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35.0.6 Page 1/8 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 05/03/2013 * Reviewed on 05/03/2013 1 Identification of the substance/mixture and of the company/undertaking · Product identifier · Trade name: EPOTEC RD 104 · CAS Number: 122-60-1 · EC number: 204-557-2 · Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. · Application of the substance / the preparation Reactive Diluents · Details of the supplier of the safety data sheet · Manufacturer/Supplier: Aditya Birla Chemicals (Thailand) Ltd. (Epoxy Division) No.2, I-5 Road, Maptaphut Industrial Estate, Maptaphut, Muang, Rayong 21150 THAILAND · Information department: [email protected] www.adityabirlachemicals.com www.epotec.info · Emergency telephone number: During normal opening times: +66-38-685233 Fax (Factory): +66-38-683982 * 2 Hazards identification · Classification of the substance or mixture GHS08 Health hazard Muta. 2 Carc. 1B H341 Suspected of causing genetic defects. H350 May cause cancer. GHS07 Acute Tox. 4 Skin Irrit. 2 Skin Sens. 1 STOT SE 3 H332 H315 H317 H335 Harmful if inhaled. Causes skin irritation. May cause an allergic skin reaction. May cause respiratory irritation. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC Toxic Carc. Cat. 2 May cause cancer. Harmful Harmful by inhalation. Possible risk of irreversible effects. Irritant Irritating to respiratory system and skin. Revision May cause sensitisation by skin contact. (Contd. on page 2) USA 35.0.6 Page 2/8 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 05/03/2013 Reviewed on 05/03/2013 Trade name: EPOTEC RD 104 (Contd. of page 1) Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Muta. Cat. 3 · Information concerning particular hazards for human and environment: Not applicable. · Label elements · Labelling according to EU guidelines: The product has been classified and marked in accordance with directives on hazardous materials. · Code letter and hazard designation of product: Carc. Cat. 2, Muta. Cat. 3 Toxic · Risk phrases: May cause cancer. Also harmful by inhalation. Irritating to respiratory system and skin. May cause sensitisation by skin contact. Possible risk of irreversible effects. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. · Safety phrases: Avoid exposure - obtain special instructions before use. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. · Classification system: · NFPA ratings (scale 0 - 4) Health = 2 2 0 Fire = 1 Reactivity = 0 · HMIS-ratings (scale 0 - 4) 1 Health = *2 Fire = 1 REACTIVITY 0 Reactivity = 0 · Other hazards · Results of PBT and vPvB assessment Not applicable. * HEALTH *2 FIRE 1 3 Composition/information on ingredients · Chemical characterization: Substances · CAS No. Description 122-60-1 Phenyl glycidyl ether · Identification number(s) · EC number: 204-557-2 · Additonal information: 100 % USA (Contd. on page 3) 35.0.6 Page 3/8 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 05/03/2013 Reviewed on 05/03/2013 Trade name: EPOTEC RD 104 (Contd. of page 2) 4 First aid measures · Description of first aid measures · General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. · After inhalation: Supply fresh air or oxygen; call for doctor. In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Immediately wash with water and soap and rinse thoroughly. · After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. · After swallowing: Induce vomiting, if person is conscious. Seek medical help. · Information for doctor: · Most important symptoms and effects, both acute and delayed No further relevant information available. · Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Firefighting measures · Extinguishing media · Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray. · For safety reasons unsuitable extinguishing agents: Water with full jet · Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. · Advice for firefighters · Protective equipment: Wear self-contained respiatory protective device. Wear fully protective suit. 6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. · Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. · Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose of the collected material according to regulations. · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. USA (Contd. on page 4) 35.0.6 Page 4/8 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 05/03/2013 Reviewed on 05/03/2013 Trade name: EPOTEC RD 104 (Contd. of page 3) 7 Handling and storage · Handling: · Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. · Information about protection against explosions and fires: Protect against electrostatic charges. Protect from heat. Keep respiratory protective device available. · Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Store in a cool location. Provide ventilation for receptacles. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Store receptacle in a well ventilated area. Keep receptacle tightly sealed. · Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection · Additional information about design of technical systems: No further data; see item 7. · Control parameters · Components with limit values that require monitoring at the workplace: 122-60-1 phenyl glycidyl ether PEL 60 mg/m³, 10 ppm REL Short-term value: C 6* mg/m³, C 1* ppm *15-min TLV 0.6 mg/m³, 0.1 ppm Skin; SEN · Additional information: The lists that were valid during the creation were used as basis. · Exposure controls · Personal protective equipment: · Breathing equipment: Use suitable respiratory protective device in case of insufficient ventilation. · Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. · Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. (Contd. on page 5) USA 35.0.6 Page 5/8 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 05/03/2013 Reviewed on 05/03/2013 Trade name: EPOTEC RD 104 (Contd. of page 4) · Eye protection: Face protection Tightly sealed goggles · Body protection: Protective work clothing Boots * 9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Form: Liquid Color: Colorless · Odor: Aromatic · Change in condition Melting point/Melting range: 3.5°C (38 °F) Boiling point/Boiling range: 245°C (473 °F) · Flash point: 115°C (239 °F) · Ignition temperature: 430°C (806 °F) · Danger of explosion: Not applicable. · Vapor pressure at 20°C (68 °F): 3.3 hPa (2 mm Hg) · Density at 25°C (77 °F): 1.1 g/cm³ (9.18 lbs/gal) · Solubility in / Miscibility with Water at 20°C (68 °F): · Other information 2.4 g/l No further relevant information available. 10 Stability and reactivity · Reactivity · Chemical stability · Thermal decomposition / conditions to be avoided: No decomposition if used and stored according to specifications. · Possibility of hazardous reactions Reacts with acids, alkalis and oxidizing agents. Reacts with amines. · Conditions to avoid No further relevant information available. · Incompatible materials: No further relevant information available. · Hazardous decomposition products: Carbon monoxide and carbon dioxide USA (Contd. on page 6) 35.0.6 Page 6/8 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 05/03/2013 Reviewed on 05/03/2013 Trade name: EPOTEC RD 104 (Contd. of page 5) * 11 Toxicological information · Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: 122-60-1 phenyl glycidyl ether Oral LD50 3850 mg/kg (rat) · Primary irritant effect: · on the skin: Irritant to skin and mucous membranes. · on the eye: Irritating effect. · Additional toxicological information: · Carcinogenic categories · IARC (International Agency for Research on Cancer) 122-60-1 phenyl glycidyl ether 2B · NTP (National Toxicology Program) Substance is not listed. 12 Ecological information · Toxicity · Aquatic toxicity: No further relevant information available. · Persistence and degradability Not easily biodegradable · Behavior in environmental systems: · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Results of PBT and vPvB assessment Not applicable. · Other adverse effects No further relevant information available. 13 Disposal considerations · Waste treatment methods · Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. * 14 Transport information · UN-Number · DOT, ADR, ADN, IMDG, IATA Void · UN proper shipping name · DOT, ADR, ADN, IMDG, IATA Void (Contd. on page 7) USA 35.0.6 Page 7/8 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 05/03/2013 Reviewed on 05/03/2013 Trade name: EPOTEC RD 104 (Contd. of page 6) · Transport hazard class(es) · DOT, ADR, ADN, IMDG, IATA · Class Void · Packing group · DOT, ADR, IMDG, IATA Void · Environmental hazards: · Marine pollutant: No · Special precautions for user Not applicable. · Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional information: * · DOT · Remarks: Not regulated for transport. · ADR · Remarks: Not regulated for transport. · IMDG · Remarks: Not regulated for transport. · IATA · Remarks: Not regulated for transport. 15 Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara · Section 313 (Specific toxic chemical listings): Substance is not listed. · TSCA (Toxic Substances Control Act): Substance is listed. · Product related hazard informations: The product has been classified and marked in accordance with directives on hazardous materials. · Hazard symbols: Carc. Cat. 2, Muta. Cat. 3 Toxic · Risk phrases: May cause cancer. Also harmful by inhalation. Irritating to respiratory system and skin. May cause sensitisation by skin contact. Possible risk of irreversible effects. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. (Contd. on page 8) USA 35.0.6 Page 8/8 Material Safety Data Sheet acc. to ISO/DIS 11014 Printing date 05/03/2013 Reviewed on 05/03/2013 Trade name: EPOTEC RD 104 (Contd. of page 7) · Safety phrases: Avoid exposure - obtain special instructions before use. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises Dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent USA