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TORTORA FUNKE CASE ninth edition MICROBIOLOGY an introduction 2 Part A Chemical Principles PowerPoint® Lecture Slide Presentation prepared by Christine L. Case Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings Chemistry Chemistry is the study of interactions between atoms and molecules. The atom is the smallest unit of matter that enters into chemical reactions. Atoms interact to form molecules. Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings The Study of Atoms Atoms are composed of Electrons: Negatively charged particles Protons: Positively charged particles Neutrons: Uncharged particles Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings The Study of Atoms Protons and neutrons are in the nucleus. Electrons move around the nucleus. Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings Figure 2.1 Chemical Elements Each chemical element has a different number of protons. Isotopes of an element are atoms with different numbers of neutrons. Isotopes of oxygen are: 16 8 O 17 8 O Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings 18 8 O Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings Table 2.1 Electronic Configurations Electrons are arranged in electron shells corresponding to different energy levels. Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings Electronic Configurations Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings Table 2.2 (1 of 2) Electronic Configurations Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings Table 2.2 (2 of 2) How Atoms Form Molecules: Chemical Bonds Atoms combine to complete the outermost shell. The number of missing or extra electrons in this shell is known as the valence. Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings How Atoms Form Molecules: Chemical Bonds A compound contains different kinds of atoms. H2O The forces holding atoms in a compound are chemical bonds. Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings How Atoms Form Molecules: Chemical Bonds The number of protons and electrons is equal in an atom. Ions are charged atoms that have gained or lost electrons. Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings Figure 2.2a Ionic Bonds Ionic bonds are attractions between ions of opposite charge. One atom loses electrons and another gains electrons. Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings Figure 2.2b Covalent Bonds Covalent bonds form when two atoms share one or more pairs of electrons. Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings Figure 2.3a Hydrogen Bonds Hydrogen bonds form when a hydrogen atom covalently bonded to an O or N atom in another molecule. Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings Figure 2.4 Molecular Weight and Moles The sum of the atomic weights in a molecule is H2O the molecular weight. One mole of a substance 2H =21 = 2 is its molecular weight in O = 16 grams. MW = 18 1 mole weighs Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings 18g Chemical Reactions Chemical reactions involve the making or breaking of bonds between atoms. A change in chemical energy occurs during a chemical reaction. Endergonic reactions absorb energy. Exergonic reactions release energy. Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings Synthesis Reactions Occur when atoms, ions, or molecules combine to form new, larger molecules. A Atom, ion, or molecule A + B Atom, ion, or molecule B Combines to form AB New molecule AB Anabolism is the synthesis of molecules in a cell. Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings Decomposition Reactions Occur when a molecule is split into smaller molecules, ions, or atoms. AB New molecule AB Breaks down into A Atom, ion, or molecule A + B Atom, ion, or molecule B Catabolism is the decomposition reactions in a cell. Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings Exchange Reactions Are part synthesis and part decomposition. NaOH + HCl NaCl Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings + H2O Reversible Reactions Can readily go in either direction. Each direction may need special conditions. Heat A + B AB Water Copyright © 2006 Pearson Education, Inc., publishing as Benjamin Cummings