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Advances in Differential Equations Volume 9, Numbers 3-4, March/April 2004, Pages 299–327 COUPLED SURFACE AND GRAIN BOUNDARY MOTION: NONCLASSICAL TRAVELING-WAVE SOLUTIONS Jacob Kanel and Amy Novick-Cohen Department of Mathematics, Technion-IIT, Haifa 32000, Israel Arkady Vilenkin The Racah Institute of Physics, The Hebrew University of Jerusalem Jerusalem 91904, Israel (Submitted by: Y. Giga) In Memory of W.W. Mullins Abstract. We study a geometric free-boundary problem for a bicrystal in which a grain boundary is attached at a groove root to the exterior surface of the bicrystal. Mathematically, this geometric problem couples motion by mean curvature of the grain boundary with surface diffusion of the exterior surface. If the groove root effects are localized, it is realistic to look for traveling-wave solutions. We show that travelingwave solutions can be determined via solutions of Problem PΨ in which Ψsss = sin Ψ, s ∈ (−∞, 0) ∪ (0, ∞), Ψ(±∞) = 0, and appropriate jump conditions are prescribed at s = 0. We prove existence of solutions to Problem PΨ for all m, 0 ≤ m < 2, where m denotes the ratio of the surface energies of the grain boundary and of the exterior surface. We show numerically that for ≈ 1.81 < m ≤ 2, the corresponding solutions to the original geometric problem are not singlevalued as functions of x, where x varies along the unperturbed exterior surface of the bicrystal. We refer to these solutions as “nonclassical traveling-wave solutions.” 1. Introduction In the present paper, we analyze traveling-wave solutions for the motion of a grain boundary which is attached at a grain groove to an exterior surface which evolves under the influence of surface diffusion in the context of a “quarter loop geometry”; see Figure 1. The quarter loop setting [5, 6] in Accepted for publication: October 2003. AMS Subject Classifications: 34A34, 34B10, 35K55, 74N15, 74N20. 299