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1st Semester - Module 3 WEEK 3 Introductory Message For the facilitator: This module was collaboratively designed, developed and evaluated by the Development and Quality Assurance Teams of SDO TAPAT to assist you in helping the learners meet the standards set by the K to 12 Curriculum while overcoming their personal, social, and economic constraints in schooling. As a facilitator, you are expected to orient the learners on how to use this module. You also need to keep track of the learners' progress while allowing them to manage their own learning. Furthermore, you are expected to encourage and assist the learners as they do the tasks included in the module. For the learner: This module was designed to provide you with fun and meaningful opportunities for guided and independent learning at your own pace and time. You will be enabled to process the contents of the learning resource while being an active learner. The following are some reminders in using this module: 1. Use the module with care. Do not put unnecessary mark/s on any part of the module. Use a separate sheet of paper in answering the exercises. 2. Don’t forget to answer Let’s Try before moving on to the other activities included in the module. 3. Read the instruction carefully before doing each task. 4. Observe honesty and integrity in doing the tasks and checking your answers. 5. Finish the task at hand before proceeding to the next. 6. Return this module to your teacher/facilitator once you are through with it. If you encounter any difficulty in answering the tasks in this module, do not hesitate to consult your teacher or facilitator. Always bear in mind that you are not alone. We hope that through this material, you will experience meaningful learning and gain deep understanding of the relevant competencies. You can do it! 2 Let’s Learn Compounds react to one another just as how elements combine chemically and through these interactions, different new compounds are formed. In this module, you will discover how to write these chemical reactions to fully understand what happens during the interactions of elements to compounds and/or compounds to another compounds. You will also learn how to balance these equations in preparation for mass relationships. Hence, you will use your knowledge in interpreting balanced chemical equations in terms of particles, moles, and mass in making molar relationships from one substance to another. This module has the following lessons: Lesson 1: Balancing Chemical Equations Lesson 2: Amounts of Substances in a Chemical Reaction After going through this module, you are expected to: 1. write and balance chemical equations; and 2. construct mole or mass ratios for a reaction in order to calculate the amount of reactant needed or amount of product formed in terms of moles or mass. Let’s Try PRE-ASSESSMENT. Access the pre-assessment in the link below: https://forms.gle/zDXCgmn4FmtyQEmq9 (Please note that an updated school link will be given by your subject teacher to access the pre-assessment file.) 3 Lesson 1 Writing and Balancing Chemical Equations Chemical reactions are happening every time everywhere, and for us to understand what transpires during these interactions we must be able to write and balance chemical equations. Let’s Recall 1. What is the difference between an empirical formula and a molecular formula? 2. Dichloroethane, a compound that is often used for dry cleaning, contains carbon, hydrogen, and chlorine. It has a molar mass of 99 g/mol. Analysis of a sample shows that it contains 24.3% carbon and 4.1% hydrogen. What is its molecular formula? Let’s Explore Spot the difference. Directions: Encircle the differences you were able to locate on these pictures. Image 1 Image 2 1. What makes image 1 different from image 2? 2. What similarities do these two images have? 3. How can this be related to chemistry? Let’s Elaborate In the previous module, you learned that elements combine to form different compounds. These elements and compounds may then be represented using symbols and formulas, respectively. You also learned that each substance has its own mass which can be calculated using important information seen in the periodic table. In this lesson you will learn what happens when elements and compounds interact with one another and be able to describe it using words and chemical symbols or formulas. 4 EVIDENCES OF CHEMICAL REACTION Before writing and/or classifying chemical reactions, you must know how to identify if a chemical reaction occurred. There are several evidences that can help you prove its occurrence. Here are some of the evidences and their examples (Brooks 2018; Study.com 2017): Table 3.1 Evidences of chemical reactions Evidence Example Change in color a half-eaten apple turns brown after exposure to air Change in odor food slowly spoils and smells rotten Formation of a solid or the formation of deposits when calcium oxides mix with water precipitate and clogs pipes Evolution of gas (bubble an antacid is dropped in a glass of water and begins to produce formation) bubbles Change in temperature is when a burning fire produces heat Production of light is the chemical reaction in the bodies of fireflies that allows them to produce light Volume change when magma inside a volcano expands rapidly due to chemical reactions that happen inside the volcano TYPES OF CHEMICAL REACTIONS Here are the five major types of chemical reactions (Licuanan 2016; Helmenstine 2020): A. Synthesis Reactions When two or more elements or compounds combine to form a new substance, we call this reaction as a synthesis reaction. It is also known as the combination reaction. The general equation for this type of reaction is: A + B → AB Example: 2C(s) + O2(g) → 2CO(g) B. Decomposition Reactions In a decomposition reaction, a reactant (compound) breaks into two or more products (an element or another compound). It is the opposite of a synthesis reaction. The simplest decomposition reaction occurs when a compound breaks into its component element. A complex decomposition, on the other hand, is resulting from the breaking down of compounds into another compounds. The general equation for this reaction is: AB → A + B Example: CaCO3(s) → CaO(s) + CO2(g) C. Single Displacement Reaction In a single displacement reaction, a free element replaces another element in a compound. This free element is more reactive than the element it replaces. This reaction is also known as substitution reaction. The general form of this reaction is: A + BC → AC + B Example: Mg(s) + Cu(NO3)2(aq) → Mg(NO3)2(aq) + Cu(s) Note that not all single displacement reaction Figure 3.1: Reactivity series of some produces result. It depends on the reactivity of the common metals [1] elements involved in the reaction. Normally, a more reactive element replaces the less reactive element in the reaction. This means that in cases where the element to be replaced is more reactive than the free element, a reaction will not occur. To help you determine whether a single displacement reaction will occur or not, a table of reactivity series of some common elements is provided in Figure 3.1. 5 D. Double Displacement Reaction A double displacement reaction, also known as metathesis reaction, happens when two ionic compounds exchange ions. A positive ion from the first compound will combine with the negative ion of the second compound, and the positive ion of the second compound combines with the negative ion of the first. This reaction usually happens when the compound is in an aqueous solution. The general form of this equation is: AB + CD → AD + CB Example: 2KI(aq) + Pb(NO3)2(aq) → 2KNO3(aq) + PbI2(s) E. Combustion Reaction This is an important classification of chemical reactions. In a combustion reaction a compound or element reacts with O2 to form oxides of the element. A carbon-containing compound will form carbon dioxide (CO2), when combusted. A sulfur-containing compound that reacts with oxygen will form sulfur dioxide (SO2). The most common combustion reaction is the combustion of hydrocarbons. Hydrocarbons contain C, and H, so when completely combustion happens it will form carbon dioxide and water as byproducts. The general formula for this reaction is Hydrocarbon + O2 → CO2 + H2O Example: CH4(g) + 2O2(g) → CO2(g) + 2H2O(g) The process in which substances interact with one another to form new substances is called a chemical reaction. The substance that undergoes a chemical reaction is called a reactant while the newly formed compound is known to be the product. For us to be able to understand chemical reactions, chemists have devised a way to represent them. They used chemical equations. Chemical equations use chemical symbols to show what happens to substances during chemical reactions. These equations come in different forms and can convey a great deal of information. (Chang and Goldsby 2016; Ebbing and Gammon 2009). WRITING CHEMICAL EQUATIONS A. Word Equations A chemical reaction may be written using the names of the substances involved. This equation is called a word equation. (Mustoe et al. 2011) Example: sodium reacts with chlorine to form sodium chloride Word equation: sodium + chlorine → sodium chloride B. Skeleton Equations A skeleton equation uses chemical formulas to simplify the chemical equation. It uses different signs and symbols that are used to illustrate the chemical equation (Mustoe et al. 2011). Let us use again the example chemical reaction mentioned above: Example: sodium reacts with chloride to form sodium chloride Skeleton equation: Na + Cl2 → NaCl In both equations, “+” means combine or reacts with and “→” means to form. The formulas on the left side of the arrow represents the reactants or the starting substance in a chemical reaction. The formulas on the right side refer to the products or results from a reaction. However, this equation is incomplete, if you look closely the number of atoms of chlorine in the reactant side is not the same as the number of its atoms on the product side. To be consistent with the Law of Conservation of Mass which states that mass is neither created nor destroyed, the number of atoms of each type of element on both sides must be the same. Thus, we need to balance the equation, and this is done by placing the appropriate coefficient in front of the compounds or elements. These coefficients give the relative number of molecules or formula units involved in the reaction. (Chang and Goldsby 2016; Flowers et al. 2018). It is understood that 1 is the coefficient when there is no number written in front of the formula. When we place a coefficient in the equation above, it will look as: 6 2Na + Cl2 → 2NaCl After placing the coefficients, you may see that each atom on both sides are of the same number. Sometimes, it is also useful to indicate the states of the substances in an equation. There are appropriate labels to indicate them. These are placed within parentheses following the chemical formula (refer to Table 3.2 for the list of symbols). After placing the phase labels, the previous equation will become: 2Na(s) + Cl2(g) → 2NaCl(s) In the equation, you can also indicate the conditions under which the reaction takes place. If the reaction is heated, you may place ∆ (capital Greek delta) over the arrow. If a catalyst, a substance that speeds up the reaction without being used up in the reaction, is involved you may write it over the arrow. See examples below: 2NaNO3(s) 2H2O2(aq) ∆ Pt Table 3.2: Symbols used in Chemical Equations Symbol + + → (s) or ↓ (l) (g) or ↑ (aq) ∆ Pt ↔ 2NaNO2(s) + O2(g) 2H2O(l) + O2(g) Meaning reacts with (reactant side) and (product side to yield solid or precipitate liquid gas in aqueous solution heat catalyst a reaction is reversible Note that platinum, Pt, is not the only catalyst that is used in chemical reactions. Other catalysts are iron, nitrogen (II) oxide, nickel, and many others. In cases that both heat and catalyst are used, you may combine the two symbols by placing one above the arrow and the other below the arrow. BALANCING CHEMICAL EQUATIONS When the coefficients in a chemical equation are correct, the number of atoms of each element are equal on both sides, then the equation is said to be balanced. When writing a chemical equation, one must identify first the identity of each of the substances involved. After the identities are identified, chemical formulas are written and then assembled in a sequence – reactants separated by an arrow from products. In this point, the equation that you wrote is likely to be unbalanced. This means that the number of atoms in the reactant side is not the same with the number of the same atoms in the product side. You must remember that in a chemical reaction, the atoms simply recombine but none are created nor destroyed. Generally, we can balance a chemical equation by following these steps (Chang and Goldsby 2016): STEP 1: Write the skeleton equation by identifying all reactants and products. STEP 2: Balance the equation by changing the coefficients of the reactants or products. You may only change the coefficient and not the subscripts since it will change the identity of the substance. You must also remember the following: 1. Use the smallest whole number coefficient. 2. Leave hydrogen, oxygen, and other elements until later. 3. Treat polyatomic ions as one unit, example phosphate, PO 4-3. 4. Balance last the elements that occur in its uncombined state, example Na or H 2. STEP 3: Check your balanced equation. Make sure that the total number of each type of atoms on both sides are equal. Let us consider the example below: Potassium nitrate and solid copper(II) hydroxide are formed from the reaction between copper(II) nitrate and potassium hydroxide. Write the balanced chemical equation for this sample. (1) Identify which are the reactants and products then write the skeleton equation: Cu(NO3)2(aq) + KOH(aq) → Cu(OH)2(s) + KNO3(aq) (2) Plan your strategy. Since all formulas involve polyatomic ions (NO 3-, then OH-), you are to balance them first. Then check if it is balanced, if not try to balance copper and potassium ions. 7 (3) Act on your strategy. There are two NO3- ions on the reactant side and one on the product side, you may place 2 in front of KNO3. Cu(NO3)2(aq) + KOH(aq) → Cu(OH)2(s) + 2KNO3(aq) Likewise, there are two OH- ions on the product side, so place 2 in front of KOH. Cu(NO3)2(aq) + 2KOH(aq) → Cu(OH)2(s) + 2KNO3(aq) (4) Check to see if the number of each type of atom on each side of the equation is balanced. Cu(NO3)2(aq) + 2KOH(aq) → Cu(OH)2(s) + 2KNO3(aq) Atoms or Ions Reactant side Product side Cu 1 1 NO32 2 K 2 2 OH 2 2 (5) Since the number of each type of atom on each side is balanced, therefore the chemical equation is balanced. Note that the steps in balancing mentioned above is balancing by inspection which is also a trial-and-error method. There is no definite step in balancing, but the listed steps above may be considered as hints or reminders to help us in balancing (Chang and Goldsby 2016; Licuanan 2016; Flowers et al. 2018). What is the purpose of balancing chemical equations? Balancing equations in chemistry gives us the correct proportions of the reactants and products. It will tell you how much product will be produced for a given chemical reaction using the given set of reactants. Your knowledge in balancing is also essential when solving mass relationships and other computations involving chemical reactions. INTERPRETING CHEMICAL EQUATIONS A balanced chemical equation can give us a great deal of information about the chemical reaction it represents. Let us look at the example below: N2 + 3H2 2NH3 One molecule One mole + + Three molecules Three moles Two molecules Two moles 2(14.007 g) = 28.014 g + 3(2.016 g) = 6.048 g 2(17.031 g) = 34.062 g 34.062 g 34.062 g Looking at the example above we may say that the balanced equation followed the Law of Conservation of Mass which says that total mass of reactants is equal to the total mass of the product after chemical reaction. This information will then be used for many purposes. Let’s Dig In ACTIVITY 1 Directions: Write a skeleton equation with proper labels for each reaction then classify which type of chemical reaction it represents. 1. Solid zinc reacts with chlorine gas to form solid zinc chloride. 2. Aqueous lead (II) nitrate reacts with solid magnesium to yield aqueous magnesium nitrate and solid lead. 3. Aqueous barium chloride reacts with aqueous sodium sulfate to yield an aqueous sodium chloride and barium sulfate as precipitate. 8 4. Liquid ethanol reacts with oxygen gas to produce carbon dioxide and water 5. Solid iron reacted with oxygen gas to form solid ferric oxide ACTIVITY 2 Directions: Balance the following equations: 1. __C2H6(g) + __O2(g) → __CO2(g) + 2. __Be2C + __H2O → __Be(OH)2 + 3. __NH3(g) + __O2(g) → __NO(g) + 4. __Ca3(PO4)2(aq) + __H3PO4(aq) → 5. __Fe2(SO4)3 + __NH3 + __H2O → __H2O(l) __CH4 __H2O(l) __Ca(H2PO4)2(aq) __Fe(OH)3 + __(NH4)2SO4 Let’s Remember Chemical reactions can be represented using chemical equations. These chemical equations are then balanced to satisfy the Law of Conservation of Mass. When balancing only the coefficients in front of each chemical formula are changed. Chemical equations can be classified as synthesis, decomposition, single displacement, double displacement and combustion reaction. Let’s Apply Directions: Accomplish the following, write your answers in a clean bond paper. A. Look around inside or outside your house. Identify five (5) activities that involve a chemical reaction. Once identified, describe what evidence/s you saw that helped you in determining the occurrence of chemical reactions. B. Using the activities that you wrote in A., write a chemical equation that may represent this reaction. Balance and classify the chemical equation. Lesson 2 Amounts of Substances in a Chemical Reaction Balanced chemical equations are used by to solve mass relationships in chemical reactions. There are different ways that we may find these balanced chemical equations useful, and one of it is that it makes stoichiometric calculations easier. Let’s Recall 1. How do we balance chemical equation? 2. Why do we need to balance chemical equations? 3. Balance the following equations: (Example: B2Br6 + 6 HNO3 → 2 B(NO3)3 + 6 HBr) a. __Na3PO4 + __HCl → __NaCl + __H3PO4 b. __TiCl4 + __H2O → __TiO2 + __HCl c. __NH3 + __O2 → __NO + __H2O d. __Fe + __HC2H3O2 → __Fe(C2H3O2)3 + __H2 e. __Hg(OH)2 + __H3PO4 → __Hg3(PO4)2 + __H2O 9 Let’s Explore COOKIES SCENARIO: You and your groupmates were tasked to make 100 cookies for a school event. You searched on the internet for the recipe and here is what you got: Ingredients: 4 tbsp unsalted butter 1/3 cup brown sugar 1/3 cup white, granulated sugar 1 egg 1 cup All Purpose Flour 1 tbsp cornstarch ½ tsp baking soda ¼ tsp Kosher salt Directions: 1. Create an “equation” based on these ingredients. 2. What is the ratio of each ingredient to another? 3. How many cookies will you be able to make if you only have 6 cups of sugar? 4. How many ingredients will you need to make all 100 cookies? Makes 20 cookies Let’s Elaborate As you learned from the previous lesson that a balanced chemical equation gives a lot of information about the reaction that took place. It relates the amounts of substances in a reaction. The coefficients you write in front of the chemical formulas represents number of moles as well as particles. It also provides the relative amounts of both reactant and product allowing you to be able to do quantitative assessments on both chemical species. Thus, you may use this information to relate one substance to another quantitatively. The quantitative study of reactants and products in a chemical reaction is called stoichiometry (Chang and Goldsby 2016; Licuanan 2016; Flowers et al. 2018). In stoichiometry we use moles to calculate the amount of product formed whether the units of reactants (or products) are moles, grams, or liters. This approach is called the mole method, which means that the stoichiometric coefficients can be interpreted as the number of moles of each substance. And we use these moles to relate reactants to products and vice versa. Basically, stoichiometry is a similar concept to how people go about different activities. Let us say for example, when you prepare food. A simple recipe for one ham sandwich requires two slices of bread, a slice of ham, a slice of cheese and a slice of tomato. Just as what you did in Activity 1, the recipe may be represented by the following “equation”: 2 slices of bread + 1 slice of ham + 1 slice of cheese + 1 slice of tomato = 1 ham sandwich Suppose that you have 12 slices of ham, how many slices of bread will you need to use all the ham? Looking at the “equation” above, the ratio of bread to ham is 2:1, and we may use it to compute as follows: 2 slices of bread 12 slices of ham x = 24 slices of bread 1 slice of ham Balanced chemical equations are used in the same manner, we use it to determine the amount of one reactant required to react with a given amount of another reactant or needed to produce a given amount of product, and so on. The coefficients are used as stoichiometric factors or molar ratios to be able to compute for a desired quantity (Flowers et al. 2018). To illustrate, consider the equation below: 4 Al(s) + 3 O2(g) → 2 Al2O3(s) 10 The stoichiometric coefficients show that four molecules of Al react with three molecules of O2 to produce 2 molecules of Al2O3. This equation can be interpreted as: 4 Al(s) 4 molecules 4 (6.022 x 1023 molecules) + 3 O2(g) 3 molecules 3 (6.022 x 1023 molecules) 4 mol → 3 mol 2 Al2O3(s) 2 molecules 2 (6.022 x 1023 molecules) 2 mol This equation may also be read as “4 moles of Al metal combines with 3 moles of O 2 gas to form 2 moles of solid Al2O3.” It shows that aluminum oxide molecules are produced from oxygen molecules in a 2:3 ratio. It also says that 2 moles of Al2O3 are stoichiometrically equivalent to 3 moles O2 and to 4 moles of Al. Looking at the balanced chemical equation we may write molar ratios as: 2 Al2O3 molecules 2 mol Al2O3 or 3 O2 molecules 3 mol O2 2 Al2O3 molecules 4 Al molecules or 2 mol Al2O3 4 mol Al 3 O2 molecules 4 Al molecules or 3 mol O2 4 mol Al These molar ratios can be used to compute the amount of aluminum oxide molecules produced form a given amount of oxygen molecules or from a given amount of aluminum molecules. Likewise, we may also use these molar ratios to compute for the required amount of aluminum molecules to produce a given amount of aluminum oxide molecules and so on. Let us use this as an example: EXAMPLE 1: Using the balanced chemical equation: 4 Al(s) + 3 O2(g) → 2 Al2O3(s) Molar ratios 4 moles Al : 3 moles O2 : 2 moles Al2O3 a. How many moles of Al2O3 will be produced if 12.1 moles of O2 reacts completely with Al? (moles O2 → moles Al2O3) 2 moles Al2O3 12.1 moles O2 x = 8.07 moles Al2O3 3 moles O2 b. How many moles of Al are needed to produce 50.7 moles Al2O3? (moles Al2O3 → mol Al) 4 moles Al 50.7 moles Al2O3 x = 101 moles Al 2 moles Al2O3 c. How many grams of Al2O3 will be produced from 36.1 moles O2? (moles O2 → moles Al2O3 → grams Al2O3) 2 moles Al2O3 101.96 g Al2O3 36.1 moles O2 x x = 2.45 x 103 g Al2O3 3 moles O2 1 mole Al2O3 d. How many grams of Al2O3 will be produced from 82 g of Al as it completely reacts with O2? (grams Al → moles Al → moles Al2O3 → grams Al2O3) 1 mole Al 2 moles Al2O3 101.96 g Al2O3 82 g Al x x x = 150 g Al2O3 26.98 g Al 4 mole Al 1 mole Al2O3 Note that to convert grams to moles requires the atomic weight of the element and/or molar mass of the compound (sum of the atomic weights of each element in the compound). Examples 1c and 1d, show us how these atomic weights are used to convert grams to moles and vice versa. 11 EXAMPLE 2: Certain race cars use methanol, also called as wood alcohol, as a fuel. In a reaction, 28.83 g of methanol are reacted with an excess of O2. Calculate the amount in grams of CO2 formed. To solve this sample problem, remember to start by writing and balancing the chemical equation first. This will always be your first step in every stoichiometric calculation. (1) Balanced equation: 2CH3OH(l) + 3O2(g) → 2CO2(g) + 4H2O(l) (2) Molar Ratios: 2 moles CH3OH : 3 moles O2 : 2 moles CO2 : 4 moles H2O (3) Required: Number of molecules of CO2 (4) Solution: g CH3OH → moles CH3OH → mole CO2 → g CO2 1 mole CH3OH 2 moles CO2 44.01 g CO2 28.83 g x x x = 39.60 g CO2 CH3OH 32. 04 g CH3OH 2 moles CH3OH 1 mole CO2 From examples 1 and 2, you may see that you may convert moles of one substance to moles of another substance, moles of the reactant to mass of the product, grams of the reactant to the grams of the product and so on. All these conversions are made easy by the stoichiometric factors or molar ratios. These molar ratios we construct from the coefficients of the balanced chemical equation is like a gateway to converting one unit of a substance to the desired unit of another substance. But these are not the only units that we could convert into using stoichiometry, look at the example below: EXAMPLE 3 The reaction of iron (III) oxide with powdered aluminum is known as the thermite reaction. A. Calculate the mass of aluminum oxide, Al2O3, that is produced when 1.65 x 1022 atoms of Al reacts with Fe2O3. B. Find how many formula units of Fe2O3 are needed to react with 0.214 g of Al? This example involves the conversion of mass to particles (atoms, molecules, ions, or formula units) therefore we will be using our knowledge of the mole concept in this problem. You learned that one mole of a substance is equal to 6.022 x 10 23 particle units. The number 6.022 x 1023 is also known as the Avogadro’s number. You can use this number or constant to convert between mass and number of particles. Let us now solve the given problem. (1) Balanced equation: (2) Molar ratio: (3) Required in A: (4) Solution for A: 1.65 x 1022 atoms Al x 2Al(s) + Fe2O3(s) → Al2O3(s) + 2Fe(l) 2 moles Al : 1 mole Fe2O3 : 1 mole Al2O3 : 2 moles Fe mass of Al2O3 (atoms Al → moles Al → moles Al2O3 → g Al2O3) 1 mole Al 1 moles Al2O3 101.96g Al2O3 23 x 6.022 x 10 atoms x 2 moles Al 1 mole Al2O3 Al = (5) Required in B: (6) Solution for B: 0.214 g Al x 1 mole Al 26.98 g Al 1.40 g Al2O3 formula units of Fe2O3 (g Al → moles Al → moles Fe2O3 → formula units Fe2O3) x 1 moles Fe2O3 2 moles Al x 6.022 x 1023 formula units Fe2O3 1 mole Fe2O3 = 2.39 x 1021 formula units Fe2O3 12 The general process for solving stoichiometric problems is summarized using the map in Figure 3.2 below: Figure 3.2: Stoichiometry Map Retrieved from: https://socratic.org/questions/how-to-solve-the-problems-of-stiohiomertywhat-is-the-formula-of-stiohiomerty Let’s Dig In ACTIVITY 1 Directions: Answer the following. Write the final answers in the correct significant figures. 1. Consider this reaction: Ba3N2 + 6 H2O → 3 Ba(OH)2 + 2 NH3 a. What is the ratio of Ba3N2 molecules to H2O molecules to Ba(OH)2 molecules to NH3 molecules? b. How many molecules of Ba3N2 is required to react with H2O to form 50 molecules of NH3 based on your ratio in part (a)? c. How many molecules of H2O are required to react completely with 6.022 x 10 23 molecules of Ba3N2? d. How many moles of Ba(OH)2 will be formed from the complete reaction of 48.3 moles Ba3N2? 2. Consider this reaction: 4 FeS + 7 O2 → 2 Fe2O3 + 4 SO2 a. What is the ratio of FeS molecules to O2 molecules to Fe2O3 molecules to SO2 molecules? b. How many molecules of SO2 will be produced from 16 molecules of FeS? c. How many molecules of O2 is required to react with FeS to yield 14 molecules of Fe2O3? d. How many moles of FeS is required to produce 18.9 g of Fe2O3? ACTIVITY 2 Directions: Write the balanced chemical equations of the following problems and compute for the required values. Show your solutions for each item. Answers must be in the correct significant figures. 1. Phosphorus pentachloride, PCl5, reacts with water to form phosphoric acid, H 3PO4, and hydrochloric acid, HCl. a. What mass of PCl5 is needed to react with an excess quantity of H2O to produce 33.9 g of H3PO4? b. How many molecules of H2O are needed to react with 4.07 g of PCl5? 2. Butane, C4H10, burns with oxygen in air to give carbon dioxide and water. a. What is the amount of water produced from 0.35 mol butane? b. How many grams of carbon dioxide will be produced if 34.0 g of butane is burned completely? 13 Let’s Remember Stoichiometric computations are made easy through the molar ratios we can obtain from the correct balanced chemical equations of a given reaction. We can use this ratio to convert moles of reactants to moles of product, moles of reactant to grams of product, grams of reactant to grams of product and more. Let’s Apply Directions: From the following list of household activities, state how stoichiometry is being used. Give an example on how stoichiometric calculations are applied in each given activity and briefly narrate how important these calculations are for the activity. Use the table below to organize your answers. Write your output in a clean short bond paper. A. Washing clothes B. Making coffee C. Preparing vegetable salad Household activity Washing clothes Making coffee Preparing vegetable salad How stoichiometry is used. Example of calculations applied Importance of stoichiometry calculation Let’s Evaluate POST ASSESSMENT. Access the post assessment in the link below: https://forms.gle/WtiDuLeSGC79wkJ96 (Please note that an updated school link will be given by your subject teacher to access the post assessment file.) 14 Let’s Extend POSTER MAKING Objective: To inform other people about the relation of different types of chemical reactions to daily life and how they can affect us. Instructions: 1. Create an interesting poster about a type of chemical reaction of choice. 2. The poster must include the following parts: a. Title of Poster b. Definition of chemical reaction c. Definition of the type of chemical reaction chosen. d. The general form of the chemical reaction. e. Give 2 real-life examples of this reaction f. Images/Drawings of the example g. Balanced chemical equations h. Discussion of its effect to the body, the environment, the industry and/or nature in general. i. Your name and section j. References/Sources 3. You may opt to choose to create: a. an e-poster (that you will be sending to your teacher online) b. a physical poster (handwritten or printed in a 17” by 28” paper / 2 long bond papers taped together) 4. The finished product must be submitted at least a week after you finish this module. 5. You will be graded using the following rubric: POSTER RUBRIC Category 4 3 2 1 Required Elements The poster includes all required elements as well as additional information. All items of importance on the poster are clearly labeled with labels that are readable. All required elements are included on the poster. All but 1 of the required elements are included on the poster Several required elements were missing. Almost all items of importance on the poster are clearly labeled with labels that are readable. Many items of importance on the poster are clearly labeled with labels that are readable. Labels are too small to view OR no important items were labeled. Graphics – Relevance All graphics are related to the topic and make it easier to understand. All borrowed graphics have a source citation. All graphics relate to the topic. One or two borrowed graphics have a source citation. Graphics do not relate to the topic OR several borrowed graphics do not have a source citation. Attractiveness The poster is exceptionally attractive in terms of design, layout, and neatness. All graphics are related to the topic and most make it easier to understand. Some borrowed graphics have a source citation. The poster is attractive in terms of design, layout, and neatness. The poster is acceptably attractive though it may be a bit messy. Grammar There are no grammatical/ mechanical mistakes on the poster. There are 1-2 grammatical/ mechanical mistakes on the poster. There are 3-4 grammatical/ mechanical mistakes on the poster. The poster is distractingly messy or very poorly designed. It is not attractive. There are more than 4 grammatical/ mechanical mistakes on the poster Labels SOURCE: https://www.uen.org/lessonplan/download/18726?lessonId=12365&segmentTypeId=2. 15 References [1] Reactivity Series of Metals. Google.com Accessed July 19, 2020 https://www.google.com/url?sa=i&url=http%3A%2F%2Fonelearningsolution.blogspot.com%2F2 015%2F02%2F33-reactivity-series-of-metals-and-its.html&psig=AOvVaw13xge2yTWWtcA_1d5glKQ&ust=1595242015518000&source=images&cd=vfe&ved=0CAIQjRxqFwoTCJ DT9uKR2eoCFQAAAAAdAAAAABAT “Types of Chemical Reaction” Accessed June 23, 2020 www2.ucdsb.on.ca/tiss/stretton/CHEM1/stoich2.html Brooks, Rebekah. 2018. “Seven Things That Indicate a Chemical Change Is Occurring” Accessed June 22, 2020. https://sciencing.com/seven-things-indicate-chemical-change-occurring12107532.html Chang, R. & Goldsby, K. Chemistry. (12th ed.). New York: McGraw-Hill, 2016. PDF. https://www.academia.edu/40191186/Chemistry_12th_Edition_by_Chang_and_Goldsby CK-12 Website. n.d. “Types of Chemical Reactions [Online Read]” Accessed June 23, 2020. https://www.ck12.org/book/ck-12-chemistry-intermediate/section/11.2/ Ebbing, D. D. & Gammon, S. D. General Chemistry. (9th ed.). New York: Houghton Mifflin Company, 2009. https://www.academia.edu/40212587/General_Chemistry_9thEbbing.Gammon?email_work_card=view-paper Flowers, P., K. Theopold, R. Langley & W.R. Robinson. 2018. Chemistry. Rice University: OpenStax https://openstax.org/details/books/chemistry Helmenstine, Anne Marie, Ph.D. 2019. "Examples of 10 Balanced Chemical Equations." ThoughtCo. Accessed June 22, 2020. https://www.thoughtco.com/examples-of-10-balanced-chemicalequations-604027. Helmenstine, Anne Marie, Ph.D. 2019. "What Is a Word Equation in Chemistry?" ThoughtCo. Accessed June 23, 2020. https://www.thoughtco.com/definition-of-word-equation-605801 Helmenstine, Anne Marie, Ph.D. 2020. "Types of Chemical Reactions." ThoughtCo. Accessed June 23, 2020. https://www.thoughtco.com/types-of-chemical-reactions-604038 Licuanan, P.B. General Chemistry 1 - Teaching Guide for Senior High School. Quezon City: Commission on Higher Education, 2016 Mustoe, F., C. Clancy, T. Doram, B. Heimbecker, M. Mazza and P. McNutly. McGraw-Hill Ryerson Chemistry 11. Toronto: McGraw-Hill Ryerson, 2011. Stoichiometry Flowchart. Socratic.org Accessed July 19 2020. https://socratic.org/questions/how-tosolve-the-problems-of-stiohiomerty-what-is-the-formula-of-stiohiomerty Study.com. (2017) "Chemical Change: Signs & Evidence." Accessed June 23, 2020 https://study.com/academy/lesson/chemical-change-signs-evidence.html. NOTE: Cover photo is originally made by Victor G. Taleon ©2020 Other illustrations are originally made by Dioneda, M.A. J. ©2020 16 Development Team of the Module Writer: Ma. Christina M. Dioneda – TSHS - Teacher II Editors: Content Evaluators: Elmer L. Belza Jr. – BNHS - Teacher II Ian Luigie D. Ordoñez – GABHS – Teacher I Jimmylin U. Sollano – UBNHS – Master Teacher I Jennievive D. Dela Cruz – TSHS – Teacher II Teresita L. Baltazar – SVNHS – Master Teacher II Language Evaluator: Wilhelmina C. Estrada – TSHS – Teacher II Reviewer: Ruby N. Montefulca – TSHS – Head Teacher I Illustrator: Ma. Alexandra Jade M. Dioneda and Victor G. Taleon Layout Artists: Ma. Christina M. Dioneda, Elvira B. Bagacina and Jayson F. Antones Management Team: Dr. Margarito B. Materum - SDS Dr. George P. Tizon – SGOD Chief Dr. Ellery G. Quintia – CID Chief Dr. Marivic T. Almo – EPS Science Quinn Norman O. Arreza, J.D. SHS Focal Dr. Daisy L. Mataac – EPS – LRMS/ALS For inquiries, please write or call: Schools Division of Taguig City and Pateros Upper Bicutan Taguig City Telefax: 8384251 Email Address: [email protected] 17