Survey
* Your assessment is very important for improving the workof artificial intelligence, which forms the content of this project
* Your assessment is very important for improving the workof artificial intelligence, which forms the content of this project
I. II. III. IV. V. VI. VII. VIII. IX. “Education is not the learning of many facts but the training of the mind to think.” – Albert Einstein To all Acadecers, Decathletes, and lovers of learning: I welcome you to the wonderful world of energy science that awaits you within the pages of this year’s Science Power Guide. Covering topics as diverse as quantum physics, radiation physics, and nuclear physics, this year’s Science Guide will teach you about how mankind unlocked the power of the atom. I, Jerry Zhao, former Decathlete of North Penn High School, will be your guide through this broad and diverse field. I have always been fascinated by the physical sciences, humanity’s continual attempt to explain the unexplainable and to understand the world around us. I hope that reading this guide will inspire you to further your studies in the applied sciences. This Power Guide will go above and beyond USAD in presenting information in a cleanly organized, comprehensive, and easily searchable format. Since many concepts in this packet pertain to multiple branches of science, I have done my best to present the big picture while remaining faithful to the all-important details. I have bolded key concepts, numbers, laws, names, dates, as well as any term bolded in the official USAD Resource Guide. For your convenience, all bolded terms have been carefully tabulated and organized in the Power Lists at the back of this guide. Since USAD cannot possibly cover all concepts important to the field of nuclear science in the Resource Guide, I have made it a point to identify and correct any gaps in information through the addition of footnotes. While these footnotes are not testable material, they will add helpful contextual information that will give you a better grasp of the subject material. Any contextual information I include in a footnote will start with “Enrichment Fact:” To ease the tediousness of this Power Guide, I have included my humorous comments and wry remarks on the subject material in the footnotes as well. While you may be entertained by my feeble attempts at comedy, you may choose to save yourself the pain by skipping any footnote which I have signed with my name. I promise I won’t be offended. I hope this Power Guide serves you well in your exploitation of nuclear science. The topics presented here will help you in competition and beyond. Happy studying! Jerry Zhao This year’s Science Resource Guide covers the history of atomic theory, quantum theory, radioactivity, nuclear fission and fusion, and the development of the atomic bomb. Section I covers 35% of the curriculum and 30% of the test material. This section walks you through the history of classical atomic theory and discusses the phenomena that form the foundation of modern quantum theory. Section II covers 24% of the curriculum and 30% of the test material. This section discusses the structure of atoms and the causes and effects of radiation. Section III covers 20% of the curriculum and 25% of the test material. This section discusses the science and applications of nuclear fusion and fission. Section IV covers 21% of the curriculum and 15% of the test material. This section focuses primarily on the Manhattan project and the development of the atomic bombs. Classical Atomic Theory Foundations of atomic theory Atomic theory describes the atom, the universe’s basic building block The first atomic models were rooted in classical1 physics Today, quantum theory informs our current models Natural philosophers developed atomic theory in the 5th century BCE They believed matter to be composed of indivisible particles The earliest references to atoms came from Democritus and Leucippus Plato proposed four fundamental types of particles: fire, water, earth, and air2 He later added a fifth fundamental element, aether Each particle had a unique shape that represented its properties Water flowed easily It hence formed an almost-spherical isocahedron Earth formed a cube since it was packed and solid The word “atom” comes from the Greek “atomos”, meaning “unable to be cut” These philosophers could not test any of their theories In the third century BCE, Aristotle proposed an opposing idea He described the basic elements as infinitely divisible Different ratios of the four elements resulted in different materials th Aristotle’s anti-atomist views lasted into the 17 century th In the 11 century, the study of atomism shifted from Europe to India The Middle Ages in Europe saw a decline in scientific thinking Islamic scholars combined Greek and Indian ideas in the Golden Age of Islam Their ideas formed the Asharite3 school of theology It returned to Europe in the Renaissance through Catholic priest Pierre Gassendi Gassendi reconciled atomism with the Catholic church He often discussed atomic theory with the philosopher Rene Descartes4 Galileo Galilei also supported atomist views In the 17th century, Robert Boyle challenged atomic theory with corpuscular theory 1 2 3 4 Corpuscules5 are divisible particles which alter the properties of matter Isaac Newton promoted corpuscular theory in his 1704 book Opticks According to him, corpuscules made up all light In the 18th century, scientists first uncovered the principles of chemical reactions French chemist Antoine Lavoisier6 created the first list of elements He identified and named hydrogen and oxygen Lavoisier also discovered that mass is conserved in chemical reactions 𝑀𝑎𝑠𝑠 𝑜𝑓 𝑟𝑒𝑎𝑐𝑡𝑎𝑛𝑡𝑠 = 𝑀𝑎𝑠𝑠 𝑜𝑓 𝑝𝑟𝑜𝑑𝑢𝑐𝑡𝑠 French chemist Joseph Proust discovered that elements combine in fixed ratios In 1864, Dmitri Mendeleev created the periodic table of elements He arranged 64 known elements by their atomic weights Other atomic properties had not been discovered yet The periodic table predicted the existence of still-to-be-discovered gallium Modern theories of the atom English chemist John Dalton penned the first principles of atomic theory He borrowed ideas from Lavoisier and Proust In 1808, he published his ideas in A New System of Chemical Philosophy Dalton also tabulated atomic weights Dalton’s Atomic Principles • • • • • Elements are composed of atoms Atoms of the same element are completely identical Atoms cannot be created, destroyed, or divided Atoms react in simple ratios to form compounds Atoms recombine in chemical reactions The development of the cathode ray tube allowed for many new observations Michael Faraday observed that a voltage between a cathode and anode caused the anode to glow The anode holds a positive charge, while the cathode holds a negative Negatively charged particles accelerate between the cathode and anode These particles form a cathode ray7 Televisions and computer monitors display images using cathode rays8 In 1897, J.J. Thomson measured the mass of a cathode ray particle He found them to be 1800 times less massive than hydrogen These negatively charged particles are now called electrons Thomson also proposed that atoms contained smaller particles like electrons in his plum pudding model 5 6 7 8 Electrons float around within the atom, like plums in plum pudding Hans Geiger and Ernest Marsden were Ernest Rutherford’s research partners In 1911, Geiger and Marsden conducted the gold foil experiment They directed a beam of positive particles at a sheet of gold foil They expected the beam to pass straight through because the electrons in the gold foil would be very small Instead, the gold foil deflected many of the particles in the ray at extreme angles Rutherford described the result as if “a 15-inch shell at a piece of tissue paper and it came back and hit you” In response to this experiment, Rutherford designed a new model He placed a dense nucleus at the atom’s core Since the positively charged ray was sometimes deflected backwards, the nucleus must be positively charged He described the atom as a planetary system, with electrons orbiting the nucleus Rutherford’s model had two inconsistencies Thermally excited atoms do not emit radiation at every frequency According to classical physics, the electrons should eventually fall into the nucleus Early Quantum Theory Wave Theory of Light Many scientists also argued over whether light is a particle or a wave Isaac Newton supported the corpuscular theory of light In his 1704 book Opticks, he described light as small particles The corpuscular theory explained reflection, but not refraction or diffraction The Dutch physicist Christiaan Huygens believed that light contained waves The wave theory explained how light diffracts around corners Optical experiments confirmed light’s wave-like properties In 1803, Thomas Young noted that two parallel slits cause alternating bands of light and dark on a screen He called this phenomenon double slit diffraction It results from constructive and destructive interference from light waves Sound waves produce a similar effect9 In the late nineteenth century, James Clerk Maxwell theorized electromagnetism He described light as a wave of oscillating electric and magnetic fields Modern scientists now understand that visible light forms only a small portion of the electromagnetic spectrum All electromagnetic waves travel at the speed of light 9 Different types of waves differ in their frequencies and wavelengths Frequency measures oscillations per second in Hertz (Hz) Wavelength measures the distance between oscillations High frequency waves have low wavelengths Blackbody Radiation All matter releases energy in the form of thermal radiation The intensity of radiation is proportional to the temperature of the object At room temperature, thermal radiation remains invisible in the infrared band Around 1000 K, the thermal radiation enters the visible band For example, metals glow red-hot According to the classical explanation, oscillating atoms act as “antennas” which project radiation Blackbodies are theoretical objects which absorb all incoming radiation Blackbodies remain in equilibrium by constantly emitting thermal radiation The ultraviolet catastrophe refers to a gap between classical expectations and 10 experimental observations According to classical theory, the intensity of thermal radiation should reach infinity as wavelength decreases However, experimental results showed that thermal radiation contains less wavelengths below ultraviolet than expected Energy Quantization Quantization refers to the discretization of possible energy levels Instead of existing at a continuous range of possible energies, a particle could only exist at certain specific energy levels A quantum of energy describes the smallest energy level a particle could have All other energy levels are multiples of this fundamental quantum German scientist Max Planck first proposed energy quantization in 1900 Planck’s Formula 𝐸 = ℎ𝑓𝑛 𝐸 = Energy ℎ = 6.63 × 10−34 𝐽 ⋅ 𝑠 = Planck’s constant 𝑓 = Frequency of oscillation 𝑛 = 1, 2, 3 … = the quantum number Since the quantum of energy is tiny, quantization is difficult to detect The Photoelectric Effect Heinrich Hertz discovered in 1887 that shining ultraviolet light on a metal will cause it to emit electrons This phenomenon is the photoelectric effect J.J. Thomson identified the emitted particles as electrons 10 Using classical theory, they reasoned that ultraviolet waves “charged” the electrons of the atom with energy After enough energy transfer, the electrons would escape In 1900, Philippe Lenard observed contradictions to the classical theory Classical Expectation Experimental Observation Time delay during which the electron gains Electron ejection happens instantaneously energy before it is ejected Any frequency of light should cause electron Only light above a certain frequency could emission if the light intensity is high enough cause electron emission Increasing light intensity increases the energy Increasing light intensity had no effect on of ejected electrons electron energy Light frequency has no effect on electron Increasing light frequency increased electron energy energy Albert Einstein proposed the quantization of light energy in 1905 The massless photon is the smallest quantum of light −19 Photons have energy on the order of 10 𝐽 Though massless, photons possess 11 momentum In the photoelectric effect, photons collide with electrons, ejecting them from the metal Einstein earned the 1921 Nobel Prize for this insight In 1923, American physicist Arthur Compton noticed that X-rays scatter upon impact with an electron This Compton scattering provided further proof for light quantization Atomic Spectra Elements emit their own unique atomic spectra of light when excited A spectrum describes a set of frequencies of light Atomic spectra act as “fingerprints” that can be used to identify an element In the 1800s, atomic spectroscopy was developed The technique identifies a sample’s chemical composition In 1868, scientists used atomic spectroscopy to identify helium in the sun Helium was only discovered on Earth 30 years later An emission spectrum describes the set of frequencies emitted by an excited atom A spectroscope uses a prism to separate the emission into wavelengths Passing white light through a set of atoms creates an absorption spectrum Lines in the spectrum mark which frequencies were absorbed Generally, the absorption spectrum marks the gaps in the emission spectrum In 1885, Swiss physicist Johann Balmer found a relationship between the frequencies of hydrogen’s emission spectrum Johannes Rydberg used Balmer’s findings in formulating the Rydberg formula 11 𝟏 𝟏 𝟏 = 𝑹𝑯 ( 𝟐 − 𝟐 ) 𝝀 𝒎 𝒏 𝝀 = wavelength of emitted light 𝑹𝑯 = 𝟏. 𝟎𝟗𝟕 × 𝟏𝟎𝟕 𝒎−𝟏 = the Rydberg constant 𝒎, 𝒏 = positive integers The Bohr Model In 1913, Danish physicist Neils Bohr created an atomic model that accounted for energy quantization He modified Rutherford’s solar system model ℎ The electron’s angular momentum now had to be a multiple of 2𝜋 Bohr had no experimental justification for this change Luckily, it worked anyway Bohr’s model has the following properties: Electrons move in circular orbits around the nucleus Only certain orbits, or energy levels, are stable Electrons do not radiate energy in their orbits This assumption contradicted known physical laws of physics12 Electrons can move between energy levels Absorbing radiation increases the energy level Emitting radiation decreases the energy level Electron Quantum Principles Quantum number, n Electron’s potential energy levels Ground state: n = 1, electron closest to nucleus n > 1 → excited states Ionization energy Energy needed to remove an electron Hydrogen: 13.6 eV Electron’s distance from nucleus at each level 𝒓𝒏 = 𝒏𝟐 𝒂𝟎 n = quantum number 𝑎0 = 0.0529 𝑛𝑚 = ground state electron radius = the Bohr radius Electron’s energy at each energy level −(𝟏𝟑. 𝟔 𝒆𝑽) 𝑬𝒏 = 𝒏𝟐 eV, or electron volt, = energy of one electron accelerated through a 1V potential difference 1 𝑒𝑉 = 1.6 × 10−19 𝐽 The negative sign implies that attraction keeps the electron around the nucleus Bohr’s model explained why the Rydberg formula worked 12 𝑚 and 𝑛 correspond to the energy levels between which an electron transitions Lines in the emission spectrum had corresponding quantum numbers Series Balmer Discovered Lyman Paschen 1906-14 1908 State transition 𝑛 > 2 → 𝑛 = 2 𝑛 > 1 → 𝑛 = 1 𝑛 > 3 → 𝑛 = 3 Bohr’s correspondence principle reconciled quantum and classical physics13 At high quantum numbers, quantum and classical predictions should match In the Bohr model, emissions at high quantum numbers match the electron’s orbital frequency In 1914, James Franck and Gustav Hertz found evidence supporting the Bohr model They fired electrons through mercury gas in a heated tube The electrons lost energy in quantized amounts of factors of 4.9 eV Franck and Hertz found that mercury emits ultraviolet radiation with similarly quantized amounts They won the 1925 Nobel Prize in Physics for this work The Bohr model still had several faults It could only describe the behavior of electrons in hydrogen The model did not explain why some lines in hydrogen’s atomic spectrum are actually two very closely spaced lines It did not account for molecule formation Particles as Waves The de Broglie Hypothesis French physicist Louis de Broglie first proposed the wave behavior of matter in his 1924 Ph.D. dissertation He compared the wave-particle behavior of light and the behavior of matter de Broglie Hypothesis 𝜆= 𝒉 = Planck’s constant ℎ 𝑝 𝑝 = particle momentum 𝜆 = de Broglie wavelength It explained why electron angular momentum must be quantized If the electrons are instead waves, their wavelengths must be factors of their orbital circumference In 1927, Bell Labs researchers confirmed the de Broglie hypothesis Clinton Davisson and Lester Germer observed a diffraction pattern when firing electrons at nickel They wanted to quantify the roughness of the crystalline nickel Since only waves can diffract, the electrons must have wavelike behavior Many innovations rely on this finding 13 Transmission electron microscopes (TEMs) use the wave behavior of electrons to achieve very high resolutions Light microscopes cannot resolve objects less than 500 nm, the approximate wavelength of visible light A TEM accelerates electrons with a wavelength of 0.0037 nm to 100 keV We do not observe the wave behavior of matter in everyday life Planck’s constant is very small An apple has a de Broglie wavelength a trillion trillion times smaller than an atom Wave-Particle Duality Wave-particle duality refers to the wave-particle behavior of both light and matter Electrons, photons, and neutrons all create a diffraction pattern in Young’s double slit experiment The experiment cannot detect the path of any individual particle In 1926, Albert Einstein14 wrote to Max Born about the strangeness of quantum mechanics He said that he could not believe God would play at dice Modern Quantum Mechanics Quantum Mechanics Quantum mechanics emerged in 1925 to unify quantum theory Classical physics had a set of laws to describe wave and particle interactions Newton’s laws described particle interactions The differential wave equation described wave behavior In 1925, Austrian physicist Ernst Schrödinger designed an equation that describes the wave-like behavior of particles The Schrödinger equation cannot be derived from existing theorems It has received experimental verification It’s solutions of wave functions are labeled by the Greek letter psi (𝜓 𝑜𝑟 Ψ) 2 In 1926, Max Born suggested that Ψ = the probability distribution of a particle Two wave functions have particular importance A wave “packet” describes a particle freely travelling through space A “particle-in-a-box” describes a particle trapped in an infinite potential well Its energy levels depend on the mass of the particle and the size of the box The Schrödinger equation suggests particles can escape potential wells with quantum tunneling Classical physics thought that a particle cannot cross potential barriers if its energy is too low Particles actually have a non-zero probability of crossing potential barriers 14 The scanning tunneling microscope (STM) uses quantum tunneling The STM forms a potential barrier between the microscope and the sample It analyzes the current based on tunneling electrons with a resolution of 0.1 nm Quantum Probability In 1935, Schrödinger presented the Schrödinger’s cat scenario It showed that a quantum system can exist in multiple states before being observed A cat is placed inside a box with a container of poison The poison has a 50% chance of being released Until someone opens the box, the cat is said to be both dead and alive Newtonian mechanics Quantum mechanics The world is deterministic The world is probabilistic Object positions are predictable and Repeated measurements of an object yield different determined results Works at larger scales Observed at the subatomic scale At large scales, uncertainty in measurements comes from the measuring instrument Quantum mechanics sets an upper limit on the precision of any measurement Measuring an object alters the object Ex: shooting a photon at a particle alters the particle’s position and velocity German physicist Werner Heisenberg proposed the Heisenberg uncertainty principle in 1927 It states the impossibility of knowing a particle’s exact position and momentum Increasing the precision of one measurement decreases that of the other 𝒉 Heisenberg uncertainty principle: 𝚫𝒙𝚫𝒑 ≥ 𝟐𝝅 Δ𝑥 = uncertainty in position Δ𝑝 = uncertainty in momentum ℎ = Planck’s constant Because the value of Planck’s constant is so small, the uncertainty principle only affects microscopic measurements In 1940, George Gamow wrote the book Mr. Tompkins in Wonderland It describes a world with a very large Planck’s constant A bank teller explored a “quantum jungle” Elephants have fuzzy skin from uncertainty in their position A gazelle spread out into a herd as if diffracted through a bamboo forest The Modern Quantum Model The modern model of the atom is the Schrödinger model Wave functions describe the electron’s waveform The amplitude of the wave function at a position describes the probability of finding an electron at that position Electrons orbit the nucleus in a probability cloud The probability could does not need to be spherical Bohr radii represent their probable positions Three quantum numbers describe the electron’s position The principal quantum number, Bohr’s original number, is 𝑛 This number describes the energy of the electron The orbital quantum number is ℓ where 0 ≤ ℓ ≤ 𝑛 − 1 Electrons with the same ℓ and 𝑛 occupy the same subshell Orbital quantum number 0 1 2 3 Subshell s p d f Subshells can be described using their principle quantum number and letter Ex: Subshell 3d has electrons with 𝑛 = 3, ℓ = 2 Superscripts denote electron configurations Sodium’s electron configuration is 1𝑠 2 2𝑠 2 2𝑝6 3𝑠 2 The orbital magnetic quantum number is 𝑚ℓ , −ℓ ≤ 𝑚ℓ ≤ ℓ The magnetic quantum number affects an atom’s behavior in a magnetic field The Zeeman effect alters the energy of electrons with differing 𝑚ℓ values Some spectral lines are actually two lines with slightly differing frequencies The spin quantum number 𝑚𝑠 does not come from the Schrödinger equation In 1925, scientists observed the yellow emission lines of sodium splitting This effect was called fine structure splitting In 1928, Paul Dirac derived a relativistic form of the Schrödinger equation It derives the spin quantum number from the electron’s angular momentum Electrons are a type of fermion, particles with half-integer spin 1 1 Electrons can have 𝑚𝑠 = or − 2 2 Usually, the spin is characterized as “spin up” or “spin down” Note that the spin number does not refer to the actual spinning motion The electron would have to spin faster than the speed of light if so The spin direction describes the electron’s contribution to the magnetic field The magnetic moment measures electrons’ tendency to align with the magnetic field Types of elements Diamagnetic • Shells are filled with electrons; electron spins cancel to 0 • Element is repelled by a magnetic field • Shells are partially filled; electron spins do not cancel out Paramagnetic • • • Ferromagnetic • (iron, nickel) • • Atoms in the element align to a magnetic field Atoms de-align when removed from the field Shells are partially filled Atoms in the element align, even without a magnetic field Used in permanent magnets Above the Curie temperature, magnetic properties are lost An electron’s state can be described by the four quantum numbers, 𝑛, ℓ, 𝑚ℓ , and 𝑚𝑠 Wolfgang Pauli proposed the Pauli exclusion principle No two electrons in an atom have the same four quantum numbers No two fermions can occupy the same quantum state Hence, electrons added to the atom fall to the lowest energy quantum level This property explains why noble gases like neon and helium do not react easily They have filled electron shells15 Alkali metals such as lithium and sodium, however, are extremely reactive They have unpaired electrons The Pauli exclusion principle does not apply to bosons Bosons are particles with integer spin, not half-integer spin In 1924, Satyendra Bose and Albert Einstein suggested that cooling a gas of bosons to 0 K would create a new state of matter This temperature is also known as absolute zero The “K” stands for “Kelvin” In 1995, Carl Weiman and Eric Cornell produced this new state of matter with laser cooling They called it the Bose-Einstein condensate Applications of Atomic Physics Lasers Atoms emit energy when an electron falls from a higher to lower energy level In spontaneous emission, the atom emits a photon in a random direction The atom remains excited for a few nanoseconds In stimulated emission, a passing photon can prompt a second photon release The passing photon’s oscillating electric field must have the same frequency as the transition frequency of the excited electron The second emitted photon oscillates in synchrony with the first Laser stands for Light Amplification by Stimulated Emission of Radiation Lasers were first designed in 1960 A reflective cavity contains and amplifies emitted light of uniform wavelength It creates a chain reaction of stimulated emissions A laser’s power ranges from 0.001 watts to 10,000 watts Lasers are widely used in medicine, industry, and research16 Qualities of Lasers Qualities of Ordinary Light and Radiation Monochromatic: carry one light Carry many different frequencies frequency Directional: do not spread as they Decrease in intensity with distance squared travel Coherent: waves travel in the same Do not travel in the same phase (ordinary phase17, so they exhibit cleaner light) interference effects Materials used in the laser must meet two requirements 15 16 17 The element’s excited state must be metastable It has to remain excited state for some time before falling to the ground state Simulated emission can then occur before spontaneous emission Most of the atoms in the laser need to be in the excited state A process called population inversion creates a sample that contains more atoms in the excited state A common design is the Helium-Neon (HeNe) laser HeNe lasers produce bright red 632.8 nm light HeNe lasers are used in physics18 demonstrations and barcode scanners Helium atoms excited by an electric current collide with neon atoms The neon atoms emit 632.8 nm radiation Laser cooling uses lasers to slow down the movement of atoms Room temperature gas particles move at 500 m/s Quantum effects cannot be easily observed at these speeds The scientific community awarded the 1997 Nobel Prize in Physics to the three scientists who developed laser cooling Laser cooling relies on two principles (1) Conservation of momentum implies that each photon from the laser carries some momentum to the gas particle it strikes The laser exerts an overall pressure on the gas particle (2) The Doppler effect describes how moving towards or away from a wave source alters the apparent frequency and wavelength A siren moving towards you sounds high pitched, while a siren moving away from you is low pitched The cooling laser has a frequency slightly below the transition’s Only particles moving towards the laser will be excited and slowed Systems involve six laser beams Two beams point in opposite directions along the x, y, and z axes In 2015, Stanford scientists cooled a sample of gas to 50 trillionths of a kelvin A rubidium atom at this temperature moves at 70 thousandths mm/se Atomic Clocks Atomic clocks use the timings of atomic transitions to tell time Unlike pendulum clocks, they do not respond to environmental changes Atomic transition timings will be identical for all atoms of an element In 1955, the first atomic clock was created using cesium This clock had an error of 1 second per 300 years Modern cesium clocks are accurate to 1 second per 300 million years19 The accuracy of frequency measurements and ability to remove measurement noise have improved In 1967, the second was redefined as the time that elapses during 9,192,631,770 hyperfine transitions of cesium-137 Hyperfine energy level differences result from magnetic interactions between electron spin and nuclear spin in the ground state The second has become the most accurately defined SI unit of measurement Elements used in atomic clocks include hydrogen, rubidium, mercury, strontium, and aluminum The National Institute of Standards and Technology uses cesium-13 18 19 Structure of the Nucleus Discovery of the Proton and Neutron Ernest Rutherford performed the gold foil experiment in 1911 He discovered the presence of a small, dense, positively charged core at the center of the atom In 1917, Rutherford carried out particle scattering with nitrogen gas He was surprised to notice hydrogen nuclei being produced from the collision He decided that the hydrogen nucleus must be a fundamental building block of matter Later scientists realized that the nucleus contains just a single proton Surprisingly, the nucleus did not have a charge proportional to its mass He suggested that the nucleus contained neutral proton-electron pairs However, electrons cannot exist inside the nucleus According to the Heisenberg uncertainty principle, the electron has a minimum energy in the nucleus It exceeded experimentally observed electron energies Experimental observations of nuclear spin also contradict this idea In 1920, Rutherford that proton-electron pairs merge into neutrons In 1930, scientists found the neutron when bombarding beryllium with alpha particles The beryllium emitted neutral highly penetrating radiation This radiation did not behave like photons It had enough energy to eject photons from paraffin (wax) English scientist James Chadwick confirmed this particle was the neutron in 1932 Nuclear Properties Nuclear physics studies the structure and interactions of the atomic nucleus Nuclei consist of protons and neutrons, known collectively as nucleons −𝟏𝟗 Protons have a positive charge of +𝟏. 𝟔 ⋅ 𝟏𝟎 Coulombs Neutrons have a negative charge and a slightly higher mass than protons Nuclei are notated by their numbers of neutrons and protons Nuclear notation: 𝑨𝒁𝑿 X Chemical symbol Atomic number - number of protons Z Unique to each element; can be omitted from notation e.g. uranium 238 = uranium with atomic mass 238 N Number of neutrons A Atomic mass number, Z + N – total number of neutrons and protons Always an integer The relative mass number describes the average atomic mass of an element This number appears on periodic tables20 It refers to the average atomic mass of all isotopes of an element, weighted by the abundance of each isotope Atomic masses are measured in unified mass units, u 𝑀𝑒𝑉 2 The 2 unit of mass comes from Einstein’s relation 𝐸 = 𝑚𝑐 𝑐 𝟏𝒖= 𝟏 𝟏𝟐 mass of 𝟏𝟐 𝑪 = 𝟏. 𝟔𝟔 × 𝟏𝟎−𝟐𝟕 𝒌𝒈 = 𝟗𝟑𝟏. 𝟒𝟗 𝑴𝒆𝑽 𝒄𝟐 Kilograms Unified Mass Units (u) 𝑴𝒆𝑽 𝒄𝟐 Proton 1.672 × 10−27 1.007276 (~1 u) 938.28 Neutron 1.675 × 10−27 1.008665 (~1 u) 939.57 Weight in Electron 9.109 × 10−31 1 5.486×10-4 (~1800 𝑢) 0.511 The nucleus is about 100,000 times smaller than the atom After the gold foil experiment, Rutherford measured the radius of the nucleus as 10−14 𝑚 He conducted scattering experiments to find this result −15 21 The actual size of a nucleus is 10 𝑚 , a femtometer It takes its name from Italian Enrico Fermi −10 The electron cloud has a radius of 10 𝑚 If an atom were a football stadium, the nucleus would be a marble22 The equation 𝑟 ≈ 𝑟0 𝐴1/3 relates atomic radius to atomic weight −15 𝑟0 = 1.2 × 10 𝑚 Nuclei have volume proportional to A Hence, all nuclei have the same density Isotopes Isotopes of an atom have equal numbers of protons but differing numbers of neutrons In Greek, “isotope” roughly means “the same place” 20 21 22 All isotopes of an element occupy the same spot on the periodic table Isotopes have similar chemical properties Neutrons do not usually affect chemical bonding They have very different nuclear properties, especially those of stability and abundance Isotope of Hydrogen Symbol Abundance Stability Plain = hydrogen 1 1𝐻 99.99% Stable Deuterium 2 1𝐻 Very little Stable Tritium 3 1𝐻 Very little Radioactive (unstable) Scientists create isotopes by bombarding nuclei with alpha particles, neutrons, or other nuclei All isotopes heavier than Californium23 (z = 98) can only be created artificially Nuclear Forces The strong nuclear force2425 holds protons and neutrons together in the nucleus This force only acts over very short ranges The binding energy is the energy needed to split apart the nucleus The total mass of a nucleus’s components exceeds that of the nucleus26 The extra mass comes from the binding energy 4 2𝐻𝑒 has an unusually high binding energy, affecting its decay properties Elements 4 2𝐻𝑒 = 2 × 10𝑛 + 2 × 11𝑝+ Mass 4.001506 𝑢 ≠ 2 × 1.008665 𝑢 + 2 × 1.007276 𝑢 Sum: 4.001506 𝑢 ≠ Sum: 4.031882 u Difference 0.03076 u = 28.3 MeV, 7 MeV/nucleon A nucleus’s binding energy relates to its nuclear stability Neutrons increase nuclear stability by not repelling protons 𝒁 Stability properties ≈56 High stability - highest binding energies, e.g. iron, nickel >60 Binding energies decrease with atomic number Larger nuclei have weak short-range nuclear forces 23 24 25 26 >20 Require many more neutrons than protons to remain stable > 83 No number of neutrons can stabilize the nucleus Quantum effects also contribute to nuclear stability Nuclei with even numbers of neutrons are more stable If the number of neutrons or the number of protons is a magic number, the nucleus is unusually stable The magic numbers are 2, 8, 20, 28, 50, 82, and 12627 Helium-4 and oxygen-16 are doubly magic In 1949, Maria Goeppert Mayer and Eugene Wigner designed a “shell” model This model of nucleons explained the presence of magic numbers The magic numbers equal the protons and neutrons needed to fill each shell Neutrons and protons are fermions and so follow the Pauli exclusion principle Protons and neutrons are fermions because they have half-integer spin When the number of protons or neutrons is even, the spins cancel out Particles of opposing spin align to decrease energy Nuclei with uneven numbers of protons or neutrons have a magnetic moment A nucleus with a magnetic moment will respond to an external magnetic field Aligning the magnetic moment with the field decreases the nucleus’s energy An oscillating magnetic field can cause the nucleus to rapidly oscillate between two energy levels Magnetic resonance imaging (MRI)28 uses a strong magnet to align all of the hydrogen-1 atoms in a body Radio waves target specific areas and break the alignment of hydrogen nuclei Without the radio waves, the nuclei fall back and release energy MRI does not damage cells, but still provides high resolution images Radioactivity The discovery of radioactivity In 1895, German physicist Wilhelm Roentgen made the first observation of x-rays He experimented with a cathode ray tube The rays passed through cloth, paper, and books to cause a view-screen to glow He called them “X” rays since they were then unknown Roentgen won the 1901 Nobel Prize for this discovery French physicist Henri Becquerel discovered spontaneous radiation later that year He observed it in uranium salts that behaved similar to Roentgen’s x-rays Radioactivity refers to spontaneous radiation Radioactive isotopes spontaneously emit radiation and In the process, they transform into other isotopes Marie Curie measured the radioactivity of many substances She built on her husband Pierre Curie‘s work on crystals She analyzed pitchblende and torbernite These minerals that contain uranium Their radioactivity was proportional to the quantity of uranium Hence, a change in uranium’s atomic structure induced radiation In 1898, the Curies discovered polonium and then radium They named polonium after Marie’s home country Poland29 The Curies and Becquerel jointly won the 1903 Nobel Prize in Physics Marie Curie also won the 1911 Nobel Prize in Chemistry 27 28 29 She is the only person ever to win two Nobel Prizes Heavy exposure to radiation ruined Marie’s health She lost most of her sight in the 1930s and died in 1934 of aplastic anemia Her original notes are too radioactive to be handled without shielding30 Radioactive decay In 1900, Ernest Rutherford and Frederick Soddy identified the three types of radiation: alpha (α), beta (β), and gamma (γ) They also suggested that radiation results from radioactive decay During radioactive decay, unstable isotopes transform into stable isotopes Charge and nucleons are always conserved The parent nucleus X transforms into a daughter nucleus Y, except in gamma decay Gamma decay involves a descent from a higher energy state X* to a lower energy state X* Type Emits Alpha Beta minus Beta plus Gamma Helium nucleus Electron and antineutrino Positron and neutrino Photon 𝟒 𝟐𝑯𝒆 𝟎 − −𝟏𝒆 𝟎 + 𝟏𝒆 𝜸 Notation Decay formula 𝑨 𝒁𝑿 Example 238 92𝑈 → 𝟒𝟐𝑯𝒆 + 𝑨−𝟒 𝒁−𝟐𝒀 → 42𝐻𝑒 + 234 88𝑇ℎ 𝑨 𝒁𝑿 → 𝟏𝟒 𝟔𝑪 𝟎 − −𝟏𝒆 ̅ + 𝒁+𝟏𝑨𝒀 + 𝟎𝟎𝒗 𝑨 𝒁𝑿 → 𝟎𝟏𝒆+ + 𝒁−𝟏𝑨𝒀 + 𝟎𝟎𝒗 ̅ → 𝒆− + 𝟏𝟒𝟕𝑵 + 𝝂 𝑨 ∗ 𝒁𝑿 𝟏𝟐 ∗ 𝟔𝑪 → → 𝑨𝒁𝑿 𝟏𝟐 𝟔𝑪 +𝜸 During alpha decay, an atom releases an alpha particle An alpha particle is two protons and two neutrons It is the same as a helium nucleus This particle’s high binding energy makes it energetically favorable for decay Emitting 2 neutrons and 2 protons individually is not energetically favorable Eg: 𝐴𝑍𝑋 → 10𝑛 + 10𝑛 + 11𝑝 + 11𝑝 + 𝐴−4 𝑍−2𝑌 Alpha decay occurs in elements at least as heavy as tellurium (𝑍 ≥ 52) Radioactive nuclides release alpha particles at 5% of the speed of light Alpha particles lose energy quickly due to their high mass They usually stop in a few centimeters During beta decay, an atom releases either an electron or positron A positron is electron’s antiparticle – an electron with a positive charge Scientists only discovered beta plus decay decades after beta minus decay −10 The positron lasts for 10 seconds in a vacuum before annihilating with an electron 30 Beta minus particles come from the nucleus, not the surrounding electron cloud A neutron in the nucleus transforms into a proton and an electron 1 1 + 0 − 0𝑛 → 1𝑝 + −1𝑒 Free neutrons outside the nucleus perform such decay in 15 minutes In the 1920s, physicists including Neils Bohr realized that conservation of energy, spin, and angular momentum did not occur in beta decay In 1930, Wolfgang Pauli hypothesized another particle in beta decay Enrico Fermi called this particle a neutrino, or “little neutral one” The neutrino was first observed in 1950 Properties of the Neutrino Neutrally charged Fermion with half-integer spin Essentially massless Weakly interacts with matter • Released by nuclei in electron capture (K-capture): The nucleus absorbs an electron from the K energy level of its electron cloud • Higher energy electron drops down to fill the shell, releasing an X-ray photon • • A proton combines with the electron in the nucleus to produce a nucleus and a neutrino The nucleus releases the neutrino • Example: 74𝐵𝑒 + 𝑒 − → 73𝐿𝑖 + 𝜈 During gamma decay, an atom releases electromagnetic radiation, or photons Gamma decay often proceeds after alpha or beta decay produces an excited nucleus Photons produced by nuclear transitions differ from those in electron transitions Nuclear transition photon Electron transition photon Gamma rays X-rays Millions of eV Tens of eV Scientists can create unstable isotopes that do not exist naturally In 1934, Irene Joliot-Curie and Frederick Curie artificially synthesized a radioactive isotope of phosphorous Irene was the daughter of Marie and Pierre Curie They fired alpha particles at aluminum 4 2𝐻𝑒 + 27 13𝐴𝑙 → 30 15𝑃 + 10𝑛; 30 15𝑃 → 30 14𝑆𝑖 + 𝑒+ Together they won the 1935 Nobel Prize in Chemistry Medically useful isotopes are produced artificially Over 3,000 radioactive isotopes have been synthesized The math of decay The timing of decay cannot be predicted for a specific nucleus31 For a group of radioactive atoms, decay happens exponentially The number of decays is proportional to the number of nuclei present and to the time that has elapsed The rate of decay has a similar exponential relation 31 Decay Laws 𝚫𝑵 = −𝝀𝑵𝚫𝒕 𝑵 = 𝑵𝟎 𝒆−𝝀𝒕 𝑹 = 𝑹𝟎 𝒆−𝝀𝒕 Δ𝑁 = number of decays in a period of time 𝑁 = number of nuclei present at a given time 𝑁0 = initial nucleus population 𝑅 = decay rate at a given time t= time elapsed Δ𝑡 = a period of time 𝑅0 = initial decay rate 𝜆 = decay constant The decay rate is measured in Curies or Becquerels 10 1 Ci (Curie) = 3.7 × 10 𝑑𝑒𝑐𝑎𝑦𝑠/𝑠 1 Bq (Becquerel) 1 𝑑𝑒𝑐𝑎𝑦/𝑠 The Becquerel became the standard unit for decay rate in 1975 The half-life of an isotope measures the time for half a sample of that isotope to decay Examples: Half-life equation 𝐥𝐧 𝟐 𝟎. 𝟔𝟗𝟑 𝑻𝑯 = = 𝝀 𝝀 Hydrogen-4 10−22 seconds Tellurium-12 1024 years Isotopes with a long half-life have a more stable nucleus In any decay, a set of particles moves from a state with high potential energy to a state with lower potential energy The mass of products will always be less than the mass of the original particles The potential energy difference comes from the mass difference Quantum mechanics explains why decay is probabilistic An alpha particle in a nucleus has a wave function The nuclear and Coulombic forces contain the alpha particle in a potential barrier The potential barrier has a size proportional to the nucleus’s size and charge Much like quantum tunneling, the alpha particle can escape the confining forces If the potential barrier is small, the alpha particle will escape more easily This isotope would have a short half life Decay chains A decay chain occurs when the daughter nucleus is also radioactive Each decay step has its own half-life The three primary decay chains in nature occur in thorium, uranium, and actinium Neptunium’s decay chain does not occur in nature A chain starts with a heavy long-life isotope and ends with a stable isotope of lead In thorium-232’s chain, bismuth-212 performs either alpha or beta minus decay Decay chains explain why short-lived isotopes still exist in nature Radium-226 has a half-life of 1,600 years The Solar System has existed for 4.6 billion years All original radium-226 has decayed Uranium-238’s decay chain replenishes the isotope 9 Uranium-238 has a half-life of 4.47 × 10 years Detecting Radioactivity Dosage measures the quantity of radiation an object receives The standard unit of dosage is the Sievert (Sv) One Sievert equals the effect of radiation that puts 1 Joule into 1 kg of tissue The United States uses the rem, equal to 0.01 Sieverts All methods of detecting radiation measure radiation’s ionizing effects Radiation ionizes atoms by removing electrons Geiger counter Scintillation counter Invented by Hans Geiger32 Proportional counter Provide information about the energy level of the radiation Measure energy of incoming radiation Essentially complex Geiger counters Radiation ionizes gas atoms, releasing electrons Radiation excites the crystal, usually NaI Incoming radiation trigger an "avalanche" of ions Electrons jump to wire and trigger electric pulse Excited crystal falls back to its ground state and releases a photon Ions move towards a highvoltage wire, changing its current Electric pulse produces clicking sound Photomultiplier tube converts photon to electric pulse Change is proportional to particle energy Contain positively charged wire surrounded by tube of inert gas Use scintillating material instead of gas American Donald Glaser invented the bubble chamber in 1952 It and its counterpart, cloud chambers, track the path of radiation The path provides information on the particle’s mass, charge, and momentum Positive and negative particles curve in opposite directions Cloud chamber Bubble chamber Medium Vaporized water or alcohol Heated liquid hydrogen Result Particles are ionized. Pressure condenses vapor around the ions, forming trails Pressure is decreased; particle in an electric or magnetic field leaves behind a trail of bubbles Practical Applications of Radiation Sources of Radiation The average American receives 6.2 mSv of background radiation every year Half of this radiation comes from man-made sources, mostly x-ray procedures One x-ray delivers 0.02 mSv to the body Less than 0.1% comes from the nuclear industry The other half comes from natural sources33 32 33 Cosmic rays Radon-222 High energy particles from beyond the solar system Mostly free protons Shielded by the atmosphere More prominent in high altitude areas >Ex: Denver receives 2x more radiation than sea level >Affects pilots' annual permitted dosages 34 Other sources Largest source of natural background radiation Radioactive minerals Found in decay chain of uranium-238 Radioactive nuclei in food Accumulates in basements as a dense gas Second most frequent cause of lung cancer after smoking Potassium-40 results in 0.4 mSv per year Can be tested for with detection kits35 Health Effects of Radiation36 Ionizing radiation has enough energy to excite electrons Both ionizing and non-ionizing radiation can thermally excite atoms, causing burns Non-ionizing radiation 𝐸𝑛𝑒𝑟𝑔𝑦 < 10 − 33 𝑒𝑉 Radio waves Microwaves Infrared, visible, sun light Ionizing radiation 𝐸𝑛𝑒𝑟𝑔𝑦 > 10 − 33 𝑒𝑉 X-rays and gamma-rays High energy UV light Decay emissions Ionizing radiation damages living things when it strikes a molecule in the body An electron is removed, creating an ion or free radical3738 (neutral molecules with unpaired electrons) The free radical react with other elements to produce irregular compounds Cells repair weak radiation damage only slowly However, the body cannot regenerate nerve cells Damage to DNA can lead to mutations, causing genetic disorders or cancer Overexposure to UV radiation causes sunburns, which can damage skin cells’ DNA Dead skin cells peel off Some forms of radiation are more dangerous than others 34 35 36 37 38 Gamma rays Alpha particles Most destructive form Travel farthest into matter Blocked by skin Highly damaging if alpha emitter is consumed39 Interact weakly with matter Neutrinos Do not affect human health Strike earth from sun with flux of 1011 neutrinos / cm2 Radiometric Dating Radiometric dating uses decay rates to calculate a material’s age The most common form is carbon dating In the 1940s, American Willard Libby developed carbon dating He won the1960 Nobel Prize in Chemistry Carbon-12 and carbon-13 are stable, but carbon-14 undergoes beta decay Carbon-14 transforms into nitrogen-14 with a half-life of 5,730 years Carbon dating only works with objects less than 50,000-years old Older materials have an undetectable carbon-14 concentration Process of carbon dating Cosmic rays produce free neutrons in the atmosphere Free neutrons combine with nitrogen-14 to form carbon-14, which has a natural abundance of 1 per trillion in living organisms and the atmosphere Living organisms take in carbon dioxide in respiration The organism dies, and carbon-14 in its body decays Ratio of carbon-14 to carbon-12 decreases with time Scientists measure the ratio to determine the organism’s age Fluctuations in the atmosphere’s carbon-14 concentration limit carbon dating’s accuracy Varying intensities of the Earth’s and Sun’s magnetic fields alter the strength of incoming cosmic rays Oceans hold carbon-14 as dissolved carbon dioxide Inconsistent ocean temperatures alter the rate at which carbon flows into the atmosphere Uranium dating works on objects older than 50,000 years Uranium-238 is used instead of carbon-14 9 This isotope has a half-life of 4.5 × 10 years The technique revealed that the oldest moon rocks and the oldest Earth rocks have the same age The moon was probably formed out of the Earth in a primordial collision Uranium dating and argon-argon dating40 have recreated the fossil records 39 40 Geologists date the rock layers in which fossils are found Primordial isotopes like uranium-238 were present in Earth’s crust at its formation 9 Earth’s age is 4.5 × 10 years 7 For a primordial isotope to be detectable its half-life must be > 5 × 10 years Industrial applications Radiation therapy destroys cancer cells’ DNA with ionizing radiation Without DNA, the cancer cells die The radiation must precisely kill only the cancerous cells Multiple low intensity beams intersect at the location of the cancerous cells41 Gamma rays are most commonly used for cancer therapy Beta radiation is used to kill skin cancer and tumors close to the skin Radiation sterilization was first used in the mid-twentieth century Gamma rays are commonly used, generally using cobalt-60 as the emitter Eggs, grains, fruits, and vegetables can be sterilized without becoming radioactive It may chemically alter the food’s taste and nutrition The United States Food and Drug Administration regulates food irradiation Smoke detectors contain under 1 microgram of radioactive americium-241 Americium-241 transforms into neptunium-237 in alpha decay The alpha particles produce a current in the detector Smoke absorbs the alpha particles, breaking the current Radioactive tracers use isotopes to create an observable path through a system Uses of radioactive tracers • Doctors42 prepare sodium iodide with radioactive iodine-131 instead of iodine-127 Medicine • The patient ingests the harmless sodium iodide • The radioactive iodide collects at the patient's thyroid glands, providing a measure of thyroid health • Doctors can then detect hemorrhage or tumor formation Agriculture • A radioactive solution is injected into a plant’s root system • The solution’s uptake throughout the plant is measured • Scientists can then detect information about the plant’s fertilizer or other chemical use • The engine's cylinder walls are coated with a tracer Auto mechanics • The engine is operated for some time • The tracer's concentration in the lubricating oil is analyzed 41 42 Nuclear Reactions A brief history Two nuclei collide and form another nucleus in a nuclear reaction Ernest Rutherford induced a nuclear reaction when he discovered the proton in 1917 He was scattering alpha particles from nitrogen gas 4 14 He induced the reaction: 2𝐻𝑒 + 7𝑁 → 17 1 8𝑂 + 1𝐻 Unfortunately, Rutherford did not understand the nuclear changes 43 occurring In 1932, Irish physicist Ernest Walton and British physicist John Cockcroft became known as the first men to “split the atom” 1 7 4 They performed the reaction 1𝑝 + 3𝐿𝑖 → 2 × 2𝐻𝑒 Like chemical reactions, compounds react to form new compounds However, nuclear reactions release energy in the order of MeVs rather than eVs Mass-energy conversion Fusion Fission Direct Involves light nuclei heavy nuclei particle-antiparticle pairs % mass converted 0.7% 0.1% 100% Particle accelerators now collide particles with tremendous amounts of energy The Large44 Hadron Collider accelerates protons to 99.9999% of the speed of light These protons have 1 TeV45 of energy The LHC is located at CERN, a research facility in Europe A reaction’s Q value measures its energy output or input 43 44 45 Reaction Energy Example Mass of reactants Exothermic: Q > 0 Endothermic: Q < 0 Released as kinetic energy of products and gamma rays Requires input - kinetic energy of reactants 2 1𝐻 + 63𝐿𝑖 → 42𝐻𝑒 + 42𝐻𝑒 4 2𝐻𝑒 2.014101 𝑢 ( 21𝐻 ) + 6.015123 𝑢 ( 63𝐿𝑖 ) = 8.029224 𝑢 Mass of 4.002603 𝑢 ( 42𝐻𝑒) + 4.002603 𝑢 ( 42𝐻𝑒) = 8.005206 𝑢 products Net energy + 147𝑁 → 17 8𝑂 + 11𝐻 4.002603 𝑢 ( 42𝐻𝑒) + 14.003704 𝑢 ( 147𝑁) = 18.005677 𝑢 16.999132 𝑢 ( 178𝑂) + 1.007825 𝑢 ( 11𝐻 ) = 18.006957 𝑢 0.024018 𝑢 = 22.4 𝑀𝑒𝑉 −0.001280 𝑢 = −1.19 𝑀𝑒𝑉 Produces 22.4 MeV Requires a little more than 1.19 MeV Actual energy input slightly exceeds the Q value in endothermic reactions The Q value energy produces the product particles at rest To maintain conservation of momentum, the products must have kinetic energy 𝒎 Required kinetic energy, 𝑲𝑬𝒎𝒊𝒏 = (𝟏 + 𝑴) |𝑸| 𝐾𝐸𝑚𝑖𝑛 = threshold energy 𝑀 = mass of stationary nucleus 𝑚 = mass of incoming nucleus 𝑄 = Q value of reaction E.g.: reaction with 42𝐻𝑒 and 14 7𝑁 → minimum energy = 1.53 MeV Fission reactions In nuclear fission, a massive nucleus releases energy and splits into fission products Most of the time, the heavy nucleus first collides with another particle In rare cases, nuclear fission occurs spontaneously Fission releases up to 100 MeV of energy per reaction Fission products, or fission fragments, are lighter nuclei released in nuclear fission These have a high neutron to proton ratio Neutrons stabilize protons in heavy nuclei “Neutron heavy” fission products decay further into even lighter nuclei46 Types of nuclei Fissile Fertile Neither Performs fission after colliding with a slow particle with energy < 1 𝑀𝑒𝑉 Performs fission after colliding with a fast particle with energy > 1 𝑀𝑒𝑉 Never performs fission English professor James Chadwick discovered the neutron in 1932 Earlier scientists created reactions by firing alpha particles or protons at nuclei After 1932, they used mostly neutrons instead The nucleus’s positive charge does not repel neutrons Low energy neutrons can still penetrate the nucleus This process is neutron bombardment In the 1930s, Enrico Fermi created new elements with neutron bombardment 46 Uranium Neptunium Plutonium 𝑍 = 92 𝑍 = 93 𝑍 = 94 Heaviest known element at the time; target of neutron bombardment New elements synthesized by neutron bombardment In 1938, German physicists Otto Hahn and Fritz Strassman noticed that nuclei tend to split in two after neutron bombardment The two pieces were each around half as massive as the target nucleus Ex: Barium is half as massive as uranium The existing theory behind decay did not explain this phenomenon Lise Meitner and Otto Robert Frisch explained this observation using the liquid drop model of the nucleus According to this model, heavy nuclei oscillate and split in half Otto Frisch first used the term “fission” He was alluding to how living cells split apart in biological fission Neils Bohr realized that the energy released in nuclear fission could be harnessed He visited the United States and worked with John Wheeler and Enrico Fermi In a chain reaction, a fission reaction sparks more reactions in neighboring nuclei Before the 1930s, scientists only knew of chemical chain reactions The finding proved a nuclear chain reaction to be theoretically possible In 1933, Hungarian Leo Szilard envisioned the self-sustaining nuclear reaction The reaction had to be triggered by a neutron and release at least one neutron The multiplication factor k measures the average number of released neutrons which will trigger another fission Some neutrons are captured without fission, and others escape the system Subcritical: 𝑲 < 𝟏 Critical: 𝑲 = 𝟏 Supercritical: 𝑲 > 𝟏 Number of reactions decreases with time Constant number of reactions → constant power generated Increasing number of reactions over time Cannot sustain decay chains Optimal for power generation Optimal for nuclear weapons Calculating energy per reaction from binding energies of nucleons Ex: 235 nucleons → 3.2 × 10−11 𝐽 = 200 𝑀𝑒𝑉 = 235 ∗ (8.5 𝑀𝑒𝑉 − 7.6 𝑀𝑒𝑉) Binding energy of nucleons Reactants: 7.6 𝑀𝑒𝑉 Products: 8.5 𝑀𝑒𝑉 Energy density Gasoline: 4.4 × 104 𝐽 Uranium: 8.8 × 1010 𝐽 The first nuclear chain reaction was observed in uranium-235 Uranium-235 can follow many decay paths It is the only isotope useful for nuclear power generation Uranium-238 absorbs neutrons without performing fission It forms 95% of all uranium, while uranium-235 constitutes 0.7% Uranium-235 releases 2.5 neutrons per decay Enriching uranium increases the concentration of useful uranium-235 Two possible Uranium-235 decay chains 𝟐𝟑𝟓 𝟏 𝟎𝒏 + 𝟗𝟐𝑼 𝟏 𝟎𝒏 → + 𝟐𝟑𝟓 𝟗𝟐𝑼 → 𝟏𝟒𝟏 𝟓𝟔𝑩𝒂 𝟏 + 𝟗𝟐 𝟑𝟔𝑲𝒓 + 𝟑 𝟎𝒏 𝟏𝟒𝟎 𝟗𝟒 𝟓𝟒𝑿𝒆 + 𝟑𝟖𝑺𝒓 + 𝟐 𝟏𝟎𝒏 Most common; produces barium and krypton Less common; produces xenon and strontium Uranium enrichment Power plants 3-4% uranium-235 → critical nuclear reactions Weapons-grade 90% uranium-235 → supercritical nuclear reactions Methods of uranium enrichment • Gas diffusion • (Early method) • • Magnetic separation • (Early method) • • • (Modern method) • Gas centrifuge Laser enrichment (Experimental) Uranium + fluorine →𝑈𝐹6 gas Lighter uranium-235 has a higher velocity at uniform temperatures Faster uranium-235 diffuses more quickly through a membrane Uranium ions enter a magnetic field The magnetic field bends the paths of the ions Lighter ions follow a more curved path Uranium hexafluoride gas is spun in a cylinder Heaver ions flow to outer edge Uranium-235 collects inside • • A stream of ions passes in front of a laser The laser accurately strikes lighter ions, shifting their paths47 • Little energy is spent Fundamentals of fusion In nuclear fusion, two smaller nuclei collide and form a larger nucleus Light nuclei conducting fusion Heavy nuclei conducting fusion Mass of reactants > mass of product Mass of product > mass of reactants Energy is released Energy must be input Example: Deuterium and tritium fuse into helium - 31𝐻 + 21𝐻 → 42𝐻𝑒 + 10𝑛 Mass of reactants: Mass of products: 2.013553 𝑢 ( 21𝐻 ) + 3.015501 𝑢 ( 31𝐻) = 5.029054 𝑢 4.001506 𝑢 ( 42𝐻𝑒) + 1.008665 𝑢 ( 10𝑛) = 5.010171 𝑢 Mass of products – mass of reactants = −0.018883 𝑢 = −17.59 𝑀𝑒𝑉 Electric forces between nuclei create a barrier to fusion called the Coulomb barrier Two nuclei brought very close together have an attractive nuclear force that overcomes the Coulomb barrier Quantum tunneling explains nuclei’s ability to cross the Coulomb barrier 7 Colliding nuclei have temperatures near 10 K In thermonuclear fusion, nuclei collide and form tightly bound nuclei 47 Like chemical combustion, it requires high temperatures to initiate Continuous energy releases sustain both types of reaction Products have less mass, and energy is output Stellar fusion produces energy in stars Their cores are fusion reactors operating at millions of degrees Young stars perform hydrogen fusion, while old stars perform helium fusion 1920 English physicist Arthur Eddington proposed that stars produce energy by combining hydrogen into helium 1934 Australian Mark Oliphant and Ernest Rutherford collide two deuterium nuclei to form helium 1939 Hans Bethe describes the proton-proton chain and the carbonnitrogen-oxygen cycle 1967 Hans Bethe wins the Nobel Prize for describing stellar fusion The Sun converts 657 million tons of hydrogen into 653 million tons of helium per day The Sun is 74% hydrogen and 25% helium by mass 4 tons of energy is released as radiation, light, and the solar wind48 The solar wind is a stream of light particles ejected during fusion A star’s gravity provides the energy for thermonuclear fusion Fusion energy generates pressure outwards Stars need to be hot and dense enough for fusion reactions to occur Light stars conduct a fusion process called the proton-proton chain The Proton-Proton Chain Reaction Energy Output 2 × ( 11𝐻 + 11𝐻 → 21𝐻 + 𝑒 + + 𝑣) 𝑄 = 2 × (0.42 𝑀𝑒𝑉) 2 × ( 11𝐻 + 21𝐻 → 32𝐻𝑒 + 𝛾) 𝑄 = 2 × (5.49 𝑀𝑒𝑉) 3 2𝐻𝑒 Total + 32𝐻𝑒 → 42𝐻𝑒 + 11𝐻 + 11𝐻 𝑄 = 12.86 𝑀𝑒𝑉 4 11𝐻 → 42𝐻𝑒 + 2𝑣 + 2𝛾 + 2𝑒 + 𝑄 = 24.68 𝑀𝑒𝑉 Positrons release more energy after colliding with electrons 2 × (𝑒 + + 𝑒 − → 𝑄); 𝑄 = 2 × (0.511 𝑀𝑒𝑉) = 1.02 𝑀𝑒𝑉 The slowest first step acts as a bottleneck It regulated the conversion rate Heavier stars follow a different process, the carbon cycle (CNO cycle) The CNO cycle converts hydrogen to helium, with no net carbon change CNO stands for carbon-nitrogen-oxygen, the intermediate elements Applications Nuclear reactors Nuclear reactors harvest energy from sustained chain reactions 48 Reactors must control the reaction rate One kilogram of uranium-235 provides the same energy as 20,000 tons of TNT In a reactor, the moderator slows down emitted neutrons The neutrons emitted by reactions have very high kinetic energies around 2 MeV Uranium-235 does not easily absorb fast neutrons Slow neutrons conduct fission with uranium-235 Uranium-238 does not absorb slow neutrons A good moderator absorbs much of the neutron’s energy The moderator should have nearly the same mass as the neutron Moderators with different masses absorb little energy Imagine a ping pong ball bouncing off a billiard ball49 Moderators Hydrogen, 𝟏𝑯 Deuterium, 𝟐𝑯 Theoretically is the best moderator but in practice absorbs neutrons to form deuterium Does not slow neutrons effectively Graphite, 𝟏𝟐𝑪 Slows neutrons without absorbing them Is found in heavy water, replacing hydrogen-1 Is used in first nuclear reactor Slows neutrons after 100 collisions Control rods50 Maintain reactor’s criticality; contain neutron-absorbing boron Reactor startup, K > 1 Reactor operation, K =1 Reactor shutdown, K <1 Rods retracted Rods control reaction rate Rods inserted Enrico Fermi created the first nuclear reactor on December 2nd, 1942 He constructed it on the University of Chicago’s racquet courts51 A pile of graphite bricks surrounded the uranium fuel Cadmium control rods penetrated the reactor core52 A concrete containment chamber surrounds the steel reactor vessel The vessel contains the core, which holds fuel surrounded by a moderator Modern reactors use water for the moderator The fuel usually contains 2-4% uranium-235 and 96-98% uranium-238 Most reactors are a type of light water reactor 49 50 51 52 Light water reactors Heavy water reactors Boiling water Pressurized water Loop of water both cools reactor and powers steam turbine Pressurized cooling loop transfers energy to a secondary loop which generates steam Heavy water moderates neutrons extremely well Radioactive coolant does not enter steam turbine Can induce reactions in unenriched fuel Common in United States Common in Canadian reactors More expensive Employs relatively simple design Coolant flows through the core and absorbs thermal energy Most reactors use water A few use liquid sodium Coolant exiting the reactor boils water to produce steam The steam generates electricity by powering a conventional steam turbine Nuclear reactors have many applications They can generate electricity, including to power ships and submarines They also generate neutrons for research, medical, and industrial use Nuclear reactors generate a significant portion of the world’s energy needs 1951 EBR-153 reactor in Arco, Idaho generates electricity for four light bulbs 1954 Soviet Union connects a nuclear reactor to the power grid 2012 Nuclear power generates 10.9% of the world’s energy 2015 438 reactors operate in 30 countries Breeder reactors Plutonium-239 is useful for nuclear fuels and nuclear weapons Plutonium-239 is not a fission product, but rather forms from uranium-238 Origins of Plutonium-239 Uranium-238 absorbs a neutron without reacting Uranium 239 has a half-life of 23.5 minutes before decaying into neptunium-239 Neptunium-239 performs a second beta decay 238 𝑈 + 1𝑛 → 239 𝑈→ 239 0 −1𝛽 𝑁𝑝 → 53 In World War II, they produced plutonium for nuclear weapons 𝑈 + 239𝑁𝑝 0 −1𝛽 Breeder reactors generate plutonium-239 239 + 239𝑃𝑢 Less effective moderators increase the number of neutrons in the reactor Liquid sodium leaves neutrons with high kinetic energy These neutrons react with uranium-238 to form plutonium-239 Some breeder reactors generate more fuel than they consume Breeder reactors have decreased since the 1980s and halted in the United States There is nothing wrong with the uranium fuel supply It has not been substantially depleted However, breeder reactors produce the fuel for nuclear weapons Governments fear the proliferation of weapons-grade nuclear fuel In addition, breeders are expensive and complex Nuclear power challenges Nuclear reactors produce hazardous radioactive wastes54 Some wastes have very long half-lives and stay hazardous for a long time Plutonium-239 has a half-life of 24,000 years These wastes must be contained safely as long as they remain dangerous Some fission products decay away quickly and can be stored temporarily Nuclear reactors must be decommissioned after 30 years of operation Radioactivity builds up on the reactors components Structural materials degrade after prolonged exposure to ionizing radiation Old reactors must be completely dismantled and radioactive materials removed This process is very expensive Nuclear reactors still hold many advantages over coal, oil, and natural gas plants55 Coal power plants release many greenhouse gases and expose workers to radon Nuclear power plants only release water vapor, which converts to snow and rain Nuclear plants release very little radiation, an average of 0.1 mSv per year This amount equals 0.003% of the average annual background radiation 1 It also constitutes the radiation from one chest x-ray 200 The United States produced 1/3 of the world’s nuclear energy in 2013 Nuclear power provided 19.5% of the country’s energy in 2014 In contrast, France generates 75% of its electricity through nuclear plants No new plants have been developed in the United States since the 1970s Political and economic forces have halted the building of new power plants Although the risk from nuclear power plants is small, accidents are high-profile and alarming Nuclear power plants are very expensive to build The United States still builds new reactors to add to existing plants Accidents can be meltdowns or explosions In meltdowns, the nuclear fuel overheats and melts through its containment Explosions occur due to over-pressurized coolant The Three Mile Island5657 incident occurred on March 29, 1979 in Pennsylvania 54 55 56 57 Three Mile Island Accident Water pump shuts down Secondary coolant loop stops circulating Reactor shuts down but still generates heat Secondary loop boils off, leaving only primary loop Primary loop overheats and overpressurizes Water floods the containment structure and is pumped outside Though it was the worst accident in United States history, it had no impact on public health The Chernobyl incident occurred on April 26th, 1986 in the former Soviet Union This was the worst nuclear accident in history A sudden power surge ruptured the reactor vessel, causing a large explosion Its radioactive cloud had 400 times more radiation than the Hiroshima bomb Thirty people died and hundreds of thousands had to evacuate58 Such a disaster could not occur in the United States, as it uses different plant designs On March 11th, 2011, the Fukushima Daiichi nuclear accident occurred in Japan It stands as the worst accident since Chernobyl Fukushima Daiichi Nuclear Accident 9.0 earthquake forces reactor to shut down Control rods drop down into the core Cooling reactors need supply of coolant Tsunami cuts power to the primary and secondary coolant pumps Reactors melt down and explode 500,000 residents evacuated A 2013 report finds that evacuated civilians suffered no health effects All 54 Japanese nuclear plants shut down Generation IV reactors will be constructed from 2030 These reactors minimize waste, increase safety, and impede nuclear proliferation Nuclear weapons Weapons research drove nuclear science in the 1940s Nuclear weapons release nuclear energy rapidly in supercritical (K >1) reactions They release energy on the order of 1 to 500,000 tons of TNT The critical mass refers to the minimum mass of fissile fuel in a nuclear weapon59 In uranium-235, the critical mass forms a 6.8 cm diameter sphere The Nagasaki bomb used another common fuel, plutonium-239 58 59 Below the critical mass At the critical mass Above the critical mass Neutrons escape fuel before colliding with a nucleus Every fission causes one more fission The reaction rate increases exponentially Nuclear fuel remains below critical mass until detonation At detonation, conventional explosives bring the pieces together Early weapons used a gun-type design An explosive fires half of the mass at the other down a barrel Modern implosion-type weapons use a sphere of explosives to compress the fuel Applications of fusion Thermonuclear weapons and hydrogen bombs release energy in nuclear fusion The fusion bomb originated in the Manhattan Project Hungarian Edward Teller suggested a fission bomb could trigger a fusion bomb In 1951, Teller and Stanislaw Ulam designed a fusion bomb Teller became known as the “father of the hydrogen bomb” The first fusion bomb detonated in 1952, using Teller’s multistage design Fission charges compress fission and fusion fuel, detonating the primary bomb The primary stage compresses and detonates a secondary fusion bomb It released 10.4 megatons of energy, 450 times more than the Nagasaki bomb The largest hydrogen bomb ever built was the Tsar Bomba th The Soviet Union tested this weapon on October 30 , 1961 It had the same energy as 50 million tons of TNT60 Scientists have been trying to harness power from fusion reactions for 50 years Potential fusion reactions for power generation must satisfy certain criteria Criteria Components (1) Must be exothermic (2) Must conserve proton and neutron number (1) Light nuclei with minimal Coulombic repulsions (2) Two reactants to maximize collision probability (3) At least two products to conserve momentum Fusion reactions with deuterium and tritium are candidates for power generation However, hydrogen is optimal for use in nuclear fusion It is the most plentiful element and all isotopes appear in water Potential fusion reactions Reaction Energy output 2 1𝐻 + 21𝐻 → 32𝐻𝑒 + 10𝑛 2 1𝐻 𝑄 = 3.27 𝑀𝑒𝑉 + 21𝐻 → 31𝐻 + 11𝐻 61 𝑄 = 4.03 𝑀𝑒𝑉 1 gram in every 30 liters of sea water, Deuterium provides same energy as 10,000 liters of gasoline Tritium 60 61 Low natural abundance; half-life of 10 years 2 1𝐻 + 21𝐻 → 42𝐻𝑒 + 10𝑛 𝑄 = 17.59 𝑀𝑒𝑉 World’s deuterium supply contains more energy than its fossil fuel plus uranium supplies Synthesized by breeding lithium-6 6 1 3 4 3𝐿𝑖 + 0𝑛 → 1𝐻 + 2𝐻𝑒 Fusion reactors have many advantages over fission reactors Fusion reactors cannot melt down as the reaction cannot become supercritical Reaction products are not used in subsequent reactions Fusion produces no pollution or radioactive waste, only helium Fusion energy requires extremely high temperatures In the sun, fusion occurs at over 10 million K These extremely high temperatures are the greatest barrier to fusion energy62 Fusion reactors must be self-sustaining at ignition, like fission reactors The energy released by a reaction can power subsequent reactions Scientists have not yet been able to achieve ignition Reactors must compress nuclei to extremely high densities to increase reactions Electrons separate from nuclei in atoms above their ionization energies The cloud of positive nuclei and negative electrons forms a plasma Most structural components would vaporize at these temperatures and densities Lawson’s Criteria Deuterium-tritium fusion 𝑛𝜏 ≥ 1014 𝑠 𝑐𝑚3 𝑛 = plasma ion density Deuterium-deuterium fusion 𝑛𝜏 ≥ 1016 𝑠 𝑐𝑚3 𝜏 = plasma confinement time In 1957, J.D. Lawson devised conditions for fusion power generation Two methods exist for generating and sustaining fusion In magnetic confinement, electromagnets trap high-temperature plasmas A strong magnetic field bends the paths of ions in the plasma cloud Magnetic confinement systems trap moving ions in a “magnetic bottle” Tokamaks are toroidal containment devices with two magnetic fields They trap the plasma in a ring shape The Soviet Union developed the tokamak after World War II Magnetic confinement aims to sustain nuclei at high temperatures Inertial confinement fusion (ICF) systems use laser beams to compress atoms A laser array compresses a target pellet containing deuterium and tritium The pellet ionizes into a plasma −9 Less than 10 seconds later, the particle reaches 108 K and fusion occurs ICF systems prevent nuclei from drifting apart by forcing them together quickly The National Ignition Facility63 is the world’s largest ICF device It lies in Lawrence Livermore National Laboratory in Livermore, California The NIF targets a 2mm hydrogen pellet with the world’s most powerful laser In 2012, the NIF shot a 500 trillion watt laser pulse This pulse has 1,000 times more energy than the United States uses in an instant At break-even, the energy output exceeds the energy needed to trigger fusion Princeton’s Tokamak Fusion Test Reactor tried to achieve this point but failed It heated plasma to over 200 million K, above hydrogen’s ignition temperature 62 63 The TFTR operated from 1982 and shut down in 1997 after 15 years The Joint European Torus (JET) is another tokamak design that operates today The world’s largest experimental fusion system is the ITER in France ITER originally stood for International Thermonuclear Experimental Reactor The European Union, India, Japan, Korea, China, Russia, and the United States collaborated on this project ITER uses a magnetic confinement system, hoping to prove its feasibility It will finish construction in 2027 and run deuterium-tritium fusion experiments The Manhattan Project Background In the decades after World War I, Italy and Germany fell under fascist rule Italy’s Benito Mussolini and the Nazi Party’s Adolf Hitler led their respective countries The two allied countries carried out racial discrimination and genocidal policies Germany’s invasion of Poland in September 1939 started World War II Enrico Fermi and Leo Szilard fled to the United States in 1939 Leo Szilard had first conceived of the nuclear chain reaction in 1933 He warned Franklin Delano Roosevelt that Germany might be researching nuclear weapons He proposed that the United States follow suit and also stockpile uranium Szilard signed the letter with Einstein’s name to attract more attention Einstein, a German-born Jew, also worried about Nazi Germany When Hitler became chancellor in 1933, Einstein chose to stay in the United States Einstein was a pacifist and opposed creating nuclear weapons He shared Szilard’s concern about German research into nuclear weapons In response to Szilard’s letter, Roosevelt created the Advisory Committee on Uranium National Bureau of Standards director Lyman Briggs chaired the committee It had the task of recommending how to proceed with nuclear research On November 1, 1939, it reported that the United States should support Fermi and Szilard’s research in chain reactions The United States purchased $6,000 of uranium oxide and graphite64 At the time, Fermi believed that nuclear reactors were possible, but not bombs Pilot research Vannevar Bush pushed for research on nuclear weapons Bush was a science administrator and president of the Carnegie Foundation He could influence United States policy in his position By 1940, he was concerned about German expansion He noticed a lack of cooperation between researchers and the military In June 1940, Bush became the chair of the National Defense Research Committee 64 Roosevelt approved this committee in less than 15 minutes This committee oversaw research and development of nuclear weapons The S-1 subcommittee studied uranium enrichment It included Ernest O. Lawrence, director of the Radiation Laboratory65 at the University of California, Berkeley He had invented the cyclotron, a particle accelerator and mass spectrometer As a mass spectrometer, it could separate uranium-235 from uranium-238 The S-1 committee needed to produce a critical mass of uranium-235 Nobody knew if the critical mass was small enough to fit on a bomber The committee explored gaseous diffusion, centrifuge separation, and electromagnetic separation as enrichment methods Simultaneously, Great Britain developed its own nuclear weapons program They estimated the critical mass to be on the order of 10 kg Its representative, physicist Mark Oliphant, visited the United States in August 1941 to help and assess the American program He encouraged the American researchers by sharing British research with them By 1941, the atomic bomb seemed to be possible th Roosevelt and his Vice President Henry Wallace met on October 9 , 1941 with Vannevar Bush Bush summarized the progress of American and British research Roosevelt asked Bush to estimate the cost of an atom bomb President Roosevelt wanted the US Army to manage bomb construction th Japan attacked Pearl Harbor on December 7 , 1941 The United States declared war on Japan the next day Starting production In March 1942, Bush informed Roosevelt that Lawrence’s cyclotron had successfully refined uranium “I think the whole thing He believed that a bomb would be complete by should be pushed not only in 1944 regard to development, but Roosevelt shared his concerns in a response (right) also with due regard to time. In May 1942, Arthur Compton asked J Robert This is very much of the Oppenheimer to perform calculations for the chain essence.” - FDR reaction Oppenheimer worked at the University of California, Berkeley66 He formed a team with Hans Bethe, John Van Vleck, Edward Teller, Felix Bloch, Emilio Segre, and Robert Serber They found they needed double the amount of fission fuel previously estimated However, they confirmed that a fission weapon could be built In June 1942, the S-1 committee researched fuel enrichment Vannevar Bush allocated $85 million for constructing enrichment plants Three plants were built to enrich uranium, and one more for plutonium The United States stockpiled uranium on Staten Island It stored 12,000 tons of uranium ore from Colorado and Canada 65 66 Fermi created a chain reaction at the University of Chicago on December 2, 1942 The S-1 committee then finalized plans for bomb development Roosevelt agreed to the proposals and allocated $500 million for the project The Manhattan Project The Army Corps of Engineers managed bomb production On August 13, 1942, they set up an office in Manhattan, New York The office became the Manhattan Engineer District, or The Manhattan Project General Leslie R. Groves became the project’s director in September 1942 He came from the Army Corps of Engineers, where he had worked on the Pentagon Groves drew criticism for his abrasive and critical personality His focused, goal-oriented management helped the project meet crucial deadlines Groves selected Oppenheimer as the leader of Project Y on July 20th, 1943 Project Y referred to the Manhattan Project’s weapons development lab Ernest Lawrence and Arthur Compton were too busy to serve as director Compton suggested Oppenheimer Oppenheimer’s mastery of science and engineering concepts impressed Groves Others opposed this choice Oppenheimer had not won a Nobel Prize and lacked administrative experience His wife Kitty and brother Frank had communist sympathies The Manhattan Project’s primary enrichment plant lay at Oak Ridge, Tennessee In October 1942, the Army Corps of Engineers purchased 60,000 acres of land It named the land Clinton Engineer Works in January 1943 Oak Ridge was a city founded to house the tens of thousands of new employees It was Tennessee’s fifth largest city in 1945 The Oak Ridge plant contained many small facilities Construction of the world’s second nuclear reactor started on February 2, 1943 The X-10 Graphite Reactor first operated on November 4, 1943 The Y-12 electromagnetic separation plant separated uranium isotopes This enrichment method based on the cyclotrons was inefficient but low-risk The K-25 gaseous diffusion plant performed enrichment with gaseous diffusion It was one of the largest single-roofed buildings in the world At the time, gaseous diffusion had not been demonstrated to work It required a barrier that could separate isotopes by their average speeds The enrichment level of this plant steadily increased as the years went by The S-1 committee rejected the centrifuge method, so no such plants were constructed Tests at the X-10 reactor showed that a full-scale reactor was needed to produce plutonium Groves hired the DuPont chemical company to construct the plant DuPont had worked on various war contracts and operated reactors Since Oak Ridge was close to Knoxville, DuPont decided to construct the plant on the Columbia River in Washington state Knoxville was a populated city Groundbreaking at the Hanford Engineer Works occurred in March 1943 The B-Reactor at Hanford was the world’s first large plutonium generator Construction started in October 1943 In September 1944, criticality was achieved Los Alamos In 1942, scientists worked on the Manhattan Project from across the country The project’s administration decided to form a centralized laboratory Oppenheimer wanted the laboratory to be in a remote location General Groves founded Site Y in northern New Mexico in 1943 It lay near the Los Alamos Ranch School, 30 miles northwest of Santa Fe The secret location had a mailing address at a P.O. box in Santa Fe Today, Site-Y is known as Los Alamos National Laboratory In 1943, Oppenheimer recruited scientists from across the nation to join Los Alamos His hires included “Berkeley Luminaries” Hans Bethe and Edward Teller Many of the scientists had won Nobel Prizes Richard Feynman and Emilio Segre would win Nobel Prizes later Albert Einstein never joined the Manhattan Project He had to create a detonation mechanism that could rapidly reach supercritical mass Subcritical masses might produce smaller explosions and blow apart the material In this case, the bomb pre-detonates, or “fizzles” Two types of detonation mechanisms were proposed At first, engineers designed a gun-type plutonium bomb They dubbed it the “Thin Man” due to its unusual shape The first shipment of plutonium arrived at Los Alamos in April 1944 from X-10 Emilio Segre realized that reactor-bred plutonium had more impurities than cyclotronmade plutonium It contained too much plutonium-240, which tends to start the chain reaction too early and fizzle out Mathematician John von Neumann proposed an implosion-type weapon in September 1943 He relied on earlier work by physicist Seth Neddermeyer Although more complex, it brought the fuel together more quickly In 1944, Oppenheimer instructed researchers to abandon the gun method On August 7th, 1944, General Groves announced that an implosion bomb would be completed by spring 1945 A uranium gun-type bomb would be finished later in August 1945 The team planned a full-scale test outside Alamogordo, New Mexico Groves only approved the test after assuring that the nuclear material would be recovered if the bomb fizzled Oppenheimer named the test “Trinity” after a poem by John Donne67 “We knew the world would not The bomb, nicknamed the “gadget”, used be the same. A few people Hanford B plutonium laughed, a few people cried, A 100-foot-tall tower suspended the bomb to most people were silent.” produce maximum power – Oppenheimer, on reactions to Energy from a midair detonation would the Trinity test expand in a sphere Observers sat in bunkers 10,000 yards north, west, and south of the tower The Trinity test occurred at 5:30 am on July 16th, 1945 The bomb released the same energy as 20,000 tons of TNT A mushroom cloud rose 7.5 miles into the air The bomb left a crater 5 feet deep and 30 feet across The steel tower was completely destroyed68 Nuclear Weapons and International Security Atomic bombing of Japan Roosevelt unexpectedly died in office on April 12, 1945 Harry Truman replaced him just three months after becoming Vice President He did not know of the Manhattan Project General Groves and Secretary of War Henry Stimson discussed the deployment of the bomb with Truman on April 25 By this time, the Allies had the upper hand in the war against Japan Nazi Germany surrendered on May 8 The Americans and British planned to invade Japan on November 1 1945 However, the invasion would have cost millions of casualties On July 26, Allied leaders presented the Potsdam Declaration to Japan Japan rejected the declaration’s terms of surrender In July, Leo Szilard and 70 scientists signed a petition against using the bomb Secretary of State James Byrnes prevented Truman from seeing the petition Ernest Lawrence wanted the military to publicly demonstrate the bomb He reasoned that the show of power would compel Japan to surrender However, a failed test would only encourage the Japanese to keep fighting Only two bombs had been produced after two years and billions of dollars It would also remove the element of surprise Japan might move prisoners of war to bombing targets The Scientific Advisory Panel rejected the proposal It concluded that direct military use of the bomb remained the only option Hiroshima and Nagasaki were selected as targets in summer 1945 Hiroshima was a major port and housed military headquarters It had not been hit with air raids, so the bomb would have a more striking effect 67 68 Manufacturing centers Kyoto and Yokohama were also considered Because Kyoto had historical significance as the former capital, it was rejected69 The seaport and industrial center Nagasaki replaced Kyoto On August 6th, 1945, the United States dropped an atom bomb on Hiroshima The bomb nicknamed “Little Boy”70 used a gun-type uranium design The bomb leveled five square miles of the city and killed 140,000 people It released the energy of 15,000 tons of TNT The blast sparked firestorms that burned anything not destroyed by the blast A radiation flash permanently burned shadows of people and objects onto walls It etched clothing patterns into skin The bomb killed or disabled 90% of Hiroshima’s medical personnel President Truman announced the bombing to the American public over radio He reasoned that this bomb would “shorten the agony of war” If Japan did not surrender, he warned, the United States would drop another bomb The United States accordingly dropped a second bomb on Nagasaki on August 9th This bomb, named “Fat Man”, was an implosion-type plutonium bomb It resembled the Trinity Test’s bomb, releasing 21,000 tons of TNT Nagasaki’s geography limited the damage to 3 square miles, killing 74,000 people Japan finally surrendered on August 15th nd The formal surrender occurred on September 2 onboard the USS Missouri American nuclear research after 1945 By 1945, the Manhattan Project rivaled the American automotive industry in scale It employed 130,000 people and cost $2 billion dollars, or $26 billion in 2015 values Many employees did not even know they were working on an atomic weapon The National Laboratories set a standard for federally-funded research Oak Ridge director Alvin Weinberg termed the federally funded lab system “Big Science” Many reporters predicted that atomic power would transform life after the war New York Times journalist William Lawrence termed the period the atomic age He had personally witnessed the Trinity Test and the bombing of Nagasaki Lewis Strauss thought that electricity would become “too cheap to meter” Newspapers and magazines imagined atomic cars and atomic medicine The United States did not know if the atomic program should remain controlled by the military In October 1945, Congress debated the May-Johnson Bill According to this proposal, the military would continue managing the program Fermi and Oppenheimer supported the bill, while Szilard opposed it In December 1945, the May-Johnson Bill was replaced by the McMahon Bill This bill gave control of the program to civilians President Truman signed it into law as the Atomic Energy Act of 1946 The United States Atomic Energy Commission (AEC) took over the nuclear research program from the army on January 1st, 1947 Five civilians sat on the board of the AEC It established the National Laboratory system and continued weapons testing 69 70 The Nuclear Regulatory Commission and the Energy Research and Development Administration replaced the AEC in 1974 In 1977, Jimmy Carter established the US Department of Energy This agency still manages the United States’ nuclear weapons and energy programs Nuclear arms race The United States and Soviet Union became rival superpowers after World War II American scientists predicted that the Soviet Union would develop an atomic bomb in the 1950s The Soviet Union surprised the world by detonating one on August 29, 1949 The superpowers rapidly grew their stockpiles of nuclear weapons Children learned to perform “duck and cover” drills to prepare for nuclear war71 The next step in atomic escalation involved thermonuclear weapons Oppenheimer publicly opposed thermonuclear weapons The United States tested a hydrogen bomb on November 1, 1952 in the Pacific The Soviets followed suit in August 1953 If either superpower attacked, both sides would be annihilated This situation has become known as mutually assured destruction (MAD) Atoms for Peace The postwar scientific community experienced rifts and regret The United States found out that Germany had not pursued nuclear weapons72 Many scientists had joined the project for the purpose of pre-empting Germany Albert Einstein deeply regretted starting the Manhattan Project In 1947, he told Newsweek that he would not have acted had he known Germany would not develop the bomb Oppenheimer told President Truman, “I feel I have blood on my hands” He pushed for an international nuclear oversight organization However, neither superpower wanted to give up nuclear weapons73 Supporters of disarmament came under suspicion as communist sympathizers AEC commissioner Lewis Strauss tried to discredit Oppenheimer After months of hearings, he had Oppenheimer’s security clearance revoked Scientists worked to warn against nuclear weapons while also gaining support for atomic energy Einstein founded the Emergency Committee of Atomic Scientists (ECAS) in 1946 This group included Leo Szilard and Hans Bethe They presented and published information promoting peaceful atomic uses In 1945, Eugene Rabinowitch co-founded the Bulletin of the Atomic Scientists This non-technical magazine on nuclear weapons exists today as a public reference on global nuclear issues74 The Bulletin has published the Doomsday Clock since 1947 The Doomsday Clock measures how close we are to atomic apocalypse 71 72 73 74 Progress of the Doomsday Clock Period Minutes from midnight 1947 Height of Cold War Thawing of Cold War January 2016 7 2 17 3 Eisenhower moved American policy towards peaceful applications of nuclear energy From MAD to Atoms for Peace 1953 Eisenhower’s December 8 “Atoms for Peace” speech at United Nations 1954 Atomic Energy Act of 1954 partially repeals 1946 Act; allows civilian nuclear power plants 1957 United Nations creates International Atomic Energy Agency (IAEA) to promote atomic energy and prevent weaponization 1950s60s Great Britain, France, and China develop nuclear weapons, but have much smaller stockpiles than the superpowers 1969 Jul 1: United States, Soviet Union, and 60 nations sign Nuclear Non-proliferation Treaty barring countries from acquiring nuclear weapons 1978 Carter signs Nuclear Non-Proliferation Act preventing the spread of weapons material but allowing foreign countries to acquire fuel for energy production All numbers in parentheses refer to the page numbers of the USAD Resource Guide where you can find the original context of the defined term. TERMS Absorption spectrum (13) Set of wavelengths absorbed by an atom (5) Aether Invisible medium that fills the universe; philosophical substance; does not exist vapor (40) Alcohol Substance used in cloud chambers particle (31, 35, 38, 43) Alpha Positively charged decay particle; equivalent to a helium-4 nucleus; can be blocked by paper; travels at 5% of the speed of light; blocked by skin; ionizing radiation momentum (15) Angular Property of the electron which Bohr quantized, modifying the Rutherford planetary model (7) Anode Positively charged end of a cathode ray tube; receives an invisible beam from the anode Antennae (10) Objects representing atoms; emit thermal radiation according to classical physics Antineutrino (37) Antiparticle of the neutrino; released in beta minus decay Antiparticle (36) Relation between the electron and positron anemia (34) Aplastic Illness caused by radiation exposure; ended Marie Curie's life spectroscopy (13) Atomic Use of spectral lines to determine a sample's chemical composition; used in 1868 to discover helium on the sun (5) Atomos Greek word for "unable to be cut" (5) Atoms Tiny units of matter; basic building blocks of the universe Background radiation (43) Naturally occurring radiation; affects everyone; mostly from radon series (16) Balmer Set of hydrogen's spectral lines caused by transition to the n=2 energy level Betaparticle (35) Less massive decay particle; can be stopped by aluminum Big Science (68) Model for federally funded research, as described by Alvin Weinberg Bose-Einstein condensate (25) New state of matter composed of particles with integer spin; created in 1995 by Carl Wieman and Eric Cornell via laser cooling (25) Bosons Particles with integer spin; unaffected by Pauli exclusion principle Break-even (59) Point at which energy output equals input in fusion reactions Cathode (7) Negatively charged end of cathode ray tube; emits invisible beam Cathode ray (7) Beam of electrons produced by cathode ray tube; travels from the cathode to the anode Chernobyl accident (54) Worst nuclear power incident in history on April 26, 1986 in the Soviet Union; released 400 times more radiation than Hiroshima (23) Cloud Metaphor for arrangement of electrons in the Schrödinger model Coherent (26) Property of laser light; light waves travelling in phase; creates good interference patterns Corpuscule (6) Theoretical infinitely divisible particles proposed by Isaac Newton rays (43) Cosmic High energy radiation originating from outside the solar system (49) Critical Situation with constant number of fission events; K = 1 (34) Crystals Subject studied by Pierre Curie before joining his wife's research (5) Cube Shape associated with earth by Plato Daughter nucleus (36) Nucleus produced by radioactive decay Deterministic (22) A Newtonian view of the world Diamagnetic (24) Materials composed of paired electrons; repelled by magnetic fields Directional (26) Property of laser light; light travelling in a uniform direction DNA(43) Cellular component damaged by ionizing radiation; contributes to mutations, disorders, and cancer Electromagnetic spectrum (9) Range of all possible electromagnetic waves Electron (7, 14, 20) Negatively charged cathode ray particle 1800 times lighter than hydrogen; atomic component; discovered by J.J. Thomson; resides at quantized energy levels; releases energy when moving down a level; used in transmission and scanning electron microscopes Emission spectrum (13) Set of wavelengths emitted by excited electrons Endothermic (47) Reaction which consumes energy; Q < 0 state (16) Excited Energy levels above the ground state Exothermic (47) Reaction which releases energy; Q > 0 Fermion (24) Particles with half-integer spin; includes electrons; two of these cannot occupy the same quantum position Ferromagnetic (24) Materials with at least one unpaired electron; includes iron and nickel; loses magnetic properties above the Curie temperature (47) Fissile Nuclei that perform fission after colliding with low-energy neutrons products (47) Fission Output of a fission reaction Fissionable (48) Nucleus that only performs fission with fast neutrons Freeradical (43) Neutral atom with unpaired electrons; created by radiation; forms harmful compounds in the body Fukushima Daiichi nuclear accident (54) Nuclear disaster following an earthquake on March 11th, 2011; forced evacuations of the surrounding area ignition (58) Fusion Point at which a fusion reaction becomes self-sustaining particle (35, 43) Gamma Photon decay particle; high energy; can only be stopped by lead plating; most destructive to life Graphite (51, 61) Moderator in first nuclear reactor; made of carbon-12; purchased in the early days of atomic research state (15) Ground Lowest allowable energy state of an atom or particle water (51) Heavy Water with two molecules of deuterium instead of hydrogen; used as a moderator in Canadian reactors Ionizing radiation (42) Radiation with enough energy to remove electrons from atoms; energy > 10 eV; includes X-rays, gamma rays, UV light, alpha particles, beta particles, and decayed neutrons Icosahedron (5) Shape associated with water by Plato Isotopes (30) Atoms with the same number of protons but different numbers of neutrons; means "the same place" in Greek series (16) Lyman Set of hydrogen's spectral lines discovered from 1906 to 1914 Magnetic moment (24) Property of the electron; measures tendency to align with a magnetic field Magnetic resonance imaging (34) Using power magnetics and radio waves to perform diagnostic imaging of patients Moderator (50) Component of a nuclear reactor; surrounds the nuclear fuel and slows down fast neutrons Monochromatic (26) Property of laser light; light of a uniform frequency (40) Muon Particle discovered in a cloud chamber NaI (40, 45) Crystal used in scintillation counters; ingested by patients when using radioactive tracers Neutrino (37, 43) Particle released in beta plus decay; first observed in 1950; has no electric charge and very little mass; does not interact with matter Neutron (29) Electrically neutral particles in the nucleus; a type of nucleon; proposed in 1920 by Ernest Rutherford Non-ionizing radiation (42) Radiation without enough energy to remove electrons from atoms, e.g. radio waves, microwaves, infrared, and visible light physics (29) Nuclear Study of the structure and behavior of the atomic nucleus Nucleon (29) Particle in the nucleus; proton or neutron Nucleus (7) Dense central core of the atom; contains protons and neutrons; positively charged Paramagnetic (24) Materials composed of unpaired electrons; have an overall magnetic moment nucleus (36) Parent Nucleus performing radioactive decay Paschen series (16) Set of hydrogen's spectral lines discovered in 1908 (13) Photon Particle form of light; first proposed by Albert Einstein; massless, yet still carries momentum Pitchblende (34) Mineral which contains uranium; studied by Marie Curie (58) Plasma Collection of superheated atoms represented by a cloud Positron (36, 40) Antiparticle of the electron; same mass as electron but opposite charge; very short lifetime outside of a vacuum; discovered in a cloud chamber Primordial isotopes (44) Isotopes created with the Earth; includes uranium-238 Probabilistic (22) A quantum view of the world Probability density (20) Field of probabilities where a particle may reside' (29) Proton Positively charged particle in the nucleus; a type of nucleon Psi (20) Greek letter denoting wave functions Quantum (11) A discrete, fundamental unit of energy Quantum mechanics (19) Field of physics which provided a unified explanation for quantum effects; rose in prominence after 1925 Radiation therapy (43) Using targeted ionizing radiation to kill cancerous cells Radioactive waste (52) Harmful radioactive fission products of uranium-235 Radiometric dating (44) Using the half-life of isotopes in a substance to determine its age; developed by Willard Libby in the 1940s Subcritical (49) Situation of decreasing number of fission events over time; K < 1 Sunburn (43) Radiation damage caused by exposure to ultraviolet radiation from the sun Supercritical (49) Situation in which the number of fission events increases exponentially with time; K > 1; used in nuclear weapons Thermal radiation (10) Radiation emitted by objects above 0 K; generally felt as infrared radiation Mile Island accident Three (53) Nuclear accident on March 28 1979 in Pennsylvania; worst nuclear accident in American history but did not have any health impacts Torbernite (34) Mineral containing uranium; studied by Marie Curie (45) Tracer Radioactive substance used to track how chemicals participate in reactions and flow through a system Uranium hexafluoride (50) Gas used in gas diffusion enrichment (34) X-rays High energy rays named by Wilhelm Roentgen for their unknown nature Units and Constants mass number (29) Atomic A; total number of neutrons and protons in the nucleus number (29) Atomic Z; the number of protons in the nucleus; indexes the elements Becquerel (39) Standard unit of radioactivity since 1975; 1 decay per second energy (32) Binding Energy required to split a nucleus apart into neutrons and protons; indicates the stability of an atom; peaks around Z=56 Bohrradius (15) 0.0529 nm; radius of ground state electron orbit in hydrogen atom of the proton (29) Charge 1.6 × 10−19 coulombs mass (54) Critical Minimum mass of fissile material for a chain reaction; for weapons-grade uranium-238, a sphere 6.8 inches in diameter temperature (24) Curie Upper limit at which ferromagnets have magnetic properties temperature (39) Curie Standard unit of radioactivity until 1975; 3.7 × 10−10 decays/s constant (38) Decay λ; corresponds to speed of decay for an isotope rate (39) Decay Also known as radioactivity; decays per second Electron volt (15) 1.6 * 10^-19 J; energy of an electron accelerated by a 1 volt potential difference level (14) Energy A specific, quantized, stable orbit of the electron Femtometer (30) 10−15 meters; the approximate radius of a nucleus (30) Fermi See femtometer Frequency (9) Speed of oscillation of a wave; measured in hertz (39) Half-life Time for half of a sample of an isotope to decay; quantifies atomic stability (9) Hertz Measures frequency of waves; equal to 1 oscillation per second Ionization energy (16) Energy required to completely remove an electron from an atom; for hydrogen, 13.6 eV numbers (33) Magic Recurring numbers of neutrons and protons which contribute to stability; 2, 8, 20, 28, 50, 82, 126 Momentum (13) Property of objects with mass and photons Multiplication factor K (49) Average number of neutrons released in a fission event that will trigger another fission event; controls criticality Nanosecond (12) Delay before electron ejection in the photoelectric effect Neutron number (29) N; the number of neutrons in the nucleus magnetic quantum Orbital number (24) 𝑚𝑙 ; can be integer values from -l to +l; associated with the Zeeman effect quantum number Orbital (24) 𝑙 ; can be non-negative integer values constant (11) Planck's 6.63 × 10−34 Joule seconds; central in quantum mechanics Principal quantum number (24) See quantum number (46) Q value The energy released by one nuclear reaction event; the difference in mass between products and reactants Quantum number (15, 23) Index of electron energy; only positive integers; represented by n atomic mass (29) Relative Mass number listed on periodic tables; average mass of all isotopes of an element weighted by abundance Rem(42) Measure of dosage commonly used in the United States; equals 1/100 sievert Rydberg constant (14) 1.097 × 107 𝑚−1 (27) Second Unit defined in 1967 as the time of 9,192,631,770 oscillations of cesium-133 through its energy states; most accurate SI unit (42) Sievert Measures dosage of ionizing radiation; represents the effect of 1 joule of radiation on 1 kg of absorbing material Spinquantum number (24) 𝑚𝑠 ; for electrons, can be +1/2 or -1/2 Temperature (27) Measures a substance's kinetic energy Threshold energy (47) Minimum kinetic energy required for an endothermic reaction mass unit (29) Unified u; 1/12 the mass of a carbon-12 atom; the mass of one proton or one neutron; 1.66 ∗ 10−27 kg Wavelength (9) Distance between successive peaks in a wave Equations mass number (29) Atomic A; total number of neutrons and protons in the nucleus decay reaction (36) Alpha → Betanegative decay reaction (36) 𝐴 𝑍𝑋 𝐴 𝑍𝑋 → 𝑍−4 𝑍−2𝑌 𝐴 𝑍+1𝑌 Betaplus decay reaction (36) 𝐴 𝑍𝑋 → 𝐴 𝑍−1𝑌 de Broglie hypothesis (17) 𝜆= rate equation (39) Decay 𝑅 = 𝑅0 𝑒 −𝜆𝑡 Differential wave equation (19) Classical equation; describes behavior of macroscopic waves Einstein's relation (29, 32) 𝐸 = 𝑚𝑐 2; explains mass difference between nucleon and nuclear weights levels in hydrogen Energy (15) 𝐸𝑛 = 13.6 Exponential decay (38) 𝑁 = 𝑁0 𝑒 −𝜆𝑡 decay reaction (37) Gamma 𝑋∗ → 𝑋 + 𝛾 Halflife equation (39) 𝑡ℎ = + 42𝐻𝑒 + 𝑒− + 𝑒+ ℎ 𝑝 ln 2 𝜆 𝑒𝑉 𝑛2 Heisenberg uncertainty principle (23) Δ𝑥Δ𝑝 ≥ 2𝜋 ; stipulates that momentum and position of a particle Lawson’s criterion (58) nτ > some number for plasma to occur; n = plasma ion density; t = plasma confinement time Newton's laws of motion (19) Classical laws; describe the behavior of macroscopic particles notation (29) Nuclear 𝐴 𝑍𝑋; relationship (11) Planck's 𝐸 = 𝑛ℎ𝑓; relationship between energy of an oscillating particle and its frequency of electrons in Radii hydrogen (15) 𝑟𝑏 = 𝑛2 𝑎0 of the nucleus (30) Radius Schrödinger equation (19) 1925 description of matter waves’ behavior; cannot be derived from fundamental equations: purely based on experimental results The Rydberg formula (14) 1 ℎ cannot both be known A = mass number; Z = atomic number 1 𝑟 = 𝑟0 𝐴3 𝜆 = 𝑅𝐻 ( 1 𝑚2 hydrogen functions (20, 23) Wave − 1 𝑛2 ); describes the wavelengths of spectral lines in Solutions to the Schrödinger equation; labeled by the Greek letter psi; describes electrons in the Schrödinger model Elements and Isotopes Actinium (39) Element which can enter a decay chain Aluminum (27) Element used in atomic clocks Americium-231 (44) Isotope in smoke detectors; alpha-decays into neptunium-1237 (44) Argon Element used in radiometric dating (48) Barium Half as massive as uranium; bombarded by Otto Hahn and Fritz Strassman; can be produced in fission of uranium-235 Beryllium (31) Discovered ca. 1930; emits radiation if struck with alpha particles Bismuth-212 (39) Isotope produced in decay chain of thorium (51) Boron Neutron-absorbing material used in control rods Californium (31) All isotopes heavier than this element do not occur naturally Carbon-12 (29, 51) Isotope used to define the unified mass unit; found in graphite Carbon-14 (36, 44) Isotope which decays into nitrogen-14 through beta decay; measured in radiometric dating Cesium-133 (27) Isotope used in atomic clocks; defines the second in the SI system Cobalt-60 (43) Isotope used in food irradiation Deuterium (31, 50, 58) Isotope of hydrogen with a proton and neutron; useful moderator; used in fusion; found in seawater Fluorine (50) Element combined with uranium in gas diffusion enrichment (7) Gallium Element predicted by Mendeleev's periodic table before its discovery; "doubly magic"; has high atomic stability Helium-4 (13,24, 25, 32, 55) Isotope discovered using atomic spectroscopy in 1868; found on the sun; a noble gas; used in lasers; produced in nuclear fusion Hydrogen (6, 14, 27, 34, 40, 58) Element discovered by Antoine Lavoisier and modeled by the Rydberg formula; used in atomic clocks and bubble chambers; aligned by magnetic waves in magnetic resonance imaging; undergoes fusion; lightest and most abundant element Iodine-131 (45) Radioactive isotope used in radioactive tracing; synthetic Iron(24, 32) Ferromagnetic material; very stable element (48) Krypton Element produced in the fission of uranium-235 Lead(35) Element used to shield against gamma radiation (24) Lithium An alkali metal Lithium-7 (46) Isotope used by Ernest Walton and John Cockcroft in the first nuclear reaction Mercury (17, 27) Element used in James Franck and Gustav Hertz's experiment with a vacuum tube; used in atomic clocks (24, 25) Neon Noble gas used in lasers Neptunium (39, 48) Artificial element; can enter a decay chain; discovered by Enrico Fermi by bombarding uranium (18, 24, 32) Nickel Element used in the Davisson-Germer experiment which proved wave-particle duality; ferromagnetic material; very stable element Nitrogen-14 (30, 56) Gas used by Ernest Rutherford in observing the emission of hydrogen nuclei after nuclear collisions; produced in the beta decay of carbon-14; present in the CNO cycle (6, 32, 56) Oxygen Element initially discovered by Antoine Lavoisier; "doubly magic"; has high atomic stability; present in the CNO cycle Phosphorous (37) Element studied by Irene Joliot-Curie and her husband Frederic Plutonium-239 (48, 52, 64) Discovered by Enrico Fermi by bombarding uranium; carcinogenic; used in nuclear weapons; produced in breeder reactors; desired product of the Hanford Engineer Works; cannot be used in guntype weapons; powered Fat Man bomb Polonium (34) Element discovered by Marie Curie and Pierre Curie Potassium-40 (42) Isotope which provides an annual dose of 0.4 mSv if ingested Radon-222 (43) Isotope responsive for most background radiation; causes lung cancer; found as a dense inert gas Rubidium (27) Gas cooled to 50 trillionth K by Stanford researchers in 2015 (24, 51) Sodium Alkali metal whose emission spectrum has split lines; used in liquid form as reactor coolant Strontium (27, 48) Element used in atomic clocks; produced in uranium-235 fission Tellurium (36) Lightest known element to perform alpha decay Thorium (39) Element which can enter a decay chain Thorium-234 (36) Isotope produced by the alpha decay of uranium-238 (31) Tritium Radioactive isotope of hydrogen with two neutrons and a proton Uranium (48) Heaviest known element in the 1930s Uranium-235 (48, 67) Isotope that produces a usable chain reaction; releases three neutrons during each fission; powered the Little Boy bomb Uranium-238 (34, 40, 49) Radioactive isotope studied by Marie Curie; alpha-decays into thorium-234 decay chain and replenishes the natural abundance of radium-226; absorbs neutrons without performing fission (48) Xenon Element produced in the fission of uranium-235 Theories and Phenomena decay (36) Alpha Decay involving the emission of a helium nucleus theory (5) Atomic Theory that all matter is composed of indivisible atoms Betadecay (36) Decay involving the emission of an electron or positron Betaminus decay (36) Decay involving the emission of an electron Betaplus decay (36) Decay involving the emission of a positron reaction (48) Chain Neutrons from one fission event triggering more events CNOcycle (56) Reactions in very hot, large stars; converts hydrogen to helium via carbon, nitrogen, and oxygen; proposed by Hans Bethe in 1939 Compton scattering (13) Discovered in 1923; scattering of X-ray radiation off free electrons; unexplainable by the wave model of light and classical physics Corpuscular theory (6) Theory that all matter contains infinitely divisible corpuscules Corpuscular theory of light (7, 9) Isaac Newton’s theory in Opticks (1704) that light consists of weightless balls; explains reflection but not refraction or diffraction Correspondence principle (16) Proposed by Niels Bohr; states that quantum theory should align with classical expectations at large scales Coulomb barrier (55) Energy barrier preventing fusion reactants from colliding Dalton's atomic theory (6) Principles in John Dalton’s 1808 A New System of Chemical Philosophy stating that identical atoms comprise an element; atoms cannot be created, destroyed, or divided, and (re)combine in simple ratios in chemical reactions de Broglie hypothesis (17) Relation of a particle's momentum with its wavelength (39) Decay Transformation of parent isotopes to daughter isotopes through the emission of alpha, beta, or gamma particles chain (39) Decay Radioactive daughter nucleus performing more decay; occurs with thorium, uranium, actinium, and neptunium Doppler cooling (27) Method of selectively slowing atoms in laser cooling Doppler effect (27) Frequency shift caused by relative motion between the observer and wave emitter; used in laser cooling slit interference (9) Double Discovered by Thomas Young in 1803; constructive and destructive interference formed when light enters two narrow slits Electron capture (37) Absorption of an orbiting electron by a nucleus; emits a neutrino Enrichment (49) Increasing proportion of uranium-235 in mined uranium (65) Fizzle Situation in which a nuclear weapon prematurely detonates without reaching its expected yield decay (37) Gamma Process in which a nucleus transitions from a high energy to a low energy state and releases a gamma ray photon Heisenberg uncertainty principle (23) Axiom that the position and momentum of a particle cannot both be known with absolute precision Induced radioactivity (37) Artificial creation of an unstable isotope artificially confinement fusion Inertial (59) Using high-power lasers to heat and compress a pellet of deuterium and tritium to start fusion; utilized by the NIF K-capture (37) Form of electron capture that absorbs it from the "K" shell cooling (27) Laser Using lasers to slow atoms; draws on photon momentum Law of conservation of matter (6) Observation that mass is conserved in chemical reactants; noted by Antoine Lavoisier in the late eighteenth century Maxwell's theory of electromagnetism (9) Description of light as a wave made up of oscillating electric and magnetic fields Meltdown (41) Result when the core of a nuclear reactor overheats and melts Mutually Assured Destruction (69) Scenario in which states completely destroy each other in mutual nuclear weapon attacks fission (47) Nuclear Heavy nucleus splitting into two lighter nuclei and releasing energy; triggered by collisions fusion (55) Nuclear Two small nuclei colliding to form a larger nucleus reaction (46) Nuclear Two nuclei colliding to form different nuclei; analogous to chemical reactions Pauliexclusion principle (24) Axiom that no two electrons have the same set of quantum numbers, except for bosons Photoelectric effect (12) First observed by Heinrich Hertz in 1887; release of electrons by metals illuminated with ultraviolet light Planetary model (7) Model of the atom inspired by Rutherford’s discovery of the nucleus; electrons orbiting a dense positively charged nucleus pudding model (7) Plum Model of the atom proposed by J.J. Thomson; featured a sea of electrons suspended in a positively charged sphere Population inversion (25) Creation of sample with more excited atoms than in the ground state Proton-proton chain (56) Multi-step solar fusion reaction; converts four protons into helium-4, positrons, neutrinos, and gamma rays; proposed by Hans Bethe in 1939 Quantum theory (9) Theory that energy and matter is quantized Quantum tunneling (20, 55) Implication of the Schrödinger equation that low energy particles can overcome tall potential barriers; basis for scanning tunneling microscope; lets particles in nuclear fusion cross Coulomb barrier Radioactive decay (35) Spontaneous emission of radiation associated with a transformation from an unstable nucleus to a stable nucleus Radioactivity (34) Spontaneous radiation emission; studied by Curies and Becquerel Refraction (9) Light bending around narrow apertures or corners Schrödinger model (23) Model of the atom which describes electrons with wave functions; features a "cloud" of electrons; the modern model of the atom wind (56) Solar Collection of low mass particles ejected by the Sun Spontaneous emission (25) An atom releasing a photon in a random direction Stimulated emission (25) Causing atom to transition to a lower energy level and release a photon; used in lasers nuclear force (32) Strong Attractive force between nucleons; counteracts repulsive force between protons Thermonuclear fusion (55) Fusion of nuclei at extremely high temperatures Ultraviolet catastrophe (11) Finding that blackbody radiation emits little ultraviolet light Wave-particle duality (18) Notion that light and matter exhibit properties of both waves and particles; seen in double slit experiment Zeeman effect (24) Fine splitting of spectral lines when substance is placed in a magnetic field Devices clock (27) Atomic Timekeeping device; relies on precise frequencies of atomic transitions B Reactor (64) First plutonium-generating reactor; located at Hanford Engineer Works Blackbody (10) Idealized object that releases all radiation it absorbs to remain in thermal equilibrium water reactor (52) Boiling Reactor using water as moderator, coolant, and source of steam reactor (52) Breeder Reactor producing useful fissile material, plutonium-239 chamber (40) Bubble Traces the path of ionizing radiation; uses liquid hydrogen; invented by Donald Glaser in 1952 Cathode ray tube (7) Device consisting of glass tubes with vacuums; creates a cathode ray; used in CRT televisions and computer monitors; used in many experiments in the 1800s chamber (40) Cloud Traces path of ionizing radiation; uses saturated vapor and piston rod (51) Control Component of a nuclear reactor; absorbs neutrons and regulates the speed of the chain reaction Cyclotron (62) First particle accelerator; invented by Ernest O. Lawrence Doomsday Clock (69) Concept created by the Bulletin of the Atomic Scientists; measures how close the world is to nuclear Armageddon Reactor (52) EBR-1 First reactor to generate electricity in 1951; located in Idaho, Fat Man (67) Plutonium implosion nuclear weapon; dropped on Nagasaki Gas centrifuge (50) Uses rapidly rotating cylinder to separate uranium-235 from uranium-238 Gas diffusion enrichment (50) Uses semi-permeable membranes to separate uranium-235 from uranium-238 counter (40) Geiger Radiation detector; uses tube of inert gas; creates clicking sound Generation IV reactor (53) Next generation nuclear reactor design; minimizes waste, enhances safety, and prevents nuclear proliferation Goldfoil apparatus (7, 30) Device which Ernest Rutherford, Hans Geiger, and Ernest Marsden used to discover the nucleus; contained a beam of positive alpha particles which deflected off a gold foil Gun-type (54) Detonation mechanism where two pieces of fuel are shot together laser (26) HeNe Common laser used in laboratories and classrooms Implosion-type (54) Detonation mechanism in which explosives compress a subcritical fuel mass; used in modern nuclear weapons ITER(59) World's largest experimental fusion reactor; funded by 7 countries JointEuropean Torus (59) Tokamak fusion reactor located in the UK K-25(63) Gaseous diffusion plant at Oak Ridge; one of the largest singleroofed buildings in the world Hadron Collider at Large CERN (46) Advanced particle accelerator capable of accelerating particles to energies greater than 1 TeV (26) Laser Device using stimulated emission to create a beam of monochromatic, directional, coherent light enrichment (50) Laser Uses tuned lasers to separate uranium-235 from uranium-238; requires little energy Boy (67) Little Uranium gun-type nuclear weapon; dropped on Hiroshima Magnetic separation enrichment (50) Uses a magnetic field to separate uranium-235 and uranium-238 National Ignition Facility (59) Largest ICF device in the world; at Lawrence Livermore National Labs in California; uses lasers to compress a hydrogen pellet reactor (50) Nuclear Device which initiates and controls a nuclear chain reaction; harnesses reaction energy for power generation in a box (20) Particle Physics model which describes an energized particle trapped in a 1 dimensional space bounded by infinitely high potential walls Photomultiplier tube (40) Component of a scintillation counter (63) Pile-1 Enrico Fermi's first nuclear reactor; built at the University of Chicago Pressurized water reactor (52) Reactor which uses a separate cooling loop of water to produce steam; common in the United States; prevents fuel leakage Proportional counters (40) Sophisticated form of Geiger counters; measures energy of radiation Scanning tunneling microscope (20) Uses quantum tunneling to achieve resolutions of 0.1 nm using electrons Schrödinger's cat (22) Scenario involving a simultaneously dead and alive cat; demonstrates the multiple states of a quantum system Scintillation counter (40) Radiation detector; relies on NaI crystal and a photomultiplier tube; can determine the energy of emitted radiation detector (44) Smoke Device using a stream of alpha-particles produced by americium241 Thermonuclear weapon (57) Nuclear weapon which uses a fission bomb to trigger a thermonuclear explosion ThinMan (65) Gun-type plutonium fission bomb; abandoned due to poor quality of available plutonium Tokamak (58) Toroidal shaped device that confines a plasma using magnetic fields; developed in the Soviet Union during World War II Tokamak Fusion Test Reactor (TFTR) (59) Tokamak fusion reactor at Princeton; never reached break-even Transmission electron microscope (18) Device which relies on the wave properties of electrons to achieve very fine image resolutions; accelerates electrons to 100 keV; has a resolution on the order of 0.0037 nm Bomb (65) Trinity First nuclear weapon ever detonated; implosion-type TsarBomba (57) Most powerful nuclear weapon detonated; a hydrogen bomb; as powerful as 50 million tons of TNT Missouri (67) U.S.S. Ship which hosted the former surrender of Japan X-10(63) Graphite reactor at Oak Ridge Y-12(63) Electromagnetic separation plant at Oak Ridge; second manmade nuclear reactor Awards and Publications Nobel Prize in Physics 1901 (34) First Nobel Prize in Physics; awarded to Wilhelm Roentgen for discovering X-rays Nobel Prize in Physics 1903 (34) Awarded to Marie Curie, Pierre Curie, and Henri Becquerel for their discoveries involving radioactivity Nobel Prize in 1911 Chemistry (34) Awarded to Marie Curie, Pierre Curie, and Henri Becquerel for their discoveries involving radioactivity Nobel Prize (13) 1921 Awarded to Albert Einstein for explaining the photoelectric effect using photons Nobel Prize in Physics 1925 (17) Awarded to James Franck and Heinrich Hertz for demonstrating that an atom's absorption energies match its emission energies Nobel Prize in 1935 Chemistry (38) Awarded to the Joliot-Curies for discovering induced radioactivity Nobel Prize in 1960 Chemistry (44) Awarded to Willard Libby for developing carbon dating Nobel Prize (57) 1967 Awarded to Hans Bethe for explaining stellar energy production Nobel Prize in Physics 1997 (27) Awarded to three physicists for developing laser cooling System of Chemical A New Philosophy (6) Published in 1808 by John Dalton; included Dalton's basic atomic principles Energy Act of 1946 Atomic (68) Placed atomic research under civilian control; passed by Harry Truman Energy Act of 1954 Atomic (69) Signed by Eisenhower; permitted the development of civilian nuclear power plants for Peace (69) Atoms Address delivered by President Eisenhower to the United Nations; outlined a commitment to peaceful atomic uses of the Atomic Bulletin Scientist (68) Non-technical magazine on nuclear weapons and nuclear security founded by Eugene Rabinowich; source of the Doomsday Clock May-Johnson Bill (68) Bill proposed in October 1945; would continue military oversight over atomic research; opposed by Szilard McMahon Bill (68) Bill proposed in December 1945 to oppose the May-Johnson Bill; placed atomic research under civilian control; incorporated in the Atomic Energy Act of 1946 Mr. Tompkins in Wonderland (23) Written in 1940 by George Gamow; describes a bank teller exploring a quantum jungle with strange animals NewYork Times (68) Newspaper of William Lawrence Newsweek (69) Quoted Einstein's opposition to the Manhattan Project Non-Proliferation Nuclear Act of 1978 (69) Signed by President Carter; prevented the spread of nuclear materials for weapons use, but allowed for peaceful use Non-Proliferation Nuclear Treaty (69) Signed in 1968 by 69 nations; prevented new nations from acquiring nuclear weapons (6, 9) Opticks Published in 1704 by Isaac Newton; suggested the corpuscular theory of light Periodic Table of Elements (6) Organization system for elements created by Dmitry Mendeleev; organized elements by atomic weight Potsdam Declaration (66) Allied leaders present terms of surrender to Japan Numbers -1/2(24) Possible spin quantum number value for electrons 20, 25) 0 (10, Minimum temperature in Kelvin for a body to release thermal radiation; absolute 0 in Kelvin; classical probability that a particle will cross a high potential wall; temperature of the Bose Einstein condensate 6.63× 10−34 (11) Value of Planck's constant in Joule-seconds (42) 10−33 Energy above which radiation is considered ionizing, in eV 10−31 (30) 9.1 × Mass of one electron, in kilograms 1.66× 10−27 (29) Mass of one unified mass unit, in kilograms; mass of a proton or neutron, in kilograms (13) 10−19 Approximate energy of a photon in Joules 10−19 (15, 29) 1.6 × Energy of an electron accelerated across a 1-volt potential difference in Joules; charge of a proton in Coulombs (30) 10−15 Approximate nuclear radius in meters; 1 femtometer, in meters 1/50trillion (27) Temperature in Kelvin to which Stanford researchers were able to supercool rubidium in 2015 (30) 10−14 Rutherford's estimate of the nuclear radius, in meters 1 trillionth (44) Portion of carbon that is carbon-14 (30, 35) 10−10 Radius of an atom's electron cloud in meters; lifespan of a positron in seconds 10−9(59) Time it takes for the NIF to achieve ignition, in seconds × 107 (14) 1.097 Value of the Rydberg constant in m^-1 1/70thousand (27) Average velocity of molecules in the supercooled rubidium produced by Stanford researchers, in mm/s × 10−4 (30) 5.486 Mass of one electron, in unified mass units (18) 0.0037 de Broglie wavelength of electrons in a transmission electron microscope in keV 0.02millisieverts (42) Dosage of a chest X-ray nanometers (15) 0.0529 Value of the Bohr radius 53) 0.1 (22, Resolution of a scanning tunneling microscope; annual dosage to a person living 50 miles from a nuclear power plant, in microsieverts 1/3 (53) Fraction of the world's nuclear energy produced by the United States 0.4 (42) Dosage of potassium-40 if ingested in millisieverts 0.4 -0.7 (22) Distance from the sample in a scanning tunneling microscope in nanometers 1/2 (24) Possible spin quantum number value for electrons (30) 0.511 Mass of one electron in mega-electron volts 0.7 (49) Percent abundance of uranium-235 in nature 42, 44, 46) 1 (12, Number of nanoseconds delay before electron ejection in the photoelectric effect; dosage which causes radiation sickness, in sieverts; quantity of americium-241 in a smoke detector, in micrograms; scale of the energy released by one nuclear reaction, in MeV 33, 34, 35, 59, 67, 69) 2 (16, Associated with the Balmer series; a magic number; Nobel Prizes awarded to Marie Curie; Denver receives this times more radiation annually than the national average; size of the pellet employed by the NIF, in mm; billions spent by the Manhattan Project; least minutes the Doomsday Clock has been from midnight 2 - 3(14) Transition of the hydrogen electron which produces red light 2.5 (48) Average number of neutrons released by fission of uranium-235 69) 3 (48, Maximum number of neutrons released by fission of uranium-235; current setting of the Doomsday Clock in minutes from midnight 3 - 4(49) Percent abundance of uranium-235 in nuclear fuel 4 (5,42) Basic elements as envisioned by Plato; minimum 4.9 (17) Energy lost by an electron colliding with mercury in eV 5 (6,35, 42, 66) Fatal radiation dosage in sieverts; principles in Dalton's atomic theory; percent of the speed of light which an alpha particle travels at; depth in feet of the Trinity test crater 6.2 (42) Average background annual dosage in the United States, in millisieverts 6.8 (54) Size of a critical mass sphere of weapons grade uranium, in cm 69) 7 (59, Members of ITER; minutes to midnight at Doomsday Clock’s creation 7.5 (66) Height in miles of the Trinity mushroom cloud 7.6 (49) Average binding energy per nucleon in uranium-235, in MeV/nucleon 42) 8 (33, Magic number; lethal dosage of radiation, in sieverts 8.5 (49) Average binding energy per nucleon in medium-sized fission products, in MeV/nucleon 9 (41) Magnitude of the earthquake which triggered the Fukushima Daiichi nuclear accident 62) 10 (58, Half-life of tritium, in years; original estimate of uranium-235 critical mass 10.4(57) Energy release of the first hydrogen bomb, in megatons TNT (52) 10.9% World's energy production generated by nuclear reactors 13.6(16) Ionization energy of hydrogen in eV 62) 15 (7, Diameter of shell mentioned by Rutherford when he commented on the results of the gold foil experiment; time it took for President Roosevelt to approve the NDRC, in minutes (52) 19.5% United States' energy production generated by nuclear reactors 20 (33) Mass number below which stable atoms contain equal numbers of neutrons and protons; a magic number 23.5(52) Half-life of uranium-239, in minutes (56) 24.68 Energy released in the proton-proton chain, in MeV 25 (56) Abundance of helium in the Sun by mass percent 26 (67) Total budget of the Manhattan project, in billions of 2015 dollars 28 (33) A magic number 52, 58, 66) 30 (13, Countries operating nuclear reactors as of 2015; liters of seawater required to collect 1g of deuterium; width in feet of the Trinity test crater 33, 57) 50 (22, Probability that Schrödinger's cat is dead or alive; a magic number; energy release of Tsar Bomba, in millions of tons of TNT 56 (32) Mass number with maximum atomic stability 60 (32) Mass number above which binding force decreases 62 (69) Countries which signed the Nuclear Non-Proliferation Treaty 64 (6) Elements known to Dmitri Mendeleev 70 (66) Scientists who signed Leo Szilard's petition to demonstrate the bomb to the Japanese 74 (56) Abundance of hydrogen in the Sun by mass percent 75%(52) France's energy production generated by nuclear reactors 82 (33) A magic number 83 (33) Mass number above which no stable isotopes exist 85 (62) Amount of money obtained by Vannevar Bush for the purpose of constructing uranium enrichment plants, in millions of dollars 49) 90 (7, Degrees some particles were deflected in the gold foil experiment; percent abundance of uranium-235 in nuclear weapons 48) 92 (29, Protons in uranium-238; atomic number of uranium 93 (48) Atomic number of neptunium 94 (48) Atomic number of plutonium 98 (31) Mass number of californium (31) 99.99% Proportion of hydrogen-1 in all isotopes of hydrogen 100 (18, 42, 48, 64) Rems in a sievert; dose above which cancer risks increase, in millisieverts; energy of a fission reaction, in MeV; height of the steel tower used in the Trinity test, in feet; energy of electrons in a transmission electron microscope, in keV 126 (33) A magic number 146 (29) Number of neutrons in uranium-238 300 (27) Years it takes for the first cesium atomic clock to lose one second 400 (54) The Chernobyl accident released this times more radiation than the Hiroshima bomb 400-700 (18) Wavelength of visible light, in nanometers 438 (52) Number of operational power generation reactors as of 2015 450 (57) Order of magnitude with which first hydrogen bomb was more powerful than the Nagasaki bomb 500 (27, 59, 62) Average velocity of molecules in room temperature gas in m/s; power output of the NIF, in trillions of watts; millions of dollars allocated to the Manhattan Project in 1942 (27) 632.8 Wavelength of HeNe laser light, in nanometers 653 (56) Tons of helium produced by the Sun every second (14) 656.3 Wavelength of the red line in the hydrogen spectrum in nanometers 657 (56) Tons of hydrogen processed by the sun every second (29) 931.49 Mass of one unified mass unit, in MeV/c2 (30) 938.28 Mass of one proton in MeV (30) 939.57 Mass of one neutron in MeV (10, 59) 1,000 Kelvin at which objects release radiation in the infrared band; when firing a laser pulse, the NIF consumes this much times more power than the entire United States (7) 1,800 Order of magnitude with which hydrogen atom is more massive than a cathode ray particle (62) 1,200 Tons of imported uranium stored at Staten Island in the Manhattan Project` (40) 1,600 Half-life of radium-226, in years (67) 21,000 Energy release of Fat Man, in tons of TNT (62) 2,403 Deaths at Pearl Harbor (38) 3,000 Artificial radioactive isotopes created in reactors and particle accelerators (44) 5,730 Half-life of carbon-14, in years (61) 6,000 Initial value of uranium oxide and graphite suggested by the Advisory Committee on Uranium, in dollars (58) 10,000 Energy of 1 gram of deuterium, in liters of gasoline (67) 15,000 Energy release of Little Boy, in tons TNT (50, 66) 20,000 Tons of TNT with energy equivalent to 1 ton of uranium or the Trinity bomb (52) 24,000 Half-life of plutonium-239, in years 104 (49) 4.4 × Energy density of gasoline, in J / g (44) 50,000 Maximum age of an item for carbon dating, in years (67) 74,000 Immediate deaths resulting from the Fat Man bombing (30, 61) 100,000 Order of magnitude that the atom is larger than the nucleus; initial value of uranium oxide and graphite suggested by the Advisory Committee on Uranium, in 2015 dollars (67) 130,000 Employees of the Manhattan Project at the end of the war (67) 140,000 Immediate deaths resulting from the Little Boy bombing (54) 500,000 Maximum energy of a fission bomb, in tons TNT 107 (55) Temperature at which nuclear fusion occurs, in Kelvin 5 × 107 (44) Minimum half-life of a primordial isotope for it to be detectable 108 (59) Temperature reached by the deuterium pellet in the NIF, in Kelvin 200 million (59) Maximum temperature reached by the TFTR, in Kelvin 300 million (27) Years taken for modern cesium atomic clocks to lose one second 109 (44) 4.5 × Half-life of uranium-238, in years; age of the Earth, in years 4.6 billion (40) Age of the Solar System, in years 9,192,631,770 (27) Oscillations of cesium-137 per second 1010 (39) 3.7 × 1 Curie in decays per second 1010 (49) 8.2 × Energy density of uranium-235, in J/g 1011(43) Flux of neutrinos on Earth's surface, neutrinos per sq cm/s 1014s/cm3 (58) Minimum value of Lawson's criterion for deuterium-tritium fusion 1016s/cm3 (58) Minimum value of Lawson's criterion for deuterium-deuterium fusion Places Alamogordo (65) New Mexico location of the Trinity test Greece (5) Ancient One of the first cultures to theorize atoms; home to Democritus, Leucippus, Plato, Aristotle Idaho (52) Arco, Site of the first nuclear reactor which generated electricity Australia (57) Home of Mark Oliphant (19) Austria Home of Erwin Schrödinger California (59) Location of Lawrence Livermore National Laboratory (51, 62) Canada Country which uses many heavy-water reactors; provided uranium for the Manhattan Project (46) CERN Location of the Large Hadron Collider (59) China ITER member state Colorado (62) Site of American uranium mines for the Manhattan project Denmark (14) Home of Niels Bohr Colorado (43) Denver, City in the United States with high cosmic radiation exposure due to its high altitude England (6, 31, 46, 48, 56, 59, 62) Home of John Dalton, James Chadwick, John Cockcroft, Arthur Eddington; site of the Joint European Torus; estimated the critical mass of uranium-235 to be 10 kg (6, 17, 34, 52, 59) France Home of Antoine Lavoisier, Joseph Proust, Louis de Broglie, Marie Curie, Pierre Curie, Henri Becquerel; generates 75% of its energy with nuclear power; site of ITER Fukushima Daiichi (41) Experienced a major nuclear accident in 2011 Germany (11, 34, 48, 61) Home of Albert Einstein, Max Planck, Wilhelm Roentgen, Otto Hahn, Fritz Strassman; home of the Nazi Party; led by Adolf Hitler Hiroshima (67) Japanese city targeted by Little Boy Hungary (48) Home of Leo Szilard (5, 59) India Early culture that theorized atoms; home to Kanada; ITER member (46) Ireland Home of Ernest Walton Italy(61) Country with a fascist government; ruled by Benito Mussolini (41) Japan Location of Fukushima Daiichi nuclear power plant (59) Japan ITER member state Knoxville (64) Populated city located close to the Oak Ridge site (67) Kokura Japanese manufacturing center; considered for nuclear bombing (59) Korea ITER member state (67) Kyoto Former capital of Japan and center of industry; considered for targeting but rejected due to its historical significance Nagasaki (67) Japanese seaport and center of industry; targeted instead of Kyoto by the Fat Man bomb Netherlands (9) Home of Christiaan Huygens OakRidge (63) City founded to house workers at the Clinton Engineer Works Harbor (62) Pearl American naval base attacked by Japan on December 7, 1941 Pennsylvania (52) Site of the Three Mile Island accident (34, 61) Poland Homeland of Marie Curie; invaded by Germany in September 1939 Racquet court (51) Location on the University of Chicago campus where the first nuclear reactor was constructed eastern Tennessee (63) Rural Site picked for the Oak Ridge nuclear plants (59) Russia ITER member state Fe (64) Santa Location of the P.O. Box of Los Alamos Scotland (9) Home of James Clerk Maxwell Union (52) Soviet First country to connect a nuclear reactor to the power grid Island (62) Staten Storage site for imported uranium during the Manhattan project Switzerland (14) Home of Johann Balmer States (13, 40, 52, 59) United Home of Arthur Compton, Donald Glaser, Willard Libby; generates 19.5% of its energy with nuclear power; world's largest producer of nuclear power; ITER member state Washington (64) State occupied by the Hanford Engineer Works Yokohama (67) Japanese manufacturing center; possible target for nuclear bomb Organizations Advisory Committee on Uranium (61) Committee formed by Roosevelt in response to Leo Szilard's letter; provided recommendations for nuclear research Corps of Engineers (62, Army 63) Oversaw plant construction and bomb assembly in the production phase of the Manhattan project Asharite School of Theology (5) Religious belief system formed by Islamic scholars studying Greek and Indian atomism Energy Commission Atomic (68) Organization which assumed control of the atomic program in 1947 Bell Labs (17) Research center at which Clinton Davisson and Lester Germer confirmed the de Broglie hypothesis Carnegie Foundation (62) Organization of which Vannevar Bush was president Catholic Church (5) Religious organization which initially opposed atomism (46) CERN Organization supporting the Large Hadron Collider Engineer Works (63) Clinton Organization established by the Army Corps of Engineers; later became Oak Ridge National Laboratory Department of Energy (68) Established in 1977 by Jimmy Carter; currently manages the National Laboratories Emergency Committee of Atomic Scientists (68) Group founded by Albert Einstein in 1946 to promote peaceful atomic applications Research and Energy Development Administration (68) Agency which partially replaced the Atomic Energy Commission in 1974 European Union (59) ITER member Hanford Engineer Works (64) Housed the B Reactor, a plutonium generating reactor International Atomic Energy Agency (69) Founded by United Nations in 1957; promotes peaceful use of nuclear materials; prevents the proliferation of nuclear weapons Lawrence Livermore National Laboratory (59) Site of the National Ignition Facility Los Alamos (64) Also known as Site Y; research area constructed to bring together scientists working on the Manhattan Project Los Alamos Ranch School (64) Site of what would become Site Y National Bureau of Standards (61) Organization directed by Lyman Briggs National Defense Research Committee (62) Proposed by Vannevar Bush to oversee development of the atomic bomb National Institute of Standards and Technology (27) Agency which regulates standards of measurements; defined the second in terms of cesium 137's oscillating frequency National Laboratory system (68) System of research centers established by the Atomic Energy Commission in the post-war era NaziParty (61) Political party which took control of Germany in 1933 NIST(27) See National Institute of Standards and Technology Regulatory Nuclear Commission (68) Agency that partially replaced the Atomic Energy Commission in 1974 OakRidge National Laboratory (68) Laboratory that grew out of the Clinton Engineer Works Princeton (59) Site of the Tokamak Fusion Test Reactor Y (63) Project Weapons development laboratory of the Manhattan Project; led by J. Robert Oppenheimer S-1 Committee (62) Subcommittee of the NRDC investigating uranium enrichment; included Ernest O. Lawrence Scientific Advisory Panel (67) Rejected a public demonstration of the nuclear bomb Site Y (64) See Los Alamos Stanford (27) Research university which supercooled rubidium to 50 trillionths of a Kelvin in 2015 Nations (69) United Founder of the International Atomic Energy Agency States Army (62) United Directed the construction of the atomic bomb University of California, Berkeley (62, 64) University of Ernest O. Lawrence, J. Robert Oppenheimer, Hans Bethe, Edward Teller University of Chicago (51) School which hosted the world's first nuclear reactor US Food and Drug Administration (43) Department overseeing food irradiation People Hitler (61) Adolf Chancellor of Germany; leader of the Nazi Party Einstein (13, 18, 25) Albert Proposed quantization of light energy (1905); won 1921 Nobel Prize for explaining the photoelectric effect; expressed doubts about quantum theory to Max Born; theorized a fourth state of matter with integer spin particles (1924) Weinberg (68) Alvin Director of Oak Ridge National Laboratory; coined the term "Big Science" to describe the National Laboratory system Lavoisier (6) Antoine Late 1700s French chemist; identified and named hydrogen and oxygen; theorized the law of conservation of matter Aristotle (5) Third century BCE Greek philosopher; disagreed with atomism; argued that matter is infinitely divisible Compton (13, 62) Arthur American physicist; noted X-ray scattering in 1923, suggesting the existence of the photon; asked J. Robert Oppenheimer to perform neutron calculations for the uranium chain reaction; suggested Oppenheimer as the director of Project Y Eddington (56) Arthur English physicist; proposed stars produce energy through hydrogen fusion CarlWieman (25) Created a Bose-Einstein condensate using laser cooling in 1995 Christiaan Huygens (9) Dutch physicist; contemporary of Newton’s; envisioned light as a wave Davisson (17) Clinton Researcher at Bell Labs; experimentally confirmed the de Broglie hypothesis by firing electrons at crystalline nickel Democritus (5) Fifth century BCE; early Greek philosopher; suggested that matter is composed of indestructible, indivisible particles Mendeleev (6, 7) Dmitri Nineteenth century chemist; created periodic table based on first 64 elements; predicted the existence of gallium Glaser (40) Donald Invented the bubble chamber in 1952 D. Eisenhower (69) Dwight President of the United States; in 1953 delivered "Atoms for Peace" speech to the United Nations Teller (57, 62) Edward Hungarian-American physicist; conceived of and designed the first hydrogen bomb; Berkeley "luminary" who worked with Oppenheimer on neutron calculations for the atomic bomb Segre (62, 65) Emilio Worked with Oppenheimer on neutron calculations; found that products of X-10 reactor had too much plutonium-240 for a guntype bomb Fermi (30, 37, 48, 51, Enrico 61) Italian physicist after whom unit of nucleic radius is named; named the neutrino; synthesized neptunium and plutonium; constructed the first nuclear reactor at the University of Chicago in 1942; fled to the United States during this period Eric Cornell (25) Created a Bose-Einstein condensate using laser cooling in 1995 Marsden (7) Ernest Assistant to Ernest Rutherford in the gold foil experiment O. Lawrence (62) Ernest Director of Radiation Laboratory at Berkeley; inventor of cyclotron Rutherford (7, 30, 35, Ernest 57) Performed 1911 gold foil experiment; discovered the nucleus; theorized the neutron in 1920; proposed planetary atomic model; proposed in 1900 that nuclear transformations release radiation; experimentally demonstrated nuclear fusion in 1934 Walton (46) Ernest Irish physicist; in 1932, induced the first artificial nuclear reaction with lithium-7 Schrödinger (19, 22) Erwin Austrian physicist; created equation describing behavior of matter waves; described quantum behavior via scenario of cat in a box Rabinowitch (68) Eugene Manhattan Project scientist; founded Bulletin of the Atomic Scientists Wigner (33) Eugene Proposed shell model for nucleons with Maria Goeppert Mayer FelixBloch (62) Worked with J. Robert Oppenheimer on neutron calculations D. Roosevelt (62) Franklin President of the United States; approved initial research into an atomic weapon; approved the NDRC Frederic Curie (37) Husband to Irene Joliot-Curie; in 1934, demonstrated induced radioactivity by generating radioactive phosphorous; won the 1935 Nobel Prize in Chemistry Frederick Soddy (35) In 1900, concluded that nuclear transformations release radiation with Ernest Rutherford FritzStrassman (48) German physicist; in 1938, discovered that bombarding uranium nuclei with neutrons produced fission products with half uranium’s mass Gamow (23) George In 1940, wrote Mr. Tompkins in Wonderland Hertz (16) Gustav In 1914, confirmed Bohr's model of the atom by firing electrons through mercury gas in a vacuum Bethe (57, 62) Hans In 1939, proposed the proton-proton chain and CNO cycle; won the 1967 Nobel Prize; "luminary" who worked with Oppenheimer on neutron calculations Geiger (7, 40) Hans Assistant to Ernest Rutherford; performed the gold foil experiment in 1911; recorded the results of the gold foil experiment in a dark room; developed a radiation detector which uses a low-pressure tube of inert gas Truman (66) Harry Vice President to President Franklin D. Roosevelt; became president in 1945 after Roosevelt died in office Heinrich Hertz (12) In 1887 discovered the photoelectric effect Becquerel (34) Henri French physicist; first observed spontaneous radiation emission Wallace (62) Henry Vice President to President Franklin D. Roosevelt Joliot-Curie (37) Irene Daughter of Marie Curie; in 1934, demonstrated induced radioactivity by generating radioactive phosphorous; won the 1935 Nobel Prize in Chemistry Newton (6, 9) Isaac 1700s - 1800s; advocated for the corpuscular theory in Opticks J. Robert Oppenheimer (62, 63) Researcher at the University of California, Berkeley; performed neutron chain calculations for the atomic bomb; assembled a team of "luminaries" to study neutron calculations; affiliated with Communism through family members; became head of Project Y J.D. Lawson (58) Proposed criteria for nuclear fusion to occur J.J. Thomson (7, 12) Measured the mass of a cathode ray particle in 1897; discovered the electron; proposed the plum pudding model of the atom; determined that sparks produced by the photoelectric effect are actually electrons Chadwick (31, 48) James English physicist; in 1931 performed experiments with paraffin to confirm the existence of the neutron Clerk Maxwell (9) James Scottish physicist; devised the unified theory of electromagnetism in the late 19th century; described light as oscillating electric and magnetic fields Franck (16) James In 1914, confirmed Bohr's model of the atom by firing electrons through mercury gas in a vacuum Carter (68) Jimmy President of the United States; established Department of Energy Balmer (14) Johann Swiss mathematical physicist; in 1885 derives a mathematical relation between the lines in hydrogen's spectrum JohnCockcroft (46) British physicist; in 1932, induced the first artificial nuclear reaction with lithium-7 JohnDalton (6) English chemist; combined discoveries of Lavoisier and Proust; formulated the first atomic theory in A New System of Chemical Philosophy; catalogued atomic weights JohnDonne (65) English poet; inspired the name of the Trinity test JohnVan Vleck (62) Worked with J. Robert Oppenheimer on neutron calculations Johnvon Neumann (65) Mathematician; in September 1943, proposed an implosion type weapon design JohnWheeler (48) Colleague of Neils Bohr Proust (6) Joseph French chemist; realized that elements react in fixed proportions (5) Kanada Fifth century BCE Hindu philosopher; suggested that matter contains indestructible, indivisible particles Leo Szilard (48, 61, 66) Hungarian physicist; in 1933, hypothesized that a nuclear chain reaction could become self-sustaining; fled to the United States; in 1939 wrote a letter under Einstein's name recommending the United States research nuclear weapons; petitioned for a public demonstration of the nuclear bomb R. Groves (63) Leslie Army Corps of Engineers General; director of the Manhattan Project from September 1942; appointed Oppenheimer as its lead Germer (17) Lester Researcher at Bell Labs who experimentally confirmed the de Broglie hypothesis by firing electrons at crystalline nickel Leucippus (5) Fifth century BCE Greek philosopher; suggested that matter is composed of indestructible, indivisible particles Straus (68) Lewis Predicted that nuclear power would make electricity free; AEC commissioner; sought to discredit Oppenheimer for opposing the hydrogen bomb Lise Meitner (48) Collaborated with Otto Hahn and Fritz Strassman de Broglie (17) Louis French physicist; in 1924, suggested a relationship between a particle's momentum and wavelength Goeppert Mayer (33) Maria In 1949, proposed a shell model for nucleons with Eugene Wigner Curie (34) Marie French-Polish physicist; discovered polonium with husband; won 1903 and 1911 Nobel Prizes; died from radiation exposure in 1934 Oliphant (57, 62) Mark Australian physicist; in 1934 experimentally demonstrated nuclear fusion; represented the British atomic team in United States MaxBorn (18, 20) Received a letter from Albert Einstein on his skepticism about quantum theory; in 1926, proposed that the square of a wave function is the particle's probability density MaxPlanck (11) German physicist; proposed the quantization of atomic energy Faraday (7) Michael Discovered that generating an electric voltage across a cathode ray tube caused the positive end to glow Bohr (14, 16, 48) Niels Danish physicist; modified the atomic model to explain quantization of energy; postulated the correspondence principle OttoHahn (48) German physicist; discovered that bombarding uranium nuclei with neutrons produced fission products half as heavy as uranium OttoRobert Frisch (48) Collaborated with Otto Hahn and Fritz Strassman; coined "fission" PaulDirac (24) In 1928, derived a relativistic form of the Schrödinger equation, incorporating the spin quantum number into quantum mechanics Lenard (12) Phillip In 1900, noticed several contradictions between the photoelectric effect and classical physics Curie (34) Pierre French physicist; discovered polonium with his wife; researched radioactivity Gassendi (5) Pierre Renaissance-era priest; reconciled atomism with Catholic beliefs (5) Plato Greek philosopher; viewed matter as consisting of four basic elements; assigned geometric shapes to types of matter Descartes (6) Rene Philosopher who debated Pierre Gassendi during the Renaissance Boyle (6) Robert Eighteenth century founder of modern chemistry; proposed corpuscular theory Serber (62) Robert Worked with J. Robert Oppenheimer on neutron calculations Satyendra Bose (25) Theorized fourth state of matter with integer spin particles SethNeddermeyer (65) Physicist; conducted theoretical work which led to the design of an implosion type weapon Stanislaw Ulam (57) Performed calculations for Edward Teller, contributing to the design of the hydrogen bomb Young (9) Thomas Noticed double-slit interference in 1803; Vannevar Bush (62) American science administrator; president of Carnegie Foundation; proposed and first chair of the NDRC Wilhelm Roentgen (34) German physicist; discovered X-rays in 1895; won 1901 Nobel Prize in Physics Libby (44) Willard American physical chemist; in the 1940s developed carbon dating; won the 1960 Nobel Prize in Chemistry Lawrence (68) William New York Times journalist who coined the term "Atomic Age" Wolfgang Pauli (24, 37) In 1925, suggested that no two electrons in an atom can share all four quantum numbers; in 1930, theorized the neutrino 𝑅 = 𝑅0 𝑒 −𝜆𝑡 𝑁 = 𝑁0 𝑒 −𝜆𝑡 𝛥𝑁 = −𝜆𝑁Δ𝑡 𝑡ℎ = ln 2 𝜆 𝑅= 𝑅0 = 𝜆= 𝑁= 𝑁0 𝑡= 𝑡ℎ = 𝜆= ℎ 𝜆= 𝑝 ℎ = 6.626 × 10−34 𝑚2 𝑘𝑔⋅𝑠 = 𝑝= 1 1 1 = 𝑅𝐻 ( 2 − 2 ) 𝜆 𝑚 𝑛 ℎ Δ𝑥Δ𝑝 ≥ 2𝜋 𝜆= 𝑅𝐻 = 1.097 × 107 𝑚−1 𝑚= 𝑛= Δ𝑥 = Δ𝑝 = ℎ = 6.626 × 10−34 𝑚2 𝑘𝑔⋅𝑠 = 𝐸= 𝑛= 𝐸 = 𝑛ℎ𝑓 ℎ = 6.626 × 10−34 𝑚2 𝑘𝑔⋅𝑠 = 𝑓= 𝐸 = 𝑚𝑐 2 𝐸= 𝑚= 𝑐 = 3 × 108 𝐸𝑛 = −13.6 𝑒𝑉 𝑛2 𝑠 = 𝐸𝑛 = 𝑛= 2 𝑟𝑏 = 𝑛= 𝑎0 = 0.0529 𝑛𝑚 = 1 𝑟0 𝐴3 𝑟= 𝑟0 = 1.2 × 10−15 𝑚 𝐴= 𝑟𝑏 = 𝑛 𝑎0 𝑟= 𝑚 𝑛= 𝜏= 𝑛𝜏 > 𝑘 𝑘 = 1014 𝑠 𝑐𝑚3 𝑘 = 1016 𝑠 𝑐𝑚3 𝐴 𝑍𝑋 𝐴 𝑍𝑋 𝐴 𝑍𝑋 𝐴−4 𝑍−2𝑌 → + 42𝐻𝑒 → 𝐴 𝑍+1𝑌 1 0𝑛 → 11𝑝 + 𝑒 − → 𝐴 𝑍−1𝑌 238 92𝑈 → + 𝑒 − + 𝑣̅ + 𝑒+ + 𝑣 234 90𝑇ℎ 14 7𝑁 + 42𝐻𝑒 14 6𝐶 → 7 4𝐵𝑒 + 𝑒 + → 73𝐿𝑖 + 𝑣 14 ∗ 6𝐶 4 2𝐻𝑒 14 6𝐶 → 30 14𝑆𝑖 + 147𝑁 → +𝛾 30 15𝑃 + 27 13𝐴𝑙 → 30 15𝑃 4 2𝐻𝑒 → + 𝑒 − + 𝑣̅ + 10𝑛 + 𝑒+ 17 8𝑂 + 11𝐻 1 1𝑝 + 73𝐿𝑖 → 2 42𝐻𝑒 2 1𝐻 + 73𝐿𝑖 → 2 42𝐻𝑒 1 0𝑛 + 235 92𝑈 → 140 54𝑋𝑒 94 + 38 𝑆𝑟 + 2 10𝑛 1 0𝑛 + 235 92𝑈 → 141 56𝐵𝑎 92 + 36 𝐾𝑟 + 3 10𝑛 2 1𝐻 + 31𝐻 → 42𝐻𝑒 + 10𝑛 + 17.59 𝑀𝑒𝑉 2 21𝐻 → 32𝐻𝑒 + 10𝑛 + 3.27 𝑀𝑒𝑉 2 21𝐻 → 31𝐻 + 11𝐻 + 4.03 𝑀𝑒𝑉 2 11𝐻 → 21𝐻 + 𝑒 + + 𝑣 + 0.42 𝑀𝑒𝑉 1 1𝐻 + 21𝐻 → 32𝐻𝑒 + 𝛾 + 5.49 𝑀𝑒𝑉 2 32𝐻𝑒 → 42𝐻𝑒 + 2 11𝐻 + 12.86 𝑀𝑒𝑉 This year’s science practice test places slightly more emphasis on understandings of the atomic model over nucleic reactions, with section I having 34% of questions against 26% and 24% for sections II (atomic nucleus and radioactivity) and section III (nuclear fission and fusion) respectively. Section I questions focus heavily on models of the atom, both classical and quantum; little appears on foundational findings leading to the quantum model such as spectral lines, the de Broglie hypothesis, wave-particle duality, and Schrödinger’s equation. Section II also focuses on atomic structure, specifically of the nucleus. Few questions address gamma decay, induced radioactivity, and radioactivity detection and effects – though this last topic offers great recall questions, so know this material well. Section III almost completely skips over Q values and the discovery of fission, while section IV omits the detonation mechanisms and Trinity Test portions, both of which will likely appear on later tests. As might be expected, section IV questions are much more factual. Those from other sections do require some lateral thinking and analysis, for example question 13 on analogies to Planck’s quantized energy states. The correct answer, B, can be identified quickly once you observe that only books increase stepwise (you cannot add half a book to a bookcase). Question 24 requires you to connect material from different sections of the guide; cathode rays stand out as not being part of the typical electromagnetic spectrum but rather a type of emission. No math needed for this test, but know the elements and reactions: for example, question 26 on the uranium-238 decay series points to an important equation, as does question 37 on the three decay chains’ products. The closest you will be to calculating anything is on question 33. Recall that doubly magic implies both neutron and proton numbers are magic; i.e. their sum (A) is twice the magnitude of a magic number. In this case, 20 x 2 = 40, option B. The more tricky questions that require you to pay close attention are the substantial number on standards and notation (11, 41, 45, 46) as well as chronology and “firsts” (2, 12, 17, 47, 48, 50). Quite a few questions came in the form of “who discovered X?” or “what did the discovery of X enable?”, so pay attention where it appears in the guide. Lastly, two questions that may need some clarification: the phrasing of question 18 leaves it unclear what it is asking about, and the distracters vary between criteria for the process to occur (A, C) and a description of the process (B, D, E). The answer, B, is relatively straightforward – in this case, no hidden meanings involved; just go with the choice that fits most closely with the term provided. For question 29, students with more general knowledge of the topic may know that though the guide does not explicitly state so, the uncertainty principle is generalizable to other quantum properties that form correlate pairs. The most well-known, and only one the guide discusses, is position and momentum.