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Shun Lee Catholic Secondary School Advanced Level – Geography – Landform System Chapter 13 Weathering Sub-system 13.1 Definition Weathering is the breakdown and alternation of materials in situ at or near the earth’s surface. 13.2 The Products of Weathering Regolith / Weathered materials / Soil 13.3 Weathering as a System Weathering can also be considered as an open system. INPUT (a) materials rocks moisture gases OUTPUT 1. regolith PROCESSES (b) energy forces including: insolation pressure 13.4 2. solution 3. gases Types of Weathering Physical Weathering (Mechanical weathering) Chemical Weathering Similarity Difference A separate category of weathering called Biological Weathering (such as the splitting of rocks by tree roots) is arguably contained in the two main types of weathering (physical and chemical weathering). Written by Clement Cheng 1 Chapter 13 The Weathering Subsystem Physical (Mechanical) Weathering a) Insolation Weathering Insolation weathering is caused by the agent sunlight. i) What is the favourable condition of insolation weathering? _____________________________________________________________________ ii) Processes A rise in temperature causes a rock to expand A fall in temperature causes it to contract. Repeated temperature changes may cause a rock to break up. iii) Where can we find insolation weathering frequently? 1. Places with large temperature fluctuations. Which place has frequent insolation weathering? ANSWER: T______________ D________________ 2. The widespread existence of coarse and angular debris. 3. The rock types most likely to be fractured by insolation weathering would seem to be: - _____________-coloured, fine-grained rocks (such as basalt), in which the low albedo ensures maximum absorption of solar energy, and - heterogeneous rocks which comprise minerals with different coefficients of expansion. b) Frost Action 1. 2. 3. 4. Conditions in areas with water supply temperature fluctuates around ____________________, e.g. in the mid-latitudes (in autumn and spring when large temperature ranges exist), high latitudes and high altitudes. rocks with a lot of small fissures or with a lot of pore spaces. absence of vegetation Written by Clement Cheng 2 Shun Lee Catholic Secondary School Advanced Level – Geography – Landform System Processes Frost weathering is that it results from “frost weathering” or “splitting” which occurs when water penetrates joints and bedding planes, undergoes a change from liquid to ice, and thus has the potential to expand by approximately 10% if unconfined by the rigidity of the surrounding rock. Successive frost cycles will widen fissures, and eventually permit large joint-bounded blocks to be detached. c) Salt Crystal Growth Process Step 1: With prolonged evaporation, ground water is drawn up to form a thin film Step 2: Step 3: of water around the soil and rock surface by capillary action. This water carries dissolved mineral salts. As evaporation takes place, the dissolved salt is crystallized and deposited in the openings in the rocks. Salt crystals grow in size and exert forces on the rocks, granular disintegration can result. Location In tropical desert d) Unloading and Spalling (sheeting / dilation) Definition Sheeting is the division of rock into “beds” by joint-like fractures that are generally parallel to the ground surface. Processes Diagrams to Illustrate the above Processes Written by Clement Cheng 3 Chapter 13 The Weathering Subsystem e) Fire f) Alternate Wetting and Drying or Rock g) Biological Effects A) Chemical Weathering i) Definition: Chemical weathering, also known as mineral alteration, is the decomposition of rock as the constituent minerals react and combine with atmospheric substances such as oxygen and carbon dioxide, to form new minerals. ii) End-product of Chemical Weathering These new minerals are called secondary minerals, which are stable in the surface environment. iii) Conditions of Chemical Weathering: 1. presence of joints 2. warm, moist climate iv) Processes a) Oxidation and Reduction Oxidation: Oxidation means a reaction with oxygen to form oxides. Favourable Environment Oxidation of minerals by gaseous oxygen occurs through the intermediate action of _______________ in which the oxygen is first dissolved. Most oxidation takes place in the aerated zone. End-product Red and yellow colours due to presence of iron oxides and hydroxides Reduction: Reduction is the process of dissociating from oxygen. It takes place usually in ______________________sites. This is carried out mainly by bacterial action, e.g. change sulphates to sulphides. It often produces green or grey colours in the soil. Written by Clement Cheng 4 Shun Lee Catholic Secondary School Advanced Level – Geography – Landform System b) Carbonation Definition Carbonation is the process resulting from the combination of various rock minerals with carbon dioxide in solution. Processes As rainwater falls through the atmosphere and percolates through the soil, it combines with carbon dioxide to produce a weak but effective acid known as carbonic acid. Results Karst landscape: Carbonic acid dissolves the calcium carbonate in these rocks to form the salt calcium bicarbonate, which is readily removed in solution. c) Solution What is Solution? It takes place in running water, or in a thin film of water around a solid particle. Mineral is dissolved by the migration of ions from the mineral into a dispersed form in the water. Factors Affecting the Rate of Solution - the amount of water passing the surface of the particle - the solubility of the solid being dissolved, e.g. common salts very soluble - the permeability of the rock - the acidity or alkalinity of the ground water. Where conditions are highly alkaline (pH > 9) some types of silica and alumina (Al2O3) are readily taken into solution. Where conditions are neutral, alumina is insoluble though its solubility will again increase with marked acidity (pH < 4). Significance By carrying ions from one place to another, solutions may lead to more combinations of reactions. Solutions also may precipitate chemicals which can lead to volume changes and enhance physical weathering. Written by Clement Cheng 5 Chapter 13 The Weathering Subsystem d) Hydration Definition In this process, water molecules are loosely absorbed into the mineral structure to produce a new hydrated (water added) form of compound. Results This is a particularly effective destruction process since the absorption and addition of water molecules into the mineral structure leads to an increase in crystal volume of over 80% in some cases. This swelling process results in considerable physical stress on the rock and eventually facilitates exfoliation or granular disintegration. It also prepares surfaces for further alteration by oxidation and carbonation. e) Hydrolysis Definition It is a process in which water and rock minerals completely combine in a true chemical reaction to produce new structure. It takes place whenever a mineral is in contact with water, even distilled water or rainwater. Results The process is very important in initiating the decomposition of feldspar, a constituent of granite, which is broken down by water and is turned into a soft powdery mineral called kaolin, thus causing the solid rock to disintegrate (granular disintegration). In warm humid regions, hydrolysis may be so effective that granite has decay to a depth of 100 m or more. f) Chelation The process occurs because plant roots are surrounded by a concentration of hydrogen ions which can exchange with the cations in adjacent minerals; the metallic cations are then adsorbed into the plant. Through this process, otherwise relatively insoluble elements such as aluminum can be mobilized. v) Types of Chemical Weathering a) Honeycomb Weathering - common in rocks with a heterogeneous structure which contain soluble minerals - Chemical weathering is selective which attacks certain minerals, especially whose are soluble. Chemical decay occurs and pores are leaving on the rock surface. With further reactions, these pores are enlarged, thus leaving as pits or cavities on the rock surface. Written by Clement Cheng 6 Shun Lee Catholic Secondary School Advanced Level – Geography – Landform System b) Spheroidal Weathering - the resulted feature is the rounded corestones - they are common in the well-jointed rocks - the process begins with the gases and rainwater which can penetrate into the joints. Chemical reactions attack the rocks along the joints and makes it to decay - concentric zone of weathered materials formed - further penetration to the deeper layer and gradually turned to rectangular rock into corestones c) Limestone Landscape - limestone is made up of calcium carbonate (CaCO3) and is well-jointed. Thus - water and gases is possible to penetrate into the rock CaCO3 is insoluble in water. When it combines with carbonic acid (H2CO3) by carbonation it forms calcium hydrogen carbonate Ca(HCO3)2 which is highly soluble. The process of solution makes the rock to decay and formed the features such as clints and grikes, underground cavern, shallow holes, etc. Written by Clement Cheng 7 Chapter 13 13.5 The Weathering Subsystem Geometrical Pattern of Physical Weathering In terms of geometry, we can identify at least four different modes of rock breakup. A) Granular Disintegration B) Exfoliation C) Block Disintegration Please check them from your cert. materials. D) Shattering Shattering is the disintegration of rock along new surface of breakage in otherwise massive, strong rock, to produce highly angular pieces with sharp corners and edges. The fractures may cut across mineral grains and other structures in the rock. Label the four patterns of weathering as shown below: Name the three types of landform caused by weathering. Written by Clement Cheng 8 Shun Lee Catholic Secondary School Advanced Level – Geography – Landform System Product of Weathering – Regolith 13.6 Comparison of Regolith between Physical Weathering and Chemical Weathering: Physical Weathering Chemical Weathering Depth of regolith Reason for the depth Texture Angularity Weathering Profile A fully developed regolith will comprise four “weathered zones” in granite by chemical weathering: - Zone I ____________________________________________ - Zone II ____________________________________________ - Zone III ____________________________________________ - Zone IV ____________________________________________ Zone Zone_______ _______ Zone _______ Zone _______ Zone _____ Written by Clement Cheng 9 Chapter 13 13.7 The Weathering Subsystem Factors Affecting Weathering A) Geological Factors 1. Rock Structure Rocks with joints, bedding planes, faults or minute cracks are more subjected to weathering for these act as strong foci for various weathering processes; increase the surface area attacked by chemical processes. 2. Chemical Composition Different rock mineral has different stability, e.g. quartz are most stable; feldspar and olivine are less stable. GENERAL RULE OF THUMB: light-coloured acidic rocks are more resistant to chemical weathering than dark-coloured basic rocks. B) 1. a) 1. 2. Exogenetic Factors Climatic Factors Precipitation Water is important in both mechanical (e.g. frost action) and chemical weathering (e.g. hydrolysis, hydration and solution) processes, and in supporting living organisms for biological weathering. Only the total amount of precipitation is not adequate. Seasonal distribution of precipitation is also important. Another important figure is the precipitation-evaporation ratio. precipitation > evaporation, there is continual movement of solutions and removal of weathered products. evaporation > precipiation, there is periodic upward movement of water, dry out of soil, crystallization of salts and lack of removal of weathered materials. b) Temperature High Temperature Environment -> Chemical Weathering + Biological Weathering Large (Diurnal) Range -> Physical Weathering Range between Freezing Point -> Physical Weathering c) Cloudiness Cloud Cover increases -> physical weathering _________ 2. Duration of Snow Cover Snow blanket reduces frost action and chemical reaction for its low temperature. Besides, it also reduces the rate of soil erosion, therefore lower the rate of weathering. Written by Clement Cheng 10 Shun Lee Catholic Secondary School Advanced Level – Geography – Landform System 3. Thunderstorms It may produce lightning, cracking boulders or starting fires. The sudden fall of cold rain on hot rock surfaces might cause them to break up. 4. - Underground Water Renewal of underground water -> chemical weathering _______ Underground water also affect the location of weathering: Indeed there is a widespread belief that the water-table marks the transition from weathering above to the “non-weathering” below, and that this is an explanation of the basal surface of weathering beneath some deep regoliths. Weathering is certainly more rapid where there is periodic wetting and drying (in the zone of water-table fluctuation), this not only ensures the arrival of “fresh” aggressive groundwater, but allows for the steady leaching of solutes. 5. a) Topographical Factors Relief Gentle Slope Effect on Weathering Chemical Effect on Weathering Physical Steep Slope b) Aspect Example 1: In cold and frosty areas, south-facing slopes will experience more melting and more cycles of freeze and thaw than north-facing slopes. Thus, they experience greater mechanical weathering. Example 2: In cold but not generally frosty areas, south-facing slopes will have more sunshine and more vegetation. So biological and chemical weathering will be greater than on south-facing slopes. Example 3: In temperate areas, south-facing slopes may be too hot at midday and have less vegetation than north-facing slopes. Written by Clement Cheng 11 Chapter 13 6. The Weathering Subsystem Biological Factors a) Vegetation Cover Positive (Accelerating) Effect: 1. The growing of roots exerts pressure to rock and disintegrate it. 2. Vegetation cover provides decaying vegetal matter, which releases organic acids which aid some types of chemical decay. Solution is also enhanced by the CO 2 produced by respiration. 3. Vegetation also affect soil moisture. These effects are partly due to the water-holding effects of root masses and humus, partly by the shade effects of plants. Shade may cut down evaporation, but transpiration may lose water at a greater rate. 4. Bacterial action and the respiration of plant roots tend to raise carbon dioxide levels in the soil atmosphere, and thereby help to accelerate solution processes. Negative Effective: But vegetation cover also reduces the removal of weathering products and decreases the rates of chemical weathering and physical weathering of the underlying rock. Vegetation cover also provides a more stable condition where temperature range is smaller. Therefore the vegetation cover may lead to less total weathering under most circumstances. b) Animals The eating or burrowing of animals cause simple breaking of particle. Animals also transfer and mix materials, move mineral materials into areas of different weathering effects. c) How about the Role of Man? (Try to list out the factors yourself) Written by Clement Cheng 12