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Processes
and
Landforms in
Limestone
Environment
28/10/2014
Learning Outcome
Describe the characteristics of limestone as a rock
Describe the chemical weathering process of limestone
 Factors affecting the development of limestone landscapes
Account for the importance of limestone environments
LIMESTONE ROCK CHARACTERISTICS

Limestone is a sedimentary rock consisting of more than 50% calcium carbonate (calcite - CaCO3). There
are many different types of limestone formed through a variety of processes.

Limestone may form inorganically or by biochemical processes. There are many types of limestone because of the
variety of conditions under which it is produced. Coral reefs are examples of limestone produced in the form of
the skeletons of the coral invertebrate animals.

Chalk is another form of biochemically produced limestone. Chalk is a soft, porous rock made up of the skeletal
parts of microscopic marine organisms. It produces the white cliffs of Dover, England.
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Coquina is the name given to limestone in the form of poorly cemented shells and shell fragments.
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The stalactites and stalagmites in caves are mostly composed of limestone of inorganic origin. Sometimes called
dripstone, this limestone is more formally called travertine.
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Another form of limestone of inorganic origin is oolitic limestone, limestone formed from small spherical grains
called ooids. These grains form on small particles suspended in shallow marine waters.

Carboniferous limestone is an example of a pervious rock, as it allows water to flow through the joints and
bedding planes. This is a well-cemented rock of low porosity, and occurring in thick beds. As they have prominent
vertical joints, they can be easily spilt into blocks for use as building stone. It is a very tough rock, and is
commonly used as roadstone, but can also be used for cement making because it is often quite pure, and as a
source of calcium carbonate for the chemical industry.

Limestone rock dissolves slowly in carbonic acid (carbon dioxide and rainwater) creating a range of distinctive
landforms.

Most weathering takes place between the blocks where the acidic rainwater can penetrate: The main processes,
which affect it, are carbonation and solution.

Due to the pervious nature of the rock, drainage is usually underground and can only be seen where the limestone
meets an area of impermeable rock. This process can be seen in the appearance of natural springs and is known
as resurgence.
CHEMICAL WEATHERING PROCESS OF LIMESTONE
 Weathering or denudation in a limestone region is affected by carbonation, and this
process is fundamental to the understanding of the region's physical geography.
 Limestone, or calcium carbonate (CaCO3), is a sedimentary rock formed by the
compressing of the remains of dead sea creatures.
 Weathering of the rock is made easy by the fact that limestone contains bedding planes
(horizontal cracks) and joints (vertical cracks) allowing water to pass through the rock.
The chemical weathering of limestone, or carbonation, occurs when the rock is
attacked by rainwater. This occurs when rain takes in carbon dioxide as it passes
through the atmosphere. Carbon dioxide (CO2) dissolves in rainwater (H2O) then forms
weak carbonic acid (H2CO3)
 Carbonic acid is especially effective at dissolving limestone. It reacts with the calcium
carbonate (CaCO3) in the limestone. This forms calcium bicarbonate (Ca(HCO3)2),
which is soluble in water. This solution percolates through rock. It removes the calcium
carbonate. When the carbonic acid seeps through limestone underground, it can open
up huge cracks or hollow out vast networks of caves.
 The chemical equation for this process is CaCO3+ H2CO3 = Ca(HCO3)2, i.e., Limestone + Carbonic acid
(rainwater) = Calcium Bicarbonate (soluble limestone)
FACTORS AFFECTING THE DEVELOPMENT OF LIMESTONE
LANDSCAPES
FACTORS AFFECTING LIMESTONE LANDSCAPES
 Purity
 Solubility of Limestone - percent calcite
 Climate - Temperature and Moisture
 Structure and Lithology - joints, fractures, porosity

Water
 Vegetation- acidity (pH) of groundwater
 Atmospheric CO2 - affects solubility of Carbonates
 Time
IMPORTANCE OF LIMESTONE ENVIRONMENTS
IMPORTANCE OF UNDERSTANDING KARST SYSTEMS
Karst landscapes make up about 10% of the Earth’s surface
They are most abundant in tropical humid regions but also occur in
temperate, tropical, alpine and polar environments
A quarter of the world’s population depend on water supplied from karst
areas
However, karst systems are vulnerable to groundwater pollution due to
the relatively rapid water flow and the lack of a natural filtration system
Local drinking water supplies risk being contaminated as a result
PROTECTING KARST RESOURCES IN THE CARIBBEAN
 The Caribbean has one of the world’s premier karst landscapes
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(which make up more than half of the total land area of the region)
About 90% of the karst is in the Greater Antilles
Other significant areas are in the Bahamas, Anguilla, Antigua, the
Cayman Islands, the Virgin Islands, Guadeloupe, Barbados, Trinidad
and Tobago, and the Netherlands Antilles
Most countries have adopted conservative strategies in the
establishment of parks, reserves and sanctuaries encompassing karst
landscapes
Regionally, there are 121 protected karst areas, covering 14.3% of
the total karst
Economic value of karst
1. Agriculture
• Some karst regions have rich and highly productive soils
• The caves may be used for specialised agricultural
activities such as fish breeding, mushroom growing and
cheese production
• In Southeast Asia, limestone caves are an important
source of bird’s nest
2.
Industry
• Limestone is an important raw material for steel-making
and cement
• It is also used to reduce some forms of industrial
pollution, e.g. by removing sulphur dioxide from gases
3. Tourism
•
•
•
Annually, about 20
million people
worldwide visit
limestone caves
The Green Grotto
Caves in Jamaica,
Harrison’s Cave in
Barbados and
Gasparee Caves in
Trinidad are tourist
attractions
Tourism is an
important source
of income for the
residents in karst
areas
Harrison's Cave
Gasparee Caves
Scientific value of karst
 Karsts are a key source of information on landform
evolution and climate change
 The caves contain important archaeological and
palaeontological material
 Karsts host various endangered plant and animal species,
both underground and on the surface
Recreational value of karst
 Karsts offer opportunities for caving, which has become a
popular recreational activity
 This contributes to tourism
THREATS TO KARST SYSTEMS
 Drawing of water within karst areas disturbs the
hydrological system
 The water level and the water quality are threatened
 Moisture within the cave microclimate is affected
 The plant and animal species in the caves are subsequently
affected
 Quarrying for precious minerals such as bauxite destroys
the caves
 Dumping of sewage and domestic and industrial waste can
lead to groundwater pollution as there is little natural
filtration in karst regions