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Sedimentary Geology 181 (2005) 73 – 91 www.elsevier.com/locate/sedgeo Late Ordovician (Ashgillian) glacial deposits in southern Jordan Brian R. Turner a,*, Issa M. Makhlouf b, Howard A. Armstrong a a Department of Earth Sciences, University of Durham, Science Laboratories, South Road, Durham, DH1 3LE, UK b Department of Earth and Environmental Sciences, Hashemite University, Zarqa, Jordan Received 29 March 2005; received in revised form 8 August 2005; accepted 26 August 2005 Abstract The Late Ordovician (Ashgillian) glacial deposits in southern Jordan, comprise a lower and upper glacially incised palaeovalley system, occupying reactivated basement and Pan-African fault-controlled depressions. The lower palaeovalley, incised into shoreface sandstones of the pre-glacial Tubeiliyat Formation, is filled with thin glaciofluvial sandstones at the base, overlain by up to 50 m of shoreface sandstone. A prominent glaciated surface near the top of this palaeovalley-fill contains intersecting glacial striations aligned E–W and NW–SE. The upper palaeovalley-fill comprises glaciofluvial and marine sandstones, incised into the lower palaeovalley or, where this is absent, into the Tubeiliyat Formation. Southern Jordan lay close to the margin of a Late Ordovician terrestrial ice sheet in Northwest Saudi Arabia, characterised by two major ice advances. These are correlated with the lower and upper palaeovalleys in southern Jordan, interrupted by two subsidiary glacial advances during late stage filling of the lower palaeovalley when ice advanced from the west and northwest. Thus, four ice advances are now recorded from the Late Ordovician glacial record of southern Jordan. Disturbed and deformed green sandstones beneath the upper palaeovalley-fill in the Jebel Ammar area, are confined to the margins of the Hutayya graben, and have been interpreted as structureless glacial loessite or glacial rock flour. Petrographic and textural analyses of the deformed sandstones, their mapped lateral transition into undeformed Tubeiliyat marine sandstones away from the fault zone, and the presence of similar sedimentary structures to those in the pre-glacial marine Tubeiliyat Formation suggest that they are a locally deformed facies equivalent of the Tubeiliyat, not part of the younger glacial deposits. Deformation is attributed to glacially induced crustal stresses and seismic reactivation of pre-existing faults, previously weakened by epeirogenesis, triggering sediment liquefaction and deformation typical of earthquake generated seismites. Deformation, confined to an area of not more than 4 km wide adjacent to the major fault zone, implies earthquake magnitudes of at least 6 (Mo). The high authigenic chlorite content of deformed Tubeiliyat sandstones compared to undeformed ones is attributed to a post-seismic hydrothermal system driven by compactional dewatering and hydrofracturing of the bedrock which acted as a groundwater recharge area, supplied by subglacial meltwater from beneath the ice sheet. Fluid movement along glacial seismotectonically reactivated faults infiltrated the adjacent Tubeiliyat sandstones under pressure and elevated geothermal gradient, where chlorite was precipitated from solution. D 2005 Elsevier B.V. All rights reserved. Keywords: Ordovician glaciation; Palaeovalleys; Sediment deformation; Jordan 1. Introduction * Corresponding author. E-mail address: [email protected] (B.R. Turner). 0037-0738/$ - see front matter D 2005 Elsevier B.V. All rights reserved. doi:10.1016/j.sedgeo.2005.08.004 The Lower Palaeozoic succession in southern Jordan (Fig. 1) includes some 750–800 m of well exposed Ordovician siliciclastic sediments deposited on the margins of the North African (Gondwana) shallow marine 74 B.R. Turner et al. / Sedimentary Geology 181 (2005) 73–91 Fig. 1. Location and geology of the study area in southern Jordan. The inset map (top right) shows the general geology of southern Jordan and the inset map (bottom left) the location of the study area in Jordan. shelf (Fig. 2), in terrestrial, subtidal marginal marine and shelf environments (Powell et al., 1994; Makhlouf, 1995; Amireh et al., 2001). During the Upper Ordovician Jordan was located in a high latitude east Gondwana setting, ~608 S of the equator (Scotese et al., 1999), and was subjected to the effects of the Late Ordovician (Hirnantian) glaciation (Fig. 3). Southern Jordan was situated less than 100 km from the margins of a terrestrial ice sheet in Northwest Saudi Arabia that was characterised by two major phases of ice advance and retreat (Vaslet, 1990). 1.1. Geological background Abed et al. (1993, Fig. 3) and Amireh et al. (2001) included all the Late Ordovician (Ashgillian) glacial sediments in southern Jordan within the Ammar Formation (Fig. 2). They divided it into two units, each underlain by a glacial erosion surface stratigraphically equivalent to those beneath the Late Ordovician glacial deposits of the Zarqa and Sarah Formations in Saudi Arabia (Vaslet, 1990) (Figs. 2 and 4). The lower unit consists of a sandy channel lag conglomerate up to 2 m thick, containing glacially faceted and striated clasts, overlain by 30 m of extensively disturbed, greenish-grey, massive, well sorted structureless sandy siltstones. The base of the disturbed sandy siltstones is only recorded from two localities near Barqa Mountain, some 10 km NNE of Jebel Ammar (Fig. 1), where it is said to be incised into the underlying Tubeiliyat Formation (Abed et al., 1993). The precise location of these two outcrops was not recorded, but field sketches from 1992 (Makhlouf, written communication, 2005) have a laterally confined, erosively based, 1 m thick channel lag, overlain by some 30 m of fine to medium-grained sandstone. The lower 15 m is a deformed, greenish-grey sandstone, and the upper 15 m a light brown sandstone containing ripple cross-lamination, flaser and wavy lamination, correlated with the structureless lower Ammar Formation at Jebel Ammar by Abed et al. (1993). The sandstone is erosively overlain by glaciofluvial palaeovalley sandstones, correlated with the upper Ammar Formation, which is unconformably overlain by Cretaceous Kurnub sandstone of the Batn al Ghul Group (Fig. 1). Current models for Late Ordovician (Ashgillian) glaciation in southern Jordan recognise up to two B.R. Turner et al. / Sedimentary Geology 181 (2005) 73–91 75 Fig. 2. Revised lithostratigraphy and chronostratigraphy for the Ordovician and Silurian in Jordan and Saudi Arabia, showing generalised depositional environments for outcrops in the southern desert study area. Subdivision of the Ammar Formation into lower and upper Ammar is based on Abed et al. (1993). major phases of glaciation (Abed et al., 1993) which are correlated with two major glacial advances recorded for Northwest Saudi Arabia (Vaslet, 1990). The first glacial advance in southern Jordan is thought to be represented by deformed and structureless glacial rock flour or loessite siltstones of the lower Ammar Formation, and the second by a palaeovalley system of the upper Ammar Formation incised into the deformed siltstones (Abed et al., 1993; Amireh et al., 2001). In this study we present new field-based data from southern Jordan, and a reinterpretation of the Late Ordovician glacial deposits, including the disturbed and structureless glacial loessite or rock flour siltstones, based on their architecture, field relationships and petrography. The relationship between glacially induced crustal stress and seismic reactivation of faults, documented for present day and past glacial regimes, is used to develop a model to explain deformation and neomorphic changes in composition of the deformed sediments associated with a major fault zone. The magnitude of the glaciotectonic earthquakes responsible for deformation can be assessed according to the relationship between earthquake magnitude and maximum epicentral distance within which liquefaction deformation can occur. 2. Glacial palaeovalleys Two types of glacially incised palaeovalley occur in the Late Ordovician of southern Jordan: a lower palaeovalley system filled predominantly with marine shoreface sandstones; and an upper palaeovalley system filled with glaciofluvial and shoreface sandstones. 2.1. Lower palaeovalley Fig. 3. Late Ordovician palaeogeographical reconstruction of eastern Gondwana showing the ice sheet (shaded) and the location of Jordan (redrawn from Sutcliffe et al., 2000). The lower palaeovalley is locally incised into the top of the Tubeiliyat Formation (Fig. 4A, Palaeovalley 1). The palaeovalley-fill is exposed in a series of low, faultbounded hills that can be traced discontinuously for 76 B.R. Turner et al. / Sedimentary Geology 181 (2005) 73–91 Fig. 4. Generalised sections of the glacial succession in the Jebel Ammar area, southern Jordan, and northwest Saudi Arabia, showing the stratigraphy and sediment fill of the glacially incised palaeovalley systems. Section A is located 0.5 km southwest of Jebel Umeir and section B is from Jebel Ammar (see Fig. 1). Section C from northwest Saudi Arabia is based on Vaslet (1990). more than 5 km from the NNW to the SSE in a direct line with Jebel Ammar and Jebel Amira (Fig. 1). The palaeovalley is 150–200 m wide, 25–50 m deep and the margins dip at 178–308. The palaeovalley-fill comprises up to 50 m of massive, fine to medium-grained sandstone (Figs. 5 and 6A) except along the base where coarse to very coarse, feldspathic, granular and pebbly sandstone occurs (Fig. 5A,B). The base of individual palaeovalley-fills is often complex, and includes up to 4 erosion surfaces (Fig. 5), associated with clast to matrix-supported conglomerates containing sandstone and siltstone intraclasts, rare granite clasts, angular to subrounded, in situ granules, pebbles and occasional small cobbles of vein quartz and quartzite, many with glacially faceted and striated surfaces. The sandstone-fill contains small-scale, low angle, intersecting trough crossbeds (5–10 cm thick and 20 cm long), ripple crosslamination, straight-crested symmetrical ripple marks, medium to large-scale hummocky cross-stratification (Fig. 5C), local erosion surfaces, water escape structures, burrows and brachiopod moulds. Some sandstones just above the incised palaeovalley base, contain brachiopods and numerous trace fossils including Harlania, Cruziana and brachiopod resting traces (Fig. 6B,C,D). A prominent glaciated surface 25 m above the base of one palaeovalley-fill (Fig. 5D) can be traced laterally for more than 200 m, as far as the outcrop will allow. The smoothed and polished surface is locally striated and grooved (Fig. 5E,F), and embedded with siltstone and sandstone intraclasts, small glacially faceted quartz pebbles, and a few horizontal burrows. The striations are 2–3 mm deep, up to 35 cm in lateral extent, and consist of two intersecting sets: one aligned E–W and the other NW–SE (Fig. 5E). The grooves are up to 30 cm long and 1 cm deep, and aligned NW–SE. Local deformation, in the form of convolute bedding, is present in the sandstone immediately below this surface, which is overlain by ~5 m B.R. Turner et al. / Sedimentary Geology 181 (2005) 73–91 Fig. 5. Measured section and photographs of the lower, glacial palaeovalley-fill, 2 km southeast of Jebel Amira (Fig. 1), showing the erosively emplaced palaeovalley base, internal sedimentary structures and glaciated surface 5 m below the glacially incised upper palaeovalley glaciofluvial sandstones. The position of the features in the photographs A–G are shown on the section. 77 78 B.R. Turner et al. / Sedimentary Geology 181 (2005) 73–91 Fig. 6. A. Massive cliff-forming sandstone filling lower palaeovalley incised into the top of the Tubeiliyat Formation. B. Brachiopod impressions covering surface of sandstone from the side of the palaeovalley. C. Brachiopods and trace fossils, including Harlania, on underside of sandstone block from just above the base of the palaeovalley. D. Cruziana traces on underside of sandstone block from side of the palaeovalley. of fine to medium-grained hummocky cross-stratified sandstone. low angle, wedge-shaped trough cross-bed sets deposited by currents flowing to the east and southeast (Fig. 5G). 2.2. Upper palaeovalley 3. Disturbed sandy siltstones The upper palaeovalley system is incised into the lower one or, where this is missing, it cuts down directly into the Tubeiliyat Formation (Fig. 4A,B, Palaeovalley 2). The upper palaeovalley system has been previously described by Abed et al. (1993) who considered it to be part of the upper Ammar Formation (Fig. 4). The palaeovalley-fill comprises erosively based, horizontally to subhorizontally bedded coarse to medium-grained sandstones containing planar and trough cross-stratification and reworked glacially faceted and striated clasts, typically concentrated in the lower 1–3 m (Fig. 4A,B, Palaeovalley 2). These sandstones fine upwards into thin, marine shoreface sandstones containing trace fossils and brachiopods (Abed et al., 1993; Amireh et al., 2001). Where the upper palaeovalley is incised into the lower palaeovalley shoreface sandstones, above the internally glaciated surface, it comprises 1–2 m of coarse to very coarse, granular and pebbly sandstone containing faceted and striated clasts that grade sharply upwards into medium to coarse sandstone (Fig. 5) containing local granular and pebbly streaks and lenses. Internally the sandstone is structured by large-scale, Disturbed sandy siltstones beneath the upper palaeovalley in the Jebel Ammar area were placed in the lower Ammar Formation by Abed et al. (1993) who interpreted them as a glacial rock flour. Later, Amireh et al. (2001) interpreted them as glacial loessite derived by erosion of the underlying Tubeiliyat Formation sandstones. 3.1. Description Up to 90 m of incompletely exposed disturbed sandy siltstones occur beneath erosively based, upper palaeovalley-fill sandstones (Fig. 7) adjacent to the Hutayya graben, a major structural feature in the area (Fig. 1). The graben trends NW–SE and is bounded by normal faults which downthrow the base of the Ammar Formation 40 m to the west, with no significant strike slip component. The beds are tilted 228–288 to the northeast adjacent to the western boundary fault (Fig. 8A) and 148 to the west along the eastern boundary fault. Although the dip of the beds persists laterally for at least 2 km parallel with the fault plane, it decreases and dies out completely within a few hundred metres away from B.R. Turner et al. / Sedimentary Geology 181 (2005) 73–91 79 Fig. 7. Measured section of the disturbed and deformed sandstones at Jebel Ammar. The photograph illustrates some of the more characteristic features of the section (see text for details). Jebel Ammar lies along the Hutayya fault zone (Fig. 1) and stands over 100 m above the generally flatlying Pleistocene erosion surface. The lower slopes are composed of disturbed pale grey-green sandstone, erosionally overlain at the top by more resistant, ferruginous-cemented, glaciofluvial upper palaeovalley sandstones containing glacially striated and faceted clasts, that grade upwards into shoreface sandstones at the top. the fault plane, whence they pass into undeformed shoreface and shelf sediments of the Tubeiliyat Formation (Fig. 9). The disturbed siltstones are a distinctive green-grey colour, characterised by soft sediment deformation of varying styles and levels of intensity which occur both vertically and laterally throughout the succession. Deformation includes: (1) recumbent folding; (2) convolute laminations (Fig. 8B); (3) isolated sand balls floating in the host sediment and pseudo-nodules (Fig. 8C); (4) rotated, deformed and rounded ripples with thin streaky elongate tails resembling tadpoles (Fig. 8D); and (5) sandstone and siltstone intraclasts, some of which dfloatT in the host sandstone (Fig. 8E). In addition rare horizontally segmented burrows, brachiopod moulds and straight- to sinuous-crested ripple marks (Fig. 8F) occur. Although the internal lamination is commonly blurred and partially to completely destroyed, close examination reveals the presence of diffuse, mm to cm-scale ripple cross-lamination at intervals throughout the succession. Brown-weathered, rounded, iron-carbonate concretions, a few centimetres to 2–3 m in diameter occur throughout the succession. Some of the larger ones, contain intersecting, very lowangle laminae sets of hummocky cross-stratification, identical to the hummocky cross-stratified concretions described by Powell (1989) and Makhlouf (1995) from the Tubeiliyat Formation. 3.2. Texture and petrography In order to test the glacial loess and rock flour models for the deformed siltstones, and their derivation from the underlying Tubeiliyat Formation (Abed et al., 80 B.R. Turner et al. / Sedimentary Geology 181 (2005) 73–91 Fig. 8. A. Tectonic tilting of beds adjacent to the western boundary fault of the Hutayya graben, Jebel Ammar. B. Convolute laminations, Jebel Amira. C. Isolated sandstone ball with faint internal laminae interpreted as a rotated and deformed ripple. D. Rotated and deformed ripple with streaky tail, Jebel Amira. E. Small, irregularly shaped, delicate inclusions of fine sandstone and siltstone (above hammer) in a slurried sandstone that has undergone total liquefaction, Jebel Ammar. F. Asymmetric current ripples on bedding surface, 1 km southeast of Jebel Amira (see Fig. 1). 1993: Amireh et al., 2001), 5 samples of disturbed sandy siltstone, 2 samples of lower palaeovalley-fill sandstone, and 2 samples of Tubeiliyat Formation sandstone were analysed for their textural properties and mineral composition. The mean grain-size of the disturbed sandy siltstone is 3.11/ with N 80% of particles in the fine to very fine sand range (2–4/) and b 10% silt and medium sand (Fig. 10). The sediment is moderately sorted and texturally submature (Folk, 1968), and the distribution is skewed towards positive phi values (+ 0.18). The disturbed sandstones contain 47% to 56.3% quartz (Table 1), most of which occur as strained undulatory grains. The feldspar content, ranges from 5.6% to 10.3%, and comprises fresh or extensively altered orthoclase with minor amounts of microcline and plagioclase. Despite their alteration kaolinisation of feldspars is rare (cf. Abed et al., 1993, Table 1). Igneous and metamorphic polycrystalline quartz rock fragments make up b1%. Muscovite and lesser amounts of biotite are prominent constituents of the sandstones, but pristine biotite is rare, as most grains are partially or completely altered to chlorite. Chlorite also occurs as authigenic grain-rimming chlorite (15–20 Am wide rims), lining pore spaces, as a neomorphic component of the matrix, and rarely as a matt of small plates imparting a local felt-like texture to the rock. The matrix (22.3%–28.6%) comprises quartz silt, muscovite, sericite and chlorite shreds and aggregates, but volumetrically chlorite is one of the most important components, and the main reason for the distinctive greenish colour of the sandstone which increases in intensity towards the Hutayya fault zone. XRD analyses of disturbed sandy siltstone by Abed et al. (1993, Fig. 7) confirms that the matrix is dominated by chlorite, illite and smectite, but with kaolinite, B.R. Turner et al. / Sedimentary Geology 181 (2005) 73–91 81 Fig. 9. Map of the Jebel Ammar area showing the distribution of the disturbed green-grey sandstone and its passage into transitional and undisturbed Tubeiliyat sandstone. The map resembles some seismic intensity maps for earthquake activity related to active fault zones (Mohindra and Bagati, 1996, Fig. 2B), except that faulting in the Jebel Ammar area has disrupted the disturbed transitional Tubeiliyat sandstone facies zone. silt and clay-size grains of quartz, muscovite, and other non-clay minerals also present. Other minor detrital constituents include pyroxene, tourmaline, zircon, rutile, garnet and iron oxides. The sandstones are arkosic wackes (Dott, 1964; Williams et al., 1982), and their detrital mineral composition and heavy mineral suite, confirms their primary derivation from predominantly granitic basement provenance rocks to the south and west (Fig. 1, inset map), which also includes minor diorite and gabbro, and numerous dolerite dykes (Bender, 1968). The disturbed sandstones have a similar composition to the lower palaeovalley-fill sandstones except for their enrichment in chlorite and chloritised biotite, and correspondingly lower amounts of biotite and muscovite (Table 1). Both sandstones differ from typical Tubeiliyat sandstones in their lower quartz and kaolinite, and higher biotite, chlorite and chloritised biotite. 3.3. Interpretation Fig. 10. Grain-size analyses of 5 samples of disturbed sandstone, 2 samples of lower palaeovalley sandstone cut into the top of the Tubeiliyat Formation and 2 samples of Tubeiliyat sandstone. Abed et al. (1993) interpreted the disturbed denigmaticT sandy siltstones as a rock flour, derived 82 B.R. Turner et al. / Sedimentary Geology 181 (2005) 73–91 Table 1 Petrographic data, disturbed, lower palaeovalley-fill sandstones and Tubeiliyat Formation sandstones Constituents Disturbed grey-green sandstone (%) Monocrystalline quartz Poly qrtz rock fragments K-feldspar and microcline Plagioclase feldspar Muscovite Biotite Chloritised biotite Chlorite Matrix Calcite (patchy cement) Kaolinite Heavy minerals 51.0 0.3 6.0 1.6 10.0 1.0 3.0 2.6 22.3 0.3 0.6 1.3 47.0 1.3 9.0 1.3 6.0 0.0 3.6 1.9 28.6 0.0 0.0 1.0 50.0 0.6 8.3 0.6 3.3 1.6 8.3 2.3 24.0 0.0 0.0 0.6 50.6 0.6 6.6 0.3 2.6 1.0 7.3 3.0 26.6 0.0 0.0 1.0 from erosion of the underlying mineralogically identical Tubeiliyat Formation, dumped rapidly on a glacially incised variable palaeorelief surface. The sandstones are moderately well sorted, but the quartz grains show no evidence of grain breakage or grinding consistent with a glacial rock flour origin. Later Amireh et al. (2001) interpreted these sediments as glacial loessite derived from wind erosion of the underlying Tubeiliyat Formation (Fig. 2). Loess is seldom been recognised in the pre-Cenozoic rock record (Fischer and Sarnthein, 1988; Johnson, 1989; Soreghan, 1992; Carroll et al., 1998; Chan, 1999; Kessler et al., 2001), probably because it is difficult to distinguish it from other similar fine-grained sandstone and siltstone. Comparison of the main diagnostic characteristics of loess, documented in the literature (Smalley, 1966; Smalley and Smalley, 1983; Pye, 1984, 1995; Nemecz et al., 2000; Zoller and Semmel, 2001; Smith et al., 2002), with those of the disturbed sandstones, show significant differences in their textural attributes, mineral composition, colour, abundance of authigenic carbonate and particularly their bedding characteristics, and absence of interbedded palaeosol horizons (Table 2). Only 7 of the 28 features listed in Table 2 were common to both and, on this basis, plus the lithological and biogenic characteristics of the disturbed sandstones, it is considered unlikely that they originated as a glacial rock flour or loessite. At Jebel Amira 90 m of deformed sandstones are exposed, without any channel base or channel margins, and a complete absence of clasts of any type. In addition the disturbed sandstones: (1) were tectonically deformed; (2) they contain sedimentary structures identical to those in the Tubeiliyat Formation; (3) they can be traced laterally into undeformed Tubeiliyat Formation; (4) they are located along fault zones; and (5) 56.3 0.6 6.3 0.3 3.6 0.3 4.6 2.3 24.6 0.0 0.6 1.3 Lower palaeovalley-fill sandstones incised into the Tubeiliyat Formation (%) Tubeiliyat Formation sandstones (%) 48.0 0.3 6.3 0.3 10.3 3.3 1.3 0.6 24.3 0.0 2.0 3.0 71.0 0.6 10.3 0.6 2.3 0.3 0.0 0.0 2.3 3.6 10.2 0.9 52.6 1.0 5.6 1.3 10.6 4.3 2.0 0.3 19.0 0.6 1.3 1.0 69.0 0.6 9.6 1.5 3.3 0.0 0.0 0.0 2.7 2.7 9.6 0.9 according to Abed et al. (1993) they have an identical mineral composition to the Tubeiliyat. However, Abed et al. (1993) analysed greenish-grey siltstones and fine sandstones, not the more typical Tubeiliyat fine to medium-grained, pale fawn-brown sandstones (Makhlouf, 1995) used in this study, hence the differences in mineral composition in Table 1. We interpret the sandstones at Jebel Ammar and Amira to be a locally disturbed facies equivalent of the upper part of the marine shelf and shoreface sandstones of the 105 m thick Tubeiliyat Formation, not part of the glacial Ammar Formation. 3.3.1. Deformation No mechanism has so far been suggested for the origin of the post-depositional deformation of the sandstones and, why these are confined to the Jebel Ammar area on either side of the Hutayya graben. Soft sediment deformation must have occurred before the sediments were lithified, whereas the same sediments must have been sufficiently lithified in order for ice to incise deep, steep-sided palaeovalleys into the Tubeiliyat Formation. The Upper Tubeiliyat (upper anceps B2 zone) was deposited contemporaneous with, and in close proximity to, the advancing ice sheet in southern Jordan and Northwest Saudi Arabia (Armstrong et al., 2005). Thus, there is no significant hiatus between the Tubeiliyat and overlying glacial deposits in southern Jordan. Indeed, Armstrong et al. (2005) consider that much of the deposition of the Tubeiliyat was glacially forced and marks the onset of glacial isostatic subsidence. The mid-Ordovician in North Africa and Arabia was characterised by tectonic instability with the main phase of tectonism occurring between the Llandeilo–Caradoc. This regional tectonism did not create new fault patterns but was characterised by epeirogenic movements B.R. Turner et al. / Sedimentary Geology 181 (2005) 73–91 83 Table 2 Comparison of the properties of disturbed Tubeiliyat sandstone with those of typical loess Texture Mineral composition Colour Bedding Post-depositional changes Loess Disturbed Tubeiliyat sandstone facies Silt content >50% Quartz grains predominate Mean grain size range: 5.75 to 4.60φ Well sorted Positively skewed in the range: +0.30 to +0.70 Texturally mature Quartz grains rounded to subrounded Quartz (40%–80%) Feldspar (5%–30%) Mica (5%–10%) Primary carbonate (0–30%) Clays (5%–20%) Heavy minerals (1%–5%) Authigenic carbonate rare Compositionally submature to immature Quartzose to slightly feldspathic siltstone Silt content <10% Quartz grains predominate Mean grain size 3.11φ Moderately sorted Positively skewed: +0.18 Plae yellow but can be buff, grey, red or brown Homogeneous; non-stratified Structureless Typically interbedded with thin palaeosols No quartz pebbles or pebble stringers Grey-green Calcium carbonate nodules and concretions Texturally submature Quartz grains angular to subangular Quartz (46.3%–52.6%) Feldspar (8.6%–11.6%) Mica (1.0%–0.3%) No primary carbonate Clays <1% Authigenic carbonate (41%–34%) Rock fragments (1%) Chlorite Heavy minerals (1–2%) Compositionally immature Subarkosic fine sandstone Locally developed horizontal bedding; disrupted bedding; convolute laminations; ripple cross-lamination; hummocky crossstratification; vertically stacked coarseningupward parasequences; no palaeosols Sparse, small, angular quartz pebbles Calcium carbonate nodules and concretions Authigenic pore-filling carbonate The shaded areas highlight the differences between the disturbed Tubeiliyat sandstone facies and typical loess. along reactivated existing Pan-African fault systems (Echikh and Sola, 2000). In some areas, such as western Libya and southern Jordan, glacially incised palaeovalleys are preferentially located along these reactivated Pan-African basement faults (Glover et al., 1999). During the early Palaeozoic Jordan was subjected to periods of epeirogenic movement which ended in the Late Ordovician sometime prior to glaciation (Sabbah and Ramini, 1996). This led to the development of two major lineament trends: one NW–SE and the other ENE–WSW, similar to the trends of the two subsidiary glacial advances. Since there is no evidence of tectonism contemporaneous with Late Ordovician glaciation in southern Jordan crustal stress and deformation were probably a result of glaciation. Glaciation induces crustal stress and seismicity, particularly in the upper 5–10 km of the crust, which is sensitive to very small changes (b0.1 Mpa) in stress (Thorson, 2000). These stresses, and moderate levels of seismicity, are mainly concentrated around the perimeters of present day continental scale ice sheets, such as Greenland and Antarctica; the interior is largely aseismic because loading by large ice sheets stabilises faults and suppresses seismic activity beneath the load in the underlying brittle crust. (Johnson, 1987, 1989; Wu and Hasegawa, 1996). Although crustal stresses occur during glacial advance and postglacial retreat, most glacial seismotectonic models favour the more significant crustal stress generated during postglacial retreat as the most likely cause of seismic activity (Johnson, 1987; Adams and Basham, 1989; Muir-Wood, 1989; Arvidsson, 1996; Stewart et al., 2000). Large palaeofaults and increased levels of seismicity in Britain and Fennoscandia are thought to have been triggered by postglacial rebound (Gregersen and Basham, 1989); a view supported by the numerical modelling work on postglacial rebound stress by Wu and Hasegawa (1996) in eastern Canada. Postglacial crustal stress is known to produce a pulse of seismotectonic activity and palaeofault reactivation which commonly leads to associated earthquake-induced soft sediment deformation features (Davenport and Ringrose, 1989). In Scotland these features formed during or immediately after deglaciation 84 B.R. Turner et al. / Sedimentary Geology 181 (2005) 73–91 (Firth and Stewart, 2000). This association has been well documented for the 1811–1812 earthquakes in the Upper Mississippi valley (Penick, 1976) and the 1886 Charleston earthquake (Dutton, 1889), amongst others (Sieh, 1981). In southern Jordan the Hutayya fault zone trends NW–SE, similar to the trend of basement and Pan-African faults which formed 630– 580 Ma (Ibrahim and McCourt, 1995). Modern studies demonstrate that faults are able to propagate through weak, poorly lithified sediments (Moran and Christian, 1990), not involving fracture of the grains, during tectonism (Moore and Byrne, 1987; Maltman, 1994). Thus, as the ice began to melt and retreat southwards, following the first glacial incision, crustal stresses caused seismic shocks and reactivation of the Hutayya fault zone, triggering soft sediment deformation adjacent to the faults. These palaeofaults, weakened by earlier tectonism, would be particularly susceptible to reactivation by later postglacial seismicity (Hicks et al., 2000). Ground shaking concentrated along these faults provides a trigger for sediment deformation through reduced overburden pressure and increased hydrostatic fluid pore pressure (Johnson, 1987). Consequently, the poorly consolidated, fine sands, adjacent to the reactivated Hutayya fault zone were liquefied and extensive- ly deformed, leading to a partial to complete loss of lamination. This may have involved some internal mixing, local sediment flowage and movement (Lowe, 1975) and the development of more locally complex, deformed and chaotically disturbed zones in response to local differences in viscosity and density due to grainsize (sand-silt). Small siltstone clasts floating in ungraded sandstone are consistent with a non-Newtonian flow rheology (Gani, 2004). Kuribayashi and Tatsuoka (1975) proposed a relationship between the Richter earthquake magnitude and the maximum epicentral distance in which soft sediment deformation, produced by liquefaction, occurs. Earthquake magnitudes of b 5 cause little or no liquefaction whereas earthquake magnitudes of 6 cause liquefaction within a radius of 4 km, extending to up to 20 km from the epicentre at magnitudes of 7 (Morgenstern, 1967; Kuribayashi and Tatsuoka, 1975, Fig. 5; Scott and Price, 1988; Mohindra and Bagati, 1996). This relationship implies that the Jebel Ammar area lay within 4 km of the epicentre of an earthquake of magnitude 6 or more, concentrated along the reactivated Hutayya fault zone. Seismic shocks travel vertically and laterally, and vertical transit may be amplified if concentrated along a major fault plane. This relationship between faulting and seismic Fig. 11. Simplified conceptual model showing the relationship between the ice sheet in Northwest Saudi Arabia and the hydrothermal system responsible for chloritisation of the deformed sandstones along the Hutayya graben in the Jebel Ammar area. Glacial meltwater infiltrated subglacial hydrofractures in the bedrock which acted as a groundwater recharge area for the initiation of a convective hydrothermal system. The hydrothermal fluids leached Mg and Fe from the rocks through which they passed as they moved towards the reactivated Hutayya fault zone in southern Jordan. Infiltration of these hydrothermal fluids, under pressure and elevated geothermal gradient, into the sandstones adjacent to the fault led to the alteration of existing minerals and the precipitation of chlorite. B.R. Turner et al. / Sedimentary Geology 181 (2005) 73–91 activity was noted by Youd (1977) and Youd and Prentice (1978), who measured the distance of liquefaction from the fault rather than the epicentre of the earthquake. Cohesiveless silts and fine to medium sands are particularly prone to seismogenic liquefaction (Lowe, 1975) when the intensity of ground shaking exceeds a critical threshold level (Seed and Idris, 1971). Above this critical threshold level variations in intensity of ground shaking are associated with different styles of soft sediment deformation (Mohindra and Bagati, 1996). However, the entire sediment pile at Jebel Ammar–Amira (at least 90 m thick locally) was affected by a similar style of deformation throughout, suggesting a single deformation event or possibly several shocks of high magnitude and duration. These can lead to extensive liquefaction and deformation of primary sedimentary structures with little preserved evidence of non-deformed zones (Scott and Price, 1988). 85 3.3.2. Sandstone composition Differences in composition between the deformed and undeformed Tubeiliyat sandstones (Table 1) may provide clues to the chemistry of circulating pore fluids and the amount of sediment cover removed by glacial erosion. The differences in composition, especially the increased amounts of authigenic chlorite in the deformed sandstone, could be explained by: (1) mixing and homogenisation of Tubeiliyat shales, siltstones and sandstones during liquefaction; (2) diagenetic alteration of kaolinite; (3) breakdown of biotite; or (4) the authigenic addition of chlorite during or following deformation. The homogenisation model seems least likely given that, whereas the Tubeiliyat shales and siltstones are chloritic (Table 1), most sandstones are chlorite free (Makhlouf, 1995) and also the most susceptible to liquefaction (Lowe, 1975). Chlorite precipitation, and the alteration of kaolinite to chlorite, implies basic (alkaline) pore solutions enriched in Fe2+ and Mg2+(Foscolos, 1985; Jahrend and Angaard, 1989; Small et al., 1992; Fig. 12. Schematic three-dimensional stratigraphic block diagram showing the relationship of Jebel Ammar–Amira and other associated hills to the Hutayya fault zone. Compactional dewatering of the sediment pile and glacial meltwater initiated chemically reactive, reducing, hydrothermal fluids, enriched in Fe and Mg, which preferentially moved upwards along the reactivated fault zone causing chloritisation of the adjacent sandstones. 86 B.R. Turner et al. / Sedimentary Geology 181 (2005) 73–91 Bjørlykke, 1999). Some of the Fe2+ and Mg2+ may have been derived from the breakdown of biotite and its alteration to chlorite, but a more likely source of these basic waters, given the extensive chlorite neomorphism in the matrix, is seawater which is typically buffered between pH 8.0 and 8.4 (Brownlow, 1979; Cookenboo and Bustin, 1999). However, any reduction in alkalinity leads to chlorite dissolution and favours a change from chlorite to illite to kaolinite. Thus, for chlorite to precipitate basic Fe2+ and Mg2+ rich pore solutions are required at low temperatures of at least 15 but less than 100 8C (Cookenboo and Bustin, 1999). Because Fe2+ is less abundant in seawater than Mg2+ an additional source of Fe2+ is required. 3.3.3. Fault-controlled hydrothermal fluids Seismically reactivated tectonic faults can act as pathways for post-seismic fluid flow under high pressure (Cox and Etheridge, 1989) as well as for heat and mass transfer (Deming, 1993). Where these fluids infiltrate the adjacent sandstones (Knipe, 1992), new minerals such as mica, chlorite and smectite may form (Cookenboo and Bustin, 1999; Warr and Cox, 2001). The source of these fluids may have been compactional dewatering and dehydration of hydrous minerals in the sediment pile. A possible additional fluid source is subglacial meltwater beneath the nearby wet-based temperate ice sheet which was forced through openings in the bedrock (hydrofracturing) under high pressure from the overlying ice (Davison and Hambrey, 1996). Hydrofracturing is an important process beneath glaciers, and has been documented from beneath the Fennoscandanavian ice sheet (Carlsson, 1979) where hydrofractures may penetrate bedrock to depths of 100 metres (Muir-Wood, 1989; M. Hambrey, written communication, 2003). Ice loading of deep seated aquifers accelerates groundwater flow and, with increasing depth (~250 m) the groundwater becomes more saline (England et al., in press). Thus, the base of the melting glacier may have acted as a groundwater recharge area (Boulton and Dobbie, 1993) for the initiation and maintenance of a meteoric waterdriven, convective, low temperature hydrothermal system (Fig. 11). These reducing hydrothermal fluids may have leached out Fe and Mg from localised diorites, gabbros and dolerite dykes along the sediment-basement contact and from the sandstone-dominated sediment pile through which the fluids moved along the Hutayya fault zone (Fig. 12). Although sandstones contain few trace metals, compaction of interbedded muds, such as the Hiswa mudstones (Fig. 2), flushed seawater enriched in Fe and Mg through the sandstones, with the Hutayya fault zone acting as the conduit for this fluid movement. These fluids may also have been involved in the sediment deformation process, especially if they were injected into the sandstones adjacent to the fault under pressure and elevated geothermal gradient, where they precipitated chlorite from solution. Given a normal continental geothermal gradient of 30 8C km 1 chloritisation would occur between 500 and 3330 m depth, hence the upper part of the Tubeiliyat Formation would have to be buried to at least 500 m to be chloritised. This is unrealistic given the time available between deposition of the Tubeiliyat and Fig. 13. Alternative conceptual models to explain the observed zone of chloritisation adjacent to the Hutayya graben. Both models assume a regional continental geothermal gradient of 30 8C km 1 and chlorite precipitates between 15 and 100 8C. Crosses denote Pan-African crystalline basement. (A) A simple 2-D isostatic model to demonstrate the effects of ice loading. The model assumes the density of ice and sedimentary rock is 1 and 2.4 g cm 3 respectively. The model is loaded by 1160 m of ice to generate 500 m of equivalent rock subsidence. If the geothermal gradient is maintained this has the effect of raising the top of the zone of chloritisation (15 8C isotherm) to coincide with the base of the ice within the graben. Outside the graben the predicted temperature at the base of the ice is 10.5 8C, the 0 8C isotherm would lie ~350 m within the ice sheet. In all cases the predicted temperatures are unrealistic. (B) Preferred bhydrothermal modelQ in which ground water, illustrated as ice meltwater, reaches the zone of chloritisation at 500 m depth. The faults bounding the reactivated Hutayya graben act as conduits to Fe and Mg richwater, and in the vicinity of the faults the geothermal gradient is raised. Zones of chloritised upper Tubeiliyat Formation occur along the faults. B.R. Turner et al. / Sedimentary Geology 181 (2005) 73–91 glacial incision. Ice loading is also rejected as the source of burial. Simple isostatic modelling, assuming a normal continental geothermal gradient, predicts unrealistic temperatures at the base of the ice sheet (Fig. 13). Our preferred bhydrothermal modelQ is driven by compaction. Ground water, likely ice meltwater, reaches the zone of chloritisation at 500 m depth. The faults bounding the Hutayya graben act as conduits to Fe and Mg rich-water and locally the geothermal gradient is raised. Zones of chloritised upper Tubeiliyat Formation occur along the faults. The temperature at the cover-basement contact is 24 8C and in this model the zone of chloritisation could theoretically extend ~2.5 km into the basement. 4. Depositional model Southern Jordan in the Late Ordovician was located b 100 km from the margin of a terrestrial ice cap in NW Saudi Arabia (Fig. 3), which formed part of a more extensive ice sheet of similar size to the present day Antarctic ice sheet (Deynoux, 1985; Vaslet, 1990; Eyles and Young, 1994). The ice cap was characterised by two major phases of ice advance and retreat (cf. Vaslet, 87 1990). Abed et al. (1993) were of the opinion that both these glacial phases, covered parts of southern Jordan with ice, whereas Powell et al. (1994) considered that only the first glacial phase, correlated with the incision beneath the Zarqa Formation in Saudi Arabia, affected southern Jordan. We propose a four stage glacial model in which the top of the Tubeiliyat shoreface and nearshore shelf sediments was incised and truncated in response to the first major glacial advance from Saudi Arabia (Fig. 14). The ice preferentially excavated NW–SE trending major fault-controlled depressions cutting steep-sided U-shaped valleys into the Tubeiliyat Formation. This implies that the sediments must have been sufficiently lithified to facilitate glacial incision. In view of the relatively short time between sediment deposition and glacial incision the degree of lithification may have been limited. However, temperature simulations for the Late Ordovician (Crowley and Baum, 1995) indicate a low temperature range from 5–0 8C for the 608 S latitude of Jordan at this time. Moreover, the ground surface in front of large ice sheets is characterised by permafrost (Fowler and Noon, 1999) which may extend down to depths of a few metres to Fig. 14. Schematic model of ice sheet evolution during the first major ice advance and retreat in NW Saudi Arabia, showing depositional environments, and its effect on southern Jordan. The lithostratigraphic sections show the glacial successions in Saudi Arabia and Southern Jordan (see Fig. 4 and text for further details). 88 B.R. Turner et al. / Sedimentary Geology 181 (2005) 73–91 several hundred metres (Burgess and Smith, 2000). Ice loading also increases the geotechnical strength of the beds beneath the ice (Stewart et al., 2000) and this, together with the permafrost-hardened ground, provides a resistant substrate for glacial incision and the cutting of the steep-sided lower palaeovalley prior to deglaciation seismotectonics and deformation. Postglacial melting, together with a concomitant rise in relative sea level and southerly transgression across the Gondwana shelf, deposited thin, transgressively reworked glaciofluvial, locally conglomeratic sandstones in the bottom of the glacially incised valley. As melting and marine transgression continued shoreface sediments were deposited in the valley (Fig. 14). The intersecting glacial striations suggest that a second and possibly a third subsidiary glacial advance interrupted deposition and final filling of the lower palaeovalley. This implies a fall in relative sea level in response to renewed ice build-up to allow for the cutting of the glacial surface, followed by a brief rise in sea level as shoreface deposition continued. The source of this ice, which lay to the west and northwest (Fig. 5), may have been subsidiary lobes of the major ice sheet in northwest Saudi Arabia. Final filling of the lower palaeovalley by shoreface sandstones was followed by a short hiatus, which may correlate with the interglacial between the two major ice advances in Saudi Arabia (Vaslet, 1990). This was followed by a further 4th major ice advance, correlated with the 2nd major ice advance in northwest Saudi Arabia. Turner et al. (2002) interpreted the upper palaeovalley as low stand tunnel valleys of the upper Ammar Formation (Abed et al., 1993) (Fig. 4). The final ice advance and formation of the upper palaeovalley may have removed interglacial sediment, or the interglacial was a period of non-deposition. The palaeovalley was subsequently filled with outwash plain sediments as the ice melted, concomitant with a transgressive rise in sea level and the deposition of shoreface sands over the glaciofluvial palaeovalleyfill sands, thereby defining a post-glacial transgressive surface (Armstrong et al., 2005). 5. Conclusions Southern Jordan in the Late Ordovician was located b100 km from the margin of a terrestrial ice sheet in Northwest Saudi Arabia characterised by two major phases of ice advance and retreat (cf. Vaslet, 1990), which have been correlated with similar events in southern Jordan (Abed et al., 1993). In additional, two subsidiary ice advances are now recognised in southern Jordan. During the first major glacial advance ice incised into permafrost-hardened and glacially loaded, Tubeiliyat shoreface and nearshore shelf deposits, preferentially excavating NW–SE trending major faultcontrolled depressions, cutting a steep-sided U-shaped valley. This first glacial advance, correlates with the first glacial advance in Northwest Saudi Arabia, and was followed by deglaciation, a rise in base level and transgressive filling of the palaeovalley with a thin, reworked bottom lag of glaciofluvial sandstones, overlain by thick, transgressive, shoreface sandstones. Late transgressive filling of the palaeovalley was interrupted by a 2nd and possibly a 3rd subsidiary glacial advance producing a glacially polished and grooved surface with intersecting glacial striations, indicating ice flow from the west and northwest. A further 4th glacial advance, which correlates with the second major ice advance in Saudi Arabia, produced a regionally extensively low stand tunnel valley beneath the ice sheet (Turner et al., 2002). This was subsequently preserved as a palaeovalley incised into the lower palaeovalley-fill deposits or, where this is missing, into the top of the Tubeiliyat Formation. Following melting the palaeovalley filled with transgressive glaciofluvial sandstones and shoreface sandstones. The upper palaeovalley is incised into deformed sandstones adjacent to the Hutayya graben in the Jebel Ammar area. These sandstones were placed in the lower Ammar Formation by Abed et al. (1993) who interpreted them as a glacial rock flour devoid of sedimentary structures. The same sediments were later interpreted as a structureless glacial loessite derived from reworking of the underlying mineralogically identical Tubeiliyat Formation (Amireh et al., 2001). However, the lack of grain breakage and grinding, and significant differences in their textural and compositional attributes compared to typical loess argues against either of these interpretations. The deformed sandstones, which are non-channelised and at least 90 m thick, contain no glacial features. However, they contain sedimentary structures similar to those in the Tubeiliyat Formation, and they can be traced laterally away from the fault zone over a distance of 4 km into undeformed Tubeiliyat. Thus, we interpret the sandstones in the Jebel Ammar area to be a locally disturbed facies equivalent of the pre-glacial marine Tubeiliyat Formation, not part of the glacial Ammar Formation, which now comprises the lower and upper regionally extensive glacial palaeovalley-fill deposits. Southern Jordan may have been subjected to postglacial seismotectonism, concentrated along the Hutayya fault zone, which had been previously weakened by epeirogenic movement. Seismic reactivation of the fault zone B.R. Turner et al. / Sedimentary Geology 181 (2005) 73–91 triggered ground shaking, sediment liquefaction and deformation adjacent to the faults. The increased authigenic chlorite content of the fault-related deformed Tubeiliyat sandstones, compared to undeformed ones, can be explained by compaction-driven low temperature hydrothermal fluids, with a possible additional fluid source from subglacial hydrofracturing of the bedrock setting up a hydrothermal system beneath the ice sheet which acted as a groundwater recharge area for the hydrothermal system. Iron and Mg were leached from the sediment pile as the fluids moved preferentially up the reactivated Hutayya fault zone. This acted as a conduit for hydrothermal fluid movement and where these hydrothermal fluids infiltrated adjacent sandstones chlorite was precipitated from solution. Acknowledgements This research was supported by the UK Natural Environmental Research Council (NERC Grant NER/ B/2000/000068), the University of Durham and the Hashemite University. 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