation #
+1
-2
Na2C2O4
+2
+6 -8 = 0
Oxidation #
+1 +3 -2
Na2C2O4
+2
+6 -8 = 0
+3
Oxidation #
CH3COOH
Oxidation #
Rewrite
C 2 H4 O2
Oxidation #
Rewrite
+1 -2
C 2 H4 O2
+4 -4 = 0
0
Oxidation #
Zn(OH)42-
Oxidation #
+2 -2 +1
Zn(OH)42+2 -8 +4 = -2
+2
Oxidation #
H2PtCl6
Oxidation #
+1 +4 -1
H2PtCl6
+2 +4 -6 = 0
+4
Oxidation #
Al(NO3)3
Oxidation #
+3 +5 -2
Al(NO3)3
+3 +15 -18 = 0
+5
Oxidation #
H3PO3
Oxidation #
+1 +3 -2
H3PO3
+3 +3 -6 = 0
+3
Oxidation #
Na2O2
Oxidation #
+1 -2
Na2O2
+2 -4 = 0
Exception - does not work, O must be -1
Oxidation #
+1 -1
-1
Na2O2
+2 -2 = 0
Exception - does not work, O must be -1
Oxidation #
CaH2
Oxidation #
+2 +1
CaH2
+2 +2 = 0
Exception - does not work, H must be -1
Oxidation #
+2 -1
-1
CaH2
+2 -2 = 0
Exception - does not work, H must be -1
Oxidation #
Fe(H2O)5(OH)2+
Oxidation #
0
-1
Fe(H2O)5(OH)2+
Water has a charge of 0
OH has a charge of -1
Oxidation #
0
-1
Fe(H2O)5(OH)2+
? + 0
-1
=
+2
Oxidation #
0
-1
Fe(H2O)5(OH)2+
? + 0
-1
=
+3
+2
Oxidation Numbers
HV2O4-

V6+
Is the above equation oxidation or reduction?
Oxidation Numbers
+3
HV2O4-

+6
V6+
Is the above equation oxidation or reduction?
Oxidation Numbers
Increase
+3
HV2O4-

+6
V6+
Is the above equation oxidation or reduction?
If the oxidation number increases it is oxidation.