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Chemistry 2/10/14 “Mystery creates wonder and wonder is the basis of man’s desire to understand.” –Neil Armstrong Do Now: 1. How many chorine atoms are in the following compound?: 4BaCl2 Agenda: 1. Students will be able to balance a chemical equation unassisted by taking notes & working in groups Announcements: Science club is meeting tomorrow after school! Introduction Chemical reactions occur when bonds between the outermost parts of atoms are formed or broken Chemical Equations Their Job: Depict the kind of reactants and products and their relative amounts in a reaction. 4 Al (s) + 3 O2 (g) ---> 2 Al2O3 (s) The numbers in the front are called Coefficients Chemical Equations Because of the principle of the conservation of matter, an equation must be balanced. It must have the same number of atoms of the same kind on both sides. Lavoisier, 1788 Symbols Used in Equations • Solid (s) • Liquid (l) • Gas (g) • Aqueous solution (aq) • + sign (combining) • → ( yields or makes ) • Reactants - left of arrow • Products- right of arrow How molecules are symbolized Cl2 2Cl 2Cl2 • Molecules may also have parenthesis to indicate numbers of atoms. E.g. Ca(OH)2 • Notice that the OH is a group O Ca O H • The 2 refers to both H and O H • How many of each atom are in the following? a) NaOH Na = 1, O = 1, H = 1 b) Ca(OH)2 Ca = 1, O = 2, H = 2 c) 3Ca(OH)2 Ca = 3, O = 6, H = 6 Balancing Equations – When balancing a chemical reaction you may add coefficients in front of the compounds to balance the reaction, but you may not change the subscripts. • Changing the subscripts changes the compound. Subscripts are determined by the valence electrons (charges for ionic or sharing for covalent) Subscripts vs. Coefficients • The subscripts tell you how many atoms of a particular element are in a compound. The coefficient tells you about the quantity, or number, of molecules of the compound. Balancing equations: MgO • The law of conservation of mass states that matter can neither be created or destroyed • Thus, atoms are neither created or destroyed, only rearranged in a chemical reaction • Thus, the number of a particular atom is the same on both sides of a chemical equation • Example: Magnesium + Oxygen • Mg + O2 MgO Mg + O O Mg O • However, this is not balanced • Left: Mg = 1, O = 2 • Right: Mg = 1, O = 1 Balance equations by “inspection” From Mg + O2 MgO 2Mg + O2 2MgO Mg + ½O2 MgO Mg2 + O2 2MgO 4Mg + 2 O2 4MgO is correct is incorrect is incorrect is incorrect Hints: start with elements that occur in one compound on each side. Treat polyatomic ions that repeat as if they were a single entity. a) P4 + 5O2 P4O10 b) 2Li + 2H2O H2 + 2LiOH c) 2Bi(NO3)3 + 3K2S Bi2S3 + 6KNO3 d) C2H6 + 3.5O2 2CO2 + 3H2O 2 C2H6 + 7 O2 4 CO2 + 6 H2O K + H2O H2 + KOH • Reactants • Products •K •K •H •H •O •O Steps to Balancing Equations There are four basic steps to balancing a chemical equation. 1. Write the correct formula for the reactants and the products. DO NOT TRY TO BALANCE IT YET! You must write the correct formulas first. And most importantly, once you write them correctly DO NOT CHANGE THE FORMULAS! 2. Find the number of atoms for each element on the left side. Compare those against the number of the atoms of the same element on the right side. 3. Determine where to place coefficients in front of formulas so that the left side has the same number of atoms as the right side for EACH element in order to balance the equation. 4. Check your answer to see if: – The numbers of atoms on both sides of the equation are now balanced. – The coefficients are in the lowest possible whole number ratios. (reduced) Some Suggestions to Help You Some Helpful Hints for balancing equations: • Take one element at a time, working left to right except for H and O. Save H for next to last, and O until last. • IF everything balances except for O, and there is no way to balance O with a whole number, double all the coefficients and try again. (Because O is diatomic as an element) Balance these skeleton equations: a) b) c) d) e) f) g) h) i) Mg + HCl MgCl2 + H2 Ca + N2 Ca3N2 NH4NO3 N2O + H2O BiCl3 + H2S Bi2S3 + HCl C4H10 + O2 CO2 + H2O O2 + C6H12O6 CO2 + H2O NO2 + H2O HNO3 + NO Cr2(SO4)3+ NaOH Cr(OH)3+ Na2SO4 Al4C3 + H2O CH4 + Al(OH)3 Balance these skeleton equations: a) b) c) d) e) f) g) h) i) Mg + 2HCl MgCl2 + H2 3Ca + N2 Ca3N2 NH4NO3 N2O + 2H2O 2BiCl3 + 3H2S Bi2S3 + 6HCl 2C4H10 + 13O2 8CO2 + 10H2O 6O2 + C6H12O6 6CO2 + 6H2O 3NO2 + H2O 2HNO3 + NO Cr2(SO4)3+ 6NaOH 2Cr(OH)3+ 3Na2SO4 Al4C3 + 12H2O 3CH4 + 4Al(OH)3 a) b) c) d) e) f) g) h) Li + H2O H2 + LiOH P4 + O2 P4O10 C2H6 + O2 CO2 + H2O CS2 + O2 CO2 + SO2 AsCl3 + H2S As2S3 + HCl AgNO3 + FeCl3 AgCl + Fe(NO3)3 KClO3 KCl + O2 SO2 + O2 SO3 a) b) c) d) e) f) g) h) 2Li + 2H2O H2 + 2LiOH P4 + 5O2 P4O10 2C2H6 + 7O2 4CO2 + 6H2O CS2 + 3O2 CO2 + 2SO2 2AsCl3 + 3H2S As2S3 + 6HCl 3AgNO3 + FeCl3 3AgCl + Fe(NO3)3 2KClO3 2KCl + 3O2 2SO2 + O2 2SO3