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Chapter 20 - Water Pollution 03/28/10 WATER POLLUTION ..\Envir. PP\News Articles\Water Drinking\State of Water.htm IN THE EARLY 1800'S, IT WAS NOT UNCOMMON FOR GARBAGE TO BE DUMPED INTO THE NEAREST RIVER OR LAKE. SUCH DUMPING ALONG WITH A COMPLETE LACK OF SANITARY PRACTICES FREQUENTLY LED TO EPIDEMICS OF WATERBORNE DISEASES. BY THE TURN OF THE CENTURY EFFORTS WERE MADE TO CONTROL THESE EPIDEMICS BY FILTERING PUBLIC WATER SUPPLIES. BY 1908, CHLORINE WAS ADDED TO MUNICIPAL WATER BEFORE IT ENTERED THE WATER MAINS. BY THE 1960'S WATERBORNE DISEASES HAD BECOME RELATIVELY RARE IN THE USA. ALTHOUGH THEY STILL PLAGUE MANY LESS DEVELOPED COUNTRIES. ..\Envir. Vids\Water\ABC News Water Everywhere But Not a Drop to Drink.flv INFECTIOUS AGENTS: WATER TRANSMITS DISEASE WHEN IT CONTAIN WATERBORNE PATHOGENS OR DISEASE PRODUCING ORGANISMS. THOSE PATHOGENS, WHICH CAN BE VIRUSES, BACTERIA, PROTOZOA OR PARASITIC WORMS, CAN CAUSE DISEASES AS DYSENTERY, TYPHOID FEVER AND CHOLERA. INFECTION CAN BE SPREAD DIRECTLY AS A RESULT OF DRINKING OR SWIMMING IN CONTAMINATED WATER OR INDIRECTLY AS A RESULT OF EATING FOOD THAT HAS BEEN CONTAMINATED TROUGH FOOD WEBS. DETECTING THE PRESENCE OF SPECIFIC PATHOGENS IS TIME CONSUMING, COSTLY AND A DIFFICULT PROCESS. WATER THEREFORE, IS ANALYZED BY A READILY IDENTIFIABLE GROUP OF MICROORGANISMS CALLED COLIFORM BACTERIA. THESE ORGANISMS ARE NORMALLY PRESENT IN THE INTESTINAL TRACT OF HUMANS AND ANIMALS, LARGE NUMBERS OF COLIFORM BACTERIA IN A WATER SAMPLE INDICATE RECENT CONTAMINATION BY UNTREATED FECES. COLIFORM BACTERIA EXCEEDING 2.2 ORGANISMS PER 100 MILLILITERS OF DRINKING WATER REQUIRE MUNICIPALITY TO EITHER CHLORINATE THE WATER OR SEEK ALTERNATIVE SOURCES OF WATER. RECREATIONAL WATER HAS AN UPPER LIMIT OF 200 COLIFORM BACTERIA PER 100 MILLILITERS OF WATER. CHLORINATION OF PUBLIC WATER SUPPLIES HAS VIRTUALLY ELIMINATED EPIDEMICS OF OFTEN FATAL WATERBORNE DISEASES IN DEVELOPED COUNTRIES AS BIOLOGICAL POLLUTION IN THE FORM OF WATERBORNE DISEASES IN THE DEVELOPED WORLD HAS DIMINISHED, CHEMICAL POLLUTION HAS INCREASED. TODAY OUR WATER RESOURCES ARE BEING ASSAULTED BY SUCH CHEMICALS AS COMMERCIAL FERTILIZERS, PESTICIDES, DETERGENTS, TRACE QUANTITIES OF METALS, ACIDIC MINE WASTE, RADIOACTIVE SUBSTANCES, AND A WIDE VARIETY OF INDUSTRIAL CHEMICALS. TODAY THERE IS GROWING CONCERN THAT CHEMICAL POLLUTANTS IN WATER MAY BE CONTAMINATING OUR FOOD AND DISRUPTING AQUATIC ECOSYSTEMS BY HINDERING THE LIFE CYCLE OF AQUATIC ORGANISMS. MOST WATER-POLLUTION PROBLEMS STEM FROM LANDBASED ACTIVITIES WITHIN DRAINAGE BASINS RATHER THAN FROM WATER BASED ACTIVITIES SUCH AS SHIPPING, BOATING AND SWIMMING. NATURAL POLLUTANTS: NATURAL AREAS, SUCH AS FORESTS, MARSHES, AND GRASSLANDS, GENERALLY CONTRIBUTE SMALL AMOUNTS OF MATERIALS TO WATERWAYS. MANMADE POLLUTANTS: AGRICULTURAL AREAS DEGRADE WATER QUALITY IN SEVERAL WAYS: EXCESSIVE SOIL EROSION WILL INCREASE THE LOAD OF SEDIMENTS. PESTICIDES, FERTILIZERS AND ANIMAL WASTES THAT ARE WASHED FROM FIELDS AND ORCHARDS WILL RUN OFF INTO STREAMS OR SEEP INTO THE GROUNDWATER. POINT AND NONPOINT SOURCES OF POLLUTION POINT SOURCE POLLUTION: A CONCENTRATED SOURCE OF WATER POLLUTION DUE TO A DRAINPIPE FORM A SEWAGE TREATMENT PLANT OR INDUSTRIAL SITE. NON POINT SOURCES: A DIFFUSED SOURCE OF WATER POLLUTION DUE TO AGRICULTURAL APPLICATIONS. NON POINT SOURCES ARE LOW CONCENTRATIONS BUT HIGH VOLUME DISCHARGES. Nonpoint Sediment from Unprotected Farmland Flows into Streams NONPOINT SOURCES Rural homes Cropland Urban streets Animal feedlot Suburban development POINT SOURCES Wastewater treatment plant Factory SEWER SYSTEM DESIGN STORM SEWER: IN CITIES BUILDINGS AND PAVED AREAS RENDER A LARGE PART OF THE URBAN SURFACE IMPERMEABLE TO RAINWATER AND SNOWMELT. TO PREVENT FLOODING LARGE STORM SEWERS PIPES ARE USED TO CHANNEL WATER RUNOFF TO NEAREST RIVER, LAKE OR OCEAN. SANITARY SEWER: A SECOND SMALLER SYSTEM OF SEWERS PIPES CALLED A SANITARY SEWER SYSTEM CARRIES WASTES OR EFFLUENTS, FROM HOMES AND COMMERCIAL AREAS TO TREATMENT PLANTS. IF THESE TWO SEWER SYSTEMS ARE COMBINED INTO ONE SYSTEM THIS TYPE OF SYSTEM IS CALLED A COMBINED SEWER SYSTEM. OXYGEN-DEMANDING WASTES MOST AQUATIC ORGANISMS ACQUIRE THEIR OXYGEN FROM THE SUPPLY THAT IS DISSOLVED IN THE WATER. THE SUPPLY OF AQUATIC OXYGEN CAN QUICKLY DIMINISH WHEN ORGANIC WASTES DECOMPOSE IN THE WATER. OXYGEN IN WATER IS DEPENDENT ON THE PROCESSES THAT ADD OXYGEN - TURBULENCE AND PHOTOSYNTHESIS AND THOSE THAT REMOVE OXYGEN RESPIRATION BY AQUATIC ORGANISM WHEN ORGANIC MATERIALS ARE ADDED TO WATER A PROLIFERATION OF OXYGEN CONSUMING DECOMPOSERS MAINLY BACTERIA AND FUNGI ARE ENCOURAGED. THESE ORGANISMS REDUCE THE OXYGEN SUPPLY AND DEPRIVE OTHER AQUATIC ORGANISM LIKE FISH OF OXYGEN. UNDER NORMAL CONDITIONS THE QUANTITY OF ORGANIC MATERIAL IS SMALL AND THE AMOUNT OF OXYGEN THAT IT UTILIZES IS LIMITED. THE CONCENTRATION OF DISSOLVED OXYGEN REMAINS RELATIVELY CONSTANT AND AT A LEVEL THAT IS HIGHER THAN 5 PPM THIS LEVEL IS USUALLY CONSIDERED TO BE CRITICAL FOR THE SURVIVAL OF MOST FISH. MOST WATER BODIES CAN REMOVE NATURAL ORGANIC WASTES WITHOUT DEPLETING THE DISSOLVED OXYGEN LOWER THAN 5 PPM (LAKE AND RIVERS CAN NATURALLY CLEANSE THEMSELVES). THE AMOUNT OF DISSOLVED OXYGEN THAT IS NEEDED TO DECOMPOSERS TO BREAK DOWN ORGANIC MATERIALS IN A GIVEN VOLUME OF WATER IS CALLED THE BIOCHEMICAL OXYGEN DEMAND (BOD). BOD IS A MEASURE OF THE LEVEL OF ORGANIC CONTAMINATION IN WASTEWATER. SEWAGE-LADEN WASTEWATER THAT ENTERS A SANITARY SEWER SYSTEM HAS AN AVERAGE BOD LEVEL OF 250 PPM, BUT MOST BODIES OF WATER LAKES AND RIVERS ARE INITIALLY LIKELY TO CONTAIN ONLY ABOUT 8 PPM OF OXYGEN. WHEN THIS SEWAGE WASTEWATER IS ADDED TO LAKE OR RIVER WATER, THE LEVELS OF DISSOLVED OXYGEN AT THE DISCHARGE POINT IS QUICKLY DEPLETED BY MICROBIAL ORGANISMS, WHICH BEGIN TO DECOMPOSE THE WASTE. THE DAILY WASTES OF JUST ONE PERSON REQUIRES THE DISSOLVED OXYGEN OF 2200 GALLONS OF WATER IF NO OXYGEN WERE ADDED TO IT. WHEN EFFLUENTS THAT HAVE HIGH LEVEL OF BOD ARE RELEASED INTO A STREAM OXYGEN LEVELS DOWNSTREAM FOLLOW A CHARACTERISTIC PATTERN CALL AN OXYGEN SAG CURVE animations\Water\river_pollution.swf ORGANIC WASTE DISCHARGES HAVE THEIR GREATEST IMPACT ON AQUATIC LIFE DURING WARM SUMMER MONTHS, WHEN THE STREAM FLOW IS LOW AND LESS DISSOLVED OXYGEN IS PRESENT IF A COMPLETE LOSS OF OXYGEN OCCURS IN A BODY OF WATER A CHANGE IN THE TYPE OF DECOMPOSER BACTERIA ALSO OCCUR - FROM AEROBIC DECOMPOSERS (THOSE THAT USE OXYGEN) TO ANAEROBIC DECOMPSERS (THOSE THAT DO NOT NEED OXYGEN). AEROBIC DECOMPOSERS PRODUCE MAINLY CARBON DIOXIDE, WATER, NITRATE AND SULFATE THAT ARE NOT USUALLY HARMFUL. ANAEROBIC DECOMPOSERS PRODUCE METHANE, AMMONIA AND HYDROGEN SULFIDE. UNDER ANAEROBIC CONDITIONS WATER BECOMES A TURBID, DECAYING MESS WITH BUBBLING METHANE AND HYDROGEN SULFIDE. Mississippi River Basin Ohio River Missouri River Mississippi River LOUISIANA Mississippi River Depleted Oxygen Gulf of Mexico Cooperstown NEW YORK PENNSYLVANIA ATLANTIC OCEAN Harrisburg NEW JERSEY MARYLAND Baltimore WEST VIRGINIA Washington DELAWARE Richmond VIRGINIA Drainage basin Norfolk Chesapeake Bay No oxygen Low concentrations of oxygen ..\Envir. Vids\Water\After the Storm-01.mpg CULTURAL EUTROPHICATION IF EXCESSIVE QUANTITIES OF PLANT NUTRIENTS ARE DISCHARGED INTO A LAKE, OCEAN BAY OR RIVER THE NATURAL AGING PROCESSES OF THOSE WATERWAYS ARE ACCELERATED. IF THE ACCELERATION IS FROM HUMAN ACTIVITY THIS PROCESS IS CALLED CULTURAL EUTROPHICATION. CULTURAL EUTHROPHICATION IS ONE OF THE MOST SERIOUS PROBLEMS FACING MANY BODIES OF WATER TODAY. IT JEOPARDIZES THE USE OF WATER FOR DRINKING, RECREATION, SPORTS AND COMMERCIAL FISHING, AGRICULTURE AND INDUSTRY. Discharge of untreated municipal sewage (nitrates and phosphates) Discharge of detergents (phosphates) Discharge of treated municipal sewage (primary and secondary treatment: nitrates and phosphates) Dissolving of nitrogen oxides (from internal combustion engines and furnaces) Natural runoff (nitrates and phosphates) Inorganic fertilizer runoff (nitrates and phosphates) Manure runoff from feedlots (nitrates, phosphates, ammonia) Lake ecosystem nutrient overload and breakdown of chemical cycling Runoff from streets, lawns, and construction lots (nitrates and phosphates) Runoff and erosion (from cultivation, mining, construction, and poor land use LIKE TERRESTRIAL PLANTS, AQUATIC PLANTS REQUIRE NITROGEN, PHOSPHORUS, POTASSIUM AND OTHER MINERALS NUTRIENTS. IN AQUATIC SYSTEMS, THE TWO NUTRIENTS THAT ARE MOST COMMONLY ACT AS LIMITING FACTORS ARE PHOSPHOROUS AND NITROGEN IN THE FORM OF EITHER NITRATE OR AMMONIA. WHEN THESE LEVELS NUTRIENTS INCREASE SOME AQUATIC ORGANISM RESPOND BY INCREASING IN NUMBER AND SIZE. FOR EXAMPLE ALGAE BLOOMS OCCUR WHEN NUTRIENTS ARE EXCESSIVE IN LAKES AND PONDS. TOXIC SUBSTANCES: AQUATIC ORGANISMS ARE AFFECTED BY OXYGEN CONSUMING POLLUTANTS AND ADDED PLANT NUTRIENTS BECAUSE THOSE SUBSTANCE DIRECTLY OR INDIRECTLY ALTER THE AMOUNTS OF OXYGEN AVAILABLE TO THEM. TOXIC SUBSTANCES, IN CONTRAST, AFFECT ORGANISMS ADVERSELY, AND SOMETIMES FATALLY BECAUSE THEY DISRUPT THE METABOLISM OF THE ORGANISMS AS A RESULT OF INGESTION OR CONTACT. OTHER WATER POLLUTANTS OIL POLLUTION: OIL SPILLS KILL MOST OF THE ORGANISMS THAT BECOME COATED WITH OIL AND CAN RESULT IN CONTAMINATED WATER FOR SEVERAL YEARS OR LONGER. SEDIMENT: EROSION-CAUSED SEDIMENTS FILL RESERVOIRS, LAKES, HARBORS AND NAVIGATION CHANNELS. SUSPENDED SEDIMENTS IMPEDE PHOTOSYNTHESIS AND CARRY NUTRIENTS INTO BODIES OF WATER. THERMAL POLLUTION: HEATED WATER DISCHARGES MAY EXCEED THE TEMPERATURE TOLERANCE LIMITS OF MANY AQUATIC ORGANISMS AND THE WITHDRAWAL OF WATER FOR COOLING PURPOSES MAY TRAP AND KILL FISH. Alaska Hawaii Arsenic level (micrograms per liter) > 50 10 - 50 Prevention Cleanup Reduce input of toxic pollutants Improve oil-spill cleanup capabilities Separate sewage and storm lines Require at least secondary treatment of coastal sewage or use wetlands, solaraquatic, or other sewage treatment methods Ban ocean dumping of sludge and hazardous dredged material Protect sensitive areas from development, oil drilling, and oil shipping Regulate coastal development Recycle used oil Require double hulls for oil tankers Require improved air pollution cleanup to reduce input from the atmosphere Solutions: methods for preventing and reducing water pollution. • Prevent groundwater contamination • Greatly reduce nonpoint runoff • Reuse treated wastewater for irrigation • Find substitutes for toxic pollutants • Work with nature to treat sewage • Practice four R's of resource use (Refuse, Reduce, Reuse, Recycle) • Reduce resource waste • Reduce air pollution • Reduce poverty • Reduce birth rates • Not depleting aquifers • Preserving ecological health of aquatic systems • Preserving water quality • Integrated watershed management • Agreements among regions and countries sharing surface water resources • Outside party mediation of water disputes between nations • Marketing of water rights • Wasting less water • Decreasing government subsides for supplying water • Increasing government subsides for reducing water waste • Slowing population growth WATER TREATMENT ..\Envir. Vids\Water\MSNBC Video Kenya Water Disease.flv ..\Envir. Vids\Water\msnbc.com video Drugs in your drinking water.flv ..\Envir. Vids\Water\Nightly News video Concern rises over chemicals in plastic bottles.flv