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Chemical Arithmetic WebQuest Worksheet Follow the WebQuest Process and answer the problems in each section. Section A 1. Calculate the formula mass of each of the following substances. a. sodium chloride (table salt) NaCl 22.99 amu + 35.45 amu = 58.44 amu b. iron (III) chloride (wastewater treatment chemical) FeCl3 55.85 amu + 3(35.45 amu) = 162.20 amu c. calcium carbonate (ingredient in antacids) CaCO3 40.08 amu + 12.01 amu + 3(16.00 amu) = 100.09 amu 2. How many molecules are contained in 1.0 mole of CH4? 1.0 mole CH4 6.02 x 1023 molecules CH4 = 6.02 x 1023 molecules CH4 1.0 mole CH4 3. How many molecules are contained in 5.0 moles of CO2? 5.0 mole CO2 6.02 x 1023 molecules CO2 = 3.01 x 1024 molecules CO2 1.0 mole CO2 4. Calculate the molar mass of each of the following substances. a. lithium carbonate (a drug used to treat bipolar disorder) Li2CO3 2(6.98 g/mole) + 12.01 g/mole + 3(16.00 g/mole) = 73.89 g/mole b. C13H21NO3 (albuterol, a drug used to treat asthma) C13H21NO3 13(12.01 g/mole) + 21(1.01 g/mole) + 14.01 g/mole + 3(16.00 g/mole) = 239.35 g/mole Section B 1. Ethyl chloride, a local anesthetic, has a chemical formula of C2H5Cl. How many moles of carbon atoms, hydrogen atoms and chlorine atoms are present in a 2.3 mole sample of ethyl chloride? 2.3 mole C2H5Cl 2 moles C atoms = 4.6 moles C atoms 1 mole C2H5Cl 2.3 mole C2H5Cl 5 moles H atoms = 12 moles H atoms 1 mole C2H5Cl 2.3 mole C2H5Cl 1 mole Cl atoms = 2.3 moles Cl atoms 1 mole C2H5Cl 2. Calculate the number of grams contained in each of the following number of moles. a. 0.500 mole of NaCl 58.44 g NaCl 0.500 mole NaCl = 29.2 g NaCl 1 mole NaCl b. 3.6 moles of C2H4 28.06 g C2H4 3.6 mole C2H4 = 1.0 x 102 g C2H4 1 mole C2H4 c. 0.820 moles of C6H8O6 0.820 mole C6H8O6 176.14 g C6H8O6 = 144 g C6H8O6 1 mole C6H8O6 3. How many moles are contained in each of the following? a. 100. g CaCl2 100. g CaCl2 1 mole CaCl2 = 0.901 mole CaCl2 110.98 g CaCl2 b. 25.5 g H2O 25.5 g H2O 1 mole H2O = 1.42 mole H2O 18.02 g H2O c. 0.250 g C9H8O4 0.250 g C9H8O4 1 mole C9H8O4 = 1.39 x 10-3 mole C9H8O4 180.17 g C9H8O4 4. Determine the mass, in grams, of 7.50 x 1017 atoms of He. 7.50 x 1017 atoms He 1 mole He = 4.98 x 10-6 mole He 6.02 x 1023 atoms He Section C 1. Write a chemical equation when gaseous methane (CH4) is heated with gaseous chlorine (Cl2) to produce liquid carbon tetrachloride (CCl4) and gaseous hydrogen chloride (HCl). CH4 + Cl2 CCl4 + HCl 2. Balance the chemical equation above. CH4 + 4 Cl2 CCl4 + 4 HCl 3. Write a balanced equation for each reaction. a. Fe + O2 Fe2O3 2 Fe + 3 O2 b. CH4 + Cl2 CH4 + 2 Cl2 2 Fe2O3 CH2Cl2 + HCl 2 CH2Cl2 + 2HCl 4. Write a balanced equation for the reaction of glucose (C6H12O6) with oxygen (O2) to form carbon dioxide (CO2) and water (H2O). C6H12O6 + 6 O2 6 CO2 + 6 H2O Section D 1. Balance the following equation: N2(g) + O2(g) N2 + O 2 NO(g) 2 NO a. How many moles of NO are formed from 3.3 moles of N2? 3.3 mole N2 2 mole NO = 6.6 mole NO 1 mole N2 b. How many moles of NO are formed from 0.50 moles of O2? 0.50 mole O2 2 mole NO = 1.0 mole NO 1 mole O2 c. How many moles of O2 are needed to form 1.8 moles of NO? 1.8 mole NO 1 mole O2 = 0.9 mole O2 2 mole NO d. How many moles of N2 are needed to completely react with 1.2 moles of O2? 1.2 mole O2 1 mole N2 = 1.2 mole N2 1 mole O2 2. Balance the following equation: Na(s) + H2O(l) 2 Na + 2 H2O NaOH(aq) + H2(g) 2 NaOH + H2 a. How many grams of NaOH are formed from 3.0 moles of Na? 3.0 mole Na 2 mole NaOH 40.00 g NaOH = 120 g NaOH 2 mole Na 1 mole NaOH b. How many grams of H2 are formed from 0.30 mole of Na? 0.30 mole Na 1 mole H2 2.02 g H2 = 0.30 g H2 2 mole Na 1 mole H2 c. How many grams of H2O are needed to react completely with 0.20 mole Na? 0.20 mole Na 2 mole H2O 18.02 g H2O = 3.6 g H2O 2 mole Na 1 mole H2O 3. Balance the following equation: Fe2O3(s) + CO(g) Fe2O3 + 3 CO Fe(s) + CO2(g) 2 Fe + 3 CO2 a. How many grams of Fe are formed from 10.0 g of Fe2O3? 10.0 g Fe2O3 1 mole Fe2O3 2 mole Fe 55.85 g Fe 1 mole Fe2O3 1 mole Fe = 6.99 g Fe 159.70 g Fe2O3 b. How many grams of Fe2O3 are needed to react completely with 25.5 g of CO? 25.5 g CO 1 mole CO 1 mole Fe2O3 159.70 g Fe2O3 28.01 g CO 3 mole CO 1 mole Fe2O3 = 48.5 g Fe2O3