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MEASUREMENTS What is the difference between these two measurement rulers? Should we record the same number for each scale reading? The second scale gives us more information, it is more precise. When writing measurements, we record the digits that we are certain of plus one estimated or uncertain digit. We consider these number significant digits 8.9 cm 8.95 cm 6.00 cm 1120 cm 0.0260 cm Significant Digits or Significant Figures • We must be aware of the limits of precision for each piece of lab equipment that we use. • We must record our data to the proper number of significant figures. • You are always allowed one estimated figure in measurements • When measured quantities are given to you, it is assumed that the proper number of significant figures were recorded. Rules for Counting Significant Figures • All non-zero digits are significant. 4 3 5 1 473 in _____ 785 m _____ 387.56 cm ____ • Zeros: – Leading Zeros are not significant. 3 1 2 0.421 L _____ 0.5 mL _____ 0.0011 cm _____ – Captive Zeros are significant. 5 70 304 m _____ 395.01 L _____ 1.008 m _____ 5 4 – Trailing Zeros are significant if there is a decimal point. 5 3 7 12.380 cm _____ 1.30 in _____ 1691.100 L _____ – Trailing Zeros are not significant if there is no decimal point. 2 500 in _____ 800 m _____ 9 010 mL _____ 2 1 3 Determine the amount of significant figures in the following examples: 3 967 L _____ 4 0.111 0 mL _____ 4 0.005 670 m _____ 4 4.530 cm _____ 4 2.700 mm _____ 4 0.006 007 m _____ 3 9.67 L _____ 1 0.000 008 mL _____ 6 0.800 008 m _____ Calculating with Significant Figures • Multiply/Divide: The number with the fewest number of sig figs will determine the number of sig figs in the answer. – Example (13.92 g/cm3)(23.3 cm3 ) = 324.103 g 4 sig figs 3 sig figs 3 sig figs 324 g Calculating with Significant Figures • Addition/Subtraction: The number with the fewest amount of decimal places determines the amount of decimal places in the answer . – Example 3.76 g + 14.83 g + 2.1 g = 20.69 g 2 decimal places 2 decimal places 1 decimal places 1 decimal places 20.7 g Rounding Rules • Round this number to 3 sig. figs. 5.29753 • Count the number of significant figures you need from left to right and underline the last sig. fig. you need. • 5.28753 • Look at the number next to the number you have underlined. Is it less than 5 or 5 and up? • 5.28753 • If the number is less than 5 (1-4) you will leave the number you have underlined as it is. • If the number is 5 or greater (5-9) you will round the number underlined up to the next number. • 5.29 Scientific Notation • Scientific notation is the way that scientists easily handle very large numbers or very small numbers. – Example: instead of writing 0.0000000056, we write 5.6 x 10-9. 10000 = 1 x 104 24327 = 2.4327 x 104 1000 = 1 x 103 7354 = 7.354 x 103 100 = 1 x 102 482 = 4.82 x 102 10 = 1 x 101 89 = 8.9 x 101 (not usually done) 1 = 100 1/10 = 0.1 = 1 x 10-1 0.32 = 3.2 x 10-1 (not usually done) 1/100 = 0.01 = 1 x 10-2 0.053 = 5.3 x 10-2 1/1000 = 0.001 = 1 x 10-3 0.0078 = 7.8 x 10-3 1/10000 = 0.0001 = 1 x 10-4 0.00044 = 4.4 x 10-4 Scientific Notation • The exponent of 10 is the number of places the decimal point must be shifted to give the number in long form. – A positive exponent shows that the decimal point is shifted that number of places to the right. – A negative exponent shows that the decimal point is shifted that number of places to the left. – 46600000 = 4.66 x 107 – 0.00053 = 5.3 x 10-4